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C. Van den Broeck

Publications and source records attributed to C. Van den Broeck.

At least 19 recordsLinked to original sources
arXiv2017

Stochastic thermodynamics for Ising chain and symmetric exclusion process

We verify the finite time fluctuation theorem for a linear Ising chain at its ends in contact with heat reservoirs. Analytic results are derived for a chain consisting of only two spins. The system can be mapped onto a model for particle transport, namely the symmetric exclusion process, in contact with thermal and particle reservoirs. We modify the symmetric exclusion process to represent a thermal engine and reproduce universal features of the efficiency at maximum power.

cond-mat.stat-mech↗
arXiv2015

Stochastic thermodynamics for kinetic equations

Stochastic thermodynamics is formulated for variables that are odd under time reversal. The invariance under spatial rotation of the collision rates due to the isotropy of the heat bath is shown to be a crucial ingredient. An alternative detailed fluctuation theorem is derived, expressed solely in terms of forward statistics. It is illustrated for a linear kinetic equation with kangaroo rates.

cond-mat.stat-mech↗
arXiv2015

Echo states for detailed fluctuation theorems

Detailed fluctuation theorems are statements about the probability distribution for the stochastic entropy production along a trajectory. It involves the consideration of a suitably transformed dynamics, such as the time reversed, the adjoint, or a combination of these. We identify specific, typically unique, initial conditions, called echo states, for which the final probability distribution of the transformed dynamics reproduces the initial distribution. In this case the detailed fluctuation theorems relate the stochastic entropy production of the direct process to that of the transformed one. We illustrate our results by an explicit analytical calculation and numerical simulations for a modulated two-state quantum dot.

cond-mat.stat-mech↗
arXiv2014

Adsorption and desorption in confined geometries: a discrete hopping model

We study the adsorption and desorption kinetics of interacting particles moving on a one-dimensional lattice. Confinement is introduced by limiting the number of particles on a lattice site. Adsorption and desorption are found to proceed at different rates, and are strongly influenced by the concentration-dependent transport diffusion. Analytical solutions for the transport and self-diffusion are given for systems of length 1 and 2 and for a zero-range process. In the last situation the self- and transport diffusion can be calculated analytically for any length.

cond-mat.stat-mech↗
arXiv2014

Diffusion of interacting particles in discrete geometries: equilibrium and dynamical properties

We expand on a recent study of a lattice model of interacting particles [Phys. Rev. Lett. 111, 110601 (2013)]. The adsorption isotherm and equilibrium fluctuations in particle number are discussed as a function of the interaction. Their behavior is similar to that of interacting particles in porous materials. Different expressions for the particle jump rates are derived from transition state theory. Which expression should be used depends on the strength of the inter-particle interactions. Analytical expressions for the self- and transport diffusion are derived when correlations, caused by memory effects in the environment, are neglected. The diffusive behavior is studied numerically with kinetic Monte Carlo (kMC) simulations, which reproduces the diffusion including correlations. The effect of correlations is studied by comparing the analytical expressions with the kMC simulations. It is found that the Maxwell-Stefan diffusion can exceed the self-diffusion. To our knowledge, this is the first time this is observed. The diffusive behavior in one-dimensional and higher dimensional systems is qualitatively the same, with the effect of correlations decreasing for increasing dimension. The length dependence of both the self- and transport diffusion is studied for one-dimensional systems. For long lengths the self-diffusion shows a one over length dependence. Finally, we discuss when agreement with experiments and simulations can be expected. The assumption that particles in different cavities do not interact is expected to hold quantitatively at low and medium particle concentrations, if the particles are not strongly interacting.

cond-mat.stat-mech↗
arXiv2013

Diffusion of interacting particles in discrete geometries

We evaluate the self-diffusion and transport diffusion of interacting particles in a discrete geometry consisting of a linear chain of cavities, with interactions within a cavity described by a free-energy function. Exact analytical expressions are obtained in the absence of correlations, showing that the self-diffusion can exceed the transport diffusion if the free-energy function is concave. The effect of correlations is elucidated by comparison with numerical results. Quantitative agreement is obtained with recent experimental data for diffusion in a nanoporous zeolitic imidazolate framework material, ZIF-8.

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arXiv2008

Intrinsic Ratchets

We present a generic formalism to describe Brownian motion of particles with intrinsic asymmetry and give predictions for the drift behavior in unbiased time-dependent force fields. Our findings are supported by molecular dynamics simulations.

cond-mat.stat-mech↗
arXiv2008

Lower bounds on dissipation upon coarse graining

By different coarse-graining procedures we derive lower bounds on the total mean work dissipated in Brownian systems driven out of equilibrium. With several analytically solvable examples we illustrate how, when, and where the information on the dissipation is captured.

cond-mat.stat-mech↗
arXiv2008

The "footprints'' of irreversibility

We reformulate the result for the entropy production given in Phys. Rev. Lett. 98, 080602 (2007) in terms of the relative entropy of microscopic trajectories. By a combination with the Crook's theorem, we identify the path variables that are sufficient to fully identify irreversibility. We show that work saturates the relative entropy, and derive the entropy production for stochastic descriptions.

cond-mat.stat-mech↗
arXiv2008

Chiral Brownian rotor and heat pump

This paper provides some comprehensive calculations supporting the results in Phys. Rev. Lett. 100, 130601 (2008) [arXiv:0711.1758].

cond-mat.stat-mech↗
arXiv2008

Rectifying the thermal Brownian motion of three-dimensional asymmetric objects

We extend the analysis of a thermal Brownian motor reported in Phys. Rev. Lett. 93, 090601 (2004) by C. Van den Broeck, R. Kawai, and P. Meurs to a three-dimensional configuration. We calculate the friction coefficient, diffusion coefficient, and drift velocity as a function of shape and present estimates based on physically realistic parameter values.

cond-mat.stat-mech↗
arXiv2007

Chiral Brownian heat pump

We present the exact analysis of a chiral Brownian motor and heat pump. Optimization of the construction predicts, for a nanoscale device, frequencies of the order of kHz and cooling rates of the order of femtojoule per second.

cond-mat.stat-mech↗
arXiv2007

Bounding dissipation in stochastic models

We generalize to stochastic dynamics the exact expression for average dissipation along an arbitrary non-equilibrium process, given in Phys. Rev. Lett. 98, 080602 (2007). We then derive lower bounds by various coarse-graining procedures and illustrate how, when and where the information on the dissipation is captured in models of over- and underdamped Brownian particles.

cond-mat.stat-mech↗
arXiv2007

Continuous and discontinuous phase transitions and partial synchronization in stochastic three-state oscillators

We investigate both continuous (second-order) and discontinuous (first-order) transitions to macroscopic synchronization within a single class of discrete, stochastic (globally) phase-coupled oscillators. We provide analytical and numerical evidence that the continuity of the transition depends on the coupling coefficients and, in some nonuniform populations, on the degree of quenched disorder. Hence, in a relatively simple setting this class of models exhibits the qualitative behaviors characteristic of a variety of considerably more complicated models. In addition, we study the microscopic basis of synchronization above threshold and detail the counterintuitive subtleties relating measurements of time averaged frequencies and mean field oscillations. Most notably, we observe a state of suprathreshold partial synchronization in which time-averaged frequency measurements from individual oscillators do not correspond to the frequency of macroscopic oscillations observed in the population.

cond-mat.stat-mech↗
arXiv2007

Comment on "Irreversibility and Fluctuation Theorem in Stationary Time Series"

In their recent paper [Phys. Rev. Lett. 98, 094101 (2007)], A. Porporato et al. studied the irreversibility and fluctuation theorem for stationary time series. In this comment, we point out that the fluctuation theorem is in fact the trivial outcome of a symmetry operation, and hence its physical contect is less convincing.

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