arXiv subjects

Charles A. Stafford

Publications and source records attributed to Charles A. Stafford.

At least 19 recordsLinked to original sources

arXiv2026

Decoherence and the Reemergence of Coherence From a Superconducting "Horizon''

In a recent paper [arXiv:2205.06279], Danielson et al. demonstrated that the mere presence of a black hole causes universal decoherence of quantum superpositions (dubbed the DSW decoherence). We analyze decoherence in a superconducting analogue [arXiv:1709.06154] of the event horizon of a black hole, where Andreev reflection plays the role of Hawking radiation. We consider a normal metal interferometer threaded by an Aharonov-Bohm flux, where one of the arms of the interferometer is coupled to a superconductor by a tunnel coupling of varying strength. At absolute zero temperature and for weak coupling, we find that the scattering states of the interferometer are decohered by Andreev reflection, a nontrivial manifestation of the proximity effect analogous to DSW decoherence from the event horizon of a black hole. However, for increasing coupling strength to the superconductor, we find a reemergence of coherence via resonant tunneling through Andreev bound states. This suggests the existence of an analogue gravitational phenomenon wherein transmission mediated by virtual Hawking radiation leads to a reemergence of coherence in an interferometer placed within a few Compton wavelengths of a black hole's event horizon.

quant-ph↗

arXiv2026

Emergence of the 2nd Law in an Exactly Solvable Model of a Quantum Wire

As remarked by Boltzmann, the Second Law of Thermodynamics is notable for the fact that it is readily proved using elementary statistical arguments, but becomes harder and harder to verify the more precise the microscopic description of a system. In this article, we investigate one particular realization of the 2nd Law, namely Joule heating in a wire under electrical bias. We analyze the production of entropy in an exactly solvable model of a quantum wire wherein the conserved flow of entropy under unitary quantum evolution is taken into account using an exact formula for the entropy current of a system of independent quantum particles. In this exact microscopic description of the quantum dynamics, the entropy production due to Joule heating does not arise automatically. Instead, we show that the expected entropy production is realized in the limit of a large number of local measurements by a series of floating thermoelectric probes along the length of the wire, which inject entropy into the system as a result of the information obtained via their continuous measurements of the system. The decoherence resulting from inelastic processes introduced by the local measurements is essential to the phenomenon of entropy production due to Joule heating, and would be expected to arise due to inelastic scattering in real systems of interacting particles.

quant-ph↗

arXiv2025

Entropy Flow at the Quantum Limit

Thermal management is a key challenge, both globally and microscopically in integrated circuits and quantum technologies. The associated heat flow $I_Q$ has been understood since the advent of thermodynamics by a process of elimination, $I_Q{=}I_E{-}μI_N$, subtracting from the energy flow $I_E$ its convective contribution. However, in the quantum limit, this formula implies the paradoxical result that the entropy entrained by heat flow is unbounded even though the entropy itself tends to zero. We resolve this conundrum by recognizing that the traditional formula for heat is missing a quantum term. The correct quantum formula predicts that the heat produced in quantum processes is vastly smaller than previously believed, with correspondingly beneficial consequences for the efficiency of quantum machines.

quant-ph↗

arXiv2025

Thermodynamics of a Quantum Subsystem

Several prior attempts to formulate the Laws of Thermodynamics for a small region within a larger quantum system have led to inconsistencies and unexplained infinities. The entropy and external work, in particular, require careful analysis when partitioning over the various subsystems. In this work, we analyze the thermodynamics of a quantum subsystem driven quasi-statically by external forces. We show that the thermodynamic functions of a quantum subsystem can be defined dynamically in terms of its local spectrum. The external work is found to be intrinsically nonlocal due to the nonlocal character of the underlying quantum states. This nonlocal quantum work can be harnessed in a "quantum lever" to provide up to 100% amplification of the local work done on a quantum subsystem.

quant-ph↗

arXiv2024

Work Sum Rule for Open Quantum Systems

A key question in the thermodynamics of open quantum systems is how to partition thermodynamic quantities such as entropy, work, and internal energy between the system and its environment. We show that the only partition under which entropy is nonsingular is based on a partition of Hilbert space, which assigns half the system-environment coupling to the system and half to the environment. However, quantum work partitions nontrivially under Hilbert-space partition, and we derive a work sum rule that accounts for quantum work at a distance. All state functions of the system are shown to be path independent once this nonlocal quantum work is properly accounted for. Our results are illustrated with application to a driven resonant level strongly coupled to a reservoir.

quant-ph↗

arXiv2024

Persistent versus dissipative Peltier effect in a topological quantum thermocouple

The Aharonov-Bohm (AB) effect on the thermoelectric properties of three-terminal quantum devices is investigated. Thermodynamic relations among the linear-response coefficients of these devices are derived and interpreted. General expressions are derived using nonequilibrium Green's functions, and applied to calculate the thermoelectric response of a model quantum thermocouple. It is shown that the AB effect can generate a large thermoelectric response in a device with particle-hole symmetry, which nominally has zero Seebeck and Peltier coefficients. In addition to modifying the external electric and thermal currents of the device, the AB effect also induces persistent electric and thermal currents. One might expect that a persistent electric current in a quantum thermocouple, through the Peltier effect, could lead to persistent Peltier cooling, violating the 1st and 2nd Laws of Thermodynamics. However, this apparent paradox is resolved by elucidating the distinction between persistent and dissipative currents in quantum thermoelectrics.

cond-mat.mes-hall↗

arXiv2024

How to Partition a Quantum Observable

We present a partition of quantum observables in an open quantum system which is inherited from the division of the underlying Hilbert space or configuration space. It is shown that this partition leads to the definition of an inhomogeneous continuity equation for generic, non-local observables. This formalism is employed to describe the local evolution of the von Neumann entropy of a system of independent quantum particles out of equilibrium. Crucially, we find that all local fluctuations in the entropy are governed by an entropy current operator, implying that the production of entanglement entropy is not measured by this partitioned entropy. For systems linearly perturbed from equilibrium, it is shown that this entropy current is equivalent to a heat current, provided that the system-reservoir coupling is partitioned symmetrically. Finally, we show that any other partition of the coupling leads directly to a divergence of the von Neumann entropy. Thus, we conclude that Hilbert-space partitioning is the only partition of the von Neumann entropy which is consistent with the Laws of Thermodynamics.

quant-ph↗

arXiv2023

On the First Law of Thermodynamics in Time-Dependent Open Quantum Systems

How to rigorously define thermodynamic quantities such as heat, work, and internal energy in open quantum systems driven far from equilibrium remains a significant open question in quantum thermodynamics. Heat is a quantity whose fundamental definition applies only to processes in systems infinitesimally perturbed from equilibrium, and as such, must be accounted for carefully in strongly-driven systems. A key insight from Mesoscopics is that infinitely far from the local driving and coupling of an open quantum system, reservoirs are indeed only infinitesimally perturbed, thereby allowing the heat dissipated to be defined. The resulting partition of the entropy necessitates a Hilbert-space partition of the energetics, leading to an unambiguous operator for the internal energy of an interacting time-dependent open quantum system. Fully general expressions for the heat current and the power delivered by various agents to the system are derived using the formalism of nonequilibrium Green's functions, establishing an experimentally meaningful and quantum mechanically consistent division of the energy of the system under consideration into Heat flowing out of and Work done on the system. The spatio-temporal distribution of internal energy in a strongly-driven open quantum system is also analyzed. This formalism is applied to analyze the thermodynamic performance of a model quantum machine: a driven two-level quantum system strongly coupled to two metallic reservoirs, which can operate in several configurations--as a chemical pump/engine or a heat pump/engine.

cond-mat.mes-hall↗

arXiv2019

The third law of thermodynamics in open quantum systems

We consider open quantum systems consisting of a finite system of independent fermions with arbitrary Hamiltonian coupled to one or more equilibrium fermion reservoirs (which need not be in equilibrium with each other). A strong form of the third law of thermodynamics, $S(T) \rightarrow 0$ as $T\rightarrow 0$, is proven for fully open quantum systems in thermal equilibrium with their environment, defined as systems where all states are broadened due to environmental coupling. For generic open quantum systems, it is shown that $S(T)\rightarrow g\ln 2$ as $T\rightarrow 0$, where $g$ is the number of localized states lying exactly at the chemical potential of the reservoir. For driven open quantum systems in a nonequilibrium steady state, it is shown that the local entropy $S({\bf x}; T) \rightarrow 0$ as $T({\bf x})\rightarrow 0$, except for cases of measure zero arising due to localized states, where $T({\bf x})$ is the temperature measured by a local thermometer.

cond-mat.mes-hall↗

arXiv2019

Scanning Tunneling Thermometry

Temperature imaging of nanoscale systems is a fundamental problem which has myriad potential technological applications. For example, nanoscopic cold spots can be used for spot cooling electronic components while hot spots could be used for precise activation of chemical or biological reactions. More fundamentally, imaging the temperature fields in quantum coherent conductors can provide a wealth of information on heat flow and dissipation at the smallest scales. However, despite significant technological advances, the spatial resolution of temperature imaging remains in the few nanometers range. Here we propose a method to map electronic temperature variations in operating nanoscale conductors by relying solely upon electrical tunneling current measurements. The scanning tunneling thermometer, owing to its operation in the tunneling regime, would be capable of mapping sub-angstrom temperature variations, thereby enhancing the resolution of scanning thermometry by some two orders of magnitude.

cond-mat.mes-hall↗

arXiv2017

Emergence of Fourier's law of heat transport in quantum electron systems

The microscopic origins of Fourier's venerable law of thermal transport in quantum electron systems has remained somewhat of a mystery, given that previous derivations were forced to invoke intrinsic scattering rates far exceeding those occurring in real systems. We propose an alternative hypothesis, namely, that Fourier's law emerges naturally if many quantum states participate in the transport of heat across the system. We test this hypothesis systematically in a graphene flake junction, and show that the temperature distribution becomes nearly classical when the broadening of the individual quantum states of the flake exceeds their energetic separation. We develop a thermal resistor network model to investigate the scaling of the sample and contact thermal resistances, and show that the latter is consistent with classical thermal transport theory in the limit of large level broadening.

cond-mat.mes-hall↗

arXiv2016

Local entropy of a nonequilibrium fermion system

The local entropy of a nonequilibrium system of independent fermions is investigated, and analyzed in the context of the laws of thermodynamics. It is shown that the local temperature and chemical potential can only be expressed in terms of derivatives of the local entropy for linear deviations from local equilibrium. The first law of thermodynamics is shown to lead to an inequality, not an equality, for the change in the local entropy as the nonequilibrium state of the system is changed. The maximum entropy principle (second law of thermodynamics) is proven: a nonequilibrium distribution has a local entropy less than or equal to a local equilibrium distribution satisfying the same constraints. It is shown that the local entropy of the system tends to zero when the local temperature tends to zero, consistent with the third law of thermodynamics.

cond-mat.mes-hall↗

arXiv2016

Local temperature of an interacting quantum system far from equilibrium

A theory of local temperature measurement of an interacting quantum electron system far from equilibrium via a floating thermoelectric probe is developed. It is shown that the local temperature so defined is consistent with the zeroth, first, second, and third laws of thermodynamics, provided the probe-system coupling is weak and broad band. For non-broad-band probes, the local temperature obeys the Clausius form of the second law and the third law exactly, but there are corrections to the zeroth and first laws that are higher-order in the Sommerfeld expansion. The corrections to the zeroth and first laws are related, and can be interpreted in terms of the error of a nonideal temperature measurement. These results also hold for systems at negative absolute temperature.

cond-mat.mes-hall↗

arXiv2016

Temperature and voltage measurement in quantum systems far from equilibrium

We show that a local measurement of temperature and voltage for a quantum system in steady state, arbitrarily far from equilibrium, with arbitrary interactions within the system, is unique when it exists. This is interpreted as a consequence of the second law of thermodynamics. We further derive a necessary and sufficient condition for the existence of a solution. In this regard, we find that a positive temperature solution exists whenever there is no net population inversion. However, when there is a net population inversion, we may characterize the system with a unique negative temperature. Voltage and temperature measurements are treated on an equal footing: They are simultaneously measured in a noninvasive manner, via a weakly-coupled thermoelectric probe, defined by requiring vanishing charge and heat dissipation into the probe. Our results strongly suggest that a local temperature measurement without a simultaneous local voltage measurement, or vice-versa, is a misleading characterization of the state of a nonequilibrium quantum electron system. These results provide a firm mathematical foundation for voltage and temperature measurements far from equilibrium.

cond-mat.mes-hall↗

arXiv2015

Cold spots in quantum systems far from equilibrium: local entropies and temperatures near absolute zero

We consider a question motivated by the third law of thermodynamics: can there be a local temperature arbitrarily close to absolute zero in a nonequilibrium quantum system? We consider nanoscale quantum conductors with the source reservoir held at finite temperature and the drain held at or near absolute zero, a problem outside the scope of linear response theory. We obtain local temperatures close to absolute zero when electrons originating from the finite temperature reservoir undergo destructive quantum interference. The local temperature is computed by numerically solving a nonlinear system of equations describing equilibration of a scanning thermoelectric probe with the system, and we obtain excellent agreement with analytic results derived using the Sommerfeld expansion. A local entropy for a nonequilibrium quantum system is introduced, and used as a metric quantifying the departure from local equilibrium. It is shown that the local entropy of the system tends to zero when the probe temperature tends to zero, consistent with the third law of thermodynamics.

cond-mat.mes-hall↗

arXiv2014

Lifetimes of Metal Nanowires with Broken Axial Symmetry

We present a theoretical approach for understanding the stability of simple metal nanowires, in particular monovalent metals such as the alkalis and noble metals. Their cross sections are of order one nanometer so that small perturbations from external (usually thermal) noise can cause large geometrical deformations. The nanowire lifetime is defined as the time required for making a transition into a state with a different cross-sectional geometry. This can be a simple overall change in radius, or a change in the cross section shape, or both. We develop a stochastic field theoretical model to describe this noise-induced transition process, in which the initial and final states correspond to locally stable states on a potential surface derived by solving the Schrodinger equation for the electronic structure of the nanowire numerically. The numerical string method is implemented to determine the optimal transition path governing the lifetime. Using these results, we tabulate the lifetimes of sodium and gold nanowires for several different initial geometries.

cond-mat.mes-hall↗

arXiv2014

Thermoelectric Corrections to Quantum Voltage Measurement

A generalization of Buttiker's voltage probe concept for nonzero temperatures is an open third terminal of a quantum thermoelectric circuit. An explicit analytic expression for the thermoelectric correction to an ideal quantum voltage measurement is derived, and interpreted in terms of local Peltier cooling/heating within the nonequilibrium system. The thermoelectric correction is found to be large (up to +-24% of the peak voltage) in a prototypical ballistic quantum conductor (graphene nanoribbon). The effects of measurement non-ideality are also investigated. Our findings have important implications for precision local electrical measurements.

cond-mat.mes-hall↗

arXiv2013

Tunable Quantum Temperature Oscillations in Graphene and Carbon Nanoribbons

We investigate the local electron temperature distribution in carbon nano-ribbon (CNR) and graphene junctions subject to an applied thermal gradient. Using a realistic model of a scanning thermal microscope, we predict quantum temperature oscillations whose wavelength is related to that of Friedel oscillations. Experimentally, this wavelength can be tuned over several orders of magnitude by gating/doping, bringing quantum temperature oscillations within reach of the spatial resolution of existing measurement techniques.

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