arXiv subjects

C. L. Degen

Publications and source records attributed to C. L. Degen.

At least 37 records · Page 2Linked to original sources

arXiv2017

Quantum sensing with arbitrary frequency resolution

Quantum sensing takes advantage of well controlled quantum systems for performing measurements with high sensitivity and precision. We have implemented a concept for quantum sensing with arbitrary frequency resolution, independent of the qubit probe and limited only by the stability of an external synchronization clock. Our concept makes use of quantum lock-in detection to continuously probe a signal of interest. Using the electronic spin of a single nitrogen vacancy center in diamond, we demonstrate detection of oscillating magnetic fields with a frequency resolution of 70 uHz over a MHz bandwidth. The continuous sampling further guarantees an excellent sensitivity, reaching a signal-to-noise ratio in excess of 10,000:1 for a 170 nT test signal measured during a one-hour interval. Our technique has applications in magnetic resonance spectroscopy, quantum simulation, and sensitive signal detection.

quant-ph↗

arXiv2017

High resolution quantum sensing with shaped control pulses

We investigate the application of amplitude-shaped control pulses for enhancing the time and frequency resolution of multipulse quantum sensing sequences. Using the electronic spin of a single nitrogen vacancy center in diamond and up to 10,000 coherent microwave pulses with a cosine square envelope, we demonstrate 0.6 ps timing resolution for the interpulse delay. This represents a refinement by over 3 orders of magnitude compared to the 2 ns hardware sampling. We apply the method for the detection of external AC magnetic fields and nuclear magnetic resonance signals of carbon-13 spins with high spectral resolution. Our method is simple to implement and especially useful for quantum applications that require fast phase gates, many control pulses, and high fidelity.

quant-ph↗

arXiv2016

Optical hyperpolarization of nitrogen donor spins in bulk diamond

We report hyperpolarization of the electronic spins associated with substitutional nitrogen defects in bulk diamond crystal. Hyperpolarization is achieved by optical pumping of nitrogen vacancy centers followed by rapid cross relaxation at the energy level matching condition in a 51 mT bias field. The maximum observed donor spin polarization is 0.9 \% corresponding to an enhancement by 25 compared to the thermal Boltzmann polarization. A further accumulation of polarization is impeded by an anomalous optical saturation effect that we attribute to charge state conversion processes. Hyperpolarized nitrogen donors may form a useful resource for increasing the efficiency of diamond-based dynamic nuclear polarization devices.

cond-mat.mes-hall↗

arXiv2016

A quantum spectrum analyzer enhanced by a nuclear spin memory

We realize a two-qubit sensor designed for achieving high spectral resolution in quantum sensing experiments. Our sensor consists of an active "sensing qubit" and a long-lived "memory qubit", implemented by the electronic and the nitrogen-15 nuclear spins of a nitrogen-vacancy center in diamond, respectively. Using state storage times of up to 45 ms, we demonstrate spectroscopy of external ac signals with a line width of 19 Hz (~2.9 ppm) and of carbon-13 nuclear magnetic resonance (NMR) signals with a line width of 190 Hz (~ 74 ppm). This represents an up to 100-fold improvement in spectral resolution compared to measurements without nuclear memory.

quant-ph↗

arXiv2016

Nanoscale imaging of current density with a single-spin magnetometer

Charge transport in nanostructures and thin films is fundamental to many phenomena and processes in science and technology, ranging from quantum effects and electronic correlations in mesoscopic physics, to integrated charge- or spin-based electronic circuits, to photoactive layers in energy research. Direct visualization of the charge flow in such structures is challenging due to their nanometer size and the itinerant nature of currents. In this work, we demonstrate non-invasive magnetic imaging of current density in two-dimensional conductor networks including metallic nanowires and carbon nanotubes. Our sensor is the electronic spin of a diamond nitrogen-vacancy center attached to a scanning tip. Using a differential measurement technique, we detect DC currents down to a few uA above a baseline current density of 2e4 A/cm2. Reconstructed images have a spatial resolution of typically 50 nm, with a best-effort value of 22 nm. Current density imaging offers a new route for studying electronic transport and conductance variations in two-dimensional materials and devices, with many exciting applications in condensed matter physics.

cond-mat.mes-hall↗

arXiv2016

Ultrasensitive mechanical detection of magnetic moment using a commercial disk drive write head

Sensitive detection of weak magnetic moments is an essential capability in many areas of nanoscale science and technology, including nanomagnetism, quantum readout of spins, and nanoscale magnetic resonance imaging. Here, we show that the write head of a commercial hard drive may enable significant advances in nanoscale spin detection. By approaching a sharp diamond tip to within 5 nm from the pole and measuring the induced diamagnetic moment with a nanomechanical force transducer, we demonstrate a spin sensitivity of 0.032 Bohr magnetons per root Hz, equivalent to 21 proton magnetic moments. The high sensitivity is enabled in part by the pole's strong magnetic gradient of up to 28 million Tesla per meter and in part by the absence of non-contact friction due to the extremely flat writer surface. In addition, we demonstrate quantitative imaging of the pole field with about 10 nm spatial resolution. We foresee diverse applications for write heads in experimental condensed matter physics, especially in spintronics, ultrafast spin manipulation, and mesoscopic physics.

cond-mat.mes-hall↗

arXiv2016

Parametric symmetry breaking in a nonlinear resonator

Much of the physical world around us can be described in terms of harmonic oscillators in thermodynamic equilibrium. At the same time, the far from equilibrium behavior of oscillators is important in many aspects of modern physics. Here, we investigate a resonating system subject to a fundamental interplay between intrinsic nonlinearities and a combination of several driving forces. We have constructed a controllable and robust realization of such a system using a macroscopic doubly clamped string. We experimentally observe a hitherto unseen double hysteresis in both the amplitude and the phase of the resonator's response function and present a theoretical model that is in excellent agreement with the experiment. Our work provides a thorough understanding of the double-hysteretic response through a symmetry breaking of parametric phase states that elucidates the selection criteria governing transitions between stable solutions. Our study motivates applications ranging from ultrasensitive force detection to low-energy computing memory units.

cond-mat.mes-hall↗

arXiv2016

Local dynamics of topological magnetic defects in the itinerant helimagnet FeGe

Chiral magnetic interactions induce complex spin textures including helical and conical spin waves, as well as particle-like objects such as magnetic skyrmions and merons. These spin textures are the basis for innovative device paradigms and give rise to exotic topological phenomena, thus being of interest for both applied and fundamental sciences. Present key questions address the dynamics of the spin system and emergent topological defects. Here we analyze the micromagnetic dynamics in the helimagnetic phase of FeGe. By combining magnetic force microscopy, single-spin magnetometry, and Landau-Lifschitz-Gilbert simulations we show that the nanoscale dynamics are governed by the depinning and subsequent motion of magnetic edge dislocations. The motion of these topologically stable objects triggers perturbations that can propagate over mesoscopic length scales. The observation of stochastic instabilities in the micromagnetic structure provides new insight to the spatio-temporal dynamics of itinerant helimagnets and topological defects, and discloses novel challenges regarding their technological usage.

cond-mat.mtrl-sci↗

arXiv2015

One- and two-dimensional nuclear magnetic resonance spectroscopy with a diamond quantum sensor

We report on Fourier spectroscopy experiments performed with near-surface nitrogen-vacancy centers in a diamond chip. By detecting the free precession of nuclear spins rather than applying a multipulse quantum sensing protocol, we are able to unambiguously identify the NMR species devoid of harmonics. We further show that by engineering different Hamiltonians during free precession, the hyperfine coupling parameters as well as the nuclear Larmor frequency can be selectively measured with high precision (here 5 digits). The protocols can be combined to demonstrate two-dimensional Fourier spectroscopy. The technique will be useful for mapping nuclear coordinates in molecules en route to imaging their atomic structure.

quant-ph↗

arXiv2015

Accelerated nanoscale magnetic resonance imaging through phase multiplexing

We report a method for accelerated nanoscale nuclear magnetic resonance imaging by detecting several signals in parallel. Our technique relies on phase multiplexing, where the signals from different nuclear spin ensembles are encoded in the phase of an ultrasensitive magnetic detector. We demonstrate this technique by simultaneously acquiring statistically polarized spin signals from two different nuclear species (1H, 19F) and from up to six spatial locations in a nanowire test sample using a magnetic resonance force microscope. We obtain one-dimensional imaging resolution better than 5 nm, and subnanometer positional accuracy.

cond-mat.mes-hall↗

arXiv2015

Spurious harmonic response of multipulse quantum sensing sequences

Multipulse sequences based on Carr-Purcell decoupling are frequently used for narrow-band signal detection in single spin magnetometry. We have analyzed the behavior of multipulse sensing sequences under real-world conditions, including finite pulse durations and the presence of detunings. We find that these non-idealities introduce harmonics to the filter function, allowing additional frequencies to pass the filter. In particular, we find that the XY family of sequences can generate signals at the 2fac, 4fac and 8fac harmonics and their odd subharmonics, where fac is the ac signal frequency. Consideration of the harmonic response is especially important for diamond-based nuclear spin sensing where the NMR frequency is used to identify the nuclear spin species, as it leads to ambiguities when several isotopes are present.

quant-ph↗

arXiv2014

Nanoscale nuclear magnetic resonance with a 1.9-nm-deep nitrogen-vacancy sensor

We present nanoscale NMR measurements performed with nitrogen-vacancy (NV) centers located down to about 2 nm from the diamond surface. NV centers were created by shallow ion implantation followed by a slow, nanometer-by-nanometer removal of diamond material using oxidative etching in air. The close proximity of NV centers to the surface yielded large 1H NMR signals of up to 3.4 uT-rms, corresponding to ~330 statistically polarized or ~10 fully polarized proton spins in a ~(1.8 nm)^3 detection volume.

cond-mat.mes-hall↗

arXiv2013

On the surface paramagnetism of diamond

We present measurements of spin relaxation times (T_1, T_1,rho, T_2) on very shallow (<5 nm) nitrogen-vacancy (NV) centers in high-purity diamond single crystals. We find a reduction of spin relaxation times up to 30x compared to bulk values, indicating the presence of ubiquitous magnetic impurities associated with the surface. Our measurements yield a density of 0.01-0.1 Bohr magnetons per nm^2 and a characteristic correlation time of 0.28(3) ns of surface states, with little variation between samples (implanted, N-doped) and surface terminations (H, F and O). A low temperature measurement further confirms that fluctuations are thermally activated. The data support the atomistic picture where impurities are associated with the top carbon layers, and not with terminating surface atoms or adsorbate molecules. The low spin density implies that the presence of a single surface impurity is sufficient to cause spin relaxation of a shallow NV center.

cond-mat.mes-hall↗

arXiv2013

Radio-frequency magnetometry using a single electron spin

We experimentally demonstrate a simple and robust protocol for the detection of weak radio-frequency magnetic fields using a single electron spin in diamond. Our method relies on spin locking, where the Rabi frequency of the spin is adjusted to match the MHz signal frequency. In a proof-of-principle experiment we detect a 7.5 MHz magnetic probe field of 40 nT amplitude with <10 kHz spectral resolution over a T_1-limited noise floor of 0.3 nT/rtHz. Rotating-frame magnetometry may provide a direct and sensitive route to high-resolution spectroscopy of nanoscale nuclear spin signals.

quant-ph↗

arXiv2012

Single-Crystal Diamond Nanomechanical Resonators with Quality Factors exceeding one Million

We present nanofabrication and mechanical measurements of single-crystal diamond cantilevers with thickness down to 85 nm, thickness uniformity better than 20 nm, and lateral dimensions up to 240 um. Quality factors exceeding one million are found at room temperature, surpassing those of state-of-the-art single-crystal silicon cantilevers of similar dimensions by roughly an order of magnitude. Force sensitivities of a few hundred zeptonewtons result for the best cantilevers at millikelvin temperatures. Single-crystal diamond could thus directly improve existing force and mass sensors by a simple substitution of resonator material, and lead to quantum nanomechanical devices with exceptionally low energy dissipation.

cond-mat.mes-hall↗

arXiv2012

Spin Properties of Very Shallow Nitrogen Vacancy Defects in Diamond

We investigate spin and optical properties of individual nitrogen-vacancy centers located within 1-10 nm from the diamond surface. We observe stable defects with a characteristic optically detected magnetic resonance spectrum down to lowest depth. We also find a small, but systematic spectral broadening for defects shallower than about 2 nm. This broadening is consistent with the presence of a surface paramagnetic impurity layer [Tisler et al., ACS Nano 3, 1959 (2009)] largely decoupled by motional averaging. The observation of stable and well-behaved defects very close to the surface is critical for single-spin sensors and devices requiring nanometer proximity to the target.

cond-mat.mes-hall↗

arXiv2010

Force-detected nuclear magnetic resonance: Recent advances and future challenges

We review recent efforts to detect small numbers of nuclear spins using magnetic resonance force microscopy. Magnetic resonance force microscopy (MRFM) is a scanning probe technique that relies on the mechanical measurement of the weak magnetic force between a microscopic magnet and the magnetic moments in a sample. Spurred by the recent progress in fabricating ultrasensitive force detectors, MRFM has rapidly improved its capability over the last decade. Today it boasts a spin sensitivity that surpasses conventional, inductive nuclear magnetic resonance detectors by about eight orders of magnitude. In this review we touch on the origins of this technique and focus on its recent application to nanoscale nuclear spin ensembles, in particular on the imaging of nanoscale objects with a three-dimensional (3D) spatial resolution better than 10 nm. We consider the experimental advances driving this work and highlight the underlying physical principles and limitations of the method. Finally, we discuss the challenges that must be met in order to advance the technique towards single nuclear spin sensitivity -- and perhaps -- to 3D microscopy of molecules with atomic resolution.

cond-mat.mes-hall↗

arXiv2008

Force-detected nuclear double resonance between statistical spin polarizations

We demonstrate nuclear double resonance for nanometer-scale volumes of spins where random fluctuations rather than Boltzmann polarization dominate. When the Hartmann-Hahn condition is met in a cross-polarization experiment, flip-flops occur between two species of spins and their fluctuations become coupled. We use magnetic resonance force microscopy to measure this effect between 1H and 13C spins in 13C-enriched stearic acid. The development of a cross-polarization technique for statistical ensembles adds an important tool for generating chemical contrast in nanometer-scale magnetic resonance.

cond-mat.stat-mech↗