Searcharxiv⌕ Search

arXiv subjects

Chang-Kui Duan

Publications and source records attributed to Chang-Kui Duan.

50 records · Page 3Linked to original sources
arXiv2010

Spectroscopy of high-energy states of lanthanide ions

We discuss recent progress and future prospects for the analysis of the 4f${N-1}$5d excited states of lanthanide ions in host materials. Ab-initio calculations for Ce$^{3+}$ in LiYF$_4$ are used to estimate crystal-field and spin-orbit parameters for the 4f$^1$ and 5d$^1$ configurations. We discuss the possibility of using excited-state absorption to probe the electronic and geometric structure of the 4f$^{N-1}$5d excited states in more detail and we illustrate these ideas with calculations for Yb$^{2+}$ ions in SrCl$_2$.

cond-mat.mtrl-sci↗
arXiv2005

Constraints on alternative models to dark energy

The recent observations of type Ia supernovae strongly support that the universe is accelerating now and decelerated in the recent past. This may be the evidence of the breakdown of the standard Friemann equation. We consider a general modified Friedmann equation. Three different models are analyzed in detail. The current supernovae data and the Wilkinson microwave anisotropy probe data are used to constrain these models. A detailed analysis of the transition from the deceleration phase to the acceleration phase is also performed.

gr-qc↗
arXiv2005

Local field effects on the radiative lifetimes of Ce$^{3+}$ in different hosts

For emitters embedded in media of various refractive indices, different theoretical models predicted substantially different dependencies of the spontaneous emission lifetime on refractive index. It has been claimed that various measurements on $4f\to 4f$ radiative transition of Eu$^{3+}$ in hosts with variable refractive index appear to favor the real-cavity model [J. Fluoresc. 13, 201 (2003) and references therein, Phys. Rev. Lett. 91, 203903 (2003)]. We notice that $5d\to 4f$ radiative transition of rare-earth ions, dominated by allowed electric-dipole transitions with line strengths less perturbed by the ligands, serves as a better test of different models. We analyze the lifetimes of $5d\to 4f$ transition of Ce$^{3+}$ in hosts of refractive indices varying from 1.4 to 2.2. The results favor the macroscopic virtual-cavity model based on Lorentz local field [J. Fluoresc. 13, 201 (2003)].

quant-ph↗
arXiv2005

A simple model for $f\to d$ transition of heavy lanthanide and actinide ions in crystals

The $f\to d$ transition model by Duan and co-workers [Phys. Rev. B {\bf 66}, 155108 (2002); J. Solid State Chem. {\bf 171}, 299 (2003)] has been very useful in interpreting the $f\to d$ absorption, emission and nonradiative relaxation of light lanthanide ions in crystals. However, based on the assumption that the $f^{N-1}$ core spin-orbit interaction is weak compared to $f\to d$ exchange interaction, this model, in the original form, is not applicable to interpretation of the $f\to d$ transitions of heavy lanthanide ions or actinide ions in crystals. In this work the model is extended to cover the cases of heavy lanthanides and actinides, where the spin-orbit interaction of $f$ orbitals may be stronger than the $f-d$ exchange nteraction. Keywords: lanthanide; f-d transition; model; spectrum; actinide; VUV;

cond-mat.mtrl-sci↗
arXiv2005

Calculation of single-beam two-photon absorption transition rate of rare-earth ions using effective operator and diagrammatic representation

Effective operators needed in single-beam two-photon transition calculations have been represented with modified Goldstone diagrams similar to the type suggested by Duan and co-workers [J. Chem. Phys. 121, 5071 (2004) ]. The rules to evaluate these diagrams are different from those for effective Hamiltonian and one-photon transition operators. It is verified that the perturbation terms considered contain only connected diagrams and the evaluation rules are simplified and given explicitly.

physics.chem-ph↗
arXiv2005

Dependence of spontaneous emission rates of emitters on the refractive index of the surrounding medial

For emitters in a medium, different macroscopic or microscopic theoretical models predict substantially different dependencies of the spontaneous emission lifetime on refractive index. Various measurements have been carried out on Eu$^{3+}$, Ce$^{3+}$ and Nd$^{3+}$ ions, and quantum dots in different surrounding medial. The dependence of the spontaneous emission rates on refractive index has been interpreted with different models. By closely examining some of the experimental results, we notice that some interpretations are based on implicit assumptions which are hard to justify, and some measurements contain too big uncertainties to discriminate among different models. In this work we reanalyse the avilable measured results and give a consistent interpretation.

physics.optics↗
arXiv2005

Local Field effects on the radiative lifetime of emitters in surrounding media: virtual- or real-cavity model?

For emitters embedded in media of various refractive indices, different macroscopic or microscopic theoretical models predict different dependencies of the spontaneous emission lifetime on refractive index. Among those models are the two most promising models: the virtual-cavity model and the real-cavity model. It is a priori not clear which model is more relevant for a given situation. By close analysis of the available experimental results and examining the assumptions underlying the two models, we reach a consistent interpretation of the experimental results and give the criteria which model should apply for a given situation.

cond-mat.mtrl-sci↗
arXiv2005

Simplified diagrammatic expansion for effective operator

For a quantum many-body problem, effective Hamiltonians that give exact eigenvalues in reduced model space usually have different expressions, diagrams and evaluation rules from effective transition operators that give exact transition matrix elements between effective eigenvectors in reduced model space. By modifying these diagrams slightly and considering the linked diagrams for all the terms of the same order, we find that the evaluation rules can be made the same for both effective Hamiltonian and effective transition operator diagrams, and in many cases it is possible to combine many diagrams into one modified diagram. We give the rules to evaluate these modified diagrams and show their validity.

quant-ph↗
arXiv2005

Conservation of connectivity of model-space effective interactions under a class of similarity transformation

Effective interaction operators usually act on a restricted model space and give the same energies (for Hamiltonian) and matrix elements (for transition operators etc.) as those of the original operators between the corresponding true eigenstates. Various types of effective operators are possible. Those well defined effective operators have been shown being related to each other by similarity transformation. Some of the effective operators have been shown to have connected-diagram expansions. It is shown in this paper that under a class of very general similarity transformations, the connectivity is conserved. The similarity transformation between hermitian and non-hermitian Rayleigh-Schrödinger perturbative effective operators is one of such transformation and hence the connectivity can be deducted from each other.

physics.comp-ph↗
arXiv2005

Calculation of single-beam two-photon absorption rate of lanthanides: effective operator method and perturbative expansion

Perturbative contributions to single-beam two-photon transition rates may be divided into two types. The first, involving low-energy intermediate states, require a high-order perturbation treatment, or an exact diagonalization. The other, involving high energy intermediate states, only require a low-order perturbation treatment. We show how to partition the effective transition operator into two terms, corresponding to these two types, in such a way that a many-body perturbation expansion may be generated that obeys the linked cluster theorem and has a simple diagrammatic representation.

physics.chem-ph↗
arXiv2005

General calculation of $4f-5d$ transition rates for rare-earth ions using many-body perturbation theory

The $4f-5d$ transition rates for rare-earth ions in crystals can be calculated with an effective transition operator acting between model $4f^N$ and $4f^{N-1}5d$ states calculated with effective Hamiltonian, such as semi-empirical crystal Hamiltonian. The difference of the effective transition operator from the original transition operator is the corrections due to mixing in transition initial and final states of excited configurations from both the center ion and the ligand ions. These corrections are calculated using many-body perturbation theory. For free ions, there are important one-body and two-body corrections. The one-body correction is proportional to the original electric dipole operator with magnitude of approximately 40% of the uncorrected electric dipole moment. Its effect is equivalent to scaling down the radial integral $\ME {5d} r {4f}$, to about 60% of the uncorrected HF value. The two-body correction has magnitude of approximately 25% relative to the uncorrected electric dipole moment. For ions in crystals, there is an additional one-body correction due to ligand polarization, whose magnitude is shown to be about 10% of the uncorrected electric dipole moment.

cond-mat.mtrl-sci↗
arXiv2004

A new alternative model to dark energy

The recent observations of type Ia supernovae strongly support that the universe is accelerating now and decelerated in the recent past. This may be the evidence of the breakdown of the standard Friedmann equation. Instead of a linear function of the matter density, we consider a general function of the matter density to modify the Freidmann equation. We propose a new model which explains the recent acceleration and the past deceleration. Furthermore, the new model also gives a decelerated universe in the future. The new model gives $Ω_{m0}=0.46$ and $z_T=0.44$.

astro-ph↗
arXiv2004

Supernova constraints on alternative models to dark energy

The recent observations of type Ia supernovae suggest that the universe is accelerating now and decelerated in the recent past. This may be the evidence of the breakdown of the standard Friedmann equation. The Friedmann equation $H^2\sim ρ$ is modified to be a general form $H^2=g(ρ)$. Three models with particular form of $g(ρ)$ are considered in detail. The supernova data published by \citet{tonry}, \citet{ddsg} and \citet{raknop03} are used to analyze the models. After the best fit parameters are obtained, we then find out the transition redshift $z_{\rm T}$ when the universe switched from the deceleration phase to the acceleration phase.

astro-ph↗