arXiv subjects

C. Paillard

Publications and source records attributed to C. Paillard.

4 recordsLinked to original sources

arXiv2026

Deformation-Potential-Driven Photostriction in Layered Ferroelectrics

The coupling between electronic excitations and lattice deformation in van der Waals ferroelectrics is governed by a competition between the electron deformation potential and the inverse piezoelectric effect. While theory predicts that piezoelectric screening should drive a polar-axis contraction in monolayer group-IV monochalcogenides, we demonstrate that in multilayer SnS, the deformation potential provides the dominant contribution, driving a polar-axis expansion even within ferroelectric domains. By correlating polarization-resolved second-harmonic generation microscopy with ultrafast reflectance spectroscopy and first-principles calculations, we resolve the anisotropic lattice response and disentangle intrinsic photostrictive strain from extrinsic thin-film interference artifacts. These results establish a microscopic hierarchy of photostrictive mechanisms and position stacking-engineered SnS as a platform for ultrafast optomechanical transduction.

cond-mat.mtrl-sci↗

arXiv2024

Superorders and acoustic modes folding in BiFeO$_3$/LaFeO$_3$ superlattices

Superlattices are materials created by the alternating growth of two chemically different materials. The direct consequence of creating a superlattice is the folding of the Brillouin zone which gives rise to additional electronic bands and phonon modes. This has been successfully exploited to achieve new transport and optical properties in semiconductor superlattices, for example. Here, we show that multiferroic BiFeO$_3$/LaFeO$_3$ superlattices are more than just periodic chemical stacking. Using transmission electron microscopy, X-ray diffraction and first-principles calculations, we demonstrate the existence of a new order of FeO$_6$ octahedra, with a period along the growth direction about twice that of the chemical supercell, i.e. a superorder. The effect of this new structural order on the lattice dynamics is studied with ultrafast optical pump-probe experiments. While a mode at 1.2 THz is attributed solely to the chemical modulation of the superlattice, the existence of another 0.7 THz mode seems to be explained only by a double Brillouin zone folding in agreement with the structural description. Our work shows that multiferroic BiFeO$_3$/LaFeO$_3$ superlattices can be used to tune the spectrum of coherent THz phonons, and potentially that of magnons or electromagnons.

cond-mat.mtrl-sci↗

arXiv2017

Photoferroelectric oxides

Giant photovoltaic effect due to bulk photovoltaic effect observed in multiferroic BiFeO3 thin films has triggered a renewed interest on photoferroelectric materials for photovoltaic applications. Tremendous advance has been done to improve power conversion efficiency (up to up to 8.1%) in photoferroelectrics via absorption increase using narrow bandgap ferroelectrics. Other strategies, as it is the more efficient use of ferroelectric internal electric field, are ongoing. Moreover, as a by-product, several progress have been also achieved on photostriction that is the photo-induced deformation phenomenon. Here, we review ongoing and promising routes to improve ferroelectrics photoresponse.

cond-mat.mtrl-sci↗

arXiv2017

Strain and Magnetic Field Induced Spin-Structure Transitions in Multiferroic BiFeO3

The magnetic-field-dependent spin ordering of strained BiFeO3 films is determined using nuclear resonant scattering and Raman spectroscopy. The critical field required to destroy the cycloidal modulation of the Fe spins is found to be significantly lower than in the bulk, with appealing implications for field-controlled spintronic and magnonic devices.

cond-mat.mtrl-sci↗