arXiv subjects

Chi-Ming Yim

Publications and source records attributed to Chi-Ming Yim.

6 recordsLinked to original sources

arXiv2025

Novel coupling between charge order and time-reversal-symmetry-breaking superconductivity

The interplay between charge-density waves (CDWs), which break translational symmetry, and spatially homogeneous superconductivity, which breaks global U(1) gauge symmetry, can give rise to an intriguing phenomenon: the pair-density wave, characterized by a spatial modulation of the superconducting order parameter. Yet how CDWs couple to unconventional superconducting states-particularly those with time-reversal symmetry breaking (TRSB)-remains largely unexplored. Here, using scanning tunneling microscopy on heavily hole-doped Ba$_{1-x}$K$_x$Fe$_2$As$_2$, which hosts an s $\pm$ is superconducting state, we reveal a previously unobserved coupling between a surface CDW and TRSB superconductivity. Experimentally, the TRSB superconductivity imparts "chirality" to the CDW, which manifests as commensurate domains separated by domain walls with $\pi$-phase slips-forming what we term a bipolar CDW. The domain walls delineate TRSB domains of opposite chirality, consistent with spontaneous breaking of U(1) $\times$ Z2. Supported by theoretical modelling, we construct a framework in which a hidden interfacial pair-density modulation (PDM) mediates a linear coupling between the surface CDW and interband Josephson currents of TRSB superconductivity. Crucially, the theory shows that realizing this linear coupling requires a controlled global phase difference $\delta$ $\phi$ = $\pi$/2 between the PDM and CDW states. Our results uncover a previously overlooked connection between charge ordering and TRSB superconductivity, opening a pathway to explore intertwined quantum orders in iron-based superconductors and other strongly correlated systems.

cond-mat.supr-con↗

arXiv2025

Evidence of pseudogap and absence of spin magnetism in the time-reversal-symmetry-breaking state of Ba$_{1-x}$K$_x$Fe$_2$As$_2$

Muon-spin-rotation ($μ$SR) experiments and the observation of a spontaneous Nernst effect indicate time-reversal symmetry breaking (BTRS) at $T_{\rm c}^{\rm Z2}$ above the superconducting transition temperature $T_{\rm c}$ in Ba$_{1-x}$K$_x$Fe$_2$As$_2$, with $x\approx0.8$. Further studies have pointed out that BTRS is caused by the formation of a new state of matter associated with the condensation of pairs of electron pairs. Despite exhibiting multiple unconventional effects that warrant further investigation, the electronic spectral properties of this electron quadrupling state remain largely unexplored. Here, we present detailed $^{75}$As nuclear magnetic resonance (NMR) measurements of Ba$_{1-x}$K$_x$Fe$_2$As$_2$, with $x = 0.77$, which has $T_{\rm c}^{\rm Z2}$ > $T_{\rm c}$ according to measurements of the spontaneous Nernst effect. The NMR data obtained in this work provide the first direct electronic spectral characteristics of the electron quadrupling state by indicating that it evolves from a pseudogap that sets in at $T^*$ well above $T_{\rm c}^{\rm Z2}$. This pseudogap behavior is consistent with $μ$SR Knight-shift, specific-heat, and transport data indicating the formation of a bound state of electrons. According to a theory of electron quadrupling condensates, such bound-state formations should precede the onset of BTRS correlations between pairs of electron pairs. The second important insight from NMR data is the absence of spin-related magnetism. The temperature dependence of the spin-lattice relaxation rate $1/T_1T$ and the evolution of the NMR linewidth prove the absence of a magnetic transition at $T_{\rm c}^{\rm Z2}$ and rule out even a proximity to some magnetic instability. This indicates that the spontaneous magnetic fields detected in this compound are not caused by spin magnetism but are associated with persistent real-space currents.

cond-mat.supr-con↗

arXiv2024

Direct observation of quantum vortex fractionalization in multiband superconductors

Magnetic field is expelled from a superconductor, unless it forms quantum vortices, consisting of a core singularity with current circulating around it. The London quantization condition implies that there is one core singularity per quantum of magnetic flux in single-component superconductors, while in multiband materials fractional vortices are possible. Here, we report the first observation of quantum vortex core fractionalization on the potassium terminated surface of multiband superconductor KFe2As2 by scanning tunneling microscopy. We observe splitting of an integer-flux vortex into several fractional vortices, leading to disparity between numbers of flux quanta and vortex cores. Our findings demonstrate that fractionalized core singularities are possible in a multiband superconductor, opening avenue for new experimental platforms with quasiparticles with fractional statistics.

cond-mat.supr-con↗

arXiv2024

Crystal structure, properties and pressure-induced insulator-metal transition in layered kagome chalcogenides

Layered materials with kagome lattice have attracted a lot of attention due to the presence of nontrivial topological bands and correlated electronic states with tunability. In this work, we investigate a unique van der Waals (vdW) material system, $A_{2}M_{3}X_{4}$ ($A$ = K, Rb, Cs; $M$ = Ni, Pd; $X$ = S, Se), where transition metal kagome lattices, chalcogen honeycomb lattices and alkali metal triangular lattices coexist simultaneously. A notable feature of this material is that each Ni/Pd atom is positioned in the center of four chalcogen atoms, forming a local square-planar environment. This crystal field environment results in a low spin state $S$ = 0 of Ni$^{2+}$/Pd$^{2+}$. A systematic study of the crystal growth, crystal structure, magnetic and transport properties of two representative compounds, Rb$_{2}$Ni$_{3}$S$_{4}$ and Cs$_{2}$Ni$_{3}$Se$_{4}$, has been carried out on powder and single crystal samples. Both compounds exhibit nonmagnetic $p$-type semiconducting behavior, closely related to the particular chemical environment of Ni$^{2+}$ ions and the alkali metal intercalated vdW structure. Additionally, Cs$_{2}$Ni$_{3}$Se$_{4}$ undergoes an insulator-metal transition (IMT) in transport measurements under pressure up to 87.10 GPa without any structural phase transition, while Rb$_{2}$Ni$_{3}$S$_{4}$ persists in its semiconducting behavior.

cond-mat.mtrl-sci↗

arXiv2021

Tuneable electron-magnon coupling of ferromagnetic surface states in PdCoO$_2$

Controlling spin wave excitations in magnetic materials underpins the burgeoning field of magnonics. Yet, little is known about how magnons interact with the conduction electrons of itinerant magnets, or how this interplay can be controlled. Via a surface-sensitive spectroscopic approach, we demonstrate a strong and highly-tuneable electron-magnon coupling at the Pd-terminated surface of the delafossite oxide PdCoO$_2$, where a polar surface charge mediates a Stoner transition to itinerant surface ferromagnetism. We show how the coupling can be enhanced 7-fold with increasing surface disorder, and concomitant charge carrier doping, becoming sufficiently strong to drive the system into a polaronic regime, accompanied by a significant quasiparticle mass enhancement. Our study thus sheds new light on electron-magnon interactions in solid-state materials, and the ways in which these can be controlled.

cond-mat.str-el↗

arXiv2018

Correct Brillouin zone and electronic structure of BiPd

A promising route to the realization of Majorana fermions is in non-centrosymmetric superconductors, in which spin-orbit-coupling lifts the spin degeneracy of both bulk and surface bands. A detailed assessment of the electronic structure is critical to evaluate their suitability for this through establishing the topological properties of the electronic structure. This requires correct identification of the time-reversal-invariant momenta. One such material is BiPd, a recently rediscovered non-centrosymmetric superconductor which can be grown in large, high-quality single crystals and has been studied by several groups using angular resolved photoemission to establish its surface electronic structure. Many of the published electronic structure studies on this material are based on a reciprocal unit cell which is not the actual Brillouin zone of the material. We show here the consequences of this for the electronic structures and show how the inferred topological nature of the material is affected.

cond-mat.mtrl-sci↗