arXiv subjects

C. Mininni

Publications and source records attributed to C. Mininni.

At least 19 recordsLinked to original sources

arXiv2026

The 10-15 GHz radio continuum survey of the Galactic Plane with SKAO

Star formation emerges from the complex interplay between gravity, turbulence, magnetic fields, and stellar feedback, all of which vary across spatial scales and Galactic environments. Over the past decades, extensive multiwavelength surveys of the Galactic Plane have progressively unveiled this complexity. Far-infrared and sub-millimetre surveys have identified and characterized tens of thousands of star-forming regions, revealing their mass, temperature, and evolutionary stage. Complementary molecular-line surveys, spanning several CO transitions and isotopologues, have mapped the gas kinematics from giant molecular clouds down to sub-parsec structures. The advent of interferometers such as ALMA has revolutionized this field, enabling systematic studies of gas dynamics, fragmentation, and collapse in dense clumps at scales of a few thousand astronomical units. At the same time, mid-infrared and radio surveys at frequencies 0.8 <= nu <= 5 GHz have traced ionised gas associated with the earliest and latest phases of massive-star evolution, including thermal radio jets, hypercompact and ultracompact HII regions, supernova remnants, planetary nebulae, and evolved massive stars. Yet, a uniform, Galaxy-wide census of ionised structures and feedback processes remains elusive. A transformational leap forward requires a sensitive, high-resolution radio survey of the Galactic Plane at 10-15 GHz, capable of resolving physical scales smaller than 0.05 pc at distances up to 20 kpc. This is precisely the goal of the SKA-Mid Galactic Plane survey, which will, with its unprecedented sensitivity, angular resolution, and mapping speed, provide the first panoptic view of ionised gas and stellar feedback across the Milky Way.

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arXiv2026

ALMAGAL IX. The chemical complexity of AG318.9477-00.1960: A line-identification template for ALMAGAL

We present a detailed molecular line analysis of one of the most chemically rich cores in the ALMAGAL sample, the high-mass core~9 in the AG318.9477-00.1960 clump (AG318-c9), located at a heliocentric distance of \sim 10.4\,\rm kpc. We further assessed whether the emission of selected COMs, that is, ethylene glycol ((CH_2OH)_2; EG), glycolaldehyde (CH_2(OH)CHO; GA), and methyl formate (CH_3OCHO; MF), can be used to trace the innermost regions of hot molecular cores (HMCs). We analysed ALMA Band~6 observations (\sim 217-221GHz). Spectral line identification and local thermodynamic equilibrium modelling were performed using the software MADCUBA. We derived the physical parameters, including the column density (N), excitation temperature (Tex), velocity, line width, and molecular abundances relative to H_2, for all detected species. The chemical inventory of AG318-c9 was compared with that of the HMC G31.41+0.31 (G31). In addition, we performed a pixel-by-pixel analysis of EG, GA, and MF to generate spatially resolved N and Tex maps and corresponding radial profiles.

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arXiv2026

The fragmentation properties of massive star-forming regions in 30Dor-10 at 2000 au resolution

The fragmentation properties of parsec-scales clumps play a fundamental role in shaping the dense gas condensations known as cores, the immediate progenitor of stars. The distribution of core masses, the so-called core mass function, is the precursor of the stellar initial mass function, which governs the distribution of stellar masses and, consequently, the evolution of galaxies. The stellar initial mass function is often described by a typical Salpeter-like slope, although deviations toward more top-heavy distributions have been reported in extreme environments, raising questions about its universality and about the physical connection between the two mass functions. To date, there are no observational constraints on the core mass function and its link to the initial mass function beyond the Milky Way. Here we present a study of the fragmentation properties and the measurement of the core mass function in an external galaxy, focusing on the 30Dor-10 region in the Large Magellanic Cloud, using high resolution observations that probe spatial scales down to 2000 au. Robust statistical analysis demonstrates that the core mass function is consistent with a Salpeter-like slope and suggests that variations in the stellar mass distribution arise from evolutionary processes rather than from initial fragmentation.

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arXiv2026

ALMAGAL VIII. Early phases of triggered star formation in source AG286.0716$-$1.8229

Several theoretical and observational studies have shown that new waves of triggered star-formation can be induced by the feedback from newly formed massive protostars, due to the expansion of H II regions. We used the millimeter dust continuum data of the ALMAGAL survey and the Anderson et al. 2014 catalog of H II regions and selected one ALMAGAL source for ALMA follow-up observations. In fact, in source AG286.0716$-$1.8229 six cores were detected at a resolution of $\sim7600$ au, but only two at a higher resolution. The 4 cores not detected at higher resolution are prestellar core candidates. We used archival data from the SMGPS and RACS to confirm whether an H II region is present in the field. We observed the source with with ALMA in Band 4, covering the emission of DCO$^+$ (2$-$1), N$_2$D$^+$ (2$-$1), DCN (2$-$1), and CH$_3$CCH (9$-$8), to estimates whether these cores are in an early phase of the star-formation process. The new Band 4 continuum image revealed three cores outside of the ALMAGAL field of view, for a total of 9 cores in the region, 8 of which are located along an arch of radius $\sim0.75$ pc. We have derived a spectral index between -0.14 and -0.4, in the frequency range of 0.8-1.6 GHz for the candidate H II region, which is consistent with optically thin free-free emission. Using plausible temperature ranges, based on the information from chemical tracers and the dust continuum, we derived mass ranges for the cores ($\sim2-16\,$M$_{\odot}$) and ranges for the virial parameter ($\sim0.3-5$). All the cores along the arch have virial parameters $\lesssim$2, with only one exception. Comparing the typical separation and mass of the cores with those expected in the case of the collect and collapse scenario and with the thermal Jean length and mass, the best agreement is found with the characteristic scales in the case of triggered star formation.

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arXiv2026

The GUAPOS project -- VII: Physical structure and molecular environment of the G31.41+0.31 HII region

Ionised regions around OB-type stars are formed at an early stage of their evolution and are important to investigate the formation process of these objects. However, so far only few observations of their physical structure and interaction with the parental molecular cloud have been made. The high resolution and sensitivity of new instruments such as ALMA and the upgraded VLA allow us to fill this gap in our knowledge. We investigate the well known core-halo ultracompact HII region G31.41+0.31 and the surrounding molecular clump with the aim to determine the density and temperature of both the ionised and neutral gas, and possibly obtain a 3D picture of their spacial distribution. We take advantage of the full-band frequency coverage at 3 mm obtained with ALMA for the GUAPOS project to image the emission of a plethora of hydrogen recombination lines towards the G31.41+0.31 HII region as well as several molecular transitions which are tracers of medium-density ($\sim$$10^4$--$10^6$ cm$^{-3}$) gas. The line data are complemented by continuum measurements obtained with the VLA at 1 cm and 7 mm. By fitting these lines also using a model that takes into account non-LTE effects we can investigate the density and temperature structure and the velocity field of the region. Our findings, based on a model fit accounting for non-LTE effects, indicate that the electron temperature of the HII region is mostly spanning a range between 5000 and 6000 K, while the density varies between 2500 and 7500 cm$^{-3}$. All in all, the distribution of these parameters as well as the corresponding velocity field hint at a cometary shaped HII region expanding away from the observer to the NW. The molecular gas appears to be still infalling towards the peak of the UC HII region, and its density and temperature are consistent with pressure confinement of the ionised gas to the SE.

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arXiv2025

ALMAGAL VI. The spatial distribution of dense cores during the evolution of cluster-forming massive clump

High-mass stars and star clusters form from the fragmentation of massive dense clumps driven by gravity, turbulence, and magnetic fields. The ALMAGAL project observed $\sim1000$ clumps at $\sim$1000\,au resolution, enabling a statistically significant characterization of this process across a large range of clump physical parameters and evolutionary stages. In this work, we investigated the spatial distribution of dense cores in the 514 massive, potentially cluster-forming, clumps hosting at least 4 cores, to trace fragmentation's initial conditions and early evolution. We used quantitative descriptors, evaluated against the clump bolometric luminosity-to-mass ratio as an indicator of evolution. Core separations were measured with the minimum spanning tree method (MST) and compared with the Jeans gravitational fragmentation theory. We used the $Q$ parameter and the mass segregation ratio, $\Lambda_{MSR}$, to evaluate whether cores have specific arrangements or differences depending on their masses. ALMAGAL cores are usually arranged in elliptical groups with an axis ratio $e\sim2.2$, but $e\geq$5 is also observed. A single characteristic core separation per clump is found in $\sim76$% of cases, but signatures of multiple fragmentation lengths not rare. Typical core separations are compatible with the clump-averaged thermal Jeans length, $\lambda^{th}_{J}$, though a population, typical of low-fragmented/young clumps, has wider separations with $l\approx3\times\lambda^{th}_{J}$. The core separation decreases on average from $l\sim22000$ au in younger systems to $l\sim7000$ au in more evolved ones. Cores are typically distributed in fractal-type subclusters, with centrally concentrated patterns appearing only at later stages, but without a progressive evolutionary transition. Finally, mass segregation is found in 110 systems, with its occurrence increasing with evolution.

astro-ph.GA↗

arXiv2025

ALMAGAL V. Relations between the core populations and the parent clump physical properties

Context. The fragmentation of massive molecular clumps into smaller, potentially star-forming cores plays a key role in the processes of high-mass star formation. The ALMAGAL project offers high-resolution data to investigate these processes across various evolutionary stages in the Galactic plane. Aims. This study aims at correlating the fragmentation properties of massive clumps, obtained from ALMA observations, with their global physical parameters (e.g., mass, surface density, and temperature) and evolutionary indicators (such as luminosity-to-mass ratio and bolometric temperature) obtained from Herschel observations. It seeks to assess whether the cores evolve in number and mass in tandem with their host clumps, and to determine the possible factors influencing the formation of massive cores (M > 24M_\odot). Methods. We analyzed the masses of 6348 fragments, estimated from 1.4 mm continuum data for 1007 ALMAGAL clumps. Leveraging this unprecedentedly large data set, we evaluated statistical relationships between clump parameters, estimated over about 0.1 pc scales, and fragment properties, corresponding to scales of a few 1000 au, while accounting for potential biases related to distance and observational resolution. Our results were further compared with predictions from numerical simulations. Results. The fragmentation level correlates preferentially with clump surface density, supporting a scenario of density-driven fragmentation, whereas it does not show any clear dependence on total clump mass. Both the mass of the most massive core and the core formation efficiency show a broad range and increase on average by an order of magnitude in the intervals spanned by evolutionary indicators such as clump dust temperature and the luminosity-to-mass ratio. This suggests that core growth continues throughout the clump evolution, favoring clump-fed over core-fed theoretical scenarios.

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arXiv2025

The GUAPOS project. VI: the chemical inventory of shocked gas

The study of the chemical composition of star-forming regions is key to understanding the chemical ingredients available during the formation of planetary systems. Because the chemical inventory of interstellar dust grains in prestellar phases might be altered by protostellar warming, an alternative to inferring the chemical composition of the grains might be to observe regions that are affected by shocks associated with molecular outflows. These shocks can desorb the molecules and might produce less chemical processing because the timescales are shorter. We present a detailed study of the chemical reservoir of a shocked region located in the G31.41+0.31 protocluster using data from the G31.41+0.31 Unbiased ALMA sPectral Observational Survey (GUAPOS). We report the detection of 30 molecular species (plus 18 isotopologs). We compared the molecular ratios in the shocked region with those derived toward the hot core of G31.41+0.31. They are poorly correlated, with the exception of N-bearing species. Our results confirm observationally that a different level of chemical alteration is present in hot cores and in shocks. While the former likely alter the molecular ratios by thermal processing during longer timescales, the latter might represent freshly desorbed material that constitutes a better proxy of the composition of the ice mantle. The similarity of the molecular ratios of the N-bearing species in the G31.41+0.31 shock and the hot core suggests that these species are predominantly formed at early evolutionary stages. Interestingly, the abundances in the G31.41+0.31 shock are better correlated with other shock-dominated regions (two protostellar outflows and a molecular cloud in the Galactic center). This suggests that gas-phase chemistry after shock-induced ejection from grains is negligible and that the composition of the ice mantle is similar regardless of the Galactic environment.

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arXiv2025

CHemical Evolution in MassIve star-forming COres (CHEMICO). I. Evolution of the temperature structure

Increasing evidence shows that most stars in the Milky Way, including the Sun, are born in star-forming regions containing also high-mass stars, but due to both observational and theoretical challenges, our comprehension of their chemical evolution is far less clear than that of their low-mass counterparts. We present the project "CHemical Evolution of MassIve star-froming COres" (CHEMICO). The project aims at investigating any aspect of the chemical evolution of high-mass star-forming cores by observing representatives of the three main evolutionary categories: high-mass starless cores, high-mass protostellar objects, and ultra-compact HII regions. We carried out an unbiased spectral line survey of the entire bandwidth at 3, 2, and 1.2 mm with the 30m telescope of the Insitut de Radioastronomie millimetrique towards three targets that represent the three evolutionary stages. The number of lines and species detected increases with evolution. In this first work, we derive the temperature structure of the targets through the analysis of the carbon-bearing species C2H, c-C3H, c-C3H2, C4H, CH3CCH, HC3N, CH3CN, and HC5N. The excitation temperature, Tex, increases with evolution in each species, although not in the same way. Hydrocarbons tend to be associated with the smallest Tex values and enhancements with evolution, while cyanides are associated with the highest Tex values and enhancements. In each target, the higher the number of atoms in the molecule, the higher Tex tends to be. The temperature structure evolves from a cold, uniform envelope traced by simple hydrocarbons in the high-mass starless core stage, to a more stratified envelope in the protostellar stage (made by a hot core, a shell with intermediate Tex, and a larger cold envelope), to finally a hot core surrounded only by a cold envelope in the Ultracompact HII stage.

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arXiv2025

PRIMAGAL: a PRIMAger Galactic Plane Far-IR polarization survey to quantify the magnetic fields' role in the formation and evolution of large star-forming filaments

The PRIMAger instrument on board the proposed PRIMA satellite will offer the unprecedented capability to obtain hundreds of square-degree maps in polarised emission at sub-arcminute resolution in four Far-IR bands. This will open a unique window to study magnetic fields in our Galaxy. PRIMAGAL, a proposed survey of polarized dust emission in the Milky Way Galactic Plane will determine the strength and orientation of magnetic fields towards several thousands of filamentary clouds in a wide range of linear masses, column densities, evolution, star-formation rates and efficiencies, and Galactic environment. This survey will address for the first time in a statistically significant fashion the role that magnetic fields play in shaping the formation, evolution and fragmentation of dense ISM filaments down to a minimum scale of 0.4 pc up to 8 kpc distance from the Sun. A 4-band polarization survey of the Galactic Plane with |b|<1{\deg} (a total of 720 sq. deg.) can be executed by PRIMAger in about 1200 hours including all mapping and instrument overhead.

astro-ph.GA↗

arXiv2025

ALMAGAL IV. Morphological comparison of molecular and thermal dust emission using the histogram of oriented gradients (HOG) method

The study of molecular line emission is crucial to unveil the kinematics and the physical conditions of gas in star-forming regions. Our aim is to quantify the reliability of using individual molecular transitions to derive physical properties of the bulk of the H2 gas, looking at morphological correlations in their overall integrated molecular line emission with the cold dust. For this study we selected transitions of H2CO, CH$_3$OH, DCN, HC$_3$N, CH$_3$CN, CH$_3$OCHO, SO, and SiO and compared them with the 1.38 mm dust continuum emission at different spatial scales in the ALMAGAL sample, that observed a total of 1013 targets covering all evolutionary stages of the high-mass star-formation process and different conditions of clump fragmentation. We used the method of the histogram of oriented gradients (HOG) implemented in the tool astroHOG to compare the morphology of integrated line emission with maps of the 1.38 mm dust continuum emission. Moreover, we calculated the Spearman's correlation coefficient, and compared it with our astroHOG results. Only H$_2$CO, CH$_3$OH, and SO show emission on spatial scales comparable with the diffuse continuum emission. However, from the HOG method, the median correlation of the emission of each of these species with the continuum is only $\sim$24-29%. In comparison with the dense fragments these molecular species still have low values of correlation. On the other hand DCN, HC$_3$N, CH$_3$CN, and CH$_3$OCHO show a good correlation with the dense dust fragments, above 60%. The worst correlation is seen with SiO, both with the extended continuum emission and with compact sources. From the comparison of the results of the HOG method and the Spearman's correlation coefficient, the HOG method gives much more reliable results than the intensity-based coefficient in estimating the level of similarity of the emission morphology.

astro-ph.GA↗

arXiv2025

Anisotropy in the carbon monoxide (CO) line emission across the Milky Way's disk

We present a study of the $^{12}$CO(1-0) line emission anisotropy across the Milky Way's disk to examine the effect of stellar feedback and Galactic dynamics on the distribution of the dense interstellar medium. The Hessian matrix method is used to characterize the CO line emission distribution and identify the preferential orientation across line-of-sight velocity channels in the Dame et al. 2001 composite Galactic plane survey, which covers the Galactic latitude range $|b|<5^{\circ}$. The structures sampled with this tracer are predominantly parallel to the Galactic plane toward the inner Galaxy, in clear contrast with the predominantly perpendicular orientation of the structures traced by neutral atomic hydrogen (HI) emission toward the same regions. The analysis of the Galactic plane portions sampled at higher angular resolution with other surveys reveals that the alignment with the Galactic plane is also prevalent at smaller scales. We find no preferential orientation in the CO emission toward the outer Galaxy, in contrast with the preferential alignment with the Galactic plane displayed by HI in that portion of the Milky Way. We interpret these results as the combined effect of the decrease in mid-plane pressure with increasing Galactocentric radius and SN feedback lifting diffuse gas more efficiently than dense gas off the Galactic plane.

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arXiv2025

ALMAGAL I. The ALMA evolutionary study of high-mass protocluster formation in the Galaxy. Presentation of the survey and early results

Fundamental questions about the physics responsible for fragmenting molecular parsec-scale clumps into cores of ~1000 au are still open, that only a statistically significant investigation with ALMA is able to address: what are the dominant agents that determine the core demographics, mass, and spatial distribution as a function of the physical properties of the hosting clumps, their evolutionary stage and the different Galactic environments in which they reside? To what extent extent is fragmentation driven by clumps dynamics or mass transport in filaments? With ALMAGAL we observed the 1.38 mm continuum and lines toward more than 1000 dense clumps in our Galaxy, with M>500M_sun, surface density > 0.1 g/cm2 and d<7.5 kpc. The ACA and two 12-m array setups were used to deliver a minimum resolution of ~1000 au over the entire sample distance range. The sample covers all evolutionary stages from infrared dark clouds (IRDCs) to HII regions from the tip of the Galactic bar to the outskirts of the Galaxy. The spectral setup includes several molecular lines to trace the multiscale physics and dynamics of gas, notably CH3CN, H2CO, SiO, CH3OH, DCN, HC3N, SO etc. We present an initial overview of the observations and the early science product and results, with a first characterization of the morphological properties of the continuum emission. We use "perimeter-versus-area" and convex hull-versus-area metrics to classify the different morphologies. More extended and morphologically complex shapes are found toward clumps that are relatively more evolved and have higher surface densities.

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arXiv2025

ALMAGAL II. The ALMA evolutionary study of high-mass protocluster formation in the Galaxy. ALMA data processing and pipeline

The ALMAGAL Large Program has observed 1017 high-mass star-forming regions distributed throughout the Galaxy, sampling different evolutionary stages and environmental conditions. In this work, we present the acquisition and processing of the ALMAGAL data. The main goal is to set up a robust pipeline that generates science-ready products, with a good and uniform quality across the whole sample. ALMAGAL observations were performed with the Atacama Large Millimeter/submillimeter Array (ALMA). Each field was observed in three different telescope arrays, being sensitive to spatial scales ranging from 1000 au up to 0.1 pc. The spectral setup allows sensitive imaging of the continuum emission at 219 GHz, and it covers multiple molecular spectral lines observed in four different spectral windows that span about 4 GHz in frequency coverage. We have designed a Python-based processing workflow to calibrate and image these observational data. This ALMAGAL pipeline includes an improved continuum determination, suited for line-rich sources; an automatic self-calibration process that improves the dynamical range of the final images; and the combination of data from different telescope arrays to produce science-ready, fully combined images. The fully combined products have spatial resolutions in the range 800-2000 au, and mass sensitivities in the range 0.02-0.07 Mo. We also present a first analysis of the spectral line information included in the ALMAGAL setup, and its potential for future scientific studies. As an example, specific spectral lines at 1000 au scales resolve the presence of multiple outflows in clusters and will help us to search for disk candidates around massive protostars. Moreover, the broad frequency bands provide information on the chemical richness of the different cluster members, which can be used to study the chemical evolution during the formation process of star clusters.

astro-ph.GA↗

arXiv2025

ALMAGAL III. Compact source catalog: Fragmentation statistics and physical evolution of the core population

The mechanisms behind the fragmentation of high-mass dense clumps into compact star-forming cores are fundamental topics in current astrophysical research. The ALMAGAL survey provides the opportunity to study this process at an unprecedented level of detail and statistical significance, featuring high-angular resolution $1.38$ mm ALMA observations of $1013$ massive dense clumps at various Galactic locations. These clumps cover a wide range of distances, masses, surface densities, and evolutionary stages. Here, we present the catalog of compact sources obtained with the CuTEx algorithm from continuum images of the full ALMAGAL clump sample combining ACA-$7$m and $12$m ALMA arrays, reaching a uniform high median spatial resolution of $\sim1400$ au. We discuss the fragmentation properties and the estimated physical parameters of the core population. The ALMAGAL compact source catalog includes $6348$ cores detected in $844$ clumps ($83\%$ of the total), with a number of cores per clump between $1$ and $49$ (median of $5$). The estimated core diameters are mostly within $\sim800-3000$ au (median of $1700$ au). We obtained core masses from $0.002$ to $345\,\mathrm{M_{\odot}}$. We evaluated the variation in the core mass function (CMF) with evolution as traced by the clump $L/M$, finding a clear, robust shift and change in slope among CMFs within subsamples at different stages. This finding suggests that the CMF shape is not constant throughout the star formation process, but rather it builds (and flattens) with evolution, with higher core masses reached at later stages. We found that all cores within a clump grow in mass on average with evolution, and the number of cores increases with the core masses. Our results favor a clump-fed scenario for high-mass star formation, in which cores form as low-mass seeds, and then gain mass while further fragmentation occurs in the clump.

astro-ph.GA↗

arXiv2024

Dynamical Accretion Flows -- ALMAGAL: Flows along filamentary structures in high-mass star-forming clusters

We use data from the ALMA Evolutionary Study of High Mass Protocluster Formation in the Galaxy (ALMAGAL) survey to study 100 ALMAGAL regions at $\sim$ 1 arsecond resolution located between $\sim$ 2 and 6 kpc distance. Using ALMAGAL $\sim$ 1.3mm line and continuum data we estimate flow rates onto individual cores. We focus specifically on flow rates along filamentary structures associated with these cores. Our primary analysis is centered around position velocity cuts in H$_2$CO (3$_{0,3}$ - 2$_{0,2}$) which allow us to measure the velocity fields, surrounding these cores. Combining this work with column density estimates we derive the flow rates along the extended filamentary structures associated with cores in these regions. We select a sample of 100 ALMAGAL regions covering four evolutionary stages from quiescent to protostellar, Young Stellar Objects (YSOs), and HII regions (25 each). Using dendrogram and line analysis, we identify a final sample of 182 cores in 87 regions. In this paper, we present 728 flow rates for our sample (4 per core), analysed in the context of evolutionary stage, distance from the core, and core mass. On average, for the whole sample, we derive flow rates on the order of $\sim$10$^{-4}$ M$_{sun}$yr$^{-1}$ with estimated uncertainties of $\pm$50%. We see increasing differences in the values among evolutionary stages, most notably between the less evolved (quiescent/protostellar) and more evolved (YSO/HII region) sources. We also see an increasing trend as we move further away from the centre of these cores. We also find a clear relationship between the flow rates and core masses $\sim$M$^{2/3}$ which is in line with the result expected from the tidal-lobe accretion mechanism. Overall, we see increasing trends in the relationships between the flow rate and the three investigated parameters; evolutionary stage, distance from the core, and core mass.

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arXiv2024

The GUAPOS project. V: The chemical ingredients of a massive stellar protocluster in the making

Most stars, including the Sun, are born in rich stellar clusters containing massive stars. Therefore, the study of the chemical reservoir of massive star-forming regions is crucial to understand the basic chemical ingredients available at the dawn of planetary systems. We present a detailed study of the molecular inventory of the hot molecular core G31.41+0.31 from the project GUAPOS (G31.41+0.31 Unbiased ALMA sPectral Observational Survey). We analyze 34 species for the first time plus 20 species analyzed in previous GUAPOS works, including oxygen, nitrogen, sulfur, phosphorus, and chlorine species. We compare the abundances derived in G31.41+0.31 with those observed in other chemically-rich sources that represent the initial and last stages of the formation of stars and planets: the hot corino in the Solar-like protostar IRAS 16293-2422 B, and the comets 67P/Churyumov-Gerasimenko and 46P/Wirtanen. The comparative analysis reveals that the chemical feedstock of the two star-forming regions are similar. The abundances of oxygen- and nitrogen-bearing molecules exhibit a good correlation for all pair of sources, including the two comets, suggesting a chemical heritage of these species during the process of star formation, and hence an early phase formation of the molecules. However, sulfur- and phosphorus-bearing species present worse correlations, being more abundant in comets. This suggests that while sulfur- and phosphorus-bearing species are predominantly trapped on the surface of icy grains in the hot close surroundings of protostars, they could be more easily released into gas phase in comets, allowing their cosmic abundances to be almost recovered.

astro-ph.GA↗

arXiv2023

The GUAPOS project: G31.41+0.31 Unbiased ALMA sPectral Observational Survey. IV. Phosphorus-bearing molecules and their relation with shock tracers

The astrochemistry of the important biogenic element phosphorus (P) is still poorly understood, but observational evidence indicates that P-bearing molecules are likely associated with shocks. We study P-bearing molecules, as well as some shock tracers, towards one of the chemically richest hot molecular core, G31.41+0.31, in the framework of the project "G31.41+0.31 Unbiased ALMA sPectral Observational Survey" (GUAPOS), observed with the Atacama Large Millimeter Array (ALMA). We have observed the molecules PN, PO, SO, SO2, SiO, and SiS, through their rotational lines in the spectral range 84.05-115.91 GHz, covered by the GUAPOS project. PN is clearly detected while PO is tentatively detected. The PN emission arises from two regions southwest of the hot core peak, "1" and "2", and is undetected or tentatively detected towards the hot core peak. the PN and SiO lines are very similar both in spatial emission morphology and spectral shape. Region "1" is in part overlapping with the hot core and it is warmer than region "2", which is well separated from the hot core and located along the outflows identified in previous studies. The column density ratio SiO/PN remains constant in regions "1" and "2", while SO/PN, SiS/PN, and SO2/PN decrease by about an order of magnitude from region "1" to region "2", indicating that SiO and PN have a common origin even in regions with different physical conditions. Our study firmly confirms previous observational evidence that PN emission is tightly associated with SiO and it is likely a product of shock-chemistry, as the lack of a clear detection of PN towards the hot-core allows to rule out relevant formation pathways in hot gas. We propose the PN emitting region "2" as a new astrophysical laboratory for shock-chemistry studies

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