Precision Measurement of M1 Optical Clock Transition in Ni12+
Highly charged ions (HCIs) have drawn significant interest in quantum metrology and in search for new physics. Among these, Ni12+ is considered as one of the most promising candidates for the next generation of HCI optical clocks, due to its two E1-forbidden transitions M1 and E2, which occur in the visible spectral range. In this work, we used the Shanghai-Wuhan Electron Beam Ion Trap to perform a high-precision measurement of the M1 transition wavelength. Our approach involved an improved calibration scheme for the spectra, utilizing auxiliary Ar+ lines for calibration and correction. Our final measured result of the M1 transition wavelength demonstrates a five-fold improvement in accuracy compared to our previous findings, reaching the sub-picometer level accuracy. In combination with our rigorous atomic-structure calculations to capture the electron correlations and relativistic effects, the quantum electrodynamic (QED) corrections were extracted. Moreover, comparing with an estimate of the one-electron QED contributions by using the GRASP2018 package, we found that the present experimental accuracy is high enough for testing the higher-order QED corrections for such a complex system with four electrons in the p subshell.