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Christopher B. Stanley

Publications and source records attributed to Christopher B. Stanley.

3 recordsLinked to original sources

Are Normalizing Flows the Key to Unlocking the Exponential Mechanism?

The Exponential Mechanism (ExpM), designed for private optimization, has been historically sidelined from use on continuous sample spaces, as it requires sampling from a generally intractable density, and, to a lesser extent, bounding the sensitivity of the objective function. Any differential privacy (DP) mechanism can be instantiated as ExpM, and ExpM poses an elegant solution for private machine learning (ML) that bypasses inherent inefficiencies of DPSGD. This paper seeks to operationalize ExpM for private optimization and ML by using an auxiliary Normalizing Flow (NF), an expressive deep network for density learning, to approximately sample from ExpM density. The method, ExpM+NF is an alternative to SGD methods for model training. We prove a sensitivity bound for the $\ell^2$ loss permitting ExpM use with any sampling method. To test feasibility, we present results on MIMIC-III health data comparing (non-private) SGD, DPSGD, and ExpM+NF training methods' accuracy and training time. We find that a model sampled from ExpM+NF is nearly as accurate as non-private SGD, more accurate than DPSGD, and ExpM+NF trains faster than Opacus' DPSGD implementation. Unable to provide a privacy proof for the NF approximation, we present empirical results to investigate privacy including the LiRA membership inference attack of Carlini et al. and the recent privacy auditing lower bound method of Steinke et al. Our findings suggest ExpM+NF provides more privacy than non-private SGD, but not as much as DPSGD, although many attacks are impotent against any model. Ancillary benefits of this work include pushing the SOTA of privacy and accuracy on MIMIC-III healthcare data, exhibiting the use of ExpM+NF for Bayesian inference, showing the limitations of empirical privacy auditing in practice, and providing several privacy theorems applicable to distribution learning.

stat.ML

Scaling Behavior of Anisotropy Relaxation in Deformed Polymers

Drawing an analogy to the paradigm of quasi-elastic neutron scattering, we present a general approach for quantitatively investigating the spatiotemporal dependence of structural anisotropy relaxation in deformed polymers by using small-angle neutron scattering. Experiments and non-equilibrium molecular dynamics simulations on polymer melts over a wide range of molecular weights reveal that their conformational relaxation at relatively high momentum transfer $Q$ and short time can be described by a simple scaling law, with the relaxation rate proportional to $Q$. This peculiar scaling behavior, which cannot be derived from the classical Rouse and tube models, is indicative of a surprisingly weak direct influence of entanglement on the microscopic mechanism of single-chain anisotropy relaxation.

cond-mat.soft

Fingerprinting molecular relaxation in deformed polymers

The flow and deformation of macromolecules is ubiquitous in nature and industry, and an understanding of this phenomenon at both macroscopic and microscopic length scales is of fundamental and practical importance. Here we present the formulation of a general mathematical framework, which could be used to extract, from scattering experiments, the molecular relaxation of deformed polymers. By combining and modestly extending several key conceptual ingredients in the literature, we show how the anisotropic single-chain structure factor can be decomposed by spherical harmonics and experimentally reconstructed from its cross sections on the scattering planes. The resulting wavenumber-dependent expansion coefficients constitute a characteristic fingerprint of the macromolecular deformation, permitting detailed examinations of polymer dynamics at the microscopic level. We apply this approach to survey a long-standing problem in polymer physics regarding the molecular relaxation in entangled polymers after a large step deformation. The classical tube theory of Doi and Edwards predicts a fast chain retraction process immediately after the deformation, followed by a slow orientation relaxation through the reptation mechanism. This chain retraction hypothesis, which is the keystone of the tube theory for macromolecular flow and deformation, was critically examined by analyzing the fine features of the two-dimensional anisotropic spectra from small-angle neutron scattering by entangled polystyrenes. It is shown that the unique scattering patterns associated with the chain retraction mechanism were not experimentally observed. This result calls for a fundamental revision of the current theoretical picture for nonlinear rheological behavior of entangled polymeric liquids.

cond-mat.soft