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Camilo Cruz

Publications and source records attributed to Camilo Cruz.

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Data-driven discovery of roughness descriptors for surface characterization and intimate contact modeling of unidirectional composite tapes

Unidirectional tapes surface roughness determines the evolution of the degree of intimate contact required for ensuring the thermoplastic molecular diffusion and the associated inter-tapes consolidation during manufacturing of composite structures. However, usual characterization of rough surfaces relies on statistical descriptors that even if they are able to represent the surface topology, they are not necessarily connected with the physics occurring at the interface during inter-tape consolidation. Thus, a key research question could be formulated as follows: Which roughness descriptors simultaneously enable tape classification-crucial for process control-and consolidation modeling via the inference of the evolution of the degree of intimate contact, itself governed by the process parameters?. For providing a valuable response, we propose a novel strategy based on the use of Rank Reduction Autoencoders (RRAEs), autoencoders with a linear latent vector space enforced by applying a truncated Singular Value Decomposition (SVD) to the latent matrix during the encoder-decoder training. In this work, we extract useful roughness descriptors by enforcing the latent SVD modes to (i) accurately represent the roughness after decoding, and (ii) allow the extraction of existing a priori knowledge such as classification or modelling properties.

cs.LG

Atomistic modeling of the hygromechanical properties of amorphous Polyamide 6,6

Polyamide 6,6 (PA66) is a key engineering polymer, whose unique mechanical properties arise from strong interchain hydrogen bonding. However, its hygroscopic nature makes it highly sensitive to water uptake, which markedly alters its thermomechanical behavior. Contrary to traditional experimental approaches, this study uses atomistic molecular dynamics (MD) simulations to investigate the role of water in modifying the glass transition temperature (Tg) and the viscoelastic response of amorphous PA66. Simulations capture a nonmonotonic dependence of Tg on water content. At low water concentrations, isolated water molecules bind to amide groups and restrict chain mobility, while beyond ~2.5 wt %, water clustering disrupts the hydrogen bond network and causes a pronounced Tg depression. Analysis of amide group fluctuations reveals a master correlation between local segmental dynamics and bulk density, verifying the known temperature humidity equivalence in terms of density variation. The computed Young's modulus exhibits systematic softening with increasing temperature and water content, consistent with experimental trends, albeit a more pronounced impact of water at low temperatures. Time temperature superposition behavior is observed for both dry and hydrated systems. This work provides molecular scale information on the hygromechanical coupling in PA66 and demonstrates the ability of MD simulations to predict water induced transitions that govern the macroscopic behavior of polyamides.

cond-mat.mtrl-sci