SearcharxivSearch

arXiv subjects

Ch. Rab

Publications and source records attributed to Ch. Rab.

At least 19 recordsLinked to original sources

Gas chemistry in the dust depleted inner regions of protoplanetary disks. I. Near-IR spectra and overtones

The molecular composition inside the dust sublimation zones of protoplanetary disks is mostly unknown but important to understanding terrestrial planet formation. A few molecules have been observed from this region, specifically CO, H2O, OH and SiO. The small surface area makes observing this region difficult, hence modeling is required to disentangle the innermost disk from regions further out. We model a protoplanetary disk around a Herbig-type star including the dust depleted inner region (approx. 0.1-0.3 au) and aim to investigate the chemistry of this region and explain existing and future observations. Methods. We post-process the dust and gas distribution of a magnetohydrostatic model with the radiation thermochemical code ProDiMo to study the chemistry and to produce observables. We find that the dust free inner disk is a molecular rich environment, where besides CO we also find H2, H2O and SiO. The gas temperature profile is complex and fluctuates between 700 and 2000 K, which is warm enough to produce CO overtone line emission. Next to the CO overtone lines we also find strong high J-level fundamental CO lines between 4.3 and 4.6 micron. The elemental enrichment of Si due to dust sublimation leads to 2 orders of magnitude more SiO abundance. The SiO gas has average temperatures of approx. 1000 K resulting in strong SiO overtone emission in the spectral range between 4 and 4.3 micron. We predict that the gas density in the dust depleted inner disk is high enough to allow for H2 formation, resulting in an molecular rich environment. For our representative Herbig model, the dust-depleted inner disk is responsible for at least 90% of the line emission for CO and H2O between 1 and 28 micron. Next to CO overtone lines, SiO overtone lines are expected to be an important tracer of a dust free inner disk.

astro-ph.SR

The SPHERE view of the Orion star-forming region

We present SPHERE/IRDIS H-band data for a sample of 23 stars in the Orion Star forming region observed within the DESTINYS (Disk Evolution Study Through Imaging of Nearby Young Stars) program. We use polarization differential imaging in order to detect scattered light from circumstellar dust. From the scattered light observations we characterize the disk orientation, radius and contrast. We analyse the disks in context of the stellar parameters and the environment of the Orion star-forming region. We use ancillary X-shooter spectroscopic observations to characterize the central stars in the systems. We furthermore use a combination of new and archival ALMA mm-continuum observations to characterize the dust masses present in the circumstellar disks. Within our sample we detect extended circumstellar disks in 10 of 23 systems. Of these, three are exceptionally extended (V351 Ori, V599 Ori and V1012 Ori) and show scattered light asymmetries which may indicate perturbations by embedded planets or (in the case of V599 Ori) by an outer stellar companion. Our high resolution imaging observations are also sensitive to close (sub)stellar companions and we detect 9 such objects in our sample of which 5 were previously unknown. We find in particular a possible sub-stellar companion (either a very low mass star or a high mass brown dwarf) 137 au from the star RY Ori. We find a strong anti-correlation between disk detection and multiplicity, with only 2 of our 10 disk detections located in stellar multiple systems. We also find a correlation between scattered light contrast and the millimetre flux suggesting that disks that have a high dust content are typically bright in near-infrared scattered light. Conversely we do not find significant correlations between scattered light contrast of the disks and the stellar mass or age.

astro-ph.SR

High-resolution [OI] line spectral mapping of TW Hya consistent with X-ray driven photoevaporation

Theoretical models indicate that photoevaporative and magnetothermal winds play a crucial role in the evolution and dispersal of protoplanetary disks and affect the formation of planetary systems. However, it is still unclear what wind-driving mechanism is dominant or if both are at work, perhaps at different stages of disk evolution. Recent spatially resolved observations by Fang et al. (2023) of the [OI] 6300 Angstrom spectral line, a common disk wind tracer, in TW Hya revealed that about 80% of the emission is confined to the inner few au of the disk. In this work, we show that state-of-the-art X-ray driven photoevaporation models can reproduce the compact emission and the line profile of the [OI] 6300 Angstrom line. Furthermore, we show that the models also simultaneously reproduce the observed line luminosities and detailed spectral profiles of both the [OI] 6300 Angstrom and the [NeII] 12.8 micron lines. While MHD wind models can also reproduce the compact radial emission of the [OI] 6300 Angstrom line, they fail to match the observed spectral profile of the [OI] 6300 Angstrom line and underestimate the luminosity of the [NeII] 12.8 micron line by a factor of three. We conclude that, while we cannot exclude the presence of an MHD wind component, the bulk of the wind structure of TW Hya is predominantly shaped by a photoevaporative flow.

astro-ph.EP

Constraining the gas distribution in the PDS 70 disk as a method to assess the effect of planet-disk interactions

Embedded planets are potentially the cause of substructures like gaps and cavities observed in several protoplanetary disks. Thus, the substructures observed in the continuum and in line emission encode information about the presence of planets in the system and how they interact with the natal disk. The pre-transitional disk around the star PDS 70 is the first case of two young planets imaged within a dust depleted gap that was likely carved by themselves. We aim to determine the spatial distribution of the gas and dust components in the PDS 70 disk. The axisymmetric substructures observed in the resulting profiles are interpreted in the context of planet-disk interactions. We develop a thermo-chemical forward model for an axisymmetric disk to explain a subset of the Atacama Large Millimeter/Submillimeter Array (ALMA) band 6 observations of three CO isotopologues plus the continuum towards PDS 70. Combining the inferred gas and dust distributions, the model results in a variable gas-to-dust ratio profile throughout the disk that spans two orders of magnitude within the first $130$ au and shows a step gradient towards the outer disk, which is consistent with the presence of a pressure maxima driven by planet-disk interactions. We find a gas density drop factor of ${\sim} 19$ at the location of the planet PDS 70 c with respect to the peak gas density at $75$ au. Combining this value with literature results on the hydrodynamics of planet-disk interactions, we find this gas gap depth to be consistent with independent planet mass estimates from infrared observations. Our findings point towards gas stirring processes taking place in the common gap due to the gravitational perturbation of both planets.

astro-ph.EP

Massive pre-main-sequence stars in M17 -- Modelling hydrogen and dust in MYSO disks

The young massive-star-forming region M17 contains optically visible massive pre-main-sequence stars that are surrounded by circumstellar disks. Such disks are expected to disappear when these stars reach the main sequence. The physical and dynamical structure of these remnant disks are poorly constrained, especially the inner regions where accretion, photo-evaporation, and companion formation and migration may be ongoing. We aim to constrain the physical properties of the inner parts of the circumstellar disks of massive young stellar objects B243 (6 Msun) and B331 (12 Msun), two systems for which the central star has been detected and characterized previously despite strong dust extinction. Two-dimensional radiation thermo-chemical modelling with ProDiMo of double-peaked hydrogen lines of the Paschen and Brackett series observed with X-shooter was used to probe the properties of the inner disks. Additionally, the dust structure was studied by fitting the optical and near-infrared spectral energy distribution. B243 features a hot gaseous inner disk with dust at the sublimation radius at 3 AU. The disk appears truncated at roughly 6.5 AU; a cool outer disk of gas and dust may be present, but it cannot be detected with our data. B331 also has a hot gaseous inner disk. A gap separates the inner disk from a colder dusty outer disk starting at up to 100 AU. In both sources the inner disk extends to almost the stellar surface. Chemistry is essential for the ionization of hydrogen in these disks. The lack of a gap between the central objects and these disks suggests that they accrete through boundary-layer accretion. This would exclude the stars having a strong magnetic field. Their structures suggest that both disks are transitional in nature, that is to say they are in the process of being cleared, either through boundary-layer accretion, photo-evaporation, or through companion activity.

astro-ph.SR

Interpreting molecular hydrogen and atomic oxygen line emission of T Tauri disks with photoevaporative disk-wind models

Winds in protoplanetary disks play an important role in their evolution and dispersal. However, what physical process is driving the winds is still unclear (i.e. magnetically vs thermally driven), and can only be understood by directly confronting theoretical models with observational data. We use hydrodynamic photoevaporative disk-wind models and post-process them with a thermo-chemical model to produce synthetic observables for the o-H$_2$ at 2.12 micron and [OI] at 0.63 micron spectral lines and directly compare the results to a sample of observations. Our photoevaporative disk-wind model is consistent with the observed signatures of the blueshifted narrow low-velocity component (NLVC), which is usually associated with slow disk winds, for both tracers. Only for one out of seven targets that show blueshifted NLVCs does the photoevaporative model fail to explain the observed line kinematics. Our results also indicate that interpreting spectral line profiles by simple methods, such as the thin-disk approximation, to determine the line emitting region can yield misleading conclusions. The photoevaporative disk-wind models are largely consistent with the studied observational data set, but it is not possible to clearly discriminate between different wind-driving mechanisms. Further improvements to the models, such as consistent modelling of the dynamics and chemistry and detailed modelling of individual targets would be beneficial. Furthermore, a direct comparison of magnetically driven disk-wind models to the observational data set is necessary in order to determine whether or not spatially unresolved observations of multiple wind tracers are sufficient to discriminate between theoretical models.

astro-ph.SR

Disk Evolution Study Through Imaging of Nearby Young Stars (DESTINYS): Scattered light detection of a possible disk wind in RY Tau

Disk winds are an important mechanism for accretion and disk evolution around young stars. The accreting intermediate-mass T-Tauri star RY Tau has an active jet and a previously known disk wind. Archival optical and new near-infrared observations of the RY Tau system show two horn-like components stretching out as a cone from RY Tau. Scattered light from the disk around RY Tau is visible in near-infrared but not seen at optical wavelengths. In the near-infrared, dark wedges that separates the horns from the disk, indicating we may see the scattered light from a disk wind. We use archived ALMA and SPHERE/ZIMPOL I-band observations combined with newly acquired SPEHRE/IRDIS H-band observations and available literature to build a simple geometric model of the RY Tau disk and disk wind. We use Monte Carlo radiative transfer modelling \textit{MCMax3D} to create comparable synthetic observations that test the effect of a dusty wind on the optical effect in the observations. We constrain the grain size and dust mass needed in the disk wind to reproduce the effect from the observations. A model geometrically reminiscent of a dusty disk wind with small micron to sub-micron size grains elevated above the disk can reproduce the optical effect seen in the observations. The mass in the obscuring component of the wind has been constrained to $1\times10^{-9} M_{\odot} \leq M \leq 5\times10^{-8} M_{\odot}$ which corresponds to a lower limit mass loss rate in the wind of about $\sim 1\times10^{-8}M_{\odot}\mathrm{yr}^{-1}$. While an illuminate dust cavity cannot be ruled out without measurements of the gas velocity, we argue that a magnetically launched disk wind is the most likely scenario.

astro-ph.SR

Dust entrainment in photoevaporative winds: Synthetic observations of transition disks

X-ray- and extreme-ultraviolet- (XEUV-) driven photoevaporative winds acting on protoplanetary disks around young T-Tauri stars may strongly impact disk evolution, affecting both gas and dust distributions. We compute dust densities for the wind regions of XEUV-irradiated transition disks with gap sizes of 20 and 30 AU, and determine whether they can be observed at wavelengths $0.7 \lesssim \lambda_\mathrm{obs} [\mu\mathrm{m}] \lesssim 1.8$ in scattered and polarised light with current instrumentation. For an XEUV-driven outflow around a $M_* = 0.7 \mathrm{M}_\odot$ T-Tauri star with $L_X = 2 \cdot 10^{30} \mathrm{erg/s}$, we find dust mass-loss rates $\dot{M}_\mathrm{dust} \lesssim 2.0 \cdot 10^{-3} \dot{M}_\mathrm{gas}$, and if we invoke vertical settling, the outflow is quite collimated. The synthesised images exhibit a distinct chimney-like structure. The relative intensity of these chimneys is low, but under optimal conditions, their detection may still be feasible with current instrumentation such as JWST NIRCam and SPHERE IRDIS.

astro-ph.EP

Self-consistent modelling of the dust component in protoplanetary and circumplanetary disks: the case of PDS 70

Direct observations of young stellar objects are important to test established theories of planet formation. PDS 70 is one of the few cases where robust evidence favours the presence of two planetary mass companions inside the gap of the transition disk. Those planets are believed to be going through the last stages of accretion from the protoplanetary disk, a process likely mediated by a circumplanetary disk (CPD). We aim to develop a three dimensional radiative transfer model for the dust component of the PDS 70 system which reproduces the system's global features observed at two different wavelengths: 855 $\mu\, \mathrm{m}$ with ALMA and 1.25 $\mu\, \mathrm{m}$ with VLT/SPHERE. We use this model to investigate the physical properties of the planetary companion PDS 70 c and its potential circumplanetary disk. We select initial values for the physical properties of the planet and CPD through appropriate assumptions about the nature and evolutionary stage of the object. We modify iteratively the properties of the protoplanetary disk until the predictions retrieved from the model are consistent with both data sets. We provide a model that jointly explains the global features of the PDS 70 system seen in submillimeter and polarised-scattered light. Our model suggests that spatial segregation of dust grains is present in the protoplanetary disk. The submillimeter modelling of the PDS 70 c source favours the presence of an optically thick CPD and places an upper limit to its dust mass of 0.7 $M_\oplus$. Furthermore, analysis of the thermal structure of the CPD demonstrates that the planet luminosity is the dominant heating mechanism of dust grains inside 0.6 au from the planet while heating by stellar photons dominates at larger planetocentric distances.

astro-ph.EP

Dust entrainment in photoevaporative winds: Densities and imaging

X-ray- and EUV- (XEUV-) driven photoevaporative winds acting on protoplanetary disks around young T-Tauri stars may crucially impact disk evolution, affecting both gas and dust distributions. We constrain the dust densities in a typical XEUV-driven outflow, and determine whether these winds can be observed at $\mu\mathrm{m}$-wavelengths in scattered and polarised light. For an XEUV-driven outflow around a $M_* = 0.7\,\mathrm{M}_\odot$ T-Tauri star with $L_X = 2 \cdot 10^{30}\,\mathrm{erg/s}$, we find a dust mass-loss rate $\dot{M}_\mathrm{dust} \lesssim 4.1 \cdot 10^{-11}\,\mathrm{M_\odot / yr}$ for an optimistic estimate of dust densities in the wind (compared to $\dot{M}_\mathrm{gas} \approx 3.7 \cdot 10^{-8}\,\mathrm{M_\odot / yr}$). The synthesised scattered-light images suggest a distinct chimney structure emerging at intensities $I/I_{\max} < 10^{-4.5}$ ($10^{-3.5}$) at $\lambda_\mathrm{obs} = 1.6$ ($0.4$) $\mu\mathrm{m}$, while the features in the polarised-light images are even fainter. Observations synthesised from our model do not exhibit clear features for SPHERE IRDIS, but show a faint wind signature for JWST NIRCam under optimal conditions. In conclusion, unambiguous detections of photoevaporative XEUV winds launched from primordial disks are at least challenging with current instrumentation; this provides a possible explanation as to why disk winds are not routinely detected in scattered or polarised light.

astro-ph.EP

New Mid-Infrared Imaging Constraints on Companions and Protoplanetary Disks around six Young Stars

Mid-infrared imaging traces the sub-micron and micron sized dust grains in protoplanetary disks and it offers constraints on the geometrical properties of the disks and potential companions, particularly if those companions have circumplanetary disks. We use the VISIR instrument and its upgrade NEAR on the VLT to take new mid-infrared images of five (pre-)transition disks and one circumstellar disk with proposed planets and obtain the deepest resolved mid-infrared observations to date in order to put new constraints on the sizes of the emitting regions of the disks and the presence of possible companions. We derotate and stack the data to find the disk properties. Where available we compare the data to ProDiMo (Protoplanetary Disk Model) radiation thermo-chemical models to achieve a deeper understanding of the underlying physical processes within the disks. We apply the circularised PSF subtraction method to find upper limits on the fluxes of possible companions and model companions with circumplanetary disks. We resolve three of the six disks and calculate position angles, inclinations and (upper limits to) sizes of emission regions in the disks, improving upper limits on two of the unresolved disks. In all cases the majority of the mid-IR emission comes from small inner disks or the hot inner rims of outer disks. We refine the existing ProDiMo HD 100546 model SED fit in the mid-IR by increasing the PAH abundance relative to the ISM, adopting coronene as the representative PAH, and increase the outer cavity radius to 22.3 AU. We produce flux estimates for putative planetary-mass companions and circumplanetary disks, ruling out the presence of planetary-mass companions with $L > 0.0028 L_{\odot}$ for $a > 180$ AU in the HD 100546 system. Upper limits of 0.5 mJy-30 mJy are obtained at 8 $\mu$m-12 $\mu$m for potential companions in the different disks.

astro-ph.EP

Interpreting high spatial resolution line observations of planet-forming disks with gaps and rings -- The case of HD 163296

Spatially resolved continuum observations of planet-forming disks show prominent ring and gap structures in their dust distribution. However, the picture from gas observations is much less clear and constraints on the radial gas density structure (i.e. gas gaps) remain rare and uncertain. We want to investigate the importance of thermo-chemical processes for the interpretation of high-spatial-resolution gas observations of planet-forming disks and their impact on derived gas properties. We apply the radiation thermo-chemical disk code ProDiMo (PROtoplanetary DIsk MOdel) to model self-consistently the dust and gas disk of HD 163296, using the DSHARP gas and dust observations. With this model we investigate the impact of dust gaps and gas gaps, considering chemistry and heating/cooling processes, on the observables and the derived gas properties. We find distinct peaks in the radial line intensity profiles of the CO line data of HD 163296 at the location of the dust gaps. Our model indicates that those peaks are not only a consequence of a gas temperature increase within the gaps but are mainly caused by the absorption of line emission from the back side of the disk by the dust rings. For two of the three prominent dust gaps in HD 163296, we find that thermo-chemical effects are negligible for deriving density gradients via measurements of the rotation velocity. However, for the gap with the highest dust depletion, the temperature gradient can be dominant and needs to be considered to derive accurate gas density profiles. Self-consistent gas and dust thermo-chemical modelling in combination with high-quality observations of multiple molecules are necessary to accurately derive gas gap depths and shapes. This is crucial to determine the origin of gaps and rings in planet-forming disks and to improve the mass estimates of forming planets if they are the cause of the gap.

astro-ph.SR

Disk Evolution Study Through Imaging of Nearby Young Stars (DESTINYS): A close low mass companion to ET Cha

To understand the formation of planetary systems, one needs to understand the initial conditions of planet formation, i.e. the young gas-rich planet forming disks. Spatially resolved high-contrast observations are of particular interest, since substructures in disks, linked to planet formation, can be detected and close companions or even planets in formation embedded in the disk can be revealed. In this study we present the first result of the DESTINYS survey (Disk Evolution Study Through Imaging of Nearby Young Stars). DESTINYS is an ESO/SPHERE large program that aims at studying disk evolution in scattered light, mainly focusing on a sample of low-mass stars (<1$M_\odot$) in nearby (~200 pc) star-forming regions. In this particular study we present the observations of the ET Cha (RECX 15) system, a nearby 'old' classical T Tauri star (5-8 Myr, ~100 pc), which is still strongly accreting. We use SPHERE/IRDIS in H-band polarimetric imaging mode to obtain high contrast images of the ET Cha system to search for scattered light from the circumstellar disk as well as thermal emission from close companions. We additionally employ VLT/NACO total intensity archival data taken in 2003. We report here the discovery of a low-mass (sub)stellar companion with SPHERE/IRDIS to ET Cha. We are estimating the mass of this new companion based on photometry. Depending on the system age it is a 5 Myr, 50 $M_{Jup}$ brown dwarf or an 8 Myr, 0.10 $M_\odot$ M-type pre-main-sequence star. We explore possible orbital solutions and discuss the recent dynamic history of the system. Independent of the precise companion mass we find that the presence of the companion likely explains the small size of the disk around ET Cha. The small separation of the binary pair indicates that the disk around the primary component is likely clearing from the outside in, explaining the high accretion rate of the system.

astro-ph.SR

Photoevaporation of the Jovian circumplanetary disk I. Explaining the orbit of Callisto and the lack of outer regular satellites

Context: The Galilean satellites are thought to have formed from a circumplanetary disk (CPD) surrounding Jupiter. When it reached a critical mass, Jupiter opened an annular gap in the solar protoplanetary disk (PPD) that might have exposed the CPD to radiation from the young Sun or from the stellar cluster in which the Solar System formed. Aims: We investigate the radiation field to which the Jovian CPD was exposed during the process of satellite formation. The resulting photoevaporation of the CPD is studied in this context to constrain possible formation scenarios for the Galilean satellites and explain architectural features of the Galilean system. Methods: We constructed a model for the stellar birth cluster to determine the intracluster far-ultraviolet (FUV) radiation field. We employed analytical annular gap profiles informed by hydrodynamical simulations to investigate a range of plausible geometries for the Jovian gap. We used the radiation thermochemical code ProDiMo to evaluate the incident radiation field in the Jovian gap and the photoevaporation of an embedded 2D axisymmetric CPD. Results: We derive the time-dependent intracluster FUV radiation field for the solar birth cluster over 10 Myr. We find that intracluster photoevaporation can cause significant truncation of the Jovian CPD. We determine steady-state truncation radii for possible CPDs, finding that the outer radius is proportional to the accretion rate $\dot{M}^{0.4}$. For CPD accretion rates $\dot M < 10^{-12} M_{\odot}$ yr$^{-1}$, photoevaporative truncation explains the lack of additional satellites outside the orbit of Callisto. For CPDs of mass $M_{\rm CPD} < 10^{-6.2 M_{\odot}}$ , photoevaporation can disperse the disk before Callisto is able to migrate into the Laplace resonance. This explains why Callisto is the only massive satellite that is excluded from the resonance.

astro-ph.EP

Observing the gas component of circumplanetary disks around wide-orbit planet-mass companions in the (sub)mm regime

Several detections of wide-orbit planet-mass/sub-stellar companions around young solar-like stars were reported in the last decade. The origin of those possible planets is still unclear but accretion tracers and VLT/SPHERE observations indicate that they are surrounded by circumplanetary material or even a circumplanetary disk. We want to investigate if the gas component of disks around wide-orbit companions is detectable with current and future (sub)mm telescopes and what constraints such gas observations can provide on the nature of the circumplanetary material and on the mass of the companion. We applied the radiation thermo-chemical disk code ProDiMo to model the dust and gas component of passive circumplanetary disks and produced realistic synthetic observables. We considered different companion properties, disk parameters and radiative environments and compared the resulting synthetic observables to telescope sensitivities and to existing dust observations. The main criterion for a successful detection is the size of the circumplanetary disk. At a distance of about 150 pc, a circumplanetary disk with an outer radius of about 10 au is detectable with ALMA in about 6 hours in optically thick CO lines. Other aspects such as the companion's luminosity, disk inclination and background radiation fields are also relevant and should be considered to optimize the observing strategy for detection experiments. For most of the known wide-orbit planet-mass companions, their maximum theoretical disk size of one third of the Hill radius would be sufficient to allow detection of CO lines. It is therefore feasible to detect their gas disks and constrain the mass of the companion through the kinematic signature. Even in the case of non-detections such observations will provide stringent constraints on disk size and gas mass, information crucial for formation theories.

astro-ph.SR

Constraining the stellar energetic particle flux in young solar-like stars

Anomalies in the abundance measurements of short lived radionuclides in meteorites indicate that the protosolar nebulae was irradiated by a large number of energetic particles ($E\gtrsim10\,$MeV), often called solar cosmic rays. The particle flux of the contemporary Sun cannot explain these anomalies, but, similar to \mbox{T Tauri} stars, the young Sun was more active and probably produced enough high energy particles. However, the stellar particle (SP) flux of young stars is essentially unknown. We model the impact of high-energy ionization sources on the chemistry of the circumstellar environment (disks and envelopes). The model includes X-ray radiative transfer and makes use of particle transport models to calculate the individual molecular hydrogen ionization rates. We study the impact on the chemistry via the ionization tracers HCO$^+$ and N$_2$H$^+$. We argue that spatially resolved observations of those molecules combined with detailed models allow for disentangling the contribution of the individual high-energy ionization sources and to put constraints on the SP flux in young stars.

astro-ph.SR

Warm dust surface chemistry. H2 and HD formation

Molecular hydrogen (H2) is the main constituent of the gas in the planet-forming disks that surround many PMS stars. H2 can be incorporated in the atmosphere of the giant planets. HD has been detected in a few disks and can be considered the most reliable tracer of H2. We wish to form H2 and HD efficiently for the varied conditions encountered in protoplanetary disks: the densities vary from 1E4 to 1E16 cm^-3; the dust temperatures range from 5 to 1500 K, the gas temperatures go from 5 to a few 1000 Kelvin, and the ultraviolet field can be 1E7 stronger than the standard interstellar field. We implemented a comprehensive model of H2 and HD formation on cold and warm grain surfaces and via hydrogenated PAHs in the physico-chemical code ProDiMo. The H2 and HD formation can proceed via the Langmuir-Hinshelwood and Eley-Ridel mechanisms for physisorbed or chemisorbed H (D) atoms. H2 and HD also form by H (D) abstraction from hydrogenated neutral and ionised PAHs and via gas phase reactions. H2 and HD are formed efficiently on dust grain surfaces from 10 to 700 K. All the deuterium is converted into HD in UV shielded regions as soon as H2 is formed by gas-phase D abstraction reactions. The detailed model compares well with standard analytical prescriptions for H2 (HD) formation. At low temperatures, H2 is formed from the encounter of two physisorbed atoms. HD molecules form on the grain surfaces and in the gas-phase. At temperatures greater than 20 K, the meeting between a weakly bound H- (or D-) atom or a gas-phase H (D) atom and a chemisorbed atom is the most efficient H2 formation route. H2 formation through hydrogenated PAHs alone is efficient above 80 K. The contribution of hydrogenated PAHs to the overall H2 and HD formation is relatively low if chemisorption on silicate is taken into account and if a small hydrogen abstraction cross-section is used.

astro-ph.GA

Warm dust surface chemistry in protoplanetary disks. Formation of phyllosilicates

The origin of the reservoirs of water on Earth is debated. The Earth's crust may contain at least three times more water than the oceans. This crust water is found in the form of phyllosilicates, whose origin probably differs from that of the oceans. We test the possibility to form phyllosilicates in protoplanetary disks, which can be the building blocks of terrestrial planets. We developed an exploratory rate-based warm surface chemistry model where water from the gas-phase can chemisorb on dust grain surfaces and subsequently diffuse into the silicate cores. We apply the phyllosilicate formation model to a zero-dimensional chemical model and to a 2D protoplanetary disk model (ProDiMo). The disk model includes in addition to the cold and warm surface chemistry continuum and line radiative transfer, photoprocesses (photodissociation, photoionization, and photodesorption), gas-phase cold and warm chemistry including three-body reactions, and detailed thermal balance. Despite the high energy barrier for water chemisorption on silicate grain surfaces and for diffusion into the core, the chemisorption sites at the surfaces can be occupied by a hydroxyl bond (-OH) at all gas and dust temperatures from 80 to 700 K for a gas density of 2E4 cm^-3. The chemisorption sites in the silicate cores are occupied at temperatures between 250 and 700 K. At higher temperatures thermal desorption of chemisorbed water occurs. The occupation efficiency is only limited by the maximum water uptake of the silicate. The timescales for complete hydration are at most 1E5 years for 1 mm radius grains at a gas density of 1E8 cm^-3. Phyllosilicates can be formed on dust grains at the dust coagulation stage in protoplanetary disks within 1 Myr. It is however not clear whether the amount of phyllosilicate formed by warm surface chemistry is sufficient compared to that found in Solar System objects.

astro-ph.GA