arXiv subjects

C. L. Carvalho

Publications and source records attributed to C. L. Carvalho.

4 recordsLinked to original sources

arXiv2019

Solution Blow Spinning Control of Morphology and Production Rate of Complex Superconducting YBa2Cu3O7-x Nanowires

The demand for nanostructured materials can increase exponentially due to the miniaturization of devices and their potential application in different areas, such as electronic and medicine. Therefore, high production rates are essential for making nanomaterials commercially available. When electrospinning (ES) and solution blow spinning (SBS) are employed for producing ceramic nanostructures, the solution injection rate can influence the morphology without, however, supply the real ceramic production rate. In this work, complex superconducting YBa2Cu3O7-x wires were prepared by using the SBS technique. We also show that the morphology can be controlled by varying the injection rate of the polymer solution and the production rate is 4.7 to 33 times higher than the rates of equivalent ceramics produced by ES. Additionally, we also suggest the term Ceramic Production Rate to refer to the production rate of ceramic structures.

physics.app-ph↗

arXiv2017

YBCO Ceramic Nanofibers obtained by the new technique of Solution Blow Spinning

This study proposes a novel solution blow spinning technique (SBS) for fabricating YBCO ceramic nanofibers. The precursor solutions were obtained from Y, Ba, and Cu metallic acetates (Ac) and poly(vinyl pyrrolidone) (PVP, Mw = 360,000). Ac:PVP concentrations of 1:1 and 5:1 were tested, resulting in ceramic nanofibers with average diameters of 359 and 375 nm, respectively. X-ray diffraction confirmed the formation of a pure phase of YBa2Cu3O7-x. This is the first study to use SBS for fabricating YBCO nanofibers, and this technique shows promise for obtaining high-quality ceramic materials.

cond-mat.mtrl-sci↗

arXiv2013

Thermal treatment of superconductor thin film of the BSCCO system using domestic microwave oven

In this work, we report the preparation of a superconductor thin film of the BSCCO system using a good quality powder with nominal composition Bi_{1.8}Pb_{0.4}Sr_2CaCu_2O_x which was thermally treated using a domestic microwave oven (2.45 GHz, 800 W). This film was grew on a single crystal of LaAlO_3(100) substrate and exhibited a crystalline structure with the c-axis perpendicular to the plane of the substrate. An onset superconducting transition temperature was measured at 80 K.

cond-mat.mtrl-sci↗

arXiv2013

Synthesis of Bi-based superconductor by microwave-assisted hydrothermal method

In this work we studied the synthesis of BSCCO-2212 superconducting phase associating a quite similar method developed by Pechini (PM) with the microwave-assisted hydrothermal method, MAH. To study the influence of MAH on the properties of BSCCO system, we synthesized two samples by such method. For one sample we used carbonates (CMAH) and for the other one we used nitrates (NMAH) as chemical reagents. We also produced a reference sample (REF) just using carbonates by PM to compare their morphological and superconducting properties. The structural properties of the samples were analyzed by scanning electron microscopy and X-ray diffraction. It can be noted that the Bi-2212 phase is predominant in all samples; MAH samples present larger grains than the REF one. However, we can observe that the magnetic behaviour of NMAH is closer to that presented by REF.

cond-mat.supr-con↗