arXiv subjects

C. M. Lisse

Publications and source records attributed to C. M. Lisse.

At least 19 recordsLinked to original sources

arXiv2026

Uniform Metallicity Measurements of M Dwarf Planet Hosts Support Metallicity-Dependent Sub-Neptune Formation

M dwarfs are the most common sites of planet formation in the Milky Way. Planet occurrence and composition are closely linked with the availability of metals in protoplanetary disks, which can be probed by measuring planet host star metallicities. In this work, we measure the metallicities ([M/H] and [Fe/H]) of 59 M dwarfs hosting 76 planets and candidates using medium-resolution near-infrared spectra collected with IRTF/SpeX. We combine these results with literature metallicity measurements for planet-hosting cool dwarfs, and present 86 stars hosting 142 candidate, validated, and confirmed planets with homogeneously derived stellar parameters. Using our updated stellar radii, we calculate planet radii from TESS transit depths for both the confirmed (N = 51, 0.6 - 12.5 R$_\oplus$, median $R_p$ = 1.8R$_\oplus$) and candidate (N = 25, 0.6 - 7.2 R$_\oplus$, median $R_p$ = 2.1R$_\oplus$) planets. We compare the metallicity distributions of super-Earth and sub-Neptune host stars, finding that M dwarfs hosting sub-Neptunes are statistically more metal-rich than those hosting super-Earths. This result is robust to the radius valley prescription used, and is likely not due to differences in the stellar samples considered. This result supports the hypothesized formation pathway whereby sub-Neptunes form beyond the water ice line where they can accrete volatiles before migrating inwards to their observed locations. The enhanced inventories of refractory elements throughout the disk and of volatiles beyond the ice line in metal-rich disks around low-mass stars may contribute to the preference seen in the observed planet sample for sub-Neptunes to orbit metal-rich M dwarfs.

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arXiv2026

First Resolution of a Main Sequence G-Star Astrosphere Using Chandra

We report resolution of a halo of X-ray line emission surrounding the Zero Age Main Sequence (ZAMS) G8.5V star HD 61005 by Chandra ACIS-S. Located only 36.4 pc distant, HD 61005 is young (approx. 100 Myr), x-ray bright (300 times Solar), observed with nearly edge-on geometry, and surrounded by Local Interstellar Medium (LISM) material denser than in the environ of the Sun. HD 61005 is known to harbor large amounts of circumstellar dust in a dense ecliptic plane full of mm-sized particles plus attached, extended wing like structures full of micron sized particles, which are evidence for a strong LISM-dust disk interaction. These properties aided our ability to resolve the 220 au wide astrosphere of HD61005, the first ever observed for a main sequence G-star. The observed x-ray emission morphology is roughly spherical, as expected for an astrospheric structure dominated by the host star. The Chandra spectrum of HD 61005 is a combination of a hard stellar coronal emission (T=8 MK) at Lx = 6 x10e29 erg per sec, plus an extended halo contribution at Lx = 1x10e29 erg per sec dominated by charge exchange (CXE) lines, such as those of OVIII and NeIX. The Chandra CXE x-ray morphology does not track the planar dust morphology but does extend out roughly to where the base of the dust wings begins. We present a toy model of x-ray emission produced by stellar wind (SW)-LISM CXE interactions, similar to the state of the young Sun when it was approximately 100 Myrs old (Guinan and Engle 2007), and transiting through an approximately 1000 times denser part of the interstellar medium (ISM) such as a Giant Molecular Cloud (Stern 2003, Opher and Loeb 2024).

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arXiv2026

SPHEREx Re-Observation of Interstellar Object 3I/ATLAS in December 2025: Detection of Increased Post-Perihelion Activity, Refractory Coma Dust, and New Coma Gas Species

In December-2025, the NASA SPHEREx spacecraft re-observed ISO 3I/ATLAS post-perihelion, finding a much more active object compared to August-2025 SPHEREx pre-perihelion observations, with marked evidence for development into an cometary body fully sublimating all its ices. The new imaging spectrophotometry was dominated by spatially resolved features due to light scattered by dust, along with thermal emission, plus gas-line emissions from CN (0.93 um), H2O (2.7 um), organic C-H (3.2 to 3.6 um), CO2 (4.25 to 4.27 um), and CO (4.6 to 4.8 um). The CO2 gas-coma continues to be extended out to a 3 arcmin radius. The continuum spectral signature of H2O-ice absorption had mostly disappeared, replaced by scattered-light plus thermal-emission from organo-silicaceous dust grains while the H2O gas-emission is 40x times brighter. The CO- and CO2-gas comae were circularly symmetric, while the other comae appear morphologically similar to the dust-coma with its pear-shaped, solar-pointing, large icy dust grains dust tail. The new appearance of CN and C-H features suggests that these carbon-rich ice species were contained either in H2O phases or were trapped under them.

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arXiv2025

SPHEREx Discovery of Strong Water Ice Absorption and an Extended Carbon Dioxide Coma in 3I/ATLAS

In mid-August 2025, 0.75-5.0 micron SPHEREx imaging spectrophotometric and ancillary NASA-IRTF SpeX 0.7-2.5 micron low-resolution spectral observations of Interstellar Object 3I ATLAS were obtained. The combined spectrophotometry is dominated by features due to water ice absorption and CO2 gas emission. A bright, 3 arcmin radius CO2 gas coma was clearly resolved, corresponding to Qgas,CO2 = 9.4 x 10{^26} molec/sec. From the SPHEREx photometry, we put conservative, preliminary 3sigma upper limits on the gas production rates for H2O and CO of 1.5 x 10{^26} and 2.8 x 10{^26} molec/sec. No obvious jet, tail, or trail structures were found in SPHEREx images. Assuming all observed 1-um flux is scattered light from an pv = 0.04 albedo spherical nucleus, its radius would be 23 km. Compared to the nucleus size limit r = 2.8km of Jewitt+ 2025, this suggests that greater than 99 percent of the measured SPHEREx continuum flux is from coma dust.

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arXiv2025

The Lyman alpha Sky as Observed by New Horizons

During September 2023 the Alice ultraviolet spectrograph on the New Horizons (NH) spacecraft was used to map diffuse Lyman alpha (Lya) emission over most of the sky, at a range of 56.9 AU from the Sun. At that distance, models predict that the interplanetary medium Lya emissions result from comparable amounts of resonant backscattering of the solar Lya line by interstellar hydrogen atoms (HI) passing through the solar system, in addition to an approximately isotropic background of 30-70 R from the Local InterStellar Medium (LISM). The NH observations show no strong correlations with nearby cloud structures of the LISM or with expected structures of the heliosphere, such as a hydrogen wall associated with the heliopause. To explain the relatively bright and uniform Lya of the LISM we propose that hot, young stars within the Local Hot Bubble (LHB) shine on its interior walls, photoionizing HI atoms there. Recombination of these ions can account for the observed 50 R Lya background, after amplification of the diffuse Lya by resonant scattering, although sophisticated (i.e., 3-D) radiative transfer models should be used to confirm this conjecture. Future observations of the diffuse Lya, with instruments capable of resolving the line profile, could provide a new window on HI populations in the LISM and heliosphere. The NH Alice all-sky Lya observations presented here may be repeated at some point in the future, if resources allow, and the two maps could be combined to provide a significant increase in angular resolution.

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arXiv2024

X-ray detection of astrospheres around three main-sequence stars and their mass-loss rates

Stellar winds of cool main sequence stars are very difficult to constrain observationally. One way to measure stellar mass loss rates is to detect soft X-ray emission from stellar astrospheres produced by charge exchange between heavy ions of the stellar wind and cold neutrals of the interstellar medium (ISM) surrounding the stars. Here we report detections of charge-exchange induced X-ray emission from the extended astrospheres of three main sequence stars, 70 Ophiuchi, epsilon Eridani, and 61 Cygni based on analysis of observations by XMM-Newton. We estimate the corresponding mass loss rates to be 66.5 +- 11.1, 15.6 +- 4.4, and 9.6 +- 4.1 times the solar mass loss rate for 70 Ophiuchi, epsilon Eridani, and 61 Cygni, respectively, and compare our results to the hydrogen wall method. We also place upper limits on the mass loss rates of several other main sequence stars. This method has potential utility for determining the mass loss rates from X-ray observations showing spatial extension beyond a coronal point source.

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arXiv2023

Palomar discovery and initial characterization of naked-eye long period comet C/2022 E3 (ZTF)

Long-period comets are planetesimal remnants constraining the environment and volatiles of the protoplanetary disc. We report the discovery of hyperbolic long-period comet C/2022 E3 (ZTF), which has a perihelion $\sim$1.11 au, an eccentricity $\gtrsim$1 and an inclination $\sim$109$^{\circ}$, from images taken with the Palomar 48-inch telescope during morning twilight on 2022 Mar 2. Additionally, we report the characterization of C/2022 E3 (ZTF) from observations taken with the Palomar 200-inch, the Palomar 60-inch, and the NASA Infrared Telescope Facility in early 2023 February to 2023 March when the comet passed within $\sim$0.28 au of the Earth and reached a visible magnitude of $\sim$5. We measure g-r = 0.70$\pm$0.01, r-i = 0.20$\pm$0.01, i-z = 0.06$\pm$0.01, z-J = 0.90$\pm$0.01, J-H = 0.38$\pm$0.01 and H-K = 0.15$\pm$0.01 colours for the comet from observations. We measure the A(0$^\circ$)f$ρ$ (0.8~$μ$m) in a 6500~km radius from the nucleus of 1483$\pm$40~cm, and CN, C$_3$, and C$_2$ production of 5.43$\pm0.11\times$10$^{25}$~mol/s, 2.01$\pm0.04\times$10$^{24}$, and 3.08$\pm0.5\times$10$^{25}$~mol/s, similar to other long period comets. We additionally observe the appearance of jet-like structures at a scale of $\sim$4,000 km in wide-field g-band images, which may be caused by the presence of CN gas in the near-nucleus coma.

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arXiv2023

Keck, Gemini, and Palomar 200-inch visible photometry of red and very-red Neptunian Trojans

Neptunian Trojans (NTs), trans-Neptunian objects in 1:1 mean-motion resonance with Neptune, are generally thought to have been captured from the original trans-Neptunian protoplanetary disk into co-orbital resonance with the ice giant during its outward migration. It is possible, therefore, that the colour distribution of NTs is a constraint on the location of any colour transition zones that may have been present in the disk. In support of this possible test, we obtained $g$, $r$, and $i$-band observations of 18 NTs, more than doubling the sample of NTs with known visible colours to 31 objects. Out of the combined sample, we found $\approx$4 objects with $g$-$i$ colours of $>$1.2 mags placing them in the very red (VR) category as typically defined. We find, without taking observational selection effects into account, that the NT $g$-$i$ colour distribution is statistically distinct from other trans-Neptunian dynamical classes. The optical colours of Jovian Trojans and NTs are shown to be less similar than previously claimed with additional VR NTs. The presence of VR objects among the NTs may suggest that the location of the red to VR colour transition zone in the protoplanetary disk was interior to 30-35 au.

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arXiv2022

Mid-Infrared Spectroscopy of Components in Chondrites: Search for Processed Materials in Young Solar Systems and Comets

We obtained mid-infrared spectra of chondrules, matrix, CAIs and bulk material from primitive type 1-4 chondrites in order to compare them with the dust material in young, forming solar systems and around comets. Our aim is to investigate whether there are similarities between the first processed materials in our early Solar System and protoplanetary disks currently forming around other stars. Chondrule spectra can be divided into two groups. 1) Chondrules dominated by olivine features at 11.3 micron and 10.0 micron. 2) mesostasis rich chondrules that show main features at 10 micron. Bulk ordinary chondrites show similar features to both groups. Fine-grained matrix is divided into three groups. 1) phyllosilicate-rich with a main band at 10 micron, 2) olivine-rich with bands at 11.3 micron and 10 micron, 3) pyroxene rich. Impact shock processed matrix from Murchison (CM2) shows features from phyllosilicate-rich, amorphous and olivine rich material. Astronomical spectra are divided into four groups based on their spectral characteristics, amorphous (group 1), pyroxene rich (group 2), olivine rich (group 3) and complex (group 4). Group 2 is similar to enstatite-rich fine grained material like e.g. Kakangari (K3) matrix. Group 3 and 4 can be explained by a combination of varying concentrations of olivine and mesostasis rich chondrules and fine grained matrix, but also show very good agreement with shock processed material. Comparison of band ratios confirms the similarity with chondritic material e.g. for HD100546, while the inner disk of HD142527 show no sign of chondrule material. Comparison between spectra indicate a general similarity between primitive solar system materials and circumstellar dust and comets.

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arXiv2022

Mid-infrared spectra of differentiated meteorites (achondrites): Comparison with astronomical observations of dust in protoplanetary and debris disks

Mid-infrared (5 micron to 25 micron) transmission/absorption spectra of differentiated meteorites (achondrites) were measured to permit comparison with astronomical observations of dust in different stages of evolution of young stellar objects. In contrast to primitive chondrites, achondrites underwent heavy metamorphism and/or extensive melting and represent more advanced stages of planetesimal evolution. Spectra were obtained from primitive achondrites (acapulcoite, winonaite, ureilite, and brachinite) and differentiated achondrites (eucrite, diogenite, aubrite, and mesosiderite silicates). The ureilite and brachinite show spectra dominated by olivine features, and the diogenite and aubrite by pyroxene features. The acapulcoite, winonaite, eucrite, and mesosiderite silicates exhibit more complex spectra, reflecting their multi-phase bulk mineralogy. Mixtures of spectra of the primitive achondrites and differentiated achondrites in various proportions show good similarities to the spectra of the few Myr old protoplanetary disks HD104237A and V410 Anon 13. A spectrum of the differentiated mesosiderite silicates is similar to the spectra of the mature debris disks HD172555 and HD165014. A mixture of spectra of the primitive ureilite and brachinite is similar to the spectrum of the debris disk HD113766. The results raise the possibility that materials produced in the early stage of planetesimal differentiation occur in the protoplanetary and debris disks.

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arXiv2022

Dust from collisions: A way to probe the composition of exo-planets?

In order to link infrared observations of dust formed during planet formation in debris disks to mid-infrared spectroscopic data of planetary materials from differentiated terrestrial and asteroidal bodies, we obtained absorption spectra of a representative suite of terrestrial crustal and mantle materials, and of typical Martian meteorites. A series of debris disk spectra characterized by a strong feature in the 9.0-9.5 micron range (HD23514, HD15407a, HD172555 and HD165014), is comparable to materials that underwent shock, collision or high temperature events. These are amorphous materials such as tektites, SiO2-glass, obsidian, and highly shocked shergottites as well as inclusions from mesosiderites (Group A). A second group (BD+20307, Beta Pictoris, HD145263, ID8, HD113766, HD69830, P1121, and Eta Corvi) have strong pyroxene and olivine bands in the 9-12 micron range and is very similar to ultramafic rocks (e.g. harzburgite, dunite)(Group B). This could indicate the occurrence of differentiated materials similar to those in our Solar System in these other systems. However, mixing of projectile and target material, as well as that of crustal and mantle material has to be taken into account in large scale events like hit-and-run and giant collisions or even large-scale planetary impacts. This could explain the olivine-dominated dust of group B. The crustal-type material of group A would possibly require the stripping of upper layers by grazing-style hit-and run encounters or high energy events like evaporation/condensation in giant collisions. In tidal disruptions or the involvement of predominantly icy/water bodies the resulting mineral dust would originate mainly in one of the involved planetesimals. This could allow attributing the observed composition to a specific body (such as e.g. Eta Corvi).

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arXiv2022

29P/Schwassmann-Wachmann: A Rosetta Stone for Amorphous Water Ice and CO <-> CO2 Conversion in Centaurs and Comets?

Centaur 29P/Schwassmann-Wachmann 1 (SW1) is a highly active object orbiting in the transitional Gateway region (Sarid et al. 2019) between the Centaur and Jupiter Family Comet regions. SW1 is unique among the Centaurs in that it experiences quasi-regular major outbursts and produces CO emission continuously; however, the source of the CO is unclear. We argue that due to its very large size (approx. 32 km radius), SW1 is likely still responding, via amorphous water ice (AWI) conversion to crystalline water ice (CWI), to the rapid change in its external thermal environment produced by its dynamical migration from the Kuiper belt to the Gateway Region at the inner edge of the Centaur region at 6 au. It is this conversion process that is the source of the abundant CO and dust released from the object during its quiescent and outburst phases. If correct, these arguments have a number of important predictions testable via remote sensing and in situ spacecraft characterization, including: the quick release on Myr timescales of CO from AWI conversion for any few km-scale scattered disk KBO transiting into the inner system; that to date SW1 has only converted between 50 to 65% of its nuclear AWI to CWI; that volume changes upon AWI conversion could have caused subsidence and cave-ins, but not significant mass wasting or crater loss on SW1; that SW1s coma should contain abundant amounts of CWI CO2-rich icy dust particles; and that when SW1 transits into the inner system within the next 10,000 years, it will be a very different kind of JFC comet.

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arXiv2022

A Predicted Dearth of Majority Hypervolatile Ices in Oort Cloud Comets

We present new, ice species-specific New Horizons/Alice upper gas coma production limits from the 01 Jan 2019 MU69/Arrokoth flyby of Gladstone et al. (2021) and use them to make predictions about the rarity of majority hypervolatile (CO, N$_2$, CH$_4$) ices in KBOs and Oort Cloud comets. These predictions have a number of important implications for the study of the Oort Cloud, including: determination of hypervolatile rich comets as the first objects emplaced into the Oort Cloud; measurement of CO/N$_2$/CH$_4$ abundance ratios in the proto-planetary disk from hypervolatile rich comets; and population statistical constraints on early (< 20 Myr) planetary aggregation driven versus later (> 50 Myr) planetary migration driven emplacement of objects into the Oort Cloud. They imply that the phenomenon of ultra-distant active comets like C/2017K2 (Jewitt et al. 2017, Hui et al. 2018) should be rare, and thus not a general characteristic of all comets. They also suggest that interstellar object 2I/Borisov did not originate in a planetary system that was inordinately CO rich (Bodewits et al. 2020), but rather could have been ejected onto an interstellar trajectory very early in its natal system's history.

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arXiv2022

Thermal Alteration and Differential Sublimation Can Create Phaethons "Rock Comet" Activity and Blue Color

In 2010 Jewitt and Li published a paper examining the behavior of comet-asteroid transition object 3200 Phaethon, arguing it was asteroid-like in its behavior throughout most of its orbit, but that near its perihelion, at a distance of only 0.165 AU from the sun, its dayside temperatures would be hot enough to vaporize rock (>1000 K, Hanus et al. 2016). Thus it would act like a "rock comet" as gases produced from evaporating rock were released from the body, in a manner similar to the more familiar sublimation of water ice into vacuum seen for comets coming within ~3 AU of the Sun. In this Note we predict that the same thermal effects that would create "rock comet" behavior with Qgas ~ 10$^{22}$ mol/sec at perihelion would also help greatly bluen Phaethon's surface via preferential thermal alteration and sublimative removal of surface Fe and refractory organics, known reddening and darkening agents. These predictions are testable by searching for signs of spectral bluening of the surfaces of other objects in Phaethon-like small perihelion orbits, and by in situ measurements of Phaethons surface and coma composition near perihelion with the upcoming DESTINY+ mission to Phaethon by JAXA.

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arXiv2022

RW Aur A : SpeX Spectral Evidence for Differentiated Planetesimal Formation, Migration and Destruction in an 3 Myr Old Excited CTTS System

We present 2007 - 2020 SpeX VISNIR spectral monitoring of the highly variable RW Aur A CTTS. We find direct evidence for a highly excited, IR bright, asymmetric, and time variable system. Comparison of the spectral and temporal trends found determines 5 different components: (1) a stable continuum from 0.7 - 1.3 um, with approx color temperature 4000K, produced by the CTTS photospheric surface; (2) variable hydrogen emission lines emitted from hot excited hydrogen in the CTTSs protostellar atmosphere/accretion envelope; (3) hot CO gas in the CTTSs protostellar atmosphere/accretion envelope; (4) highly variable 1.8-5.0 um thermal continuum emission with color temperature ranging from 1130 to 1650K, due to a surrounding accretion disk that is spatially variable and has an inner wall at r = 0.04 AU and T = 1650K, and outer edges at approx 1200K; and (5) transient, bifurcated signatures of abundant Fe II + associated SI, SiI, and SrI in the systems jet structures. The bifuracted signatures first appeared in 2015, but these collapsed and disappeared into a small single peak protostellar atmosphere feature by late 2020. The temporal evolution of RW Aur As spectral signatures is consistent with a dynamically excited CTTS system forming differentiated Vesta-sized planetesimals in an asymmetric accretion disk and migrating them inward to be destructively accreted. By contrast, nearby, coeval binary companion RW Aur B evinces only (1) a stable WTTS photospheric continuum from 0.7 - 1.3 um + (3) cold CO gas in absorption + (4) stable 1.8-5.0 um thermal disk continuum emission with color temperature approx 1650K.

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arXiv2022

A Near Surface Temperature Model of Arrokoth

A near surface thermal model for Arrokoth is developed based on the recently released $10^5$ facet model of the body. This thermal solution takes into account Arrokoth's surface re-radiation back onto itself. The solution method exploits Arrokoth's periodic orbital character to develop a thermal response using a time-asymptotic solution method, which involves a Fourier transform solution of the heat equation, an approach recently used by others. We display detailed thermal solutions assuming that Arrokoth's near surface material's thermal inertia ${\cal I} = $ 2.5 W/m$^{-2}$K$^{-1}$s$^{1/2}$. We predict that at New Horizons' encounter with Arrokoth its encounter hemisphere surface temperatures were $\sim$ 57-59 K in its polar regions, 30-40 K on its equatorial zones, and 11-13 K for its winter hemisphere. Arrokoth's orbitally averaged temperatures are around 30-35 K in its polar regions, and closer to 40 K near its equatorial zones. Thermal reradiation from the surrounding surface amounts to less than 5\% of the total energy budget, while the total energy ensconced into and exhumed out Arrokoth's interior via thermal conduction over one orbit is about 0.5\% of the total energy budget. As a generalized application of this thermal modeling together with other KBO origins considerations, we favor the interpretation that New Horizons' REX instrument's $29 \pm 5$K brightness temperature measurement is consistent with Arrokoth's near surface material's being made of sub-to-few mm sized tholin-coated amorphous \water ice grains with 1 W/m$^{-2}$K$^{-1}$s$^{1/2}$ $< {\cal I} < $10-20 W/m$^{-2}$K$^{-1}$s$^{1/2}$, and which are characterized by an X-band emissivity in the range 0.9 and 1.

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arXiv2022

Operating Spacecraft Around Comets: Evaluation of the Near-Nucleus Environment

We present a study of the current state of knowledge concerning spacecraft operations and potential hazards while operating near a comet nucleus. Starting from simple calculations comparing the cometary coma environment to benign conditions on Earth, we progress to sophisticated engineering models of spacecraft behavior, and then confront these models with recent spacecraft proximity operations experience. Finally, we make recommendations from lessons learned for future spacecraft missions that enter into orbit around a comet for long-term operations. All of these considerations indicate that, with a proper spacecraft design and operations planning, the near-nucleus environment can be a relatively safe region in which to operate, even for an active short period comet near perihelion with gas production rates as high as 1e29 molecules/s. With gas densities similar to those found in good laboratory vacuums, dust densities similar to Class 100 cleanrooms, dust particle velocities of 10s of m/s, and microgravity forces that permit slow and deliberate operations, the conditions around a comet are generally more benign than a typical day on Mars. Even in strong dust jets near the nucleus surface, dust densities tend to be only a few grains/cm3, about the same as in a typical interior room on Earth. Stochastic forces on a modern spacecraft with tens of square meters of projected surface area can be accounted for using modern Attitude Control Systems to within tens of meters navigation error; surface contamination issues are only important for spacecraft spending months to years within a few kilometers of the nucleus surface; and the issues the Rosetta spacecraft faced, confusion of celestial star trackers by sunlit dust particles flying past the spacecraft, will be addressed using the next generation of star trackers implementing improved transient rejection algorithms.

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arXiv2020

On the Origin and Thermal Stability of Arrokoths and Plutos Ices

We discuss in a thermodynamic, geologically empirical way the long-term nature of the stable majority ices that could be present in Kuiper Belt Object 2014 MU69 after its 4.6 Gyr residence in the EKB as a cold classical object. Considering the stability versus sublimation into vacuum for the suite of ices commonly found on comets, Centaurs, and KBOs at the average ~40K sunlit surface temperature of MU69 over Myr to Gyr, we find only 3 common ices that are truly refractory: HCN, CH3OH, and H2O (in order of increasing stability). NH3 and H2CO ices are marginally stable and may be removed by any positive temperature excursions in the EKB, as produced every 1e8 - 1e9 yrs by nearby supernovae and passing O/B stars. To date the NH team has reported the presence of abundant CH3OH and evidence for H2O on MU69s surface (Lisse et al. 2017, Grundy et al. 2020). NH3 has been searched for, but not found. We predict that future absorption feature detections will be due to an HCN or poly-H2CO based species. Consideration of the conditions present in the EKB region during the formation era of MU69 lead us to infer that it formed "in the dark", in an optically thick mid-plane, unable to see the nascent, variable, highly luminous Young Stellar Object-TTauri Sun, and that KBOs contain HCN and CH3OH ice phases in addition to the H2O ice phases found in their Short Period comet descendants. Finally, when we apply our ice thermal stability analysis to bodies/populations related to MU69, we find that methanol ice may be ubiquitous in the outer solar system; that if Pluto is not a fully differentiated body, then it must have gained its hypervolatile ices from proto-planetary disk sources in the first few Myr of the solar systems existence; and that hypervolatile rich, highly primordial comet C/2016 R2 was placed onto an Oort Cloud orbit on a similar timescale.

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