arXiv subjects

Cecilia Ceccarelli

Publications and source records attributed to Cecilia Ceccarelli.

At least 109 records · Page 6Linked to original sources

arXiv2015

Constraining the abundances of complex organics in the inner regions of solar-type protostars

The high abundances of Complex Organic Molecules (COMs) with respect to methanol, the most abundant COM, detected towards low-mass protostars, tend to be underpredicted by astrochemical models. This discrepancy might come from the large beam of the single-dish telescopes, encompassing several components of the studied protostar, commonly used to detect COMs. To address this issue, we have carried out multi-line observations of methanol and several COMs towards the two low-mass protostars NGC1333-IRAS2A and -IRAS4A with the Plateau de Bure interferometer at an angular resolution of 2 arcsec, resulting in the first multi-line detection of the O-bearing species glycolaldehyde and ethanol and of the N-bearing species ethyl cyanide towards low-mass protostars other than IRAS 16293. The high number of detected transitions from COMs (more than 40 methanol transitions for instance) allowed us to accurately derive the source size of their emission and the COMs column densities. The COMs abundances with respect to methanol derived towards IRAS2A and IRAS4A are slightly, but not substantitally, lower than those derived from previous single-dish observations. The COMs abundance ratios do not vary significantly with the protostellar luminosity, over five orders of magnitude, implying that low-mass hot corinos are quite chemically rich as high-mass hot cores. Astrochemical models still underpredict the abundances of key COMs, such as methyl formate or di-methyl ether, suggesting that our understanding of their formation remains incomplete.

astro-ph.SR↗

arXiv2015

Formation of complex organic molecules in cold objects: the role of gas phase reactions

While astrochemical models are successful in reproducing many of the observed interstellar species, they have been struggling to explain the observed abundances of complex organic molecules. Current models tend to privilege grain surface over gas phase chemistry in their formation. One key assumption of those models is that radicals trapped in the grain mantles gain mobility and react on lukewarm (>30 K) dust grains. Thus, the recent detections of methyl formate (MF) and dimethyl ether (DME) in cold objects represent a challenge and may clarify the respective role of grain surface and gas phase chemistry. We propose here a new model to form DME and MF with gas phase reactions in cold environments, where DME is the precursor of MF via an efficient reaction overlooked by previous models. Furthermore, methoxy, a precursor of DME, is also synthetized in the gas phase from methanol, which is desorbed by a non-thermal process from the ices. Our new model reproduces fairy well the observations towards L1544. It also explains, in a natural way, the observed correlation between DME and MF. We conclude that gas phase reactions are major actors in the formation of MF, DME and methoxy in cold gas. This challenges the exclusive role of grain-surface chemistry and favours a combined grain-gas chemistry.

astro-ph.SR↗

arXiv2014

The origin of complex organic molecules in prestellar cores

Complex organic molecules (COMs) have been detected in a variety of environments, including cold prestellar cores. Given the low temperature of these objects, these last detections challenge existing models. We report here new observations towards the prestellar core L1544. They are based on an unbiased spectral survey of the 3mm band at the IRAM-30m telescope, as part of the Large Program ASAI. The observations allow us to provide the full census of the oxygen bearing COMs in this source. We detected tricarbon monoxide, methanol, acetaldehyde, formic acid, ketene, and propyne with abundances varying from 5e-11 to 6e-9. The non-LTE analysis of the methanol lines shows that they are likely emitted at the border of the core, at a radius of ~8000 AU where T~10 K and nH2~2e4 cm-3. Previous works have shown that water vapour is enhanced in the same region because of the photodesorption of water ices. We propose that a non-thermal desorption mechanism is also responsible for the observed emission of methanol and COMs from the same layer. The desorbed oxygen and a tiny amount of desorbed methanol and ethene are enough to reproduce the abundances of tricarbon monoxide, methanol, acetaldehyde and ketene measured in L1544. These new findings open the possibility that COMs in prestellar cores originate in a similar outer layer rather than in the dense inner cores, as previously assumed, and that their formation is driven by the non-thermally desorbed species.

astro-ph.SR↗

arXiv2014

Cosmic ray induced ionisation of a molecular cloud shocked by the W28 supernova remnant

Cosmic rays are an essential ingredient in the evolution of the interstellar medium, as they dominate the ionisation of the dense molecular gas, where stars and planets form. However, since they are efficiently scattered by the galactic magnetic fields, many questions remain open, such as where exactly they are accelerated, what is their original energy spectrum, and how they propagate into molecular clouds. In this work we present new observations and discuss in detail a method that allows us to measure the cosmic ray ionisation rate towards the molecular clouds close to the W28 supernova remnant. To perform these measurements, we use CO, HCO$^+$, and DCO$^+$ millimetre line observations and compare them with the predictions of radiative transfer and chemical models away from thermodynamical equilibrium. The CO observations allow us to constrain the density, temperature, and column density towards each observed position, while the DCO$^+$/HCO$^+$ abundance ratios provide us with constraints on the electron fraction and, consequently, on the cosmic ray ionisation rate. Towards positions located close to the supernova remnant, we find cosmic ray ionisation rates much larger ($\gtrsim100$) than those in standard galactic clouds. Conversely, towards one position situated at a larger distance, we derive a standard cosmic ray ionisation rate. Overall, these observations support the hypothesis that the $γ$ rays observed in the region have a hadronic origin. In addition, based on CR diffusion estimates, we find that the ionisation of the gas is likely due to $0.1 -1$ GeV cosmic rays. Finally, these observations are also in agreement with the global picture of cosmic ray diffusion, in which the low-energy tail of the cosmic ray population diffuses at smaller distances than the high-energy counterpart.

astro-ph.GA↗

arXiv2014

Deuterium Fractionation: the Ariadne's Thread from the Pre-collapse Phase to Meteorites and Comets today

The Solar System formed about 4.6 billion years ago from a condensation of matter inside a molecular cloud. Trying to reconstruct what happened is the goal of this chapter. For that, we put together our understanding of Galactic objects that will eventually form new suns and planetary systems, with our knowledge on comets, meteorites and small bodies of the Solar System today. Our specific tool is the molecular deuteration, namely the amount of deuterium with respect to hydrogen in molecules. This is the Ariadne's thread that helps us to find the way out from a labyrinth of possible histories of our Solar System. The chapter reviews the observations and theories of the deuterium fractionation in pre-stellar cores, protostars, protoplanetary disks, comets, interplanetary dust particles and meteorites and links them together trying to build up a coherent picture of the history of the Solar System formation. We emphasise the interdisciplinary nature of the chapter, which gathers together researchers from different communities with the common goal of understanding the Solar System history.

astro-ph.EP↗

arXiv2013

Water deuterium fractionation in the inner regions of two solar type protostars

The [HDO]/[H2O] ratio is a crucial parameter for probing the history of water formation. So far, it has been measured for only three solar type protostars and yielded different results, possibly pointing to a substantially different history in their formation. In the present work, we report new interferometric observations of the HDO 4 2,2 - 4 2,3 line for two solar type protostars, IRAS2A and IRAS4A, located in the NGC1333 region. In both sources, the detected HDO emission originates from a central compact unresolved region. Comparison with previously published interferometric observations of the H218$O 3 1,3 - 2 2,0 line shows that the HDO and H$_2$O lines mostly come from the same region. A non-LTE LVG analysis of the HDO and H218$O line emissions, combined with published observations, provides a [HDO]/[H2O] ratio of 0.3 - 8 % in IRAS2A and 0.5 - 3 % in IRAS4A. First, the water fractionation is lower than that of other molecules such as formaldehyde and methanol in the same sources. Second, it is similar to that measured in the solar type protostar prototype, IRAS16293-2422, and, surprisingly enough, larger than that measured in NGC1333 IRAS4B. {The comparison of the measured values towards IRAS2A and IRAS4A with the predictions of our gas-grain model GRAINOBLE gives similar conclusions to those for IRAS 16293, arguing that these protostars {share} a similar chemical history, although they are located in different clouds.

astro-ph.GA↗

arXiv2012

Water ice deuteration: a tracer of the chemical history of protostars

Context. Millimetric observations have measured high degrees of molecular deuteration in several species seen around low-mass protostars. The Herschel Space Telescope, launched in 2009, is now providing new measures of the deuterium fractionation of water, the main constituent of interstellar ices. Aims. We aim at theoretically studying the formation and the deuteration of water, which is believed to be formed on interstellar grain surfaces in molecular clouds. Methods. We used our gas-grain astrochemical model GRAINOBLE, which considers the multilayer formation of interstellar ices. We varied several input parameters to study their impact on water deuteration. We included the treatment of ortho- and para-states of key species, including H2, which affects the deuterium fractionation of all molecules. The model also includes relevant laboratory and theoretical works on the water formation and deuteration on grain surfaces. In particular, we computed the transmission probabilities of surface reactions using the Eckart model, and we considered ice photodissociation following molecular dynamics simulations. Results. The use of a multilayer approach allowed us to study the influence of various parameters on the abundance and the deuteration of water. Deuteration of water is found to be very sensitive to the ortho-to-para ratio of H2 and to the total density, but it also depends on the gas/grain temperatures and the visual extinction of the cloud. Since the deuteration is very sensitive to the physical conditions, the comparison with sub-millimetric observation towards the low-mass protostar IRAS 16293 allows us to suggest that water ice is formed together with CO2 in molecular clouds with limited density, whilst formaldehyde and methanol are mainly formed in a later phase, where the condensation becomes denser and colder.

astro-ph.GA↗

arXiv2012

Herschel CHESS discovery of the fossil cloud that gave birth to the Trapezium and Orion KL

As part of the Herschel Guaranteed Time Key Programme CHESS, we present the discovery of a diffuse gas component in the foreground of the intermediate-mass protostar OMC-2 FIR 4, located in the Orion A region. Making use of the full HIFI spectrum of OMC-2 FIR 4 obtained in CHESS, we detected several ground-state lines from OH+, H2O+, HF, and CH+, all of them seen in absorption against the dust continuum emission of the protostar's envelope. The lines peak at a velocity of 9 km/s, which is blue-shifted by 2 km/s with respect to the systemic velocity of OMC-2 FIR 4 (V = 11.4 km/s). We derived column densities for each species, as well as an upper limit to the column density of the undetected H3O+. In order to model and characterise the foreground cloud, we used the Meudon PDR code to run a homogeneous grid of models that spans a reasonable range of densities, visual extinctions, cosmic ray ionisation rates and far-ultraviolet (FUV) radiation fields. The results of our modelling indicate that the foreground cloud is composed of predominantly neutral diffuse gas (n(H) = 100 cm-3) and is heavily irradiated by an external source of FUV that most likely arises from the nearby Trapezium OB association. The cloud is 6 pc thick and bears many similarities with the so-called C+ interface between Orion-KL and the Trapezium cluster, 2 pc south of OMC-2 FIR 4. We conclude that the foreground cloud we detected is an extension of the C+ interface seen in the direction of Orion KL, and interpret it to be the remains of the parental cloud of OMC-1, which extends from OMC-1 up to OMC-2.

astro-ph.GA↗

arXiv2012

Our astrochemical heritage

Our Sun and planetary system were born about 4.5 billion years ago. How did this happen and what is our heritage from these early times? This review tries to address these questions from an astrochemical point of view. On the one hand, we have some crucial information from meteorites, comets and other small bodies of the Solar System. On the other hand, we have the results of studies on the formation process of Sun-like stars in our Galaxy. These results tell us that Sun-like stars form in dense regions of molecular clouds and that three major steps are involved before the planet formation period. They are represented by the pre-stellar core, protostellar envelope and protoplanetary disk phases. Simultaneously with the evolution from one phase to the other, the chemical composition gains increasing complexity. In this review, we first present the information on the chemical composition of meteorites, comets and other small bodies of the Solar System, which is potentially linked to the first phases of the Solar System's formation. Then we describe the observed chemical composition in the pre-stellar core, protostellar envelope and protoplanetary disk phases, including the processes that lead to them. Finally, we draw together pieces from the different objects and phases to understand whether and how much we inherited chemically from the time of the Sun's birth.

astro-ph.GA↗

arXiv2012

Hydrogen Fluoride in High-Mass Star-forming Regions

Hydrogen fluoride has been established to be an excellent tracer of molecular hydrogen in diffuse clouds. In denser environments, however, the HF abundance has been shown to be approximately two orders of magnitude lower. We present Herschel/HIFI observations of HF J=1-0 toward two high-mass star formation sites, NGC6334 I and AFGL 2591. In NGC6334 I the HF line is seen in absorption in foreground clouds and the source itself, while in AFGL 2591 HF is partially in emission. We find an HF abundance with respect to H2 of 1.5e-8 in the diffuse foreground clouds, whereas in the denser parts of NGC6334 I, we derive a lower limit on the HF abundance of 5e-10. Lower HF abundances in dense clouds are most likely caused by freeze out of HF molecules onto dust grains in high-density gas. In AFGL 2591, the view of the hot core is obstructed by absorption in the massive outflow, in which HF is also very abundant 3.6e-8) due to the desorption by sputtering. These observations provide further evidence that the chemistry of interstellar fluorine is controlled by freeze out onto gas grains.

astro-ph.GA↗

arXiv2012

A study of deuterated water in the low-mass protostar IRAS16293-2422

The HDO/H2O ratio is a powerful diagnostic to understand the evolution of water from the first stages of star formation to the formation of planets and comets. Our aim is to determine precisely the abundance distribution of HDO towards the low-mass protostar IRAS16293-2422 and learn more about the water formation mechanisms by determining the HDO/H2O abundance ratio. A spectral survey of the source IRAS16293-2422 was carried out in the framework of the CHESS Herschel Key program with the HIFI instrument, allowing the detection of numerous HDO lines. Other transitions have been observed previously with ground-based telescopes. The spherical Monte Carlo radiative transfer code RATRAN was used to reproduce the observed line profiles of HDO by assuming an abundance jump. To determine the H2O abundance throughout the envelope, a similar study was made of the H2-18O observed lines, as the H2O main isotope lines are contaminated by the outflows. We derive an inner HDO abundance of 1.7e-7 and an outer HDO abundance of 8e-11. To reproduce the HDO absorption lines, it is necessary to add an absorbing layer in front of the envelope. It may correspond to a water-rich layer created by the photodesorption of the ices at the edges of the molecular cloud. The HDO/H2O ratio is ~1.4-5.8% in the hot corino whereas it is ~0.2-2.2% in the outer envelope. It is estimated at ~4.8% in the added absorbing layer. Although it is clearly higher than the cosmic D/H abundance, the HDO/H2O ratio remains lower than the D/H ratio derived for other deuterated molecules observed in the same source. The similarity of the ratios derived in the hot corino and in the added absorbing layer suggests that water formed before the gravitational collapse of the protostar, contrary to formaldehyde and methanol, which formed later once the CO molecules had depleted on the grains.

astro-ph.GA↗

arXiv2012

Formaldehyde and methanol deuteration in protostars: fossiles from a past fast high density pre-collapse phase

Extremely high deuteration of several molecules have been observed around low mass protostars since a decade. Among them, formaldehyde and methanol present particularly high deuteration, with observations of abundant doubly and triply deuterated forms. Both species are thought to be mainly formed on interstellar grains during the low temperature and dense pre-collapse phase by H and D atom additions on the iced CO. We present here a theoretical study of the formaldehyde and methanol deuteration obtained with our gas-grain model, GRAINOBLE. This model takes into account the multilayer nature of the mantle and explores the robustness of the results against the uncertainties of poorly constrained chemical and surface model parameters. The comparison of the model predictions with the observations leads to two major results: i) the observed high deuteration is obtained during the last phase of the pre-collapse stage, when the density reaches 5 10^6 cm^-3, and this phase is fast, lasting only several thousands years. ii) D and H abstraction and substitution reactions are crucial in making up the observed deuteration ratios; This work shows the power of chemical composition as a tool to reconstruct the past history of protostars.

astro-ph.GA↗

arXiv2012

The CHESS survey of the L1157-B1 shock: the dissociative jet shock as revealed by Herschel--PACS

Outflows generated by protostars heavily affect the kinematics and chemistry of the hosting molecular cloud through strong shocks that enhance the abundance of some molecules. L1157 is the prototype of chemically active outflows, and a strong shock, called B1, is taking place in its blue lobe between the precessing jet and the hosting cloud. We present the Herschel-PACS 55--210 micron spectra of the L1157-B1 shock, showing emission lines from CO, H2O, OH, and [OI]. The spatial resolution of the PACS spectrometer allows us to map the warm gas traced by far-infrared (FIR) lines with unprecedented detail. The rotational diagram of the high-Jup CO lines indicates high-excitation conditions (Tex ~ 210 +/- 10 K). We used a radiative transfer code to model the hot CO gas emission observed with PACS and in the CO (13-12) and (10-9) lines measured by Herschel-HIFI. We derive 200 10^5 cm-3. The CO emission comes from a region of about 7 arcsec located at the rear of the bow shock where the [OI] and OH emission also originate. Comparison with shock models shows that the bright [OI] and OH emissions trace a dissociative J-type shock, which is also supported by a previous detection of [FeII] at the same position. The inferred mass-flux is consistent with the "reverse" shock where the jet is impacting on the L1157-B1 bow shock. The same shock may contribute significantly to the high-Jup CO emission.

astro-ph.GA↗

arXiv2012

Rotating Disks and Non-Kinematic Double Peaks

Double-peaked line profiles are commonly considered a hallmark of rotating disks, with the distance between the peaks a measure of the rotation velocity. However, double-peaks can arise also from radiative transfer effects in optically thick non-rotating sources. Utilizing exact solutions of the line transfer problem we present a detailed study of line emission from geometrically thin Keplerian disks. We derive the conditions for emergence of kinematic double peaks in optically thin and thick disks, and find that it is generally impossible to disentangle the effects of kinematics and line opacity in observed double-peaked profiles. Unless supplemented by additional information, a double-peaked profile alone is not a reliable indicator of a rotating disk. In certain circumstances, triple and quadruple profiles might be better indicators of rotation in optically thick disks.

astro-ph.GA↗

arXiv2011

Multilayer modeling of porous grain surface chemistry I. The GRAINOBLE model

Mantles of iced water, mixed with CO, H2CO, and CH3OH are formed during the so called prestellar core phase. In addition, radicals are also thought to be formed on the grain surfaces, and to react to form complex organic molecules later on, during the warm-up phase of the protostellar evolution. We aim to study the formation of the grain mantles during the prestellar core phase and the abundance of H2CO, CH3OH, and radicals trapped in them. We have developed a macrosopic statistic multilayer model that follows the formation of grain mantles with time and that includes two effects that may increase the number of radicals trapped in the mantles: i) at each time of the mantle formation, only the surface layer is chemically active rather than the entire bulk, and ii) the porous structure of grains allows to trap reactive particles. The model considers a network of H, O and CO forming neutral species such as water, CO, formaldehyde, and methanol, plus several radicals. We run a large grid of models to study the impact of the mantle multilayer nature and grain porous structure. In addition, we explored the influence of the uncertainty of other key parameters on the mantle composition. Our model predicts relatively large abundances of radicals. In addition, the multilayer approach makes it possible to follow the chemical differentiation within the grain mantle, showing that the mantles are far from being uniform. For example, methanol is mostly present in the outer layers of the mantles whereas CO and other reactive species are trapped in the inner layers. The overall mantle composition depends on the density and age of the prestellar core, and on some microscopic parameters. Comparison with observations allows us to constrain the value of few parameters and provide some indications on the physical conditions during the formation of the ices.

astro-ph.GA↗

arXiv2010

TIMASSS : The IRAS16293-2422 Millimeter And Submillimeter Spectral Survey: Tentative Detection of Deuterated Methyl Formate (DCOOCH3)

High deuterium fractionation is observed in various types of environment such as prestellar cores, hot cores and hot corinos. It has proven to be an efficient probe to study the physical and chemical conditions of these environments. The study of the deuteration of different molecules helps us to understand their formation. This is especially interesting for complex molecules such as methanol and bigger molecules for which it may allow to differentiate between gas-phase and solid-state formation pathways. Methanol exhibits a high deuterium fractionation in hot corinos. Since CH3OH is thought to be a precursor of methyl formate we expect that deuterated methyl formate is produced in such environments. We have searched for the singly-deuterated isotopologue of methyl formate, DCOOCH3, in IRAS 16293-2422, a hot corino well-known for its high degree of methanol deuteration. We have used the IRAM/JCMT unbiased spectral survey of IRAS 16293-2422 which allows us to search for the DCOOCH3 rotational transitions within the survey spectral range (80-280 GHz, 328-366 GHz). The expected emission of deuterated methyl formate is modelled at LTE and compared with the observations.} We have tentatively detected DCOOCH3 in the protostar IRAS 16293-2422. We assign eight lines detected in the IRAM survey to DCOOCH3. Three of these lines are affected by blending problems and one line is affected by calibration uncertainties, nevertheless the LTE emission model is compatible with the observations. A simple LTE modelling of the two cores in IRAS 16293-2422, based on a previous interferometric study of HCOOCH3, allows us to estimate the amount of DCOOCH3 in IRAS 16293-2422. Adopting an excitation temperature of 100 K and a source size of 2\arcsec and 1\farcs5 for the A and B cores, respectively, we find that N(A,DCOOCH3) = N(B,DCOOCH3) ~ 6.10^14 /cm2. The derived deuterium fractionation is ~ 15%, consistent with values for other deuterated species in this source and much greater than that expected from the deuterium cosmic abundance. DCOOCH3, if its tentative detection is confirmed, should now be considered in theoretical models that study complex molecule formation and their deuteration mechanisms. Experimental work is also needed to investigate the different chemical routes leading to the formation of deuterated methyl formate.

astro-ph.GA↗

arXiv2010

The solar type protostar IRAS16293-2422: new constraints on the physical structure

Context: The low mass protostar IRAS16293-2422 is a prototype Class 0 source with respect to the studies of the chemical structure during the initial phases of life of Solar type stars. Aims: In order to derive an accurate chemical structure, a precise determination of the source physical structure is required. The scope of the present work is the derivation of the structure of IRAS16293-2422. Methods: We have re-analyzed all available continuum data (single dish and interferometric, from millimeter to MIR) to derive accurate density and dust temperature profiles. Using ISO observations of water, we have also reconstructed the gas temperature profile. Results: Our analysis shows that the envelope surrounding IRAS16293-2422 is well described by the Shu "inside-out" collapsing envelope model or a single power-law density profile with index equal to 1.8. In contrast to some previous studies, our analysis does not show evidence of a large (>/- 800 AU in diameter) cavity. Conclusions: Although IRAS16293-2422 is a multiple system composed by two or three objects, our reconstruction will be useful to derive the chemical structure of the large cold envelope surrounding these objects and the warm component, treated here as a single source, from single-dish observations of molecular emission.

astro-ph.SR↗

arXiv2009

Training of Instrumentalists and Development of New Technologies on SOFIA

This white paper is submitted to the Astronomy and Astrophysics 2010 Decadal Survey (Astro2010)1 Committee on the State of the Profession to emphasize the potential of the Stratospheric Observatory for Infrared Astronomy (SOFIA) to contribute to the training of instrumentalists and observers, and to related technology developments. This potential goes beyond the primary mission of SOFIA, which is to carry out unique, high priority astronomical research. SOFIA is a Boeing 747SP aircraft with a 2.5 meter telescope. It will enable astronomical observations anywhere, any time, and at most wavelengths between 0.3 microns and 1.6 mm not accessible from ground-based observatories. These attributes, accruing from the mobility and flight altitude of SOFIA, guarantee a wealth of scientific return. Its instrument teams (nine in the first generation) and guest investigators will do suborbital astronomy in a shirt-sleeve environment. The project will invest $10M per year in science instrument development over a lifetime of 20 years. This, frequent flight opportunities, and operation that enables rapid changes of science instruments and hands-on in-flight access to the instruments, assure a unique and extensive potential - both for training young instrumentalists and for encouraging and deploying nascent technologies. Novel instruments covering optical, infrared, and submillimeter bands can be developed for and tested on SOFIA by their developers (including apprentices) for their own observations and for those of guest observers, to validate technologies and maximize observational effectiveness.

astro-ph.IM↗