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C. Sulkowski

Publications and source records attributed to C. Sulkowski.

3 recordsLinked to original sources

The effect of Fe and Ru substitution for Ni on the thermopower in MgCNi_3

The intermetallic perovskite MgCNi3 is a superconductor with a Tc=7 K. Substitution of Fe and Ru for Ni decreases Tc monotonically as the doping concentration is increased. Here we report thermopower measurements, S(T), on MgCNi3, MgCNi3-xFex and MgCNi3-xRux. For MgCNi3, the thermopower is negative, - 12.5 mikroV/K, at 300 K. The absolute value of S decreases as x increases in MgCNi3-xFex and MgCNi3-xRux. The sign of S changes from negative to positive at low temperatures for values of x > 0.01. These data show that the carriers in MgCNi3 are electrons, and by increasing x and decreasing temperature, the participation of hole carriers clearly increases. The influence of the magnetic moments of the Fe atoms on the thermopower is not visible.

cond-mat.supr-con

On the effect of heterovalent substitutions in ruthenocuprates

We discuss the properties of superconducting derivatives of the RuSr2GdCu2O8 (1212-type) ruthenocuprate, for which heterovalent doping has been achieved through partial substitution of Cu ions into the RuO2 planes (Ru1-xSr2GdCu2+xO8-d, 0 Ru doping achieved in these phases is found to decrease the temperature for magnetic ordering as well the volume fraction of the magnetic phase.

cond-mat.supr-con

Magnetism and superconductivity in Ru(1-x)Sr2RECu(2+x)O(8-d) (RE=Gd, Eu) and RuSr2Gd(1-y)Ce(y)Cu2O8 compounds

We discuss the properties of new superconducting compositions of Ru(1-x)Sr2RECu(2+x)O(8-d) (RE=Gd, Eu) ruthenocuprates that were synthesized at 600 atm. of oxygen at 1080 C. By changing ratio between the Ru and Cu, the temperature of superconducting transition (Tc) raises up to Tc max=72 K for x=0.3, 0.4. The hole doping achieved along the series increases with Cu->Ru substitution. For x different than x=0, Tc can be subsequently tuned between Tc max and 0 K by changing oxygen content in the compounds. The magnetic characteristics of the RE=Gd and Eu based compounds are interpreted as indicative of constrained dimensionality of the superconducting phase. Muon spin rotation experiments reveal the presence of the magnetic transitions at low temperatures (Tm=14-2 K for x=0.1-0.4) that can originate in the response of Ru/Cu sublattices. RuSr2Gd(1-y)Ce(1-y)Cu2O8 (0 Gd substitution. Properties of these two series allow us to propose phase diagram for 1212-type ruthenocuprates that links their properties to the hole doping achieved in the systems. Non-superconducting single-phase RuSr2GdCu2O8 and RuSr2EuCu2O8 are reported and discussed in the context of the properties of substituted compounds.

cond-mat.supr-con