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Carlo Bradac

Publications and source records attributed to Carlo Bradac.

At least 19 recordsLinked to original sources

Physics-Based versus Data-Driven Classification of Single-Photon Quantum Emitters from Sparse Autocorrelation Data

Identifying single photon emitters from large, inhomogeneous candidate populations is key to realizing many quantum applications. This requires measuring the emitters second order autocorrelation function, whose statistical reliability is fundamentally limited by acquisition time. Machine learning classifiers can accelerate identification from sparse data, but their performance relative to physics-based inference has not been systematically examined. Here, we introduce sequential Bayesian inference for single photon emitter classification and benchmark it against Levenberg-Marquardt fitting and a feedforward neural network. We use synthetic training and test data calibrated against real Hanbury Brown-Twiss measurements from hexagonal boron nitride emitters, enabling evaluation against an exactly known ground-truth emitter number under realistic noise and background conditions. All three approaches achieve high, near-perfect accuracy with sufficient integration time, but differ greatly in convergence rate and robustness under sparse photon statistics. The neural network is most robust at short integration times. The Bayesian classifier reaches near-perfect accuracy fastest, while retaining full physical interpretability. Levenberg-Marquardt fitting remains a valuable, fully interpretable method, achieving the highest recall despite being the slowest to converge. These results lead to several key conclusions. No single method dominates across all performance metrics. Relying on any one metric alone can give a misleading picture of classifier performance, particularly under sparse photon statistics. Physics-based and data-driven methods are complementary rather than competing approaches. Together, these findings provide practical guidance for selecting and combining classification strategies for scalable single-photon-source screening and other quantum-emitter characterization tasks.

quant-ph

Data-Driven Review and Machine Learning Prediction of Diamond Vacancy Center Synthesis

Diamond and diamond color centers have become prime hardware candidates for solid state-based technologies in quantum information and computing, optics, photonics and (bio)sensing. The synthesis of diamond materials with specific characteristics and the precise control of the hosted color centers is thus essential to meet the demands of advanced applications. Yet, challenges remain in improving the concentration, uniform distribution and quality of these centers. Here, we perform a review and meta-analysis of some of the main diamond synthesis methods and their parameters for the synthesis of N-, Si-, Ge- and Sn-vacancy color-centers. We extract quantitative data from over 60 experimental papers and organize it in a large database (170 data sets and 1692 entries). We then use the database to train two machine learning algorithms to make robust predictions about the fabrication of diamond materials with specific properties from careful combinations of synthesis parameters. We use traditional statistical indicators to benchmark the performance of the algorithms and show that they are powerful and resource-efficient tools for researchers and material scientists working with diamond color centers and their applications.

cond-mat.mtrl-sci

Machine Learning Based Optical Thermometry Using Photoluminescence and Raman Spectra of Diamonds Containing SiV Centers

Micro- and nanothermometry enable precise temperature monitoring and control at the micro- and nanoscale, and have become essential diagnostic tools in applications ranging from high-power microelectronics to biosensing and nanomedicine. Most existing techniques rely on secondary micro- and nanothermometers that require individual calibration of each sensor, ideally both off- and in-situ, before use. We present an alternative approach that overcomes this limitation by employing fluorescent diamonds containing silicon-vacancy centers, where the thermo-sensitive physical quantities are the centers' photoluminescence and the diamond host's Raman signals. The photoluminescence and Raman data are analyzed using two multi-feature regression algorithms that leverage a minimal number of calibration diamonds and temperature set points to predict the temperature of previously unseen diamonds. Using this approach, the models achieve accuracies as low as 0.7 K, resolutions down to 0.6 K Hz$^{-1/2}$, and sensitivity as high as 0.04 K$^{-1}$. These correspond to improvements of roughly 70 percent (over threefold) in accuracy, 50 percent (twofold) in resolution, and 567 percent (sevenfold) in sensitivity compared with traditional single-feature models. Our approach is particularly suited to applications where pre-deployment calibration of every thermosensor is impractical, and it is generalizable to any thermometry platform with two or more simultaneously measurable temperature-dependent observables.

cond-mat.mtrl-sci

Fast characterization of optically detected magnetic resonance spectra via data clustering

Optically detected magnetic resonance (ODMR) has become a well-established and powerful technique for measuring the spin state of solid-state quantum emitters, at room temperature. Relying on spin-dependent recombination processes involving the emitters ground, excited and metastable states, ODMR is enabling spin-based quantum sensing of nanoscale electric and magnetic fields, temperature, strain and pressure, as well as imaging of individual electron and nuclear spins. Central to many of these sensing applications is the ability to reliably analyze ODMR data, as the resonance frequencies in these spectra map directly onto target physical quantities acting on the spin sensor. However, this can be onerous, as relatively long integration times -- from milliseconds up to tens of seconds -- are often needed to reach a signal-to-noise level suitable to determine said resonances using traditional fitting methods. Here, we present an algorithm based on data clustering that overcome this limitation and allows determining the resonance frequencies of ODMR spectra with better accuracy (~1.3x factor), higher resolution (~4.7x factor) and/or overall fewer data points (~5x factor) than standard approaches based on statistical inference. The proposed clustering algorithm (CA) is thus a powerful tool for many ODMR-based quantum sensing applications, especially when dealing with noisy and scarce data sets.

quant-ph

Ultralow-power cryogenic thermometry based on optical-transition broadening of a two-level system in diamond

Cryogenic temperatures are the prerequisite for many advanced scientific applications and technologies. The accurate determination of temperature in this range and at the submicrometer scale is, however, nontrivial. This is due to the fact that temperature reading in cryogenic conditions can be inaccurate due to optically induced heating. Here, we present an ultralow power, optical thermometry technique that operates at cryogenic temperatures. The technique exploits the temperature dependent linewidth broadening measured by resonant photoluminescence of a two level system, a germanium vacancy color center in a nanodiamond host. The proposed technique achieves a relative sensitivity of 20% 1/K, at 5 K. This is higher than any other all optical nanothermometry method. Additionally, it achieves such sensitivities while employing excitation powers of just a few tens of nanowatts, several orders of magnitude lower than other traditional optical thermometry protocols. To showcase the performance of the method, we demonstrate its ability to accurately read out local differences in temperatures at various target locations of a custom-made microcircuit. Our work is a definite step towards the advancement of nanoscale optical thermometry at cryogenic temperatures.

physics.optics

Machine and quantum learning for diamond-based quantum applications

In recent years, machine and quantum learning have gained considerable momentum sustained by growth in computational power and data availability and have shown exceptional aptness for solving recognition- and classification-type problems, as well as problems that require complex, strategic planning. In this work, we discuss and analyze the role machine and quantum learning are playing in the development of diamond-based quantum technologies. This matters as diamond and its optically-addressable spin defects are becoming prime hardware candidates for solid state-based applications in quantum information, computing and metrology. Through a selected number of demonstrations, we show that machine and quantum learning are leading to both practical and fundamental improvements in measurement speed and accuracy. This is crucial for quantum applications, especially for those where coherence time and signal-to-noise ratio are scarce resources. We summarize some of the most prominent machine and quantum learning approaches that have been conducive to the presented advances and discuss their potential for proposed and future quantum applications.

quant-ph

Real-time ratiometric optical nanoscale thermometry

All optical nanothermometry has become a powerful, noninvasive tool for measuring nanoscale temperatures in applications ranging from medicine to nanooptics and solid-state nanodevices. The key features of any candidate nanothermometer are sensitivity and resolution. Here, we demonstrate a real time, diamond based nanothermometry technique with sensitivity and resolution much larger than those of any existing all optical method. The distinct performance of our approach stems from two factors. First, temperature sensors nanodiamonds cohosting two Group IV colour centers engineered to emit spectrally separated Stokes and AntiStokes fluorescence signals under excitation by a single laser source. Second, a parallel detection scheme based on filtering optics and high sensitivity photon counters for fast readout. We demonstrate the performance of our method by monitoring temporal changes in the local temperature of a microcircuit and a MoTe2 field effect transistor. Our work lays the foundation for time resolved temperature monitoring and mapping of micro, nanoscale devices such as microfluidic channels, nanophotonic circuits, and nanoelectronic devices, as well as complex biological environments such as tissues and cells.

physics.optics

Sub-nanoscale Temperature, Magnetic Field and Pressure sensing with Spin Centers in 2D hexagonal Boron Nitride

Spin defects in solid-state materials are strong candidate systems for quantum information technology and sensing applications. Here we explore in details the recently discovered negatively charged boron vacancies ($V_B^-$) in hexagonal boron nitride (hBN) and demonstrate their use as atomic scale sensors for temperature, magnetic fields and externally applied pressure. These applications are possible due to the high-spin triplet ground state and bright spin-dependent photoluminescence (PL) of the $V_B^-$. Specifically, we find that the frequency shift in optically detected magnetic resonance (ODMR) measurements is not only sensitive to static magnetic fields, but also to temperature and pressure changes which we relate to crystal lattice parameters. Our work is important for the future use of spin-rich hBN layers as intrinsic sensors in heterostructures of functionalized 2D materials.

cond-mat.mtrl-sci

Bottom-Up Synthesis of Hexagonal Boron Nitride Nanoparticles with Intensity-Stabilized Quantum Emitters

Fluorescent nanoparticles are widely utilized in a large range of nanoscale imaging and sensing applications. While ultra-small nanoparticles (size <10 nm) are highly desirable, at this size range their photostability can be compromised due to effects such as intensity fluctuation and spectral diffusion caused by interaction with surface states. In this letter, we demonstrate a facile, bottom-up technique for the fabrication of sub-10-nm hBN nanoparticles hosting photostable bright emitters via a catalyst-free hydrothermal reaction between boric acid and melamine. We also implement a simple stabilization protocol that significantly reduces intensity fluctuation by ~85% and narrows the emission linewidth by ~14% by employing a common sol-gel silica coating process. Our study advances a promising strategy for the scalable, bottom-up synthesis of high-quality quantum emitters in hBN nanoparticles.

physics.optics

Room Temperature Coherent Control of Spin Defects in hexagonal Boron Nitride

Optically active defects in solids with accessible spin states are promising candidates for solid state quantum information and sensing applications. To employ these defects as quantum building blocks, coherent manipulation of their spin state is required. Here we realize coherent control of ensembles of boron vacancy (V$_B^-$) centers in hexagonal boron nitride (hBN). Specifically, by applying pulsed spin resonance protocols, we measure spin-lattice relaxation time ($T_1$) of 18 $μ$s and spin coherence time ($T_2$) of 2 $μ$s at room temperature. The spin-lattice relaxation time increases by three orders of magnitude at cryogenic temperature. Furthermore, employing a two- and three-pulse electron spin-echo envelope modulation (ESEEM) we separate the quadrupole and hyperfine interactions with the surrounding nuclei. Finally, by applying a method to decouple the spin state from its inhomogeneous nuclear environment - a "hole-burning" - the spectral optically detected magnetic resonance linewidth is significantly reduced to several tens of kHz, thus extending the spin coherence time by a factor of three. Our results are important for employment of van der Waals materials for quantum technologies, specifically in the context of using hBN as a high-resolution quantum sensor for hybrid quantum systems including 2D heterostructures, nanoscale devices and emerging atomically thin magnets.

cond-mat.mes-hall

Versatile Direct Writing of Dopants in a Solid State Host Through Recoil Implantation

Modifying material properties at the nanoscale is crucially important for devices in nanoelectronics, nanophotonics and quantum information. Optically active defects in wide band gap materials, for instance, are vital constituents for the realisation of quantum technologies. Yet, the introduction of atomic defects through direct ion implantation remains a fundamental challenge. Herein, we establish a universal method for material doping by exploiting one of the most fundamental principles of physics - momentum transfer. As a proof of concept, we direct-write arrays of emitters into diamond via momentum transfer from a Xe+ focused ion beam (FIB) to thin films of the group IV dopants pre-deposited onto a diamond surface. We conclusively show that the technique, which we term knock-on doping, can yield ultra-shallow dopant profiles localized to the top 5 nm of the target surface, and use it to achieve sub-50 nm lateral resolution. The knock-on doping method is cost-effective, yet very versatile, powerful and universally suitable for applications such as electronic and magnetic doping of atomically thin materials and engineering of near-surface states of semiconductor devices.

physics.app-ph

Photoluminescence and photochemistry of the $V_B^-$ defect in hexagonal boron nitride

Extensive photochemical and spectroscopic properties of the $V_B^-$ defect in hexagonal boron nitride are calculated, concluding that the observed photoemission associated with recently observed optically-detected magnetic resonance is most likely of (1)3E" to (1)3A2' origin. Rapid intersystem crossing from the defect's triplet to singlet manifolds explains the observed short excited-state lifetime and very low quantum yield. New experimental results reveal smaller intrinsic spectral bandwidths than previously recognized, interpreted in terms spectral narrowing and zero-phonon-line shifting induced by the Jahn-Teller effect. Different types of computational methods are applied to map out the complex triplet and singlet defect manifolds, including the doubly ionised formulation of the equation-of-motion coupled-cluster theory that is designed to deal with the open-shell nature of defect states, and mixed quantum-mechanics/molecular-mechanics schemes enabling 5763-atom simulations. Two other energetically feasible spectral assignments from amongst the singlet and triplet manifolds are considered, but ruled out based on inappropriate photochemical properties.

cond-mat.mtrl-sci

Identifying Carbon as the Source of Visible Single Photon Emission from Hexagonal Boron Nitride

Single photon emitters (SPEs) in hexagonal boron nitride (hBN) have garnered significant attention over the last few years due to their superior optical properties. However, despite the vast range of experimental results and theoretical calculations, the defect structure responsible for the observed emission has remained elusive. Here, by controlling the incorporation of impurities into hBN and by comparing various synthesis methods, we provide direct evidence that the visible SPEs are carbon related. Room temperature optically detected magnetic resonance (ODMR) is demonstrated on ensembles of these defects. We also perform ion implantation experiments and confirm that only carbon implantation creates SPEs in the visible spectral range. Computational analysis of hundreds of potential carbon-based defect transitions suggest that the emission results from the negatively charged VBCN- defect, which experiences long-range out-of-plane deformations and is environmentally sensitive. Our results resolve a long-standing debate about the origin of single emitters at the visible range in hBN and will be key to deterministic engineering of these defects for quantum photonic devices.

physics.app-ph

Engineering spin defects in hexagonal boron nitride

Two-dimensional hexagonal boron nitride offers intriguing opportunities for advanced studies of light-matter interaction at the nanoscale, specifically for realizations in quantum nanophotonics. Here, we demonstrate the engineering of optically-addressable spin defects based on the negatively-charged boron vacancy center. We show that these centers can be created in exfoliated hexagonal boron nitride using a variety of focused ion beams (nitrogen, xenon and argon), with nanoscale precision. Using a combination of laser and resonant microwave excitation, we carry out optically detected magnetic resonance spectroscopy measurements, which reveal a zero-field ground state splitting for the defect of ~3.46 GHz. We also perform photoluminescence excitation spectroscopy and temperature dependent photoluminescence measurements to elucidate the photophysical properties of the center. Our results are important for advanced quantum and nanophotonics realizations involving manipulation and readout of spin defects in hexagonal boron nitride.

physics.app-ph

Optical Thermometry with Quantum Emitters in Hexagonal Boron Nitride

Nanoscale optical thermometry is a promising non-contact route for measuring local temperature with both high sensitivity and spatial resolution. In this work, we present a deterministic optical thermometry technique based on quantum emitters in nanoscale hexagonal boron-nitride. We show that these nanothermometers exhibit better performance than that of homologous, all-optical nanothermometers both in sensitivity and range of working temperature. We demonstrate their effectiveness as nanothermometers by monitoring the local temperature at specific locations in a variety of custom-built micro-circuits. This work opens new avenues for nanoscale temperature measurements and heat flow studies in miniaturized, integrated devices.

physics.app-ph

Near-field energy transfer between a luminescent 2D material and color centers in diamond

Energy transfer between fluorescent probes lies at the heart of many applications ranging from bio-sensing and -imaging to enhanced photo-detection and light harvesting. In this work, we study Förster resonance energy transfer (FRET) between shallow defects in diamond --- nitrogen-vacancy (NV) centers --- and atomically-thin, two-dimensional materials --- tungsten diselenide (WSe$_2$). By means of fluorescence lifetime imaging, we demonstrate the occurrence of FRET in the WSe$_2$/NV system. Further, we show that in the coupled system, NV centers provide an additional excitation pathway for WSe$_2$ photoluminescence. Our results constitute the first step towards the realization of hybrid quantum systems involving single-crystal diamond and two-dimensional materials that may lead to new strategies for studying and controlling spin transfer phenomena and spin valley physics.

quant-ph

Integrated on chip platform with quantum emitters in layered materials

Integrated quantum photonic circuitry is an emerging topic that requires efficient coupling of quantum light sources to waveguides and optical resonators. So far, great effort has been devoted to engineering on-chip systems from three-dimensional crystals such as diamond or gallium arsenide. In this study, we demonstrate room temperature coupling of quantum emitters embedded within a layered hexagonal boron nitride to an on-chip aluminium nitride waveguide. We achieved 1.2% light coupling efficiency of the device and realise transmission of single photons through the waveguide. Our results serve as a foundation for the integration of layered materials with on-chip components and for the realisation of integrated quantum photonic circuitry.

physics.app-ph

Quantum Nanophotonics with Group IV defects in Diamond

Diamond photonics is an ever growing field of research driven by the prospects of harnessing diamond and its colour centres as suitable hardware for solid-state quantum applications. The last two decades have seen the field been shaped by the nitrogen-vacancy (NV) centre both with breakthrough fundamental physics demonstrations and practical realizations. Recently however, an entire suite of other diamond defects has emerged. They are M V colour centres, where M indicates one of the elements in the IV column of the periodic table Si, Ge, Sn and Pb, and V indicates lattice vacancies, i.e. missing next-neighbour carbon atoms. These centres exhibit a much stronger emission into the zero phonon line then the NV centre, they display inversion symmetry, and can be engineered using ion implantation all attractive features for scalable quantum photonic architectures based on solid-state, single-photon sources. In this perspective, we highlight the leading techniques for engineering and characterizing these diamond defects, discuss the current state-of-the-art of group IV-based devices and provide an outlook of the future directions the field is taking towards the realisation of solid-state quantum photonics with diamond.

physics.optics