Searcharxiv⌕ Search

arXiv subjects

Christian D. Santangelo

Publications and source records attributed to Christian D. Santangelo.

At least 55 records · Page 3Linked to original sources
arXiv2012

Packing Squares in a Torus

The densest packings of N unit squares in a torus are studied using analytical methods as well as simulated annealing. A rich array of dense packing solutions are found: density-one packings when N is the sum of two square integers; a family of "gapped bricklayer" Bravais lattice solutions with density N/(N+1); and some surprising non-Bravais lattice configurations, including lattices of holes as well as a configuration for N=23 in which not all squares share the same orientation. The entropy of some of these configurations and the frequency and orientation of density-one solutions as N goes to infinity are discussed.

cond-mat.stat-mech↗
arXiv2011

Developed Smectics: When Exact Solutions Agree

In the limit where the bending modulus vanishes, we construct layer configurations with arbitrary dislocation textures by exploiting a connection between uniformly-spaced layers in two dimensions and developable surfaces in three dimensions. We then show how these focal textures can be used to construct layer configurations with finite bending modulus.

cond-mat.soft↗
arXiv2011

Smectic Pores and Defect Cores

Riemann's minimal surfaces are a complete, embeddable, one-parameter family of minimal surfaces with translational symmetry along one direction. It's infinite number of planar ends are joined together by an array of necks, closely matching the morphology of a bicontinuous, lamellar system with pores connecting alternating layers. We demonstrate explicitly that Riemann's minimal surfaces are composed of a nonlinear sum of two oppositely-handed helicoids. This description is particularly appropriate for describing smectic liquid crystals containing two screw dislocations.

cond-mat.soft↗
arXiv2011

Frustrated order on extrinsic geometries

We study, analytically and theoretically, defects in a nematically-ordered surface that couple to the extrinsic geometry of a surface. Though the intrinsic geometry tends to confine topological defects to regions of large Gaussian curvature, extrinsic couplings tend to orient the nematic in the local direction of maximum or minimum bending. This additional frustration is unavoidable and most important on surfaces of negative Gaussian curvature, where it leads to a complex ground state thermodynamics. We show, in contradistinction to the well-known effects of intrinsic geometry, that extrinsic curvature expels disclinations from the region of maximum curvature above a critical coupling threshold. On catenoids lacking an "inside-outside" symmetry, defects are expelled altogether.

cond-mat.soft↗
arXiv2011

Minimal resonances in annular non-Euclidean strips

Differential growth processes play a prominent role in shaping leaves and biological tissues. Using both analytical and numerical calculations, we consider the shapes of closed, elastic strips which have been subjected to an inhomogeneous pattern of swelling. The stretching and bending energies of a closed strip are frustrated by compatibility constraints between the curvatures and metric of the strip. To analyze this frustration, we study the class of "conical" closed strips with a prescribed metric tensor on their center line. The resulting strip shapes can be classified according to their number of wrinkles and the prescribed pattern of swelling. We use this class of strips as a variational ansatz to obtain the minimal energy shapes of closed strips and find excellent agreement with the results of a numerical bead-spring model. Within this class of strips, we derive a condition under which a strip can have vanishing mean curvature along the center line.

cond-mat.mtrl-sci↗
arXiv2009

Buckling Thin Disks and Ribbons with Non-Euclidean Metrics

I consider the problem of a thin membrane on which a metric has been prescribed, for example by lithographically controlling the local swelling properties of a polymer thin film. While any amount of swelling can be accommodated locally, geometry prohibits the existence of a global strain-free configuration. To study this geometrical frustration, I introduce a perturbative approach. I compute the optimal shape of an annular, thin ribbon as a function of its width. The topological constraint of closing the ribbon determines a relationship between the mean curvature and number of wrinkles that prevents a complete relaxation of the compression strain induced by swelling and buckles the ribbon out of the plane. These results are then applied to thin, buckled disks, where the expansion works surprisingly well. I identify a critical radius above which the disk in-plane strain cannot be relaxed completely.

cond-mat.soft↗
arXiv2009

Mesophases of soft-sphere aggregates

Soft spheres interacting via a hard core and range of attractive and repulsive "soft-shoulder" potentials self-assemble into clusters forming a variety of mesophases. We combine a mean field theory developed from a lattice model with a level surface analysis of the periodic structures of soft-sphere aggregates to study stable morphologies for all clustering potentials. We develop a systematic approach to the thermodynamics of mesophase assembly in the low-temperature, strong-segregation and predict a generic sequence of phases including lamella, hexagonal-columnar and body-center cubic phases, as well as the associated inverse structures. We discuss the finite-temperature corrections to strong segregation theory in terms of Sommerfeld-like expansion and how these corrections affect the thermodynamic stability of bicontinuous mesophase structures, such as gyroid. Finally, we explore the opposite limit of weakly-segregated particles, and predict the generic stability of a bicontinuous cluster morphology within the mean-field phase diagram.

cond-mat.soft↗
arXiv2008

Diffusion and binding of finite-size particles in confined geometries

Describing the diffusion of particles through crowded, confined environments with which they can interact is of considerable biological and technological interest. Under conditions where the confinement dimensions become comparable to the particle dimensions, steric interactions between particles, as well as particle-wall interactions, will play a crucial role in determining transport properties. To elucidate the effects of these interactions on particle transport, we consider the diffusion and binding of finite-size particles within a channel whose diameter is comparable to the size of the particles. Using a simple lattice model of this process, we calculate the steady-state current and density profiles of both bound and free particles in the channel. We show that the system can exhibit qualitatively different behavior depending on the ratio of the channel width to the particle size. We also perform simulations of this system, and find excellent agreement with our analytic results.

cond-mat.soft↗
arXiv2007

Geometric Theory of Columnar Phases on Curved Substrates

We study thin self-assembled columns constrained to lie on a curved, rigid substrate. The curvature presents no local obstruction to equally spaced columns in contrast to curved crystals for which the crystalline bonds are frustrated. Instead, the vanishing compressional strain of the columns implies that their normals lie on geodesics which converge (diverge) in regions of positive (negative) Gaussian curvature, in analogy to the focussing of light rays by a lens. We show that the out of plane bending of the cylinders acts as an effective ordering field.

cond-mat.soft↗
arXiv2006

Triply-Periodic Smectics

Twist-grain-boundary phases in smectics are the geometrical analogs of the Abrikosov flux lattice in superconductors. At large twist angles, the nonlinear elasticity is important in evaluating their energetics. We analytically construct the height function of a pi/2 twist-grain-boundary phase in smectic-A liquid crystals, known as Schnerk's first surface. This construction, utilizing elliptic functions, allows us to compute the energy of the structure analytically. By identifying a set of heretofore unknown defects along the pitch axis of the structure, we study the necessary topological structure of grain boundaries at other angles, concluding that there exist a set of privileged angles and that the π/2 and π/3 grain boundary structures are particularly simple.

cond-mat.soft↗
arXiv2006

Soft Spheres Make More Mesophases

We use both mean-field methods and numerical simulation to study the phase diagram of classical particles interacting with a hard-core and repulsive, soft shoulder. Despite the purely repulsive interaction, this system displays a remarkable array of aggregate phases arising from the competition between the hard-core and shoulder length scales. In the limit of large shoulder width to core size, we argue that this phase diagram has a number of universal features, and classify the set of repulsive shoulders that lead to aggregation at high density. Surprisingly, the phase sequence and aggregate size adjusts so as to keep almost constant inter-aggregate separation.

cond-mat.soft↗
arXiv2006

Undulated cylinders of charged diblock copolymers

We study the cylinder to sphere morphological transition of diblock copolymers in aqueous solution with a hydrophobic block and a charged block. We find a metastable undulated cylinder configuration for a range of charge and salt concentrations which, nevertheless, occurs above the threshold where spheres are thermodynamically favorable. By modeling the shape of the cylinder ends, we find that the free energy barrier for the transition from cylinders to spheres is quite large and that this barrier falls significantly in the limit of high polymer charge and low solution salinity. This suggests that observed undulated cylinder phases are kinetically trapped structures.

cond-mat.soft↗
arXiv2006

Elliptic Phases: A Study of the Nonlinear Elasticity of Twist-Grain Boundaries

We develop an explicit and tractable representation of a twist-grain-boundary phase of a smectic A liquid crystal. This allows us to calculate the interaction energy between grain boundaries and the relative contributions from the bending and compression deformations. We discuss the special stability of the 90 degree grain boundaries and discuss the relation of this structure to the Schwarz D surface.

cond-mat.soft↗
arXiv2006

Smectic Liquid Crystals: Materials with One-Dimensional, Periodic Order

Smectic liquid crystals are materials formed by stacking deformable, fluid layers. Though smectics prefer to have flat, uniformly-spaced layers, boundary conditions can impose curvature on the layers. Since the layer spacing and curvature are intertwined, the problem of finding minimal configurations for the layers becomes highly nontrivial. We discuss various topological and geometrical aspects of these materials and present recent progress on finding some exact layer configurations. We also exhibit connections to the study of certain embedded minimal surfaces and briefly summarize some important open problems.

math.DG↗
arXiv2005

Computing Counterion Densities at Intermediate Coupling

By decomposing the Coulomb interaction into a long distance component appropriate for mean-field theory, and a nonmean-field short distance component, we compute the counterion density near a charged surface for all values of the counterion coupling parameter. A modified strong-coupling expansion that is manifestly finite at all coupling strengths is used to treat the short distance component. We find a nonperturbative correction related to the lateral counterion correlations that modifies the density at intermediate coupling.

cond-mat.soft↗
arXiv2004

Interaction Between Two Rows of Localized Adsorption Sites in a 2D One-Component Plasma

We compute the free energy for two rows of localized adsorption sites embedded in a two dimensional one-component plasma with neutralizing background density $ρ$. The interaction energy between the adsorption sites is repulsive. We also compute the average occupation number of the adsorption sites and compare it to the result for a single row of sites. The exact result indicates that the discretization does not induce charge asymmetry and no attractive forces occur.

cond-mat.soft↗
arXiv2004

Pore formation in fluctuating membranes

We study the nucleation of a single pore in a fluctuating lipid membrane, specifically taking into account the membrane fluctuations, as well as the shape fluctuations of the pore. For large enough pores, the nucleation free energy is well-described by shifts in the effective membrane surface tension and the pore line tension. Using our framework, we derive the stability criteria for the various pore formation regimes. In addition to the well-known large-tension regime from the classical nucleation theory of pores, we also find a low-tension regime in which the effective line and surface tensions can change sign from their bare values. The latter scenario takes place at sufficiently high temperatures, where the opening of a stable pore of finite size is entropically favorable.

cond-mat.soft↗