Production of heavy $α$-elements and $^{44}$Ti in Cas A: comparison to abundances from 1D core-collapse supernova models and evidence for Carbon-Oxygen shell mergers
The merger between the carbon (C) and oxygen (O) shells hours to days before the collapse of a massive star significantly changes its nucleosynthesis, which is reflected in the elemental ratios observed in supernova remnants (SNRs). We present a nucleosynthesis study of $^{44}$Ti production in core-collapse supernovae (CCSNe), highlighting large silicon (Si), sulfur (S), calcium (Ca), and, most importantly, argon (Ar) to neon (Ne) ratios as diagnostics for carbon-oxygen (C--O) shell mergers. We compare yields from eight different sets of CCSNe models to observations of Cassiopeia A (Cas A), and show that C--O shell mergers are consistently the models that best match X-ray and infrared observations. These models produce high Ar/Ne ratios ($\gtrsim 0.1$), due to $^{20}$Ne depletion and production of $^{36}$Ar and $^{38}$Ar, while lower ratios are obtained from non-merger cases. Based on the Ar/Ne diagnostic, we compare the range of expected $^{44}$Ti produced by C--O shell mergers, which is up to $\sim 20 - 30 \%$ of the overall $^{44}$Ti, but expected to be located outside the reverse shock. Based on the sets of models considered, the photon flux expected from the $^{44}$Ti synthesized in the C--O shell merger in Cas A is below the $NuSTAR$ and $COSI$ detection limits, compatible with current limits locating most of the $^{44}$Ti interior to the reverse shock, but might be detectable from proposed missions like $ASCENT$. Finally, for the SNR of 1987A, a dominant C--O merger origin of the observed $^{44}$Ti is unlikely based on the observed redshift in its $^{44}$Ti line.