arXiv subjects

Carlos A Rios Ocampo

Publications and source records attributed to Carlos A Rios Ocampo.

3 recordsLinked to original sources

arXiv2026

Real-time Multi-instrument Autonomous Discovery of Novel Phase-change Memory Materials

Autonomous labs enable the integration of automated experiment execution, data analysis and decision making. The main challenge remains the integration of diverse data streams from multiple instruments, where the data is often heterogeneous and unsynchronized. The standard learning process of undetermined synthesis-process-structure-property relationships (SPSPR) usually relies on post-experiment analysis after data is fully collected, not during live experiments, and decision making is carried out independently across characterization equipment. Here, we demonstrate the Multi-instrument Autonomous Discovery (MAD) framework -- combining structural property mapping and functional property optimization simultaneously in a closed-loop manner. As an example, we applied MAD to phase change memory (PCM) materials, and, in particular on the Mn-Sb-Te ternary, a previously unexplored materials system for PCM. A multi-output model is employed to merge data from x-ray diffraction (XRD) and electrical resistance measurements simultaneously through a co-regionalization kernel that models the relationship between them. The output probabilistic posterior and uncertainty quantification facilitate decision making with shared knowledge, while the goals are different across tasks. We aimed to maximize the knowledge of crystal structure distribution using non-negative matrix factorization (NMF), while in parallel, we find the composition with the maximum resistance value, an important figure of merit for PCM. Leveraging MAD, we found promising electrical PCMs and identified the SPSPR within 25 closed-loop iterations, corresponding to a seven-fold speed-up. The framework opens a new path of study in large-scale autonomous facilities, where future experiments can be run in parallel together, not independently.

cond-mat.mtrl-sci↗

arXiv2026

Ultra-Thin Aluminum-Doped Silver for Transmissive Thermally Reconfigurable Visible Photonics

Functional materials with high electrical conductivity and optical transmittance are vital for thermally tunable free-space photonic systems. Conventional transparent conductors such as graphene and indium tin oxide are limited by high contact resistance, poor mechanical stability, or complex fabrication. Ultra-thin metals, such as pure silver, have also been explored with limited success due to thermal instability and dewetting. Here, we propose an ultra-thin Al-doped Ag film to tackle these challenges. Aluminum promotes heterogeneous nucleation of silver, enabling the formation of continuous, smooth films that are thermally stable at reduced thicknesses while maintaining excellent electrical conductivity and transparency. We find that a 12 nm Al-doped Ag film exhibits an average transmittance of 80% across the visible range with a sheet resistance of 8.3$\pm$1.16 $Ω$cm$^2$. Moreover, on-chip Al-doped Ag microheaters exhibit uniform, rapid thermal response, and stable electrical performance, maintaining functionality for over $10^7$ ON and OFF cycles at temperatures below 400$°$C. Furthermore, as a benchmark, we demonstrate reversible phase-change switching in Ge$_2$Sb$_2$Se$_4$Te (GSST) and VO$_2$. 30$\times$30 $μ$m$^2$ GSST cells exhibited complete crystallization and amorphization under 2.2 V - 200 ms and 4.1V - 50$μ$s pulses, respectively, resulting in a 40% transmission contrast at 780 nm and a tenfold improvement in power consumption compared to similar devices. Additionally, VO$_2$ films displayed reversible insulator-to-metal transitions near 65°C with reflectance and transmittance modulation in the visible and the near-infrared at frequencies up to 25 Hz with room for improvement. These results establish Al-doped Ag as a robust transparent metallic heater for integration in dynamic metasurfaces, optical coatings, and more.

physics.optics↗

arXiv2025

Incorporating Si into Sb2Se3: Tailoring Optical Phase Change Materials via Nanocomposites

Chalcogenide-based optical phase change materials (OPCMs) exhibit a large contrast in refractive index when reversibly switched between their stable amorphous and crystalline states. OPCMs have rapidly gained attention due to their versatility as nonvolatile amplitude or phase modulators in various photonic devices. However, open challenges remain, such as achieving reliable response and transparency spanning into the visible spectrum, a combination of properties in which current broadband OPCMs (e.g., Ge2Sb2Se4Te1, Sb2Se3, or Sb2S3) fall short. Discovering novel materials or engineering existing ones is, therefore, crucial in extending the application scope of OPCMs. Here, we use magnetron co-sputtering to study the effects of Si doping into Sb2Se3. We employ ellipsometry, X-ray diffraction, Raman spectroscopy, and scanning and transmission electron microscopy to investigate the effects of Si doping on the optical properties and crystal structure and compare these results with those from first principles calculations. Moreover, we study the crystallization and melt-quenching of thin films via nano-differential scanning calorimetry (NanoDSC). Our experiments demonstrate that 20% Si doping increases the transparency window in both states, specifically to 800 nm (1.55 eV) in the amorphous phase, while reducing power consumption by lowering the melting temperature. However, this reduction comes at the cost of reducing the refractive index contrast between states and slowing the kinetics of the phase transition.

cond-mat.mtrl-sci↗