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Caroline Piaulet

Publications and source records attributed to Caroline Piaulet.

At least 19 recordsLinked to original sources

NIRPS detection of delayed atmospheric escape from the warm and misaligned Saturn-mass exoplanet WASP-69b

Near-infrared high-resolution echelle spectrographs unlock access to fundamental properties of exoplanets, from their atmospheric escape and composition to their orbital architecture, which can all be studied simultaneously from transit observations. We present the first results of the newly commissioned ESO near-infrared spectrograph, NIRPS, from three transits of WASP-69b. We used the RM Revolutions technique to better constrain the orbital architecture of the system. We extracted the high-resolution helium absorption profile to study its spectral shape and temporal variations. Then, we made 3D simulations from the EVE code to fit the helium absorption time series. We measure a slightly misaligned orbit for WASP-69b (psi of 28.7+/-5.7 deg). We confirm the detection of helium with an average excess absorption of 3.17+/-0.05%. The helium absorption is spectrally and temporally resolved, extends to high altitudes and has a strong velocity shift up to -29.5+/-2.5 km/s 50 minutes after egress. EVE simulations put constraints on the mass loss of 2.25 10^11 g/s and hint at reactive chemistry within the cometary-like tail and interaction with the stellar winds that allow the metastable helium to survive longer than expected. Our results suggest that WASP-69b is undergoing a transformative phase in its history, losing mass while evolving on a misaligned orbit. This work shows how combining multiple observational tracers such as orbital architecture, atmospheric escape, and composition, is critical to understand exoplanet demographics and their formation and evolution. We demonstrate that NIRPS can reach precisions similar to HARPS for RM studies, and the high data quality of NIRPS leads to unprecedented atmospheric characterization. The high stability of NIRPS combined with the large GTO available for its consortium, enables in-depth studies of exoplanets as well as large population surveys.

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Hydride ion continuum hides absorption signatures in the NIRPS near-infrared transmission spectrum of the ultra-hot gas giant WASP-189b

Ultra-hot Jupiters showcase extreme atmospheric conditions, including molecular dissociation, ionisation, and significant day-to-night temperature contrasts. Their close proximity to host stars subjects them to intense stellar irradiation, driving high temperatures where hydride ions (H$^-$) significantly contribute to opacity, potentially obscuring metal features in near-infrared transmission spectra. We investigate the atmosphere of WASP-189b, targeting atomic, ionic, and molecular species (H, He, Fe, Ti, V, Mn, Na, Mg, Ca, Cr, Ni, Y, Ba, Sc, Fe$^+$, Ti$^+$, TiO, H$_2$O, CO, and OH), focusing on (i) the role of H$^-$ as a source of continuum opacity, and (ii) the relative hydride-to-Fe abundance using joint optical and near-infrared data. We present two transits of WASP-189b gathered simultaneously in the optical with HARPS and near-infrared with NIRPS, supported by photometric light curves from EulerCam and ExTrA. Transmission spectra were analysed via cross-correlation to detect absorption features and enhance the signal-to-noise ratio. Atmospheric retrievals quantified relative abundances by fitting overall metallicity and proxies for TiO, H$^-$, and e$^-$. Only atomic iron is detected in HARPS data (S/N ~5.5), but not in NIRPS, likely due to H$^-$ continuum dampening. Retrievals on HARPS-only and HARPS+NIRPS suggest the hydride-to-Fe ratio exceeds equilibrium predictions by about 0.5 dex, hinting at strong hydrogen ionisation. Including NIRPS data helps constrain H$^-$ abundance and set an upper limit on free electron density, unconstrained in HARPS-only data. These results emphasise H$^-$ as a significant continuum opacity source impeding detection of planetary absorption features in WASP-189b's near-infrared transmission spectrum.

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A roadmap for the atmospheric characterization of terrestrial exoplanets with JWST

Ultra-cool dwarf stars are abundant, long-lived, and uniquely suited to enable the atmospheric study of transiting terrestrial companions with JWST. Amongst them, the most prominent is the M8.5V star TRAPPIST-1 and its seven planets. While JWST Cycle 1 observations have started to yield preliminary insights into the planets, they have also revealed that their atmospheric exploration requires a better understanding of their host star. Here, we propose a roadmap to characterize the TRAPPIST-1 system -- and others like it -- in an efficient and robust manner. We notably recommend that -- although more challenging to schedule -- multi-transit windows be prioritized to mitigate the effects of stellar activity and gather up to twice more transits per JWST hour spent. We conclude that, for such systems, planets cannot be studied in isolation by small programs, but rather need large-scale, jointly space- and ground-based initiatives to fully exploit the capabilities of JWST for the exploration of terrestrial planets.

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Transmission Spectroscopy of the Habitable Zone Exoplanet LHS 1140 b with JWST/NIRISS

LHS 1140 b is the second-closest temperate transiting planet to the Earth with an equilibrium temperature low enough to support surface liquid water. At 1.730$\pm$0.025 R$_\oplus$, LHS 1140 b falls within the radius valley separating H$_2$-rich mini-Neptunes from rocky super-Earths. Recent mass and radius revisions indicate a bulk density significantly lower than expected for an Earth-like rocky interior, suggesting that LHS 1140 b could either be a mini-Neptune with a small envelope of hydrogen ($\sim$0.1% by mass) or a water world (9--19% water by mass). Atmospheric characterization through transmission spectroscopy can readily discern between these two scenarios. Here, we present two JWST/NIRISS transit observations of LHS 1140 b, one of which captures a serendipitous transit of LHS 1140 c. The combined transmission spectrum of LHS 1140 b shows a telltale spectral signature of unocculted faculae (5.8 $σ$), covering $\sim$20% of the visible stellar surface. Besides faculae, our spectral retrieval analysis reveals tentative evidence of residual spectral features, best-fit by Rayleigh scattering from an N$_2$-dominated atmosphere (2.3 $σ$), irrespective of the consideration of atmospheric hazes. We also show through Global Climate Models (GCM) that H$_2$-rich atmospheres of various compositions (100$\times$, 300$\times$, 1000$\times$solar metallicity) are ruled out to $>$10 $σ$. The GCM calculations predict that water clouds form below the transit photosphere, limiting their impact on transmission data. Our observations suggest that LHS 1140 b is either airless or, more likely, surrounded by an atmosphere with a high mean molecular weight. Our tentative evidence of an N$_2$-rich atmosphere provides strong motivation for future transmission spectroscopy observations of LHS 1140 b.

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NIRPS first light and early science: breaking the 1 m/s RV precision barrier at infrared wavelengths

The Near-InfraRed Planet Searcher or NIRPS is a precision radial velocity spectrograph developed through collaborative efforts among laboratories in Switzerland, Canada, Brazil, France, Portugal and Spain. NIRPS extends to the 0.98-1.8 $μ$m domain of the pioneering HARPS instrument at the La Silla 3.6-m telescope in Chile and it has achieved unparalleled precision, measuring stellar radial velocities in the infrared with accuracy better than 1 m/s. NIRPS can be used either stand-alone or simultaneously with HARPS. Commissioned in late 2022 and early 2023, NIRPS embarked on a 5-year Guaranteed Time Observation (GTO) program in April 2023, spanning 720 observing nights. This program focuses on planetary systems around M dwarfs, encompassing both the immediate solar vicinity and transit follow-ups, alongside transit and emission spectroscopy observations. We highlight NIRPS's current performances and the insights gained during its deployment at the telescope. The lessons learned and successes achieved contribute to the ongoing advancement of precision radial velocity measurements and high spectral fidelity, further solidifying NIRPS' role in the forefront of the field of exoplanets.

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JWST Reveals CH$_4$, CO$_2$, and H$_2$O in a Metal-rich Miscible Atmosphere on a Two-Earth-Radius Exoplanet

Even though sub-Neptunes likely represent the most common outcome of planet formation, their natures remain poorly understood. In particular, planets near 1.5-2.5$\,R_\oplus$ often have bulk densities that can be explained equally well with widely different compositions and interior structures, resulting in grossly divergent implications for their formation. Here, we present the full 0.6-5.2$\,μ\mathrm{m}$ JWST NIRISS/SOSS+NIRSpec/G395H transmission spectrum of the 2.2$\,R_\oplus$ TOI-270d ($4.78\,M_\oplus$, $T_\mathrm{eq}$=350-380 K), delivering unprecedented sensitivity for atmospheric characterization in the sub-Neptune regime. We detect five vibrational bands of CH$_4$ at 1.15, 1.4, 1.7, 2.3, and 3.3$\,μ$m (9.4$σ$), the signature of CO$_2$ at 4.3$\,μ$m (4.8$σ$), water vapor (2.5$σ$), and potential signatures of SO$_2$ at 4.0$\,μ\mathrm{m}$ and CS$_2$ at 4.6$\,μ\mathrm{m}$. Intriguingly, we find an overall highly metal-rich atmosphere, with a mean molecular weight of $5.47_{-1.14}^{+1.25}$. We infer an atmospheric metal mass fraction of $58_{-12}^{+8}\%$ and a C/O of $0.47_{-0.19}^{+0.16}$, indicating that approximately half the mass of the outer envelope is in high-molecular-weight volatiles (H$_2$O, CH$_4$, CO, CO$_2$) rather than H$_2$/He. We introduce a sub-Neptune classification scheme and identify TOI-270d as a "miscible-envelope sub-Neptune" in which H$_2$/He is well-mixed with the high-molecular-weight volatiles in a miscible supercritical metal-rich envelope. For a fully miscible envelope, we conclude that TOI-270d's interior is $90_{-4}^{+3}\,$wt$\,\%$ rock/iron, indicating that it formed as a rocky planet that accreted a few wt % of H$_2$/He, with the overall envelope metal content explained by magma-ocean/envelope reactions without the need for significant ice accretion. TOI-270d may well be an archetype of the overall population of sub-Neptunes.

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Nightside clouds and disequilibrium chemistry on the hot Jupiter WASP-43b

Hot Jupiters are among the best-studied exoplanets, but it is still poorly understood how their chemical composition and cloud properties vary with longitude. Theoretical models predict that clouds may condense on the nightside and that molecular abundances can be driven out of equilibrium by zonal winds. Here we report a phase-resolved emission spectrum of the hot Jupiter WASP-43b measured from 5-12 $μ$m with JWST's Mid-Infrared Instrument (MIRI). The spectra reveal a large day-night temperature contrast (with average brightness temperatures of 1524$\pm$35 and 863$\pm$23 Kelvin, respectively) and evidence for water absorption at all orbital phases. Comparisons with three-dimensional atmospheric models show that both the phase curve shape and emission spectra strongly suggest the presence of nightside clouds which become optically thick to thermal emission at pressures greater than ~100 mbar. The dayside is consistent with a cloudless atmosphere above the mid-infrared photosphere. Contrary to expectations from equilibrium chemistry but consistent with disequilibrium kinetics models, methane is not detected on the nightside (2$σ$ upper limit of 1-6 parts per million, depending on model assumptions).

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Near-Infrared Transmission Spectroscopy of HAT-P-18$\,$b with NIRISS: Disentangling Planetary and Stellar Features in the Era of JWST

The JWST Early Release Observations (ERO) included a NIRISS/SOSS (0.6-2.8$\,μ$m) transit of the $\sim\,$850$\,$K Saturn-mass exoplanet HAT-P-18$\,$b. Initial analysis of these data reported detections of water, escaping helium, and haze. However, active K dwarfs like HAT-P-18 possess surface heterogeneities $-$ starspots and faculae $-$ that can complicate the interpretation of transmission spectra, and indeed, a spot-crossing event is present in HAT-P-18$\,$b's NIRISS/SOSS light curves. Here, we present an extensive reanalysis and interpretation of the JWST ERO transmission spectrum of HAT-P-18$\,$b, as well as HST/WFC3 and $\textit{Spitzer}$/IRAC transit observations. We detect H$_2$O (12.5$\,σ$), CO$_2$ (7.3$\,σ$), a cloud deck (7.4$\,σ$), and unocculted starspots (5.8$\,σ$), alongside hints of Na (2.7$\,σ$). We do not detect the previously reported CH$_4$ ($\log$ CH$_4$ $<$ -6 to 2$\,σ$). We obtain excellent agreement between three independent retrieval codes, which find a sub-solar H$_2$O abundance ($\log$ H$_2$O $\approx -4.4 \pm 0.3$). However, the inferred CO$_2$ abundance ($\log$ CO$_2$ $\approx -4.8 \pm 0.4$) is significantly super-solar and requires further investigation into its origin. We also introduce new stellar heterogeneity considerations by fitting for the active regions' surface gravities $-$ a proxy for the effects of magnetic pressure. Finally, we compare our JWST inferences to those from HST/WFC3 and $\textit{Spitzer}$/IRAC. Our results highlight the exceptional promise of simultaneous planetary atmosphere and stellar heterogeneity constraints in the era of JWST and demonstrate that JWST transmission spectra may warrant more complex treatments of the transit light source effect.

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Characterizing the Near-infrared Spectra of Flares from TRAPPIST-1 During JWST Transit Spectroscopy Observations

We present the first analysis of JWST near-infrared spectroscopy of stellar flares from TRAPPIST-1 during transits of rocky exoplanets. Four flares were observed from 0.6--2.8 $μ$m with NIRISS and 0.6--3.5 $μ$m with NIRSpec during transits of TRAPPIST-1b, f, and g. We discover P$α$ and Br$β$ line emission and characterize flare continuum at wavelengths from 1--3.5 $μ$m for the first time. Observed lines include H$α$, P$α$-P$ε$, Br$β$, He I $λ$0.7062$μ$m, two Ca II infrared triplet (IRT) lines, and the He I IRT. We observe a reversed Paschen decrement from P$α$-P$γ$ alongside changes in the light curve shapes of these lines. The continuum of all four flares is well-described by blackbody emission with an effective temperature below 5300 K, lower than temperatures typically observed at optical wavelengths. The 0.6--1 $μ$m spectra were convolved with the TESS response, enabling us to measure the flare rate of TRAPPIST-1 in the TESS bandpass. We find flares of 10$^{30}$ erg large enough to impact transit spectra occur at a rate of 3.6$\substack{+2.1 \\ -1.3}$ flare d$^{-1}$, $\sim$10$\times$ higher than previous predictions from K2. We measure the amount of flare contamination at 2 $μ$m for the TRAPPIST-1b and f transits to be 500$\pm$450 and 2100$\pm$400 ppm, respectively. We find up to 80% of flare contamination can be removed, with mitigation most effective from 1.0--2.4 $μ$m. These results suggest transits affected by flares may still be useful for atmospheric characterization efforts.

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Water absorption in the transmission spectrum of the water-world candidate GJ9827d

Recent work on the characterization of small exoplanets has allowed us to accumulate growing evidence that the sub-Neptunes with radii greater than $\sim2.5\,R_\oplus$ often host H$_2$/He-dominated atmospheres both from measurements of their low bulk densities and direct detections of their low mean-molecular-mass atmospheres. However, the smaller sub-Neptunes in the 1.5-2.2 R$_\oplus$ size regime are much less understood, and often have bulk densities that can be explained either by the H$_2$/He-rich scenario, or by a volatile-dominated composition known as the "water world" scenario. Here, we report the detection of water vapor in the transmission spectrum of the $1.96\pm0.08$ R$_\oplus$ sub-Neptune GJ9827d obtained with the Hubble Space Telescope. We observed 11 HST/WFC3 transits of GJ9827d and find an absorption feature at 1.4$μ$m in its transit spectrum, which is best explained (at 3.39$σ$) by the presence of water in GJ9827d's atmosphere. We further show that this feature cannot be caused by unnoculted star spots during the transits by combining an analysis of the K2 photometry and transit light-source effect retrievals. We reveal that the water absorption feature can be similarly well explained by a small amount of water vapor in a cloudy H$_2$/He atmosphere, or by a water vapor envelope on GJ9827d. Given that recent studies have inferred an important mass-loss rate ($>0.5\,$M$_\oplus$/Gyr) for GJ9827d making it unlikely to retain a H-dominated envelope, our findings highlight GJ9827d as a promising water world candidate that could host a volatile-dominated atmosphere. This water detection also makes GJ9827d the smallest exoplanet with an atmospheric molecular detection to date.

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Atmospheric Reconnaissance of TRAPPIST-1 b with JWST/NIRISS: Evidence for Strong Stellar Contamination in the Transmission Spectra

TRAPPIST-1 is a nearby system of seven Earth-sized, temperate, rocky exoplanets transiting a Jupiter-sized M8.5V star, ideally suited for in-depth atmospheric studies. Each TRAPPIST-1 planet has been observed in transmission both from space and from the ground, confidently rejecting cloud-free, hydrogen-rich atmospheres. Secondary eclipse observations of TRAPPIST-1 b with JWST/MIRI are consistent with little to no atmosphere given the lack of heat redistribution. Here we present the first transmission spectra of TRAPPIST-1 b obtained with JWST/NIRISS over two visits. The two transmission spectra show moderate to strong evidence of contamination from unocculted stellar heterogeneities, which dominates the signal in both visits. The transmission spectrum of the first visit is consistent with unocculted starspots and the second visit exhibits signatures of unocculted faculae. Fitting the stellar contamination and planetary atmosphere either sequentially or simultaneously, we confirm the absence of cloud-free hydrogen-rich atmospheres, but cannot assess the presence of secondary atmospheres. We find that the uncertainties associated with the lack of stellar model fidelity are one order of magnitude above the observation precision of 89 ppm (combining the two visits). Without affecting the conclusion regarding the atmosphere of TRAPPIST-1 b, this highlights an important caveat for future explorations, which calls for additional observations to characterize stellar heterogeneities empirically and/or theoretical works to improve model fidelity for such cool stars. This need is all the more justified as stellar contamination can affect the search for atmospheres around the outer, cooler TRAPPIST-1 planets for which transmission spectroscopy is currently the most efficient technique.

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The Near Infrared Imager and Slitless Spectrograph for the James Webb Space Telescope -- III. Single Object Slitless Spectroscopy

The Near Infrared Imager and Slitless Spectrograph instrument (NIRISS) is the Canadian Space Agency (CSA) contribution to the suite of four science instruments of JWST. As one of the three NIRISS observing modes, the Single Object Slitless Spectroscopy (SOSS) mode is tailor-made to undertake time-series observations of exoplanets to perform transit spectroscopy. The SOSS permits observing point sources between 0.6 and 2.8 um at a resolving power of 650 at 1.25 um using a slit-less cross-dispersing grism while its defocussing cylindrical lens enables observing targets as bright as J=6.7 by spreading light across 23 pixels along the cross-dispersion axis. This paper officially presents the design of the SOSS mode, its operation, characterization, and its performance, from ground-based testing and flight-based Commissioning. On-sky measurements demonstrate a peak photon conversion efficiency of 55% at 1.2 um. The first time-series on the A-type star BD+60o1753 achieves a flux stability close to the photon-noise limit, so far tested to a level of 20 parts per million on 40-minute time-scales after simply subtracting a long-term trend. Uncorrected 1/f noise residuals underneath the spectral traces add an extra source of noise equivalent to doubling the readout noise. Preliminary analysis of a HAT-P-14b transit time-series indicates that it is difficult to remove all the noise in pixels with partially saturated ramps. Overall, the SOSS delivers performance at the level required to tackle key exoplanet science programs such as detecting secondary atmospheres on terrestrial planets and measuring abundances of several chemical species in gas giants.

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A broadband thermal emission spectrum of the ultra-hot Jupiter WASP-18b

Close-in giant exoplanets with temperatures greater than 2,000 K (''ultra-hot Jupiters'') have been the subject of extensive efforts to determine their atmospheric properties using thermal emission measurements from the Hubble and Spitzer Space Telescopes. However, previous studies have yielded inconsistent results because the small sizes of the spectral features and the limited information content of the data resulted in high sensitivity to the varying assumptions made in the treatment of instrument systematics and the atmospheric retrieval analysis. Here we present a dayside thermal emission spectrum of the ultra-hot Jupiter WASP-18b obtained with the NIRISS instrument on JWST. The data span 0.85 to 2.85 $μ$m in wavelength at an average resolving power of 400 and exhibit minimal systematics. The spectrum shows three water emission features (at $>$6$σ$ confidence) and evidence for optical opacity, possibly due to H$^-$, TiO, and VO (combined significance of 3.8$σ$). Models that fit the data require a thermal inversion, molecular dissociation as predicted by chemical equilibrium, a solar heavy element abundance (''metallicity'', M/H = 1.03$_{-0.51}^{+1.11}$ $\times$ solar), and a carbon-to-oxygen (C/O) ratio less than unity. The data also yield a dayside brightness temperature map, which shows a peak in temperature near the sub-stellar point that decreases steeply and symmetrically with longitude toward the terminators.

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Eureka!: An End-to-End Pipeline for JWST Time-Series Observations

$\texttt{Eureka!}$ is a data reduction and analysis pipeline for exoplanet time-series observations, with a particular focus on JWST data. Over the next 1-2 decades, JWST will pursue four main science themes: Early Universe, Galaxies Over Time, Star Lifecycle, and Other Worlds. Our focus is on providing the astronomy community with an open source tool for the reduction and analysis of time-series observations of exoplanets in pursuit of the fourth of these themes, Other Worlds. The goal of $\texttt{Eureka!}$ is to provide an end-to-end pipeline that starts with uncalibrated FITS files and ultimately yields precise exoplanet spectra. The pipeline has a modular structure with six stages, and each stage uses a "Eureka! Control File" (ECF) to allow for easy control of the pipeline's behavior. Stage 5 also uses a "Eureka! Parameter File" (EPF) to control the fitted parameters. We provide template ECFs for the MIRI, NIRCam, NIRISS, and NIRSpec instruments on JWST and the WFC3 instrument on the Hubble Space Telescope (HST). These templates give users a good starting point for their analyses, but $\texttt{Eureka!}$ is not intended to be used as a black box tool, and users should expect to fine-tune some settings for each observation in order to achieve optimal results. At each stage, the pipeline creates intermediate figures and outputs that allow users to compare $\texttt{Eureka!}$'s performance using different parameter settings or to compare $\texttt{Eureka!}$ with an independent pipeline. The ECF used to run each stage is also copied into the output folder from each stage to enhance reproducibility. Finally, while $\texttt{Eureka!}$ has been optimized for exoplanet observations (especially the latter stages of the code), much of the core functionality could also be repurposed for JWST time-series observations in other research domains thanks to $\texttt{Eureka!}$'s modularity.

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Evidence for the volatile-rich composition of a 1.5-$R_\oplus$ planet

The population of planets smaller than approximately $1.7~R_\oplus$ is widely interpreted as consisting of rocky worlds, generally referred to as super-Earths. This picture is largely corroborated by radial-velocity (RV) mass measurements for close-in super-Earths but lacks constraints at lower insolations. Here we present the results of a detailed study of the Kepler-138 system using 13 Hubble and Spitzer transit observations of the warm-temperate $1.51\pm0.04~R_\oplus$ planet Kepler-138 d ($T_{\mathrm{eq, A_B=0.3}}$~350 K) combined with new Keck/HIRES RV measurements of its host star. We find evidence for a volatile-rich "water world" nature of Kepler-138 d, with a large fraction of its mass contained in a thick volatile layer. This finding is independently supported by transit timing variations, RV observations ($M_d=2.1_{-0.7}^{+0.6}~M_\oplus$), as well as the flat optical/IR transmission spectrum. Quantitatively, we infer a composition of $11_{-4}^{+3}$\% volatiles by mass or ~51% by volume, with a 2000 km deep water mantle and atmosphere on top of a core with an Earth-like silicates/iron ratio. Any hypothetical hydrogen layer consistent with the observations ($<0.003~M_\oplus$) would have swiftly been lost on a ~10 Myr timescale. The bulk composition of Kepler-138 d therefore resembles those of the icy moons rather than the terrestrial planets in the solar system. We conclude that not all super-Earth-sized planets are rocky worlds, but that volatile-rich water worlds exist in an overlapping size regime, especially at lower insolations. Finally, our photodynamical analysis also reveals that Kepler-138 c ($R_c=1.51 \pm 0.04~R_\oplus$, $M_c=2.3_{-0.5}^{+0.6}~M_\oplus$) is a slightly warmer twin of Kepler-138 d, i.e., another water world in the same system, and we infer the presence of Kepler-138 e, a likely non-transiting planet at the inner edge of the habitable zone.

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Is the hot, dense sub-Neptune TOI-824b an exposed Neptune mantle? Spitzer detection of the hot day side and reanalysis of the interior composition

The Kepler and TESS missions revealed a remarkable abundance of sub-Neptune exoplanets. Despite this abundance, our understanding of the nature and compositional diversity of sub-Neptunes remains limited, to a large part because atmospheric studies via transmission spectroscopy almost exclusively aimed for low-density sub-Neptunes and even those were often affected by high-altitude clouds. The recent TESS discovery of the hot, dense TOI-824b ($2.93\,R_\oplus$ and $18.47\,M_\oplus$) opens a new window into sub-Neptune science by enabling the study of a dense sub-Neptune via secondary eclipses. Here, we present the detection of TOI-824b's hot day side via Spitzer secondary eclipse observations in the $3.6$ and $4.5\,\mathrm{μm}$ channels, combined with a reanalysis of its interior composition. The measured eclipse depths (142$^{+57}_{-52}$ and 245$^{+75}_{-77}$ ppm) and brightness temperatures (1463$^{+183}_{-196}$ and 1484$^{+180}_{-202}$ K) indicate a poor heat redistribution ($f>$ 0.49) and a low Bond albedo (A$_{B}<$ 0.26). We conclude that TOI-824b could be an "exposed Neptune mantle": a planet with a Neptune-like water-rich interior that never accreted a hydrogen envelope or that subsequently lost it. The hot day-side temperature is then naturally explained by a high-metallicity envelope re-emitting the bulk of the incoming radiation from the day side. TOI-824b's density is also consistent with a massive rocky core that accreted up to 1% of hydrogen, but the observed eclipse depths favor our high-metallicity GCM simulation to a solar-metallicity GCM simulation with a likelihood ratio of 7:1. The new insights into TOI-824b's nature suggest that the sub-Neptune population may be more diverse than previously thought, with some of the dense hot sub-Neptunes potentially not hosting a hydrogen-rich envelope as generally assumed for sub-Neptunes.

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Early Release Science of the exoplanet WASP-39b with JWST NIRCam

Measuring the metallicity and carbon-to-oxygen (C/O) ratio in exoplanet atmospheres is a fundamental step towards constraining the dominant chemical processes at work and, if in equilibrium, revealing planet formation histories. Transmission spectroscopy provides the necessary means by constraining the abundances of oxygen- and carbon-bearing species; however, this requires broad wavelength coverage, moderate spectral resolution, and high precision that, together, are not achievable with previous observatories. Now that JWST has commenced science operations, we are able to observe exoplanets at previously uncharted wavelengths and spectral resolutions. Here we report time-series observations of the transiting exoplanet WASP-39b using JWST's Near InfraRed Camera (NIRCam). The long-wavelength spectroscopic and short-wavelength photometric light curves span 2.0 - 4.0 $μ$m, exhibit minimal systematics, and reveal well-defined molecular absorption features in the planet's spectrum. Specifically, we detect gaseous H$_2$O in the atmosphere and place an upper limit on the abundance of CH$_4$. The otherwise prominent CO$_2$ feature at 2.8 $μ$m is largely masked by H$_2$O. The best-fit chemical equilibrium models favour an atmospheric metallicity of 1-100$\times$ solar (i.e., an enrichment of elements heavier than helium relative to the Sun) and a sub-stellar carbon-to-oxygen (C/O) ratio. The inferred high metallicity and low C/O ratio may indicate significant accretion of solid materials during planet formation or disequilibrium processes in the upper atmosphere.

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Early Release Science of the Exoplanet WASP-39b with JWST NIRSpec G395H

Measuring the abundances of carbon and oxygen in exoplanet atmospheres is considered a crucial avenue for unlocking the formation and evolution of exoplanetary systems. Access to an exoplanet's chemical inventory requires high-precision observations, often inferred from individual molecular detections with low-resolution space-based and high-resolution ground-based facilities. Here we report the medium-resolution (R$\sim$600) transmission spectrum of an exoplanet atmosphere between 3-5 $μ$m covering multiple absorption features for the Saturn-mass exoplanet WASP-39b, obtained with JWST NIRSpec G395H. Our observations achieve 1.46x photon precision, providing an average transit depth uncertainty of 221 ppm per spectroscopic bin, and present minimal impacts from systematic effects. We detect significant absorption from CO$_2$ (28.5$σ$) and H$_2$O (21.5$σ$), and identify SO$_2$ as the source of absorption at 4.1 $μ$m (4.8$σ$). Best-fit atmospheric models range between 3 and 10x solar metallicity, with sub-solar to solar C/O ratios. These results, including the detection of SO$_2$, underscore the importance of characterising the chemistry in exoplanet atmospheres, and showcase NIRSpec G395H as an excellent mode for time series observations over this critical wavelength range.

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