arXiv subjects

Chantal Valeriani

Publications and source records attributed to Chantal Valeriani.

At least 19 recordsLinked to original sources

arXiv2026

Partial vision leads to an unexpected emergent collective behavior in active aligning particles

The Vicsek Model represents a paradigmatic framework for understanding the collective motion of active aligning particles, traditionally assuming isotropic interaction fields. Inspired by biological systems characterized by limited perception and blind spots, we propose a generalized Vicsek model featuring two distinct, non-overlapping angular vision cones. We systematically investigate the non-equilibrium phase behavior of this system by tuning the aperture area ({\alpha}) and the front-back orientation (\b{eta}) of the cones. Our results reveal that restricting the lateral vision area destabilizes global order, shifts the critical noise, and induces highly dense traveling bands. Furthermore, breaking the front-back symmetry introduces non-reciprocal interactions that profoundly alter the emergent spatial structures: forward-biased vision drives strong clustering through "follow the leader" alignment, whereas backward-biased alignment stabilizes an exceptionally homogeneous flocking state with suppressed density fluctuations. Finally, we incorporate short-range volume exclusion, demonstrating that the structural integrity of these novel tightly-clustered phases is highly sensitive to steric interactions. Our work provides new insights into the interplay between non-reciprocal perception, spatial anisotropy, and physical constraints in active matter.

cond-mat.soft↗

arXiv2026

Many-body activity emerging in a monolayer of air-fluidized hollow pentagons

Particles governed by many-body interactions exhibit remarkably complex structures and dynamics. We experimentally investigate a monolayer of pentagon particles subjected to an up-lifting air flow which induces many-body aerodynamic interactions and stochastic motion akin to a thermal bath. To minimize air flow resistance, particles move collectively with interactions dictated by their geometry: hollow particles exhibit effective attraction, whereas solid particles repel each other. Under sufficiently large air flow, sparsely packed hollow pentagons overcome substrate friction and undergo long-time diffusive motion. Under lower air flow, we see a coexistence of isolated, static pentagons and densely packed, "active" clusters, whose particles display super-diffusivity. This "emergent activity" arises collectively when locally disordered structures interact with the air flow, resulting in correlated motion across broad temporal and spatial scales. Using Langevin dynamics simulations of two-dimensional attractive active pentagons, whose activity is an effective result of the local packing density, we further unravel the basic features of this emergent activity.

cond-mat.soft↗

arXiv2026

Template-free fabrication of reconfigurable magnetic micropillars and filaments through controlled Nanoflower assembly and actuation

Magnetic nanoflowers (MNFs), which exhibit large intrinsic magnetic losses and high specific absorption rates under clinically relevant alternating magnetic fields, highlight strong potential as efficient mediators for magnetic hyperthermia. In this work, we provide a versatile platform for creating dynamic, field-responsive microstructures based on MNFs through a flexible, low-cost, and template-free self-assembly strategy driven by tunable interparticle interactions, external magnetic fields, and spatial confinement. By controlling ionic strength, particle coverage, surface charge, particle concentration, and confinement, MNFs spontaneously assemble in aqueous solution into magnetic micropillars and microfilaments without predefined scaffolds, with low ionic strength favoring reversible assemblies and intermediate salt concentrations yielding stable, irreversible structures. The size, geometry, and dynamic response of these architectures can be precisely tuned, enabling field-induced behaviors such as cilia-like rotations, oscillations, and torque-driven detachment of micropillars into free-standing, swarming microfilaments. L-dopamine (L-DOPA) was used for surface modification in this work, as it is a biocompatible ligand offering catechol, amine, and carboxylate groups. Resulting MNFs@L-DOPA have negative surface charge and show assembly behavior qualitatively similar to the uncoated system under magnetic actuation. Together, these results establish practical guidelines for the template-free design of biomimetic, functional magnetic and elongated microarchitectures, highlighting their potential for microfluidic manipulation and bio-microrobotic applications.

cond-mat.soft↗

arXiv2026

Shear and bulk viscosities of water up to 1.6 GPa and anomaly in the structural relaxation time

Deep in the Earth's crust, pressure exceeds one thousand times the atmospheric pressure. Water still flows under these conditions, but experiences dramatic changes in structure and fluidity. Using combined dynamic and inelastic light scattering techniques, we simultaneously measure the shear and bulk viscosities of water as a function of pressure. The former increases faster than the latter, so that their ratio shows a two-fold decrease from 0 to 1.6 GPa; we confirm this trend with simulations. We analyze our results in terms of the structural relaxation time $\tau$. Contrary to other liquids, pressure initially accelerates relaxation in water. Our measurements reveal that $\tau$ reaches a minimum close to 1 ps around 0.5 GPa. We interpret $\tau$ as a the equilibration time of hydrogen bonds, and propose that the minimum in $\tau$ arises from a structural anomaly which allows fastest interconversion between local structures in water, and generates a cascade of thermodynamic and dynamic anomalies.

cond-mat.soft↗

arXiv2026

Phase fluctuations in a confined fluid

Fluid phase equilibrium depends on the external constraints imposed on a system. In a closed system with fixed volume, depending on the average density, a vapor bubble may be stable, metastable, or unstable, with respect to the homogeneous liquid phase. In the case where the bubble is metastable, we study its lifetime, i.e. the average waiting time needed to observe bubble collapse, and the corresponding lifetime of the homogeneous liquid. For the smallest systems, we predict the possibility to observe phase flipping, when the fluid oscillates between states with and without bubble. We provide an example of phase flipping in a simulation of a Lennard-Jones fluid.

cond-mat.soft↗

arXiv2026

How Phase Coexistence affects the mechanical properties of heterogeneous 2D suspensions

Although numerical simulations of rheological measurements typically focus on homogeneous systems, heterogeneity can profoundly impact material properties. We report on the rheological properties of a suspension of two-dimensional Lennard-Jones particles across the gas/liquid and the gas/solid coexistence lines of the system. We show how the presence of multiple coexisting states has a significant impact on the mechanical properties of these systems when compared with their homogeneous reference counterparts. Our results establish an extended map to navigate a landscape where not only density and temperature, but also phase coexistence, dictate the transition from viscous to elastic-dominated behavior under shear. These results provides a benchmark for future research into heterogeneous fluids where the coexistence of complex dynamic states is frequently observed.

cond-mat.soft↗

arXiv2026

Effective interactions in active Brownian particles

We report an approach to obtain effective pair potentials which describe the structure of two-dimensional systems of active Brownian particles. The pair potential is found by an inverse method, which matches the radial distribution function found from two different schemes. The inverse method, previously demonstrated via simulated equilibrium configurations of passive particles, has now been applied to a suspension of active particles. Interestingly, although active particles are inherently not in equilibrium, we still obtain effective interaction potentials which accurately describe the structure of the active system. Treating these effective potentials as if they were those of equilibrium systems, furthermore allows us to measure effective chemical potentials and pressures. Both the passive interactions and active motion of the active Brownian particles contribute to their effective interaction potentials.

cond-mat.soft↗

arXiv2026

Structural and dynamic anomalous properties of TIP4P/2005 water at extreme pressures

Water shows numerous thermodynamic, dynamic, and structural anomalies. Recent experiments [Eichler et al. Phys. Rev. Lett. 134, 134101 (2025)], based on measurements of shear and bulk viscosities of liquid water up to 1.6 GPa, have reported the existence of a minimum in the variation of the structural relaxation time {\tau}{\alpha} with pressure at room temperature. Here we investigate this and related properties with molecular dynamics simulations of the TIP4P/2005 water model, performed at extreme pressures commensurate with the experiments. Specifically, we compute dynamic (self-diffusion, shear and bulk viscosities, and structural relaxation time) and structural (oxygen-oxygen radial distribution function and structure factor, translational order parameter) properties down to 220 K and up to 2.7 GPa. We find good agreement with the experimental observations, and confirm the existence of a minimum in {\tau}{\alpha} . The microscopic information obtained from the simulations suggests that this anomaly is connected with the sudden reorganization of the hydrogen bond network induced by pressurization.

cond-mat.soft↗

arXiv2025

Active Matter as a framework for living systems-inspired Robophysics

Robophysics investigates the physical principles that govern living-like robots operating in complex, realworld environments. Despite remarkable technological advances, robots continue to face fundamental efficiency limitations. At the level of individual units, locomotion remains a challenge, while at the collective level, robot swarms struggle to achieve shared purpose, coordination, communication, and cost efficiency. This perspective article examines the key challenges faced by bio-inspired robotic collectives and highlights recent research efforts that incorporate principles from active-matter physics and biology into the modeling and design of robot swarms.

cond-mat.soft↗

arXiv2025

Spontaneous Emergence of Solitary Waves in Active Flow Networks with Elastic Elements

Flow networks are fundamental for understanding systems such as animal and plant vasculature or power distribution grids. These networks can encode, transmit, and transform information embodied in the spatial and temporal distribution of their flows. In this work, we focus on a minimal yet physically grounded system that allows us to isolate the fundamental mechanisms by which active flow networks generate and regulate emergent dynamics capable of supporting information transmission. The system is composed of active units that pump fluid and elastic units that store volume. From first principles, we derive a discrete model -- an active flow network -- that enables the simulation of large systems with many interacting units. Numerically, we show that the pressure field can develop solitary waves, resulting in the spontaneous creation and transmission of localized packets of information stored in the physical properties of the flow. We characterize how these solitary waves emerge from disordered initial conditions in a one-dimensional network, and how their size and propagation speed depend on key system parameters. Finally, when the elastic units are coupled to their neighbors, the solitary waves exhibit even richer dynamics, with diverse shapes and finite lifetimes that display power-law behaviors that we can predict analytically. Together, these results show how simple fluidic elements can collectively create, shape and transport information, laying the foundations for understanding -- and ultimately engineering -- information processing in active flow systems.

physics.flu-dyn↗

arXiv2025

Phase behaviour and dynamical features of a two-dimensional binary mixture of active/passive spherical particles

In this work we have characterized the phase behaviour and the dynamics of bidimensional mixtures of active and passive Brownian particles. We have evaluated state diagrams at several concentrations of the passive components finding that, while passive agents tend to hinder phase separation, active agents force crystal-like structures on passive colloids. In order to study how passive particles affect the dynamics of the mixture, we have computed the long-time diffusion coefficient of each species, concluding that active particles induce activity and super-diffusive behaviour on passive ones. Interestingly, at the density at which the system enters a MIPS state the active particles' diffusivity shows an inflection point and the passive particles' one goes through a maximum, due to the change in the dynamics of the active components, as shown in the displacement's probability distribution function.

cond-mat.soft↗

arXiv2025

Confinement-induced collective motion in suspensions of run-and-tumble particles

Collective motion is ubiquitous in active systems at all length and time scales. The mechanisms behind such collective motion usually are alignment interactions between active particles, effective alignment after collisions between agents or symmetry-breaking fluctuations induced by passive species in active suspensions. In this article, we introduce a new type of collective motion in the shape of a traveling band induced purely by confinement, where no explicit or effective alignment are prescribed among active agents. We study a suspension of run-and-tumble particles confined in microchannels comprising asymmetric boundaries: one flat wall and one array of funnel-like obstacles. We study the phase behavior of the confined active suspension upon changes in the packing fraction and the persistence length to define the stability region of the traveling band. We characterize the traveling band structurally and dynamically and study its stability with respect to the tilt angle of the obstacles. Lastly, we describe the mechanism of motion of the band, which resembles the tracked locomotion of some heavy vehicles like tractors, finding that a counter-flux of active particles in the lower part of the band, explained in terms of source-sink and vacancy diffusion mechanisms, is the facilitator of the traveling band and sustains its motion. We name this new collective phenomenon confinement-induced tracked locomotion

cond-mat.soft↗

arXiv2025

Sorting of binary active-passive mixtures in designed microchannels

Mixtures of active and passive particles are ubiquitous at the microscale. Many essential microbial processes involve interactions with dead or immotile cells or passive crowders. When passive objects are immersed in active baths, their transport properties are enhanced and can be tuned by controlling active agents' spatial and orientational distribution. Active-passive mixtures provide a platform to explore fundamental questions about the emergent behaviour of passive objects under simultaneous thermal and active noise and a foundation for technological applications in cargo delivery and bioremediation. In this work, we use computational simulations to study an active-passive mixture confined in microchannels designed with funnel-like obstacles that selectively allow the passage of passive particles. Active particles follow overdamped Langevin translational dynamics and run-and-tumble rotational dynamics. We find that adjusting the tumbling rate of active agents and the microchannel geometry leads to a maximum enhancement of the transport properties of the passive particles (diffusion coefficient and advective velocity) that correlates with the highest mixture sorting efficiency and the shortest response time.

cond-mat.soft↗

arXiv2025

Dynamics and rupture of doped Motility Induced Phase Peparation

Adding a small amount of passive (Brownian) particles to a two-dimensional dense suspension of repulsive active Brownian particles does not affect the appearance of a motility-induced phase separation into a dense and a dilute phase, caused by the persistence of the active particles' direction of motion. Unlike a purely active suspension, the dense slab formed in an elongated system of a passive-active mixture may show, over long periods of time, a stable and well-defined propagation of the interfaces, because of the symmetry breaking caused by the depletion of passive particles on one side of the slab. We investigate these dynamical structures via average density profile calculations, revealing an asymmetry between the two interfaces, and enabling a kinetic analysis of the slab movement. The apparent movement of the dense slab is not a pure source/sink effect, nor a rigid displacement of all the particles, but a self-sustained combination of both effects. Furthermore, we analyse the specific fluctuations that produce, cancel and abruptly reverse the slab motion.

cond-mat.soft↗

arXiv2025

Geometrical entanglement and alignment regulate self-organization in active ring polymer suspensions

We study the emerging self-organization in active ring suspensions, focusing on how the rings' orientational order and geometric entanglement vary with density and spatial confinement. To quantify entanglement, we introduce the wrapping number, a pairwise measure of ring interpenetration, while orientational order is characterized by the alignment of the normal vectors to the rings' osculating planes. Both wrapping number and alignment distinguish active from passive systems, and their combination aptly identifies the self-organized states that emerge with the onset of activity. Mutual-information analysis reveals a significant correlation between alignment and wrapping number across all considered active conditions. However, self-organization displays a non-monotonic dependence on the activity-induced entanglement. Specifically, moderate wrapping stabilizes contacts of neighboring aligned rings, while excessive entanglement disrupts alignment. We show that this competition arises because increasing entanglement interferes with the planar conformations required to form aligned stacks. Given the simplicity of this microscopic mechanism, analogous effects may occur more generally in polymer systems where the degree of entanglement is regulated by out-of-equilibrium effects.

cond-mat.soft↗

arXiv2025

Collective filament wrapping and nested spiral formation in active polydisperse systems

We investigate a two-dimensional polydisperse suspension of self-propelled semiflexible filaments and reveal a collective wrapping mechanism that is absent in monodisperse systems. At intermediate activity levels, long filaments coil around shorter ones, forming nested spiral structures stabilized by filament length disparity. These assemblies generalize the single-filament spiraling seen in active systems into cooperative, multi-filament configurations. As activity increases, the nested spirals undergo structural transitions: medium-length filaments unwind, longer filaments encapsulate shorter ones, and eventually all spiral structures dissolve. This reorganization is reflected in the dynamics, where van Hove distributions uncover coexisting confined and motile filament populations. Our findings identify filament length as a key control parameter for nonequilibrium self-assembly and establish inter-filament wrapping as a minimal mechanism for hierarchical organization in active matter. This mechanism provides a simple model for the cooperative confinement and structural hierarchy observed in both biological and synthetic active systems.

cond-mat.soft↗

arXiv2025

Optimal Translocation of Living \& Active Filaments in Confinement

Active filament translocation through confined spaces is central to processes ranging from DNA transport through nanopores to cytoskeletal dynamics in cell migration. Here, we use living filamentous \textit{Tubifex tubifex} worms as a model system to investigate how activity and filament conformation govern transport in confinement. By tuning activity via temperature and tracking worm dynamics in a two-chamber geometry connected by a narrow bridge, we quantify their translocation behavior and conformational states. In contrast to passive polymers and filaments, we find that contour length has negligible influence on trapping dynamics, while activity and reorientation jointly control escape. Strikingly, translocation efficiency is maximized at an intermediate temperature ($20^\circ$C), where a balance between directed propulsion and rotational diffusion optimizes exploration. We show that trapping times are governed by the interplay between the timescale of conformational rearrangements and the conformational entropy, quantifying the diversity of accessible shapes. Simulations of tangentially driven active filaments quantitatively reproduce the experimental observations and provide a minimal physical framework to rationalize the existence of an optimal activity. More broadly, our results identify general principles governing active filament transport in confinement, with implications for both biological systems and the design of synthetic active slender objects.

cond-mat.soft↗

arXiv2025

MIPS is a Maxwell fluid with an extended and non-monotonic crossover

Understanding the mechanical properties of active suspensions is crucial for their potential applications in materials engineering. Among the various phenomena in active matter that have no analogue in equilibrium systems, motility-induced phase separation (MIPS) in active colloidal suspensions is one of the most extensively studied. However, the mechanical properties of this fundamental active state of matter remain poorly understood. This study investigates the rheology of a suspension of active colloidal particles under constant and oscillatory shear. Systems consisting of pseudo-hard active Brownian particles exhibiting co-existence of dense and dilute phases behave as a viscoelastic Maxwell fluid at low and high frequencies, displaying exclusively shear thinning across a wide range of densities and activities. Remarkably, the cross-over point between the storage and loss moduli is non-monotonic, rising with activity before the MIPS transition but falling with activity after the transition, revealing the subtleties of how active forces and intrinsically out-of-equilibrium phases affect the mechanical properties of these systems.

cond-mat.soft↗