arXiv subjects

Channon Visscher

Publications and source records attributed to Channon Visscher.

At least 55 records · Page 3Linked to original sources

arXiv2020

Retrieval of SDSS J1416+1348AB

We present the distance-calibrated spectral energy distribution (SED) of the d/sdL7 SDSS J14162408+1348263A (J1416A) and an updated SED for SDSS J14162408+1348263B (J1416B). We also present the first retrieval analysis of J1416A using the Brewster retrieval code base and the second retrieval of J1416B. We find that the primary is best fit by a non-grey cloud opacity with a power-law wavelength dependence, but is indistinguishable between the type of cloud parameterization. J1416B is best fit by a cloud-free model, consistent with the results from Line et al. (2017). Most fundamental parameters derived via SEDs and retrievals are consistent within 1 sigma for both J1416A and J1416B. The exceptions include the radius of J1416A, where the retrieved radius is smaller than the evolutionary model-based radius from the SED for the deck cloud model, and the bolometric luminosity which is consistent within 2.5 sigma for both cloud models. The pair's metallicity and Carbon-to-Oxygen (C/O) ratio point towards formation and evolution as a system. By comparing the retrieved alkali abundances while using two opacity models, we are able to evaluate how the opacities behave for the L and T dwarf. Lastly, we find that relatively small changes in composition can drive major observable differences for lower temperature objects.

astro-ph.SR↗

arXiv2020

Observations of Disequilibrium CO Chemistry in the Coldest Brown Dwarfs

Cold brown dwarfs are excellent analogs of widely separated, gas giant exoplanets, and provide insight into the potential atmospheric chemistry and physics we may encounter in objects discovered by future direct imaging surveys. We present a low resolution R $\sim$ 300 $M$-band spectroscopic sequence of seven brown dwarfs with effective temperatures between 750 K and 250 K along with Jupiter. These spectra reveal disequilibrium abundances of carbon monoxide (CO) produced by atmospheric quenching. We use the eddy diffusion coefficient (K$_{zz}$) to estimate the strength of vertical mixing in each object. The K$_{zz}$ values of cooler gaseous objects are close to their theoretical maximum and warmer objects show weaker mixing, likely due to less efficient convective mixing in primarily radiative layers. The CO-derived K$_{zz}$ values imply that disequilibrium phosphine (PH$_{3}$) should be easily observable in all of the brown dwarfs, but none as yet show any evidence for PH$_{3}$ absorption. We find that ammonia is relatively insensitive to atmospheric quenching at these effective temperatures. We are able to improve the fit to WISE 0855's $M$-band spectrum by including both CO and water clouds in the atmospheric model.

astro-ph.EP↗

arXiv2019

Imaging Cool Giant Planets in Reflected Light: Science Investigations and Synergy with Habitable Planets

Planned astronomical observatories of the 2020s will be capable of obtaining reflected light photometry and spectroscopy of cool extrasolar giant planets. Here we explain that such data are valuable both for understanding the origin and evolution of giant planets as a whole and for preparing for the interpretation of similar datasets from potentially habitable extrasolar terrestrial planets in the decades to follow.

astro-ph.EP↗

arXiv2018

From thermal dissociation to condensation in the atmospheres of ultra hot Jupiters: WASP-121b in context

A new class of exoplanets has emerged: the ultra hot Jupiters, the hottest close-in gas giants. Most of them have weaker than expected spectral features in the $1.1-1.7μm$ bandpass probed by HST/WFC3 but stronger spectral features at longer wavelengths probed by Spitzer. This led previous authors to puzzling conclusions about the thermal structures and chemical abundances of these planets. Using the SPARC/MITgcm, we investigate how thermal dissociation, ionization, H$^-$ opacity and clouds shape the thermal structures and spectral properties of ultra hot Jupiters with a special focus on WASP-121b. We expand our findings to the whole population of ultra hot Jupiters through analytical quantification of the thermal dissociation and its influence on the strength of spectral features. We predict that most molecules are thermally dissociated and alkalies are ionized in the dayside photospheres of ultra hot Jupiters. This includes H$_{\rm 2}$O, TiO, VO, and H$_{\rm 2}$ but not CO, which has a stronger molecular bond. The vertical molecular gradient created by the dissociation significantly weakens the spectral features from water while the $4.5μm$ CO feature remain unchanged. The water band in the HST/WFC3 bandpass is further weakened by H$^-$ continuum opacity. Molecules are expected to recombine before reaching the limb, leading to order of magnitude variations of the chemical composition and cloud coverage between the limb and the dayside. Overall, molecular dissociation provides a qualitative understanding of the lack of strong spectral feature of water in the $1-2μm$ bandpass observed in most ultra hot Jupiters. Quantitatively, however, our model does not provide a satisfactory match to the WASP-121b emission spectrum. Together with WASP-33b and Kepler-33Ab, they seem the outliers among the population of ultra hot Jupiters in need of a more thorough understanding.

astro-ph.EP↗

arXiv2018

An L Band Spectrum of the Coldest Brown Dwarf

The coldest brown dwarf, WISE 0855, is the closest known planetary-mass, free-floating object and has a temperature nearly as cold as the solar system gas giants. Like Jupiter, it is predicted to have an atmosphere rich in methane, water, and ammonia, with clouds of volatile ices. WISE 0855 is faint at near-infrared wavelengths and emits almost all its energy in the mid-infrared. Skemer et al. 2016 presented a spectrum of WISE 0855 from 4.5-5.1 micron (M band), revealing water vapor features. Here, we present a spectrum of WISE 0855 in L band, from 3.4-4.14 micron. We present a set of atmosphere models that include a range of compositions (metallicities and C/O ratios) and water ice clouds. Methane absorption is clearly present in the spectrum. The mid-infrared color can be better matched with a methane abundance that is depleted relative to solar abundance. We find that there is evidence for water ice clouds in the M band spectrum, and we find a lack of phosphine spectral features in both the L and M band spectra. We suggest that a deep continuum opacity source may be obscuring the near-infrared flux, possibly a deep phosphorous-bearing cloud, ammonium dihyrogen phosphate. Observations of WISE 0855 provide critical constraints for cold planetary atmospheres, bridging the temperature range between the long-studied solar system planets and accessible exoplanets. JWST will soon revolutionize our understanding of cold brown dwarfs with high-precision spectroscopy across the infrared, allowing us to study their compositions and cloud properties, and to infer their atmospheric dynamics and formation processes.

astro-ph.EP↗

arXiv2017

Retrieval of atmospheric properties of cloudy L dwarfs

We present the first results from applying the spectral inversion technique in the cloudy L dwarf regime. Our new framework provides a flexible approach to modelling cloud opacity which can be built incrementally as the data requires, and improves upon previous retrieval experiments in the brown dwarf regime by allowing for scattering in two stream radiative transfer. Our first application of the tool to two mid-L dwarfs is able to reproduce their near-infrared spectra far more closely than grid models. Our retrieved thermal, chemical, and cloud profiles allow us to estimate $T_{\rm eff} = 1796^{+23}_{-25}$ K and $\log g = 5.21^{+0.05}_{-0.08}$ for 2MASS J05002100+0330501 and for 2MASSW J2224438-015852 we find $T_{\rm eff} = 1723^{+18}_{-19}$ K and $\log g = 5.31^{+0.04}_{-0.08}$, in close agreement with previous empirical estimates. Our best model for both objects includes an optically thick cloud deck which passes $τ_{cloud} \geq 1$ (looking down) at a pressure of around 5 bar. The temperature at this pressure is too high for silicate species to condense, and we argue that corundum and/or iron clouds are responsible for this cloud opacity. Our retrieved profiles are cooler at depth, and warmer at altitude than the forward grid models that we compare, and we argue that some form of heating mechanism may be at work in the upper atmospheres of these L dwarfs. We also identify anomalously high CO abundance in both targets, which does not correlate with the warmth of our upper atmospheres or our choice of cloud model, and find similarly anomalous alkali abundance for one of our targets. These anomalies may reflect unrecognised shortcomings in our retrieval model, or inaccuracies in our gas phase opacities.

astro-ph.SR↗

arXiv2016

High temperature condensate clouds in super-hot Jupiter atmospheres

Deciphering the role of clouds is central to our understanding of exoplanet atmospheres, as they have a direct impact on the temperature and pressure structure, and observational properties of the planet. Super-hot Jupiters occupy a temperature regime similar to low mass M-dwarfs, where minimal cloud condensation is expected. However, observations of exoplanets such as WASP-12b (Teq ~ 2500 K) result in a transmission spectrum indicative of a cloudy atmosphere. We re-examine the temperature and pressure space occupied by these super-hot Jupiter atmospheres, to explore the role of the initial Al- and Ti-bearing condensates as the main source of cloud material. Due to the high temperatures a majority of the more common refractory material is not depleted into deeper layers and would remain in the vapor phase. The lack of depletion into deeper layers means that these materials with relatively low cloud masses can become significant absorbers in the upper atmosphere. We provide condensation curves for the initial Al- and Ti-bearing condensates that may be used to provide quantitative estimates of the effect of metallicity on cloud masses, as planets with metal-rich hosts potentially form more opaque clouds because more mass is available for condensation. Increased metallicity also pushes the point of condensation to hotter, deeper layers in the planetary atmosphere further increasing the density of the cloud. We suggest that planets around metal-rich hosts are more likely to have thick refractory clouds, and discuss the implication on the observed spectra of WASP-12b.

astro-ph.EP↗

arXiv2016

The Hunt for Planet Nine: Atmosphere, Spectra, Evolution, and Detectability

We investigate the physical characteristics of the Solar System's proposed Planet Nine using modeling tools with a heritage in studying Uranus and Neptune. For a range of plausible masses and interior structures, we find upper limits on the intrinsic Teff, from ~35-50 K for masses of 5-20 M_Earth, and we also explore lower Teff values. Possible planetary radii could readily span from 3 to 6 R_Earth depending on the mass fraction of any H/He envelope. Given its cold temperature, the planet encounters significant methane condensation, which dramatically alters the atmosphere away from simple Neptune-like expectations. We find the atmosphere is strongly depleted in molecular absorption at visible wavelengths, suggesting a Rayleigh scattering atmosphere with a high geometric albedo approaching 0.75. We highlight two diagnostics for the atmosphere's temperature structure, the first being the value of the methane mixing ratio above the methane cloud. The second is the wavelength at which cloud scattering can be seen, which yields the cloud-top pressure. Surface reflection may be seen if the atmosphere is thin. Due to collision-induced opacity of H2 in the infrared, the planet would be extremely blue (instead of red) in the shortest wavelength WISE colors if methane is depleted, and would, in some cases, exist on the verge of detectability by WISE. For a range of models, thermal fluxes from ~3-5 microns are ~20 orders of magnitude larger than blackbody expectations. We report a search of the AllWISE Source Catalog for Planet Nine, but find no detection.

astro-ph.EP↗

arXiv2016

The atmospheric circulation of a nine-hot Jupiter sample: Probing circulation and chemistry over a wide phase space

We present results from an atmospheric circulation study of nine hot Jupiters that comprise a large transmission spectral survey using the Hubble and Spitzer Space Telescopes. These observations exhibit a range of spectral behavior over optical and infrared wavelengths which suggest diverse cloud and haze properties in their atmospheres. By utilizing the specific system parameters for each planet, we naturally probe a wide phase space in planet radius, gravity, orbital period, and equilibrium temperature. First, we show that our model "grid" recovers trends shown in traditional parametric studies of hot Jupiters, particularly equatorial superrotation and increased day-night temperature contrast with increasing equilibrium temperature. We show how spatial temperature variations, particularly between the dayside and nightside and west and east terminators, can vary by hundreds of K, which could imply large variations in Na, K, CO and CH4 abundances in those regions. These chemical variations can be large enough to be observed in transmission with high-resolution spectrographs, such as ESPRESSO on VLT, METIS on the E-ELT, or with MIRI and NIRSpec aboard JWST. We also compare theoretical emission spectra generated from our models to available Spitzer eclipse depths for each planet, and find that the outputs from our solar-metallicity, cloud-free models generally provide a good match to many of the datasets, even without additional model tuning. Although these models are cloud-free, we can use their results to understand the chemistry and dynamics that drive cloud formation in their atmospheres.

astro-ph.EP↗

arXiv2015

The LEECH Exoplanet Imaging Survey: Characterization of the Coldest Directly Imaged Exoplanet, GJ 504 b, and Evidence for Super-Stellar Metallicity

As gas giant planets and brown dwarfs radiate away the residual heat from their formation, they cool through a spectral type transition from L to T, which encompasses the dissipation of cloud opacity and the appearance of strong methane absorption. While there are hundreds of known T-type brown dwarfs, the first generation of directly-imaged exoplanets were all L-type. Recently, Kuzuhara et al. (2013) announced the discovery of GJ 504 b, the first T dwarf exoplanet. GJ 504 b provides a unique opportunity to study the atmosphere of a new type of exoplanet with a ~500 K temperature that bridges the gap between the first directly imaged planets (~1000 K) and our own Solar System's Jupiter (~130 K). We observed GJ 504 b in three narrow L-band filters (3.71, 3.88, and 4.00 microns), spanning the red end of the broad methane fundamental absorption feature (3.3 microns) as part of the LEECH exoplanet imaging survey. By comparing our new photometry and literature photometry to a grid of custom model atmospheres, we were able to fit GJ 504 b's unusual spectral energy distribution for the first time. We find that GJ 504 b is well-fit by models with the following parameters: T_eff=544+/-10 K, g<600 m/s^2, [M/H]=0.60+/-0.12, cloud opacity parameter of f_sed=2-5, R=0.96+/-0.07 R_Jup, and log(L)=-6.13+/-0.03 L_Sun, implying a hot start mass of 3-30 M_jup for a conservative age range of 0.1-6.5 Gyr. Of particular interest, our model fits suggest that GJ 504 b has a super-stellar metallicity. Since planet formation can create objects with non-stellar metallicities, while binary star formation cannot, this result suggests that GJ 504 b formed like a planet, not like a binary companion.

astro-ph.EP↗

arXiv2013

Compositional diversity in the atmospheres of hot Neptunes, with application to GJ 436b

Neptune-sized extrasolar planets that orbit relatively close to their host stars -- often called "hot Neptunes" -- are common within the known population of exoplanets and planetary candidates. Similar to our own Uranus and Neptune, inefficient accretion of nebular gas is expected produce hot Neptunes whose masses are dominated by elements heavier than hydrogen and helium. At high atmospheric metallicities of 10-10,000x solar, hot Neptunes will exhibit an interesting continuum of atmospheric compositions, ranging from more Neptune-like, H2-dominated atmospheres to more Venus-like, CO2-dominated atmospheres. We explore the predicted equilibrium and disequilibrium chemistry of generic hot Neptunes and find that the atmospheric composition varies strongly as a function of temperature and bulk atmospheric properties such as metallicity and the C/O ratio. Relatively exotic H2O, CO, CO2, and even O2-dominated atmospheres are possible for hot Neptunes. We apply our models to the case of GJ 436b, where we find that a CO-rich, CH4-poor atmosphere can be a natural consequence of a very high atmospheric metallicity. From comparisons of our results with Spitzer eclipse data for GJ 436b, we conclude that although the spectral fit from the high-metallicity forward models is not quite as good as the fit obtained from pure retrieval methods, the atmospheric composition predicted by these forward models is more physically and chemically plausible. High-metallicity atmospheres (orders of magnitude in excess of solar) should therefore be considered as a possibility for GJ 436b and other hot Neptunes.

astro-ph.EP↗

arXiv2013

Quantitatively Assessing the Role of Clouds in the Transmission Spectrum of GJ 1214b

Recent observations of the super-Earth GJ 1214b show that it has a relatively featureless transmission spectrum. One suggestion is that these observations indicate that the planet's atmosphere is vertically compact, perhaps due to a water-rich composition that yields a large mean molecular weight. Another suggestion is that the atmosphere is hydrogen/helium-rich with clouds that obscure predicted absorption features. Previous models that incorporate clouds have included their effect without a strong physical motivation for their existence. Here, we present model atmospheres of GJ 1214b that include physically-motivated clouds of two types. We model the clouds that form as a result of condensation in chemical equilibrium, as they likely do on brown dwarfs, which include KCl and ZnS for this planet. We also include clouds that form as a result of photochemistry, forming a hydrocarbon haze layer. We use a photochemical kinetics model to understand the vertical distribution and available mass of haze-forming molecules. We model both solar and enhanced-metallicity cloudy models and determine the cloud properties necessary to match observations. In enhanced-metallicity atmospheres, we find that the equilibrium clouds can match the observations of GJ 1214b if they are lofted high into the atmosphere and have a low sedimentation efficiency (fsed=0.1). We find that models with a variety of hydrocarbon haze properties can match the observations. Particle sizes from 0.01 to 0.25 micron can match the transmission spectrum with haze-forming efficiencies as low as 1-5%.

astro-ph.EP↗

arXiv2013

Chemistry of Impact-Generated Silicate Melt-Vapor Debris Disks

In the giant impact theory for lunar origin, the Moon forms from material ejected by the impact into an Earth-orbiting disk. Here we report the initial results from a silicate melt-vapor equilibrium chemistry model for such impact-generated planetary debris disks. In order to simulate the chemical behavior of a two-phase (melt+vapor) disk, we calculate the temperature-dependent pressure and chemical composition of vapor in equilibrium with molten silicate from 2000 to 4000 K. We consider the elements O, Na, K, Fe, Si, Mg, Ca, Al, Ti, and Zn for a range of bulk silicate compositions (Earth, Moon, Mars, eucrite parent body, angrites, and ureilites). In general, the disk atmosphere is dominated by Na, Zn, and O2 at lower temperatures (< 3000 K) and SiO, O2, and O at higher temperatures. The high-temperature chemistry is consistent for any silicate melt composition, and we thus expect abundant SiO, O2, and O to be a common feature of hot, impact-generated debris disks. In addition, the saturated silicate vapor is highly oxidizing, with oxygen fugacity (fO2) values (and hence H2O/H2 and CO2/CO ratios) several orders of magnitude higher than those in a solar-composition gas. High fO2 values in the disk atmosphere are found for any silicate composition because oxygen is the most abundant element in rock. We thus expect high oxygen fugacity to be a ubiquitous feature of any silicate melt-vapor disk produced via collisions between rocky planets.

astro-ph.EP↗

arXiv2012

A Comparison of Near-Infrared Photometry and Spectra for Y Dwarfs with a New Generation of Cool Cloudy Models

We present YJHK photometry, or a subset, for the six Y dwarfs discovered in WISE data by Cushing et al.. The data were obtained using NIRI on the Gemini North telescope. We also present a far-red spectrum obtained using GMOS-North for WISEPC J205628.90+145953.3. We compare the data to Morley et al. (2012) models, which include cloud decks of sulfide and chloride condensates. We find that the models with these previously neglected clouds can reproduce the energy distributions of T9 to Y0 dwarfs quite well, other than near 5um where the models are too bright. This is thought to be because the models do not include departures from chemical equilibrium caused by vertical mixing, which would enhance the abundance of CO, decreasing the flux at 5um. Vertical mixing also decreases the abundance of NH_3, which would otherwise have strong absorption features at 1.03um and 1.52um that are not seen in the Y0 WISEPC J205628.90+145953.3. We find that the five Y0 to Y0.5 dwarfs have 300 < T_eff K < 450, 4.0 < log g < 4.5 and f_sed ~ 3. These temperatures and gravities imply a mass range of 5 - 15 M_Jupiter and ages around 5 Gyr. We suggest that WISEP J182831.08+265037.8 is a binary system, as this better explains its luminosity and color. We find that the data can be made consistent with observed trends, and generally consistent with the models, if the system is composed of a T_eff = 325 K and log g <~ 4.5 primary, and a T_eff = 300 K and log g >~ 4.0 secondary, corresponding to masses of 10 and 7 M_Jupiter and an age around 2 Gyr. If our deconvolution is correct, then the T_eff = 300 K cloud-free model fluxes at K and W2 are too faint by 0.5 - 1.0 magnitudes. We will address this discrepancy in our next generation of models, which will incorporate water clouds and mixing.

astro-ph.SR↗

arXiv2012

Neglected Clouds in T and Y Dwarf Atmospheres

As brown dwarfs cool, a variety of species condense in their atmospheres, forming clouds. Iron and silicate clouds shape the emergent spectra of L dwarfs, but these clouds dissipate at the L/T transition. A variety of other condensates are expected to form in cooler T dwarf atmospheres. These include Cr, MnS, Na2S, ZnS, and KCl, but the opacity of these optically thinner clouds has not been included in previous atmosphere models. Here, we examine their effect on model T and Y dwarf atmospheres. The cloud structures and opacities are calculated using the Ackerman & Marley (2001) cloud model, which is coupled to an atmosphere model to produce atmospheric pressure-temperature profiles in radiative-convective equilibrium. We generate a suite of models between Teff = 400 and 1300 K, log g=4.0 and 5.5, and condensate sedimentation efficiencies from fsed=2 to 5. Model spectra are compared to two red T dwarfs, Ross 458C and UGPS 0722-05; models that include clouds are found to match observed spectra significantly better than cloudless models. The emergence of sulfide clouds in cool atmospheres, particularly Na2S, may be a more natural explanation for the "cloudy" spectra of these objects, rather than the re-emergence of silicate clouds that wane at the L-to-T transition. We find that sulfide clouds provide a mechanism to match the near- and mid-infrared colors of observed T dwarfs. Our results indicate that including the opacity of condensates in T dwarf atmospheres is necessary to accurately determine the physical characteristics of many of the observed objects.

astro-ph.SR↗

arXiv2012

Two nearby sub-Earth-sized exoplanet candidates in the GJ 436 system

We report the detection of UCF-1.01, a strong exoplanet candidate with a radius 0.66 +/- 0.04 times that of Earth (R_{\oplus}). This sub-Earth-sized planet transits the nearby M-dwarf star GJ 436 with a period of 1.365862 +/- 8x10^{-6} days. We also report evidence of a 0.65 +/- 0.06 R_{\oplus} exoplanet candidate (labeled UCF-1.02) orbiting the same star with an undetermined period. Using the Spitzer Space Telescope, we measure the dimming of light as the planets pass in front of their parent star to assess their sizes and orbital parameters. If confirmed, UCF-1.01 and UCF-1.02 would be called GJ 436c and GJ 436d, respectively, and would be part of the first multiple-transiting-planet system outside of the Kepler field. Assuming Earth-like densities of 5.515 g/cm^3, we predict both candidates to have similar masses (~0.28 Earth-masses, M_{\oplus}, 2.6 Mars-masses) and surface gravities of ~0.65 g (where g is the gravity on Earth). UCF-1.01's equilibrium temperature (T_{eq}, where emitted and absorbed radiation balance for an equivalent blackbody) is 860 K, making the planet unlikely to harbor life as on Earth. Its weak gravitational field and close proximity to its host star imply that UCF-1.01 is unlikely to have retained its original atmosphere; however, a transient atmosphere is possible if recent impacts or tidal heating were to supply volatiles to the surface. We also present additional observations of GJ 436b during secondary eclipse. The 3.6-micron light curve shows indications of stellar activity, making a reliable secondary eclipse measurement impossible. A second non-detection at 4.5 microns supports our previous work in which we find a methane-deficient and carbon monoxide-rich dayside atmosphere.

astro-ph.EP↗

arXiv2012

Chemical Timescales in the Atmospheres of Highly Eccentric Exoplanets

Close-in exoplanets with highly eccentric orbits are subject to large variations in incoming stellar flux between periapse and apoapse. These variations may lead to large swings in atmospheric temperature, which in turn may cause changes in the chemistry of the atmosphere from higher CO abundances at periapse to higher CH4 abundances at apoapse. Here we examine chemical timescales for CO<->CH4 interconversion compared to orbital timescales and vertical mixing timescales for the highly eccentric exoplanets HAT-P-2b and CoRoT-10b. As exoplanet atmospheres cool, the chemical timescales for CO<->CH4 tend to exceed orbital and/or vertical mixing timescales, leading to quenching. The relative roles of orbit-induced thermal quenching and vertical quenching depend upon mixing timescales relative to orbital timescales. For both HAT-P-2b and CoRoT-10b, vertical quenching will determine disequilibrium CO<->CH4 chemistry at faster vertical mixing rates (Kzz > 10^7 cm^2 s^-1), whereas orbit-induced thermal quenching may play a significant role at slower mixing rates (Kzz < 10^7 cm^2 s^-1). The general abundance and chemical timescale results - calculated as a function of pressure, temperature, and metallicity - can be applied for different atmospheric profiles in order to estimate the quench level and disequilibrium abundances of CO and CH4 on hydrogen-dominated exoplanets. Observations of CO and CH4 on highly eccentric exoplanets may yield important clues to the chemical and dynamical properties of their atmospheres.

astro-ph.EP↗

arXiv2011

Quenching of Carbon Monoxide and Methane in the Atmospheres of Cool Brown Dwarfs and Hot Jupiters

We explore CO-CH4 quench kinetics in the atmospheres of substellar objects using updated time-scale arguments, as suggested by a thermochemical kinetics and diffusion model that transitions from the thermochemical-equilibrium regime in the deep atmosphere to a quench-chemical regime at higher altitudes. More specifically, we examine CO quench chemistry on the T dwarf Gliese 229B and CH4 quench chemistry on the hot-Jupiter HD 189733b. We describe a method for correctly calculating reverse rate coefficients for chemical reactions, discuss the predominant pathways for CO-CH4 interconversion as indicated by the model, and demonstrate that a simple time-scale approach can be used to accurately describe the behavior of quenched species when updated reaction kinetics and mixing-length-scale assumptions are used. Proper treatment of quench kinetics has important implications for estimates of molecular abundances and/or vertical mixing rates in the atmospheres of substellar objects. Our model results indicate significantly higher Kzz values than previously estimated near the CO quench level on Gliese 229B, whereas current model-data comparisons using CH4 permit a wide range of Kzz values on HD 189733b. We also use updated reaction kinetics to revise previous estimates of the Jovian water abundance, based upon the observed abundance and chemical behavior of carbon monoxide. The CO chemical/observational constraint, along with Galileo entry probe data, suggests a water abundance of approximately 0.51-2.6x solar (for a solar value of H2O/H2=9.61E-04) in Jupiter's troposphere, assuming vertical mixing from the deep atmosphere is the only source of tropospheric CO.

astro-ph.EP↗