Chirag Manchanda | Searcharxiv

arXiv2022

Chemical speciation and source apportionment of ambient PM2.5 in New Delhi before, during, and after the Diwali fireworks

Diwali is among the most important Indian festivals, and elaborate firework displays mark the evening's festivities. This study assesses the impact of Diwali on the concentration, composition, and sources of ambient PM2.5. We observed the total PM2.5 concentrations to rise to 16 times the pre-firework levels, while each of the elemental, organic, and black carbon fractions of ambient PM2.5 increased by a factor of 46.1, 3.7, and 5.6, respectively. The concentration of species like K, Al, Sr, Ba, S, and Bi displayed distinct peaks during the firework event and were identified as tracers. The average concentrations of potential carcinogens, like As, exceeded US EPA screening levels for industrial air by a factor of ~9.6, while peak levels reached up to 16.1 times the screening levels. The source apportionment study, undertaken using positive matrix factorization, revealed the fireworks to account for 95% of the total elemental PM2.5 during Diwali. The resolved primary organic emissions, too, were enhanced by a factor of 8 during Diwali. Delhi has encountered serious haze events following Diwali in recent years; this study highlights that biomass burning emissions rather than the fireworks drive the poor air quality in the days following Diwali.

physics.ao-ph↗

arXiv2021

Variation in chemical composition and sources of PM2.5 during the COVID-19 lockdown in Delhi

The Government of India (GOI) announced a nationwide lockdown starting 25th March 2020 to contain the spread of COVID-19, leading to an unprecedented decline in anthropogenic activities and in turn improvements in ambient air quality. This is the first study to focus on highly time-resolved chemical speciation and source apportionment of PM$_{2.5}$ to assess the impact of the lockdown and subsequent relaxations on the sources of ambient PM$_{2.5}$ in Delhi, India. The elemental, organic, and black carbon fractions of PM$_{2.5}$ were measured at the IIT Delhi campus from February 2020 to May 2020. We report source apportionment results using positive matrix factorization (PMF) of organic and elemental fractions of PM$_{2.5}$ during the different phases of the lockdown. The resolved sources such as vehicular emissions, domestic coal combustion, and semi-volatile oxygenated organic aerosol (SVOOA) were found to decrease by 96%, 95%, and 86%, respectively, during lockdown phase-1 as compared to pre-lockdown. An unforeseen rise in O$_3$ concentrations with declining NO$_x$ levels was observed, similar to other parts of the globe, leading to the low-volatility oxygenated organic aerosols (LVOOA) increasing to almost double the pre-lockdown concentrations during the last phase of the lockdown. The effect of the lockdown was found to be less pronounced on other resolved sources like secondary chloride, power plants, dust-related, hydrocarbon-like organic aerosols (HOA), and biomass burning related emissions, which were also swayed by the changing meteorological conditions during the four lockdown phases. The results presented in this study provide a basis for future emission control strategies, quantifying the extent to which constraining certain anthropogenic activities can ameliorate the ambient air.

physics.ao-ph↗