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C. Ledoux

Publications and source records attributed to C. Ledoux.

At least 109 records · Page 6Linked to original sources

First detection of CO in a high-redshift DLA

We present the first detection of carbon monoxide (CO) in a damped Lyman-alpha system (DLA) at z_abs =2.41837 toward SDSS J143912.04+111740.5. We also detected H_2 and HD molecules. The measured total column densities (in log units) of H I, H_2, and CO are 20.10\pm0.10, 19.38\pm0.10, and 13.89\pm0.02, respectively. The molecular fraction, f = 2N(H_2)/(N(HI)+2N(H_2)) = 0.27^{+0.10}_{-0.08}, is the highest among all known DLAs. The abundances relative to solar of S, Zn, Si, and Fe are -0.03\pm0.12, +0.16\pm0.11, -0.86\pm0.11, and -1.32\pm0.11, respectively, indicating a high metal enrichment and a depletion pattern onto dust-grains similar to the cold ISM of our Galaxy. The measured {N(CO)/N(H_2) = 3x10^{-6}} is much less than the conventional CO/H_2 ratio used to convert the CO emission into gaseous mass but is consistent with what is measured along translucent sightlines in the Galaxy. The CO rotational excitation temperatures are higher than those measured in our Galactic ISM for similar kinetic temperature and density. Using the C I fine structure absorption lines, we show that this is a consequence of the excitation being dominated by radiative pumping by the cosmic microwave background radiation (CMBR). From the CO excitation temperatures, we derive T_CMBR = 9.15 \pm 0.72 K, while 9.315 \pm 0.007 K is expected from the hot big-bang theory. This is the most precise high-redshift measurement of T_CMBR and the first confirmation of the theory using molecular transitions at high redshift.

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Molecular hydrogen in high-redshift Damped Lyman-alpha systems: The VLT/UVES database

We present the current status of ongoing searches for molecular hydrogen in high-redshift (1.8 < zabs <= 4.2) Damped Lyman-alpha systems (DLAs) capitalising on observations performed with the ESO Very Large Telescope (VLT) Ultraviolet and Visual Echelle Spectrograph (UVES). We identify 77 DLAs/strong sub-DLAs, with log N(HI) >= 20 and z_abs > 1.8, which have data that include redshifted H2 Lyman and/or Werner-band absorption lines. This sample of HI, H2 and metal line measurements, performed in an homogeneous manner, is more than twice as large as our previous sample (Ledoux et al. 2003) and considers every system in which searches for H2 could be completed so far, including all non-detections. H2 is detected in thirteen of the systems with molecular fractions of values between f=5x10^-7 and f=0.1, where f=2N(H2)/(2N(H2)+N(HI)). Upper limits are measured for the remaining 64 systems with detection limits of typically log N(H2)=14.3, corresponding to log f<-5. We find that about 35% of the DLAs with metallicities relative to solar [X/H]>=-1.3 (i.e., 1/20th solar), with X = Zn, S or Si, have molecular fractions log f>-4.5, while H2 is detected -- regardless of the molecular fraction -- in 50% of them. In contrast, only about 4% of the [X/H]<-1.3 DLAs have log f>-4.5. We show that the presence of H2 does not strongly depend on the total neutral hydrogen column density, although the probability of finding log f>-4.5 is higher for log N(HI)>=20.8 than below this limit (19% and 7% respectively). The overall H2 detection rate in log N(HI)>=20 DLAs is found to be about 16% (10% considering only log f>-4.5 detections) after correction for a slight bias towards large N(HI). [truncated]

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Excitation mechanisms in newly discovered H2-bearing Damped Lyman-alpha clouds: systems with low molecular fractions

We probe the physical conditions in high-redshift damped Ly-alpha systems using the observed molecular fraction and the rotational excitation of molecular hydrogen. We report two new detections of H2 at z = 2.402 and 1.989 toward, respectively, HE 0027-1836 and HE 2318-1107. We also present a detailed analysis of our recent H2 detection toward Q2343+125. All three systems have low molecular fractions, log f < -4, with f = 2N(H2)/(2N(H2) + N(HI)). Only one such H2 system was known previously. The depletion patterns for Si, S, Ti, Cr, Mn, Fe and Ni in the three systems are found to be very similar to what is observed in diffuse gas of the Galactic halo. H2 absorption from rotational levels up to J = 5 is observed in a single component toward HE 0027-1836. We show that the width (Doppler parameter) of the H2 lines increases with increasing J and that the kinetic energy derived from the Doppler parameter is linearly dependent on the relative energy of the rotational levels. The excitation temperature is found to be 90 K for J = 0 to J = 2 and ~500 K for higher J levels. Single isothermal PDR models fail to reproduce the observed rotational excitations. A two-component model is needed: one component of low density (~50 cm-3) with weak illumination (chi = 1) to explain the J <= 2 rotational levels and another of high density (~500 cm-3) with strong illumination (chi = 30) for J >= 3 levels. However, the juxtaposition of these two PDR components may be ad-hoc and the multicomponent structure could result either from turbulent dissipation or C-shocks.

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Detection of GRB 060927 at z = 5.47: Implications for the Use of Gamma-Ray Bursts as Probes of the End of the Dark Ages

We report on follow-up observations of the GRB 060927 using the ROTSE-IIIa telescope and a suite of larger aperture ground-based telescopes. An optical afterglow was detected 20 s after the burst, the earliest rest-frame detection of optical emission from any GRB. Spectroscopy performed with the VLT about 13 hours after the trigger shows a continuum break at lambda ~ 8070 A produced by neutral hydrogen absorption at z~5.6. We also detect an absorption line at 8158 A which we interpret as SiII at z=5.467. Hence, GRB 060927 is the second most distant GRB with a spectroscopically measured redshift. The shape of the red wing of the spectral break can be fitted by a damped Lyalpha profile with a column density with log(N_HI/cm^-2) ~ 22.5. We discuss the implications of this work for the use of GRBs as probes of the end of the dark ages and draw three main conclusions: i) GRB afterglows originating from z>6 should be relatively easy to detect from the ground, but rapid NIR monitoring is necessary to ensure that they are found; ii) The presence of large HI column densities in some GRBs host galaxies at z>5 makes the use of GRBs to probe the reionization epoch via spectroscopy of the red damping wing challenging; iii) GRBs appear crucial to locate typical star-forming galaxies at z>5 and therefore the type of galaxies responsible for the reionization of the universe.

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A multi-wavelength study of z = 3.15 Lyman-alpha emitters in the GOODS South Field

Context: Ly-alpha-emitters have proven to be excellent probes of faint, star-forming galaxies in the high redshift universe. However, although the sample of known emitters is increasingly growing, their nature (e.g. stellar masses, ages, metallicities, star-formation rates) is still poorly constrained. Aims: We aim to study the nature of Ly-alpha-emitters, to find the properties of a typical Ly-alpha-emitting galaxy and to compare these properties with the properties of other galaxies at similar redshift, in particular Lyman-break galaxies. Methods: We have performed narrow-band imaging at the VLT, focused on Ly-alpha at redshift z ~ 3.15, in the GOODS-S field. We have identified a sample of Ly-alpha-emitting candidates, and we have studied their Spectral Energy Distributions (SEDs). Results: We find that the emitters are best fit by an SED with low metallicity (Z/Z_sun = 0.005), low dust extinction (A_V ~ 0.32) and medium stellar masses of approximately 10^9 M_sun. The age is not very well constrained. One object out of 24 appears to be a high redshift Ly-alpha-emitting dusty starburst galaxy. We find filamentary structure as traced by the Ly-alpha-emitters at the 4 sigma level. The rest-frame UV SED of these galaxies is very similar to that of Lyman Break Galaxies (LBGs) and comply with the selection criteria for U-band drop-outs, except they are intrinsically fainter than the current limit for LBGs. Conclusion: Ly-alpha-emitters are excellent probes of galaxies in the distant universe, and represent a class of star-forming, dust and AGN free, medium mass objects.

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Physical conditions in the neutral interstellar medium at z=2.43 toward Q2348-011

We obtained a high-resolution VLT-UVES spectrum of the quasar Q2348-011 over a wavelength range that covers most of the prominent metal and molecular absorption lines from the log N(HI)=20.50+-0.10 damped Lyman-alpha system at zabs=2.43. From the column density ratios and the relative populations of H2 rotational and CI fine-structure levels, we derive the physical conditions (relative abundances, dust-depletion, particle density, kinetic temperature and ionizing flux) and discuss physical conditions in the neutral phase. Molecular hydrogen is detected in seven components in the first four rotational levels (J = 0-3) of the vibrational ground state. Absorption lines of H2 J = 4 (resp. J = 5) are also detected in six (resp. two) of these components. This leads to a total molecular fraction of log f = -1.69+0.37-0.58. We confirm the earlier findings that there is a correlation between N(FeII)/N(SII) and N(SiII)/N(SII) indicative of a dust-depletion pattern. Surprisingly, however, the depletion of metals onto dust in the H2 components is not large in this system: [Fe/S] = -0.8 to -0.1. The gas in H2-bearing components is found to be cold but still hotter than similar gas in our Galaxy (T > 130 K, instead of typically 80 K). and dense (n=100-200 cm^-3). There is an anti-correlation between the logarithm of the photo-absorption rate, and log N(H2)/N(CI) derived for each H2 component. We show that this is mostly due to shielding effects and implies that the photo- absorption rate is a good indicator of the physical conditions in the gas. We find that the gas is immersed in a intense UV field, about one order of magnitude higher than in the solar vicinity. The results suggest that the gas in H2-bearing DLAs is clumpy, and star-formation occurs in the associated object.

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The nature of the dwarf starforming galaxy associated with GRB 060218 / SN2006aj

We present high resolution VLT UVES and low resolution FORS optical spectroscopy of supernova 2006aj and its host galaxy, associated with the nearby (z = 0.03342) gamma-ray burst GRB 060218. This host galaxy is a unique case, as it is one of the few nearby GRB host galaxies known, and it is only the second time high resolution spectra have been taken of a nearby GRB host galaxy (after GRB 980425). The resolution, wavelength range and S/N of the UVES spectrum combined with low resolution FORS spectra allow a detailed analysis of the circumburst and host galaxy environments. We analyse the emission and absorption lines in the spectrum, combining the high resolution UVES spectrum with low resolution FORS spectra and find the metallicity and chemical abundances in the host. We probe the geometry of the host by studying the emission line profiles. Our spectral analysis shows that the star forming region in the host is metal poor with 12 + log(O/H) = 7.54 (+0.17, -0.10) (~0.07 Z_sun), placing it among the most metal deficient subset of emission-line galaxies. It is also the lowest metallicity found so far for a GRB host from an emission-line analysis. Given the stellar mass of the galaxy of ~10^7 M_sun and the SFR (H alpha) = 0.065 +/- 0.005 M_sun/yr, the high specific star formation rate indicates an age for the galaxy of less than ~200 Myr. The brightest emission lines are clearly asymmetric and are well fit by two Gaussian components separated by ~22$ km/s. We detect two discrete Na I and Ca II absorption components at the same redshifts as the emission components. We tentatively interpret the two components as arising from two different starforming regions in the host, but high resolution imaging is necessary to confirm this.

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A log N(HI) = 22.6 DLA in a dark gamma-ray burst: the environment of GRB 050401

The optical afterglow spectrum of GRB050401 (at z=2.8992+/-0.0004) shows the presence of a DLA, with log(nHI)=22.6+/-0.3. This is the highest column density ever observed in a DLA, and is about five times larger than the strongest DLA detected so far in any QSO spectrum. From the optical spectrum, we also find a very large Zn column density, allowing us to infer an abundance of [Zn/H]=-1.0+/-0.4. These large columns are supported by the X-ray spectrum from Swift-XRT which shows a column density (in excess of Galactic) of log(nH)=22.21^{+0.06}_{-0.08} assuming solar abundances (at z=2.9). The comparison of this X-ray column density, which is dominated by absorption due to alpha-chain elements, and the HI column density derived from the Ly-alpha absorption line, allows us to derive a metallicity for the absorbing matter of [alpha/H]=-0.4+/-0.3. The optical spectrum is reddened and can be well reproduced with a power-law with SMC extinction, where A_V=0.62+/-0.06. But the total optical extinction can also be constrained in a way which is independent of the shape of the extinction curve: from the optical-to-X-ray spectral energy distribution we find, 0.5<~A_V<~4.5. However, even this upper limit, independent of the shape of the extinction curve, is still well below the dust column that is inferred from the X-ray column density, i.e. A_V=9.1^{+1.4}_{-1.5}. This discrepancy might be explained by a small dust content with high metallicity (low dust-to-metals ratio). `Grey' extinction cannot explain the discrepancy since we are comparing the metallicity to a measurement of the total extinction (without reference to the reddening). Little dust with high metallicity may be produced by sublimation of dust grains or may naturally exist in systems younger than a few hundred Myr.

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HI column densities of z > 2 Swift gamma-ray bursts

Context: Before the launch of the Swift satellite, the majority of the gamma-ray burst (GRB) afterglows for which Ly-alpha was redshifted into the observable spectrum showed evidence for a damped Ly-alpha absorber. This small sample indicated that GRBs explode either in galaxies, or regions within them, having high neutral hydrogen column densities. Aims: To increase the spectroscopic sample of GRBs with z > 2 and hence establish the N(HI) distribution along GRB lines-of-sight. Methods: We have obtained six z > 2 GRB afterglow spectra and fitted the Ly-alpha absorption line in each case to determine N(HI). This has been complemented with 12 other Swift N(HI) values from the literature. Results: We show that the peak of the GRB N(HI) distribution is qualitatively consistent with a model where GRBs originate in Galactic-like molecular clouds. However, a systematic difference, in particular an excess of low column-density systems compared to the predictions, indicates that selection effects and conditions within the cloud (e.g. strong ionization) influence the observed N(HI) range. We also report the discovery of Ly-alpha emission from the GRB 060714 host, corresponding to a star-formation rate of approximately 0.8 M_Sun/year. Finally, we present accurate redshifts of the six bursts: z = 3.240 +/- 0.001 (GRB 050319), z = 2.198 +/- 0.002 (GRB 050922C), z = 3.221 +/- 0.001 (GRB 060526), z = 3.425 +/- 0.002 (GRB 060707), z = 2.711 +/- 0.001 (GRB 060714) and z = 3.686 +/- 0.002 (GRB 060906).

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An optical supernova associated with the X-ray flash XRF 060218

Long-duration gamma-ray bursts (GRBs) are associated with type Ic supernovae that are more luminous than average and that eject material at very high velocities. Less-luminous supernovae were not hitherto known to be associated with GRBs, and therefore GRB-supernovae were thought to be rare events. Whether X-ray flashes - analogues of GRBs, but with lower luminosities and fewer gamma-rays - can also be associated with supernovae, and whether they are intrinsically 'weak' events or typical GRBs viewed off the axis of the burst, is unclear. Here we report the optical discovery and follow-up observations of the type Ic supernova SN 2006aj associated with X-ray flash XRF 060218. Supernova 2006aj is intrinsically less luminous than the GRB-supernovae, but more luminous than many supernovae not accompanied by a GRB. The ejecta velocities derived from our spectra are intermediate between these two groups, which is consistent with the weakness of both the GRB output and the supernova radio flux. Our data, combined with radio and X-ray observations, suggest that XRF 060218 is an intrinsically weak and soft event, rather than a classical GRB observed off-axis. This extends the GRB-supernova connection to X-ray flashes and fainter supernovae, implying a common origin. Events such as XRF 060218 are probably more numerous than GRB-supernovae.

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Metallicity as a criterion to select H2 bearing Damped Lyman-alpha systems

We characterize the importance of metallicity on the presence of molecular hydrogen in damped Lyman-alpha (DLA) systems. We construct a representative sample of 18 DLA/sub-DLA systems with log N(HI)>19.5 at high redshift (zabs>1.8) with metallicities relative to solar [X/H]>-1.3(with[X/H]= logN(X)/N(H)-log(X/H)solar and X either Zn, S or Si). We gather data covering the expected wavelength range of redshifted H2 absorption lines on all systems in the sample from either the literature (10 DLAs), the UVES-archive or new VLT-UVES observations for four of them. The sample is large enough to discuss for the first time the importance of metallicity as a criterion for the presence of molecular hydrogen in the neutral phase at high-z. From the new observations, we report two new detections of molecular hydrogen in the systems at zabs=2.431 toward Q2343+125 and zabs=2.426 toward Q2348-011. We compare the H2 detection fraction in the high-metallicity sample with the detection fraction in the overall sample from Ledoux et al. (2003). We show that the fraction of DLA systems with logf=log 2N(H2)/(2N(H2)+N(HI))>-4 is as large as 50% for [X/H]>-0.7 when it is only about 5% for [X/H]<-1.3 and about 15% in the overall sample (with -2.5<[X/H]<-0.3). This demonstrates that the presence of molecular hydrogen at high redshift is strongly correlated with metallicity.

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Velocity-Metallicity Correlation for high-z DLA Galaxies: Evidence for a Mass-Metallicity Relation?

We used our database of VLT-UVES quasar spectra to build up a sample of 70 Damped Lyman-alpha (DLA) or strong sub-DLA systems with total neutral hydrogen column densities of log N(HI)>20 and redshifts in the range 1.7 2.43) and the lower (z_abs<2.43) redshift halves of our sample. However, the two populations of systems are statistically different. There is a strong redshift evolution in the sense that the mean metallicity and mean velocity width increase with decreasing redshift. We argue that the existence of a DLA velocity-metallicity correlation, over more than a factor of 100 spread in metallicity, is probably the consequence of an underlying mass-metallicity relation for the galaxies responsible for DLA absorption lines. Assuming a simple linear scaling of the galaxy luminosity with the mass of the dark-matter halo, we find that the slope of the DLA velocity-metallicity relation is consistent with that of the luminosity-metallicity relation derived for local galaxies. [...] abridged.

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Probing Cosmic Chemical Evolution with Gamma-Ray Bursts: GRB060206 at z=4.048

Aim: We present early optical spectroscopy of the afterglow of the gamma-ray burst GRB 060206 with the aim of determining the metallicity of the GRB absorber and the physical conditions in the circumburst medium. We also discuss how GRBs may be important complementary probes of cosmic chemical evolution. Method: Absorption line study of the GRB afterglow spectrum. Results: We determine the redshift of the GRB to be z=4.04795+/-0.00020. Based on the measurement of the neutral hydrogen column density from the damped Lyman-alpha line and the metal content from weak, unsaturated Sii lines we derive a metallicity of [S/H] =-0.84+/-0.10. This is one of the highest metallicities measured from absorption lines at z~4. From the very high column densities for the forbidden Siii*, Oi*, and Oi** lines we infer very high densities and low temperatures in the system. There is evidence for the presence of H$_2$ molecules with logN(H_2) ~ 17.0, translating into a molecular fraction of logf \~ -3.5 with f=2N(H_2)/(2N(H_2)+ N(Hi)). Even if GRBs are only formed by single massive stars with metallicities below ~0.3Z(solar), they could still be fairly unbiased tracers of the bulk of the star formation at z>2. Hence, metallicities as derived for GRB060206 here for a complete sample of GRB afterglows will directly show the distribution of metallicities for representative star-forming galaxies at these redshifts.

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Abundance analysis of 5 early-type stars in the young open cluster IC2391

It is unclear whether chemically peculiar stars of the upper main sequence represent a class completely distinct from normal A-type stars, or whether there exists a continuous transition from the normal to the most peculiar late F- to early B-type stars. A systematic abundance analysis of open cluster early-type stars would help to relate the observed differences of the chemical abundances of the photospheres to other stellar characteristics, without being concerned by possible different original chemical composition. Furthermore, if a continuous transition region from the very peculiar to the so called normal A-F stars exists, it should be possible to detect objects with mild peculiarities. As a first step of a larger project, an abundance analysis of 5 F-A type stars in the young cluster IC2391 was performed using high resolution spectra obtained with the UVES instrument of the ESO VLT. Our targets seem to follow a general abundance pattern: close to solar abundance of the light elements and iron peak elements, heavy elements are slightly overabundant with respect to the sun, similar to what was found in previous studies of normal field A-type stars of the galactic plane. We detected a weakly chemically peculiar star, HD74044. Its element pattern contains characteristics of CP1 as well as CP2 stars, enhanced abundances of iron peak elements and also higher abundances of Sc, Y, Ba and Ce. We did not detect a magnetic field in this star (detection limit was 2kG). We also studied the star SHJM2, proposed as a pre-main sequence object in previous works. Using spectroscopy we found a high surface gravity, which suggests that the star is very close to the ZAMS.

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Molecular Hydrogen in a Damped Lyman-alpha System at z_abs=4.224

We present the direct detection of molecular hydrogen at the highest redshift known today (z_abs=4.224) in a Damped Lyman-alpha (DLA) system toward the quasar PSS J1443+2724. This absorber is remarkable for having one of the highest metallicities amongst DLA systems at z_abs>3, with a measured iron abundance relative to Solar of -1.12+/-0.10. We provide for the first time in this system accurate measurements of NI, MgII, SII and ArI column densities. The sulfur and nitrogen abundances relative to Solar, -0.63+/-0.10 and -1.38+/-0.10 respectively, correspond exactly to the primary nitrogen production plateau. H2 absorption lines are detected in four different rotational levels (J=0, 1, 2 and 3) of the vibrational ground-state in three velocity components with total column densities of log N(H2)=17.67, 17.97, 17.48 and 17.26 respectively. The J=4 level is tentatively detected in the strongest component with log N(H2)~14. The mean molecular fraction is log f=-2.38+/-0.13, with f=2N(H2)/(2N(H2)+N(HI)). We also measure log N(HD)/N(H2)<-4.2. The excitation temperatures T_{01} for the two main components of the system are 96 and 136 K respectively. We argue that the absorbing galaxy, whose star-formation activity must have started at least 2-5x10^8 yrs before z=4.224, is in a quiescent state at the time of observation. The density of the gas is small, n_H<=50 cm^{-3}, and the temperature is of the order of T~90-180 K. The high excitation of neutral carbon in one of the components can be explained if the temperature of the Cosmic Microwave Background Radiation has the value expected at the absorber redshift, T=14.2 K.

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The most metal-poor damped Ly alpha system at z<3: constraints on early nucleosynthesis

To constrain the conditions for very early nucleosynthesis in the Universe we compare the chemical enrichment pattern of an extremely metal-poor damped Lyman alpha (DLA) absorber with predictions from recent explosive nucleosynthesis model calculations. For this, we have analyzed chemical abundances in the DLA system at z_abs=2.6183 toward the quasar Q0913+072 (z_em=2.785) using public UVES/VLT high spectral resolution data. The total neutral hydrogen column density in this absorber is logN(HI)=20.36. Accurate column densities are derived for CII, NI, OI, AlII, SiII, and FeII. Upper limits are given for FeIII and NiII. With [C/H]=-2.83, [N/H]=-3.84, and [O/H]=-2.47, this system represents one of the most metal-poor DLA systems investigated so far. It offers the unique opportunity to measure accurate CNO abundances in a protogalactic structure at high redshift. Given the very low overall abundance level and the observed abundance pattern, the data suggest that the chemical evolution of this DLA system is dominated by one or at most a few stellar generations. With reference to numerical model calculations, the chemical abundances in the DLA system are consistent with an enrichment from a single starburst of a zero-metallicity population of massive stars (10-50 M_sun) exploding as core-collapse Supernovae (SNe), i.e., the classical Type II Supernovae (SNeII), and possibly as hyper-energetic (E>10^51erg) core-collapse Supernovae, so-called Hypernovae (HNe), as well. In contrast, models using non-zero metallicity progenitors or other explosion mechanisms, such as pair-instability Supernovae (PISNe) or Type Ia Supernovae (SNeIa), do not match the observed abundance pattern.

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Relative abundance pattern along the profile of high redshift Damped Lyman-alpha systems

We investigated abundance ratios along the profiles of six high-redshift Damped Lyman-alpha systems, three of them associated with H2 absorption, and derived optical depths in each velocity pixel. The variations of the pixel abundance ratios were found to be remarkably small and usually smaller than a factor of two within a profile. This result holds even when considering independent sub-clumps in the same system. The depletion factor is significantly enhanced only in those components where H2 is detected. There is a strong correlation between [Fe/S] and [Si/S] abundances ratios, showing that the abundance ratio patterns are definitely related to the presence of dust. The depletion pattern is usually close to the one seen in the warm halo gas of our Galaxy.

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Early-type stars observed in the ESO UVES Paranal Observatory Project: I -- Interstellar Na I UV, Ti II and Ca II K observations

We present an analysis of interstellar Na I (lambda=3302.37Å, 3302.98Å), Ti II (lambda=3383.76Å) and Ca II K (lambda=3933.66Å) absorption features for 74 sightlines towards O- and B-type stars in the Galactic disc. The data were obtained from the UVES Paranal Observatory Project, at a spectral resolution of 3.75km/s and with mean signal to noise ratios per pixel of 260, 300 and 430 for the Na I, Ti II and Ca II observations, respectively. Interstellar features were detected in all but one of the Ti II sightlines and all of the Ca II sightlines. The dependence of the column density of these three species with distance, height relative to the Galactic plane, H I column density, reddening and depletion relative to the solar abundance has been investigated. We also examine the accuracy of using the Na I column density as an indicator of that for H I. In general we find similar strong correlations for both Ti and Ca, and weaker correlations for Na. Our results confirm the general belief that Ti and Ca occur in the same regions of the interstellar medium and also that the Ti II/Ca II ratio is constant over all parameters. We hence conclude that the absorption properties of Ti and Ca are essentially constant under the general interstellar medium conditions of the Galactic disc.

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