arXiv subjects

Chi-Te Liang

Publications and source records attributed to Chi-Te Liang.

23 records · Page 2Linked to original sources

arXiv2013

Nitrogen-Doped Graphene Sheets Grown by Chemical Vapor Deposition: Synthesis and Influence of Nitrogen Impurities on Carrier Transport

A significant advance toward achieving practical applications of graphene as a two-dimensional material in nanoelectronics would be provided by successful synthesis of both n-type and p-type doped graphene. However reliable doping and a thorough understanding of carrier transport in the presence of charged impurities governed by ionized donors or acceptors in the graphene lattice are still lacking. Here we report experimental realization of few-layer nitrogen-doped (N-doped) graphene sheets by chemical vapor deposition of organic molecule 1, 3, 5-triazine on Cu metal catalyst. By reducing the growth temperature, the atomic percentage of nitrogen doping is raised from 2.1 % to 5.6 %. With increasing doping concentration, N-doped graphene sheet exhibits a crossover from p-type to n-type behavior accompanied by a strong enhancement of electron-hole transport asymmetry, manifesting the influence of incorporated nitrogen impurities. In addition, by analyzing the data of X-ray photoelectron spectroscopy, Raman spectroscopy, and electrical measurements, we show that pyridinic and pyrrolic N impurities play an important role in determining the transport behavior of carriers in N-doped graphene sheets.

cond-mat.mes-hall↗

arXiv2013

Ultrahigh-Gain Phototransistors Based on Graphene-MoS2 Heterostructures

Due to its high carrier mobility, broadband absorption, and fast response time, graphene is attractive for optoelectronics and photodetection applications. However, the extraction of photoelectrons in conventional metal-graphene junction devices is limited by their small junction area, where the typical photoresponsivity is lower than 0.01 AW-1. On the other hand, the atomically thin layer of molybdenum disulfide (MoS2) is a two-dimensional (2d) nanomaterial with a direct and finite band gap, offering the possibility of acting as a 2d light absorber. The optoelectronic properties of the heterostructure of these two films is therefore of great interest. The growth of large-area graphene using chemical vapour deposition (CVD) has become mature nowadays. However, the growth of large-area MoS2 monolayer is still challenging. In this work, we show that a large-area and continuous MoS2 monolayer is achievable using a CVD method. Both graphene and MoS2 layers are transferable onto desired substrates, making possible immediate and large-scale optoelectronic applications. We demonstrate that a phototransistor based on the graphene/MoS2 heterostructure is able to provide a high photoresponsivity greater than 107 A/W while maintaining its ultrathin and planar structure. Our experiments show that the electron-hole pairs are produced in the MoS2 layer after light absorption and subsequently separated across the layers. Contradictory to the expectation based on the conventional built-in electric field model for metal-semiconductor contacts, photoelectrons are injected into the graphene layer rather than trapped in MoS2 due to the alignment of the graphene Fermi level with the conduction band of MoS2. The band alignment is sensitive to the presence of a perpendicular electric field arising from, for example, Coulomb impurities or an applied gate voltage, resulting in a tuneable photoresponsivity.

cond-mat.mtrl-sci↗

arXiv2009

Theory of the quantum Hall effect in graphene

We study the quantum Hall effect (QHE) in graphene based on the current injection model. In our model, the presence of disorder, the edge-state picture, extended states and localized states, which are believed to be indispensable ingredients in describing the QHE, do not play an important role. Instead the boundary conditions during the injection into the graphene sheet, which are enforced by the presence of the Ohmic contacts, determine the current-voltage characteristics.

cond-mat.mes-hall↗

arXiv2008

Half integer features in the quantum Hall Effect: experiment and theory

The quantum Hall effect is one of the most important developments in condensed matter physics of the 20th century. The standard explanations of the famous integer quantized Hall plateaus in the transverse resistivity are qualitative, and involve assumptions about disorder, localized states, extended states, edge states, Fermi levels pinned by Landau levels, etc. These standard narratives give plausible reasons for the existence of the plateaus, but provide little in the way of even a qualitative understanding of the shape and width of the Hall plateaus, much less a first principles calculation. The injection model presented in this paper changes that situation. Rather than focusing on the middle of the Hall device, we follow the electrons to their source: one corner of the Hall bar and its steep electric field gradients. We find the entire resistivity curve including the Hall plateaus is calculable as a function of magnetic field, temperature, and current. The new higher current experiments reported here show remarkable half integer features for the first time; these are faithfully reproduced by the injection theory. The Hall plateaus and half integer inflections are shown to result from the local density of states appropriate to the magnetic field and the strong electric field gradient at the injection corner.

cond-mat.mes-hall↗

arXiv2000

Large transconductance oscillations in a single-well vertical Aharonov-Bohm interferometer

Aharonov-Bohm (AB) interference is reported for the first time in the conductance of a vertical nanostructure based on a single GaAs/AlGaAs quantum well (QW). The two lowest subbands of the well are spatially separated by the Hartree barrier originating from electronic repulsion in the modulation-doped QW and provide AB two-path geometry. Split-gates control the in-plane electronic momentum dispersion. In our system, we have clearly demonstrated AB interference in both electrostatic and magnetic modes. In the latter case the magnetic field was applied parallel to the QW plane, and perpendicular to the 0.02 um^2 AB loop. In the electrostatic mode of operation the single-QW scheme adopted led to large transconductance oscillations with relative amplitudes exceeding 30 %. The relevance of the present design strategy for the implementation of coherent nanoelectronic devices is underlined.

cond-mat.mes-hall↗