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Caroline Arnold

Publications and source records attributed to Caroline Arnold.

5 recordsLinked to original sources

Building Age Estimation: A New Multi-Modal Benchmark Dataset and Community Challenge

Estimating the construction year of buildings is critical for advancing sustainability, as older structures often lack energy-efficient features. Sustainable urban planning relies on accurate building age data to reduce energy consumption and mitigate climate change. In this work, we introduce MapYourCity, a novel multi-modal benchmark dataset comprising top-view Very High Resolution (VHR) imagery, multi-spectral Earth Observation (EO) data from the Copernicus Sentinel-2 satellite constellation, and co-localized street-view images across various European cities. Each building is labeled with its construction epoch, and the task is formulated as a seven-class classification problem covering periods from 1900 to the present. To advance research in EO generalization and multi-modal learning, we organized a community-driven data challenge in 2024, hosted by ESA $\Phi$-lab, which ran for four months and attracted wide participation. This paper presents the Top-4 performing models from the challenge and their evaluation results. We assess model generalization on cities excluded from training to prevent data leakage, and evaluate performance under missing modality scenarios, particularly when street-view data is unavailable. Results demonstrate that building age estimation is both feasible and effective, even in previously unseen cities and when relying solely on top-view satellite imagery (i.e. with VHR and Sentinel-2 images). The MapYourCity dataset thus provides a valuable resource for developing scalable, real-world solutions in sustainable urban analytics.

cs.CV

Outcoupling from a Bose-Einstein condensate in the strong-field limit

Atoms can be extracted from a trapped Bose-Einstein condensate (BEC) by driving spin-flips to untrapped states. The coherence properties of the BEC are transfered to the released atoms, creating a coherent beam of matter refered to as an atom laser. In this work, the extraction of atoms from a BEC is investigated numerically by solving a coupled set of Gross-Pitaevskii equations in up to three dimensions. The result is compared to experimental data and a semiclassical rate model. In the weak-coupling regime, quantitative agreement is reached between theory and experiment and a semiclassical rate model. In the strong-coupling regime, the atom laser enters a trapped state that manifests itself in a saturation of the rate of out-coupled atoms observed in new experimental data. The semiclassical rate model fails, but the numerical descriptions yield qualitative agreement with experimental data at the onset of saturation.

cond-mat.quant-gas

Simulated XUV Photoelectron Spectra of THz-pumped Liquid Water

Highly intense, sub-picosecond terahertz (THz) pulses can be used to induce ultrafast temperature jumps (T-jumps) in liquid water. A supercritical state of gas-like water with liquid density is established, and the accompanying structural changes are expected to give rise to time-dependent chemical shifts. We investigate the possibility of using extreme ultraviolet (XUV) photoelectron spectroscopy as a probe for ultrafast dynamics induced by sub-picosecond THz pulses of varying intensities and frequencies. To this end, we use ab initio methods to calculate photoionization cross sections and photoelectron energies of (H2O)$_{20}$ clusters embedded in an aqueous environment represented by point charges. The cluster geometries are sampled from ab initio molecular dynamics simulations modeling the THz-water interactions. We find that the peaks in the valence photoelectron spectrum are shifted by up to 0.4 eV after the pump pulse, and that they are broadened with respect to unheated water. The shifts can be connected to structural changes caused by the heating, but due to saturation effects they are not sensitive enough to serve as a thermometer for T-jumped water.

physics.chem-ph

Towards attochemistry: Control of nuclear motion through conical intersections and electronic coherences

The effect of nuclear dynamics and conical intersections on electronic coherences is investigated employing a two-state, two-mode linear vibronic coupling model. Exact quantum dynamical calculations are performed using the multi-configuration time-dependent Hartree method (MCTDH). It is found that the presence of a non-adiabatic coupling close to the Franck-Condon point can preserve electronic coherence to some extent. Additionally, the possibility of steering the nuclear wavepackets by imprinting a relative phase between the electronic states during the photoionization process is discussed. It is found that the steering of nuclear wavepackets is possible given that a coherent electronic wavepacket embodying the phase difference passes through a conical intersection. A conical intersection close to the Franck-Condon point is thus a necessary prerequisite for control, providing a clear path towards attochemistry.

physics.chem-ph

Electronic decoherence following photoionization: full quantum-dynamical treatment of the influence of nuclear motion

Photoionization using attosecond pulses can lead to the formation of coherent superpositions of the electronic states of the parent ion. However, ultrafast electron ejection triggers not only electronic but also nuclear dynamics---leading to electronic decoherence, which is typically neglected on time scales up to tens of femtoseconds. We propose a full quantum-dynamical treatment of nuclear motion in an adiabatic framework, where nuclear wavepackets move on adiabatic potential energy surfaces expanded up to second order at the Franck-Condon point. We show that electronic decoherence is caused by the interplay of a large number of nuclear degrees of freedom and by the relative topology of the potential energy surfaces. Application to $\mathrm{H_2O}$, paraxylene, and phenylalanine shows that an initially coherent state evolves to an electronically mixed state within just a few femtoseconds. In these examples the fast vibrations involving hydrogen atoms do not affect electronic coherence at short times. Conversely, vibrational modes involving the whole molecular skeleton, which are slow in the ground electronic state, quickly destroy it upon photoionization.

physics.chem-ph