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Camille L. Latune

Publications and source records attributed to Camille L. Latune.

7 recordsLinked to original sources

Entropy production versus memory effects in two-level open quantum systems

We compare several definitions of entropy production rate introduced in the literature from a large variety of situations and motivations, and then analyze their relations with memory effects. Considering a relevant experimental example of a qubit interacting with a single bosonic mode playing the role of a finite bath, we show that all definitions of entropy production coincide at weak coupling. In a stronger coupling regime, significant discrepancies emerge between the different entropy production rates, although some similarities in the overall behaviour remain. However, surprisingly, two of these definitions --one based on local quantities of the system and the other on non-local quantities-- coincide exactly, even in the case of strong coupling. Finally, a high degree of correspondence is observed when memory effects characterized by P-divisibility are compared with the sign of all entropy production rates in the case of weak coupling. Such correspondence degrades at stronger coupling, leading us to extend the concept of entropy production to the dynamical map. We show a perfect equivalence between the sign of this enlarged concept of entropy production and P-divisibility, both numerically and analytically, in the case of phase-covariant master equations.

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Cyclic quantum engines enhanced by strong bath coupling

While strong system-bath coupling produces rich and interesting phenomena, applications to quantum thermal engines have been so far pointing mainly at detrimental effects. The delicate trade-off between efficiency loss due to strong coupling and power increase due to faster equilibration, while acknowledged, remained largely unexplored owing to the challenge of assessing precisely the equilibration time. Here, we overcome this obstacle by exploiting exact numerical simulations based on the hierarchical equations of motion (HEOM) formalism. We show that a quantum Otto cycle can perform better at strong (but not ultrastrong) coupling in that the product of the efficiency times the output power is maximized in this regime. In particular, we show that strong coupling allows one to obtain engines with larger efficiency than their weakly coupled counterparts, while sharing the same output power. Conversely, one can design strongly coupled engines with larger power than their weakly coupled counterparts, while sharing the same efficiency. Overall, our results provide situations where strong coupling can directly enhance the performance of thermodynamic operations, re-enforcing the importance of studying quantum thermal engines beyond standard configurations.

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Negative contributions to entropy production induced by quantum coherences

The entropy production in dissipative processes is the essence of the arrow of time and the second law of thermodynamics. For dissipation of quantum systems, it was recently shown that the entropy production contains indeed two contributions: a classical one and a quantum one. Here we show that for degenerate (or near-degenerate) quantum systems there are additional quantum contributions which, remarkably, can become negative. Furthermore, such negative contributions are related to significant changes in the ongoing thermodynamics. This includes phenomena such as generation of coherences between degenerate energy levels (called horizontal coherences), alteration of energy exchanges and, last but not least, reversal of the natural convergence of the populations toward the thermal equilibrium state. Going further, we establish a complementarity relation between horizontal coherences and population convergence, particularly enlightening for understanding heat flow reversals. Conservation laws of the different types of coherences are derived. Some consequences for thermal machines and resource theory of coherence are suggested.

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Collective heat capacity for quantum thermometry and quantum engine enhancements

The performances of quantum thermometry in thermal equilibrium together with the output power of certain class of quantum engines share a common characteristic: both are determined by the heat capacity of the probe or working medium. After noticing that the heat capacity of spin ensembles can be significantly modified by collective coupling with a thermal bath, we build on the above observation to investigate the respective impact of such collective effect on quantum thermometry and quantum engines. We find that the precision of the temperature estimation is largely increased at high temperatures, reaching even the Heisenberg scaling - inversely proportional to the number of spins. For Otto engines operating close to the Carnot efficiency, collective coupling always enhances the output power. Some tangible experimental platforms are suggested.

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Thermodynamics from indistinguishability: mitigating and amplifying the effects of the bath

Rich quantum effects emerge when several quantum systems are indistinguishable from the point of view of the bath they interact with. In particular, delocalised excitations corresponding to coherent superposition of excited states appear and change drastically the dynamics and steady state of the systems. Such phenomena, which are central mechanisms of superradiance, present interesting properties for thermodynamics and potentially other quantum technologies. Indeed, a recent paper [Phys. Rev. A 99, 052105 (2019)] studies these properties in a pair of indistinguishable two-level systems and points out surprising effects of mitigation and amplification of the bath's action on the energy and entropy of the pair. Here, we generalise the study to ensembles of arbitrary number of spins of arbitrary size (i.e. dimension). We confirm that the previously uncovered mitigation and amplification effects remain, but also that they become more and more pronounced with growing number of spins and growing spin size. Moreover, we find that the free energy variation and the entropy production associated with the bath-driven dissipation are systematically reduced, formalising the idea of mitigation of the bath's action. Most remarkably, the combination of mitigation effects from two baths at different temperatures can result in amplifying their action. This is illustrated with cyclic thermal machines, and leads to large power enhancements. The reduction of irreversibility is also an interesting aspect since irreversibility is known to limit the performance of thermodynamic tasks. The above findings might also lead to interesting applications in collective work extraction, quantum battery charging, state protection, light harvesting devices, quantum biology, but also for the study of entropy production. Moreover, some experimental realisations and observations suggest that such effects are within reach.

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Heat flow reversals without reversing the arrow of time: the role of internal quantum coherences and correlations

One of the stunning consequences of quantum correlations in thermodynamics is the reversal of the arrow of time, recently shown experimentally in [K. Micadei, et al., Nat. Commun. 10:2456 (2019)], and manifesting itself by a reversal of the heat flow (from the cold system to the hot one). Here, we show that contrary to what could have been expected, heat flow reversal can happen without reversal of the arrow of time. Moreover, contrasting with previous studies, no initial correlations between system and bath is required. Instead, the heat flow reversal only relies on internal quantum coherences or correlations, which provides practical advantages over previous schemes: one does not need to have access to the bath in order to reverse the heat flow. The underlying mechanism is explained and shown to stem from the collective system-bath coupling and the impact of non-energetic coherences (coherences between degenerate energy levels) on apparent temperatures. The phenomenon is first uncovered in a broad framework valid for diverse quantum systems containing energy degeneracy. By the end of the paper, aiming at experimental realisations, more quantitative results are provided for a pair of two-level systems. Finally, as a curiosity, we mention that our scheme can be adapted as a correlations-to-energy converter, which have the particularity to be able to operate at constant entropy, similarly to ideal work sources.

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Apparent temperature: demystifying the relation between quantum coherence, correlations, and heat flows

Heat exchanges are the essence of Thermodynamics. In order to investigate non-equilibrium effects like quantum coherence and correlations in heat flows we introduce the concept of apparent temperature. Its definition is based on the expression of the heat flow between out-of-equilibrium quantum systems. Such apparent temperatures contain crucial information on the role and impact of correlations and coherence in heat exchanges. In particular, both behave as populations, affecting dramatically the population balance and therefore the apparent temperatures and the heat flows. We show how seminal results can be re-obtained, offering an interesting alternative point of view. We also present new predictions and suggest a simple experiment to test them. Our results show how quantum and non-equilibrium effects can be used advantageously, finding applications in quantum thermal machine designs and non-equilibrium thermodynamics but also in collective-effect phenomena.

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