arXiv subjects

Christopher R. Glein

Publications and source records attributed to Christopher R. Glein.

At least 19 recordsLinked to original sources

arXiv2026

Tracing the source of carbon oxides on the large moons of Uranus

The Uranian moons Ariel, Umbriel, Titania, and Oberon are enriched in CO2 mixed with CO, but the origin(s) of these carbon oxides, be they primarily native or radiolytic, remains uncertain. Using data collected by NIRSpec on the James Webb Space Telescope (JWST), we measured the spectral signature of CO2 and other carbon oxides to help disentangle these hypotheses. Through comparison to laboratory data, we find that many of the detected spectral features are consistent with CO2 ice, including 12CO2 scattering peaks (4.15 - 4.26 microns), multi-lobe 13CO2 bands (4.35 - 4.43 microns), and CO2 biphonon and triphonon modes (4.80 - 5.25 microns). Our measurements show that CO2 and CO are concentrated on the trailing hemispheres of the inner moons Ariel and Umbriel, potentially supporting a radiolytic production hypothesis, consistent with prior ground-based results. However, many of the identified spectral features are only observed in thick crystalline ice deposits measured in the laboratory, which may be difficult to form via radiolysis of carbon-bearing material mixed in icy regoliths. Similarly, the data exhibit weak 4.02 microns and 4.40 microns bands, hinting at the presence of carbonate minerals and 13CO2 clathrates, respectively, possibly formed in the interiors of these moons. Furthermore, JWST has revealed that CO2 is widespread at Uranus, present in its system of rings, ring moons, and irregular satellites, consistent with its largest moons accreting CO2 and other carbon oxides from the Uranian subnebula. We conclude that exposed carbon oxides are potentially native, with their surface distributions shaped by charged particle irradiation and seasonal sublimation-condensation cycles.

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arXiv2026

Unusually Hot Interiors Could Reconcile the Missing Methane Problem for Warm-to-Hot Exoplanets with Hydrogen Atmospheres

JWST is revolutionizing the field of exoplanet atmospheres by delivering unprecedented spectroscopic constraints on their chemical compositions. It has provided tight constraints on the abundances of dominant carbon- and oxygen-bearing species on numerous warm-to-hot exoplanets with hydrogen-dominated atmospheres. Under thermochemical equilibrium, many of these exoplanets should have abundant methane (CH4); however, CH4 has, so far, only been spotted in a few cases. Here, we present a simple, geochemistry-inspired framework to explore whether elevated intrinsic temperatures (T$\rm_{int}$) can account for the CH4 depletions. Instead of using computationally expensive, forward grid models, our fast analytical framework focuses on two key chemical equilibria: CO-CH4 and CO-CO2, allowing us to quickly constrain the minimum Tint that is consistent with JWST-observed abundances of H2O, CO, CH4, and CO2. Applying this framework to 12 warm-to-hot exoplanets, we find that several targets require minimum Tint values exceeding those predicted by standard evolution models, while others remain consistent with lower Tint solutions or exhibit degeneracies with other solutions. Our sample enables an initial exploration of population-level trends: while many exoplanets broadly follow an empirical Teq-Tint relation derived from the hot Jupiter mass-radius population, a subset of targets lie well above this trend. The apparent need for hotter interiors suggests that while Ohmic dissipation is probably an important heat source among the general population, additional heating processes, such as tidal heating, may also play important roles for some planets. Our results demonstrate the diagnostic power of atmospheric chemistry as a complementary probe of exoplanet interiors.

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arXiv2025

Rotational Dynamics in Pulsational Pair-Instability Supernovae: Implications for Mass-Loss and Transient Events

Pulsational pair-instability supernovae (PPISNe) are transient events occurring in progenitor stars with helium cores of approximately 32-65 solar masses, where rapid electron-positron pair production induces pressure loss, collapse, and pulsations driving episodic mass loss. The number, strength, and duration of these pulses can lead to shell collisions that produce shock-powered transients, potentially explaining some of the most luminous events, such as superluminous supernovae, and other rare transients. Rapid progenitor rotation lowers the PPISN mass threshold and influences the dynamics, energetics, and chemical composition of PPISN-driven pulses. In this study, we computed 1D evolutionary models of massive, rotating PPISN progenitor stars with zero-age main-sequence masses of 85-140 solar masses and solar metallicity and 10% solar metallicity. Our analysis reveals strong correlations between PPISN ejected mass and total energy as well as between ejected mass and peak ejected shell velocity. Additionally, moderate correlations indicate that higher initial PPISN progenitor mass leads to greater mass ejection and energy release, while negative correlations show that rapid rotation appears to reduce mass ejection and kinetic energy of the shells. Subsequent pulses lead to hydrogen-poor, carbon- and oxygen-enriched ejected shells, indicating the effect of rotationally-induced chemical mixing in PPISN-driven episodic mass loss with implications for their transients. We model the light curve and synthetic spectra that arise from the collision of two H-poor shells for one of our models using the radiation transport code SuperLite. We find that shock-heated H-poor PPISN shell collisions from rapidly rotating progenitors can lead to moderately luminous H-poor transients that share some similarities with observed SLSN-I events.

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arXiv2025

Phosphates Reveal High pH Ocean Water on Enceladus

Enceladus offers our best opportunity for exploring the chemistry of an ocean on another world. Here, we perform geochemical modeling to show how the distribution of phosphate species found in ice grains from Enceladus's plume provides a very straightforward constraint on the pH of the host solution. The ratio of HPO$_4$/PO$_4$ species serves as a pH indicator. We find evidence of moderately alkaline water (pH 10.1-11.6)--significantly more alkaline than current estimates (~8-9) of the pH of Enceladus's ocean. Nevertheless, the pH range from phosphates is consistent with the CO$_2$/H$_2$O ratio measured in the plume if CO$_2$ exsolves from ocean water according to its equilibrium solubility. A simple energy balance can be used to quantify volatile fractionation during gas transport inside Enceladus's tiger stripes; we deduce that ~83% of water vapor is removed as ice during transport between the liquid-vapor interface and where gases exit the subsurface. We also explore how CO$_2$ degassing may lead to an increase in the apparent pH of ocean water. We generate maps of allowed combinations of pH and dissolved inorganic carbon concentration of the source water for a wide range of scenarios. Our preferred interpretation, constrained by the observed heat flux, implies minimal CO$_2$ degassing from ocean water. Hence, the pH recorded by phosphates should closely approximate that of the ocean; our best estimate is pH ~10.6. Such a high pH seems to reflect a major role of silicates enriched in Na, Mg, or Fe(II) interacting extensively with ocean water. Silica nanoparticles would not form or would subsequently dissolve if the pH is too high (>10.5). The outgassing model presented here provides a new path to quantify the dissolved concentrations of volatile species.

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arXiv2025

Deciphering Sub-Neptune Atmospheres: New Insights from Geochemical Models of TOI-270 d

The nature of sub-Neptunes is one of the hottest topics in exoplanetary science. Temperate sub-Neptunes are of special interest because some could be habitable. Here, we consider whether these planets might instead be rocky worlds with thick, hot atmospheres. Can recent JWST observations of TOI-270 d be understood in terms of such a model? We perform thermochemical equilibrium calculations to infer conditions of quenching of C-H-O-N species. Our results indicate apparent CO$_2$-CH$_4$ equilibrium between ~900 and ~1100 K. The CO abundance should be quenched higher in the atmosphere where the equilibrium CO/CO$_2$ ratio is lower, potentially explaining a lack of CO. N$_2$ is predicted to dominate the nitrogen budget. We confirm that the atmosphere of TOI-270 d is strongly enriched in both C and O$_g$$_a$$_s$ relative to protosolar H, whereas N is likely to be less enriched or even depleted. We attempt to reproduce these enrichments by modeling the atmosphere as nebular gas that extracted heavy elements from accreted solids. This type of model can explain the C/H and O$_g$$_a$$_s$/H ratios, but despite supersolar C/N ratios provided by solids, the NH$_3$ abundance will probably be too high unless there is a nitrogen sink in addition to N$_2$. A magma ocean may be implied, and indeed the oxygen fugacity of the deep atmosphere seems sufficiently low to support the sequestration of reduced N in silicate melt. The evaluation presented here demonstrates that exoplanetary geochemistry now approaches a level of sophistication comparable to that achieved within our own solar system.

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arXiv2025

JWST Reveals Spectral Tracers of Recent Surface Modification on Europa

Europa has been modified by a variety of geologic processes, exposing internally-derived materials that are heavily irradiated by charged particles trapped in Jupiter's magnetosphere. Prior spectral analysis of H2O ice on Europa relied on low signal-to-noise data at wavelengths >2.5 microns, limiting assessment of a 3.1 micron Fresnel peak that is diagnostic of exposed crystalline ice. We report new measurements of H2O ice spectral features using high signal-to-noise data collected by the NIRSpec spectrograph (1.48 - 5.35 microns) on the James Webb Space Telescope. These data reveal a narrow 3.1 micron crystalline H2O ice Fresnel peak, which is primarily located at southern latitudes in Tara and Powys Regiones. Our analysis indicates that crystalline ice exposed in these low-latitude regiones is likely sustained by ongoing thermal (re)crystallization outpacing charged particle amorphization of the top 10 microns of Europa's regolith over short timescales (<15 days). We also measured H2O ice features centered near 1.5 microns, 1.65 microns, and 2.0 microns, and a broad 3.6 micron H2O continuum peak, which are all stronger at northern latitudes, in contrast to the 3.1 micron Fresnel peak identified at southern latitudes. These results support the hypothesis that H2O ice in Europa's regolith is vertically stratified, with amorphous ice grains dominating its exposed surface, except in Tara and Powys Regiones. We also find that a previously detected 4.38 micron 13O2 feature is present almost exclusively at southern latitudes in Tara and Powys Regiones, likely derived from an internal source of carbon-bearing material.

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arXiv2024

The role of ammonia in the distribution of volatiles in the primordial hydrosphere of Europa

The presence of a hydrosphere on Europa raises questions about its habitability, and studies of its volatile inventory can provide insight into its formation process. Different scenarios suggest that Europa's volatiles could be derived from cometary ices or devolatilized building blocks. The study of post-accretion processes, in particular the "open ocean" phase that likely occurred before the formation of the icy crust, is crucial to distinguish these origins, as this phase is likely to have influenced the volatile inventory. The abundance of ammonia in Europa's building blocks is also crucial for understanding the composition of its ocean and primordial atmosphere. We aim to investigate ocean-atmosphere equilibrium during the post-accretion period by varying the ammonia fraction in the atmosphere. Our model evaluates the vapor-liquid equilibrium of water and volatiles, as well as the chemical equilibrium within the ocean, to study Europa's early hydrosphere. We explore two initial conditions: one in which Europa's hydrosphere originates from comet-like building blocks, and another in which it forms in equilibrium with a thick, CO$_2$-rich atmosphere. In both scenarios, the initial ratio of accreted CO$_2$ to NH$_3$ determines the magnitude of their partial pressures in Europa's early atmosphere. If this ratio exceeds a certain threshold (set to $10^{-4}$ in this study), the atmosphere will be CO$_2$-rich; otherwise, it will be CO$_2$-depleted by multiple orders of magnitude. Overall, our work provides a initial assessment of the distribution of primordial volatiles in Europa's primitive hydrosphere, and provides a baseline for interpreting data from the upcoming Europa Clipper mission.

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arXiv2024

Prominent mid-infrared excess of the dwarf planet (136472) Makemake discovered by JWST/MIRI indicates ongoing activity

We report on the discovery of a very prominent mid-infrared (18-25 {\mu}m) excess associated with the trans-Neptunian dwarf planet (136472) Makemake. The excess, detected by the MIRI instrument of the James Webb Space Telescope, along with previous measurements from the Spitzer and Herschel space telescopes, indicates the occurrence of temperatures of about 150 K, much higher than what solid surfaces at Makemake's heliocentric distance could reach by solar irradiation. We identify two potential explanations: a continuously visible, currently active region, powered by subsurface upwelling and possibly cryovolcanic activity, covering <1% of Makemake's surface, or an as yet undetected ring containing very small carbonaceous dust grains, which have not been seen before in trans-Neptunian or Centaur rings. Both scenarios point to unprecedented phenomena among trans-Neptunian objects and could greatly impact our understanding of these distant worlds.

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arXiv2024

Volatile-rich Sub-Neptunes as Hydrothermal Worlds: The Case of K2-18 b

Temperate exoplanets between the sizes of Earth and Neptune, known as "sub-Neptunes", have emerged as intriguing targets for astrobiology. It is unknown whether these planets resemble Earth-like terrestrial worlds with a habitable surface, Neptune-like giant planets with deep atmospheres and no habitable surface, or something exotic in between. Recent JWST transmission spectroscopy observations of the canonical sub-Neptune, K2-18 b, revealed ~1% CH4, ~1% CO2, and a non-detection of CO in the atmosphere. While previous studies proposed that the observed atmospheric composition could help constrain the lower atmosphere's conditions and determine the interior structure of sub-Neptunes like K2-18 b, the possible interactions between the atmosphere and a hot, supercritical water ocean at its base remain unexplored. In this work, we investigate whether a global supercritical water ocean, resembling a planetary-scale hydrothermal system, can explain these observations on K2-18 b-like sub-Neptunes through equilibrium aqueous geochemical calculations. We find that the observed atmospheric CH4/CO2 ratio implies a minimum ocean temperature of ~710 K, whereas the corresponding CO/CO2 ratio allows ocean temperatures up to ~1070 K. These results indicate that a global supercritical water ocean on K2-18 b is plausible. While life cannot survive in such an ocean, this work represents the first step towards understanding how a global supercritical water ocean may influence observable atmospheric characteristics on volatile-rich sub-Neptunes. Future observations with better constrained CO and NH$_3$ mixing ratios could further help distinguish between possible interior compositions of K2-18 b.

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arXiv2024

A broad set of solar and cosmochemical data indicates high C-N-O abundances for the solar system

We examine the role of refractory organics as a major C carrier in the outer protosolar nebula and its implications for the compositions of large Kuiper belt objects (KBOs) and CI chondrites. By utilizing Rosetta measurements of refractory organics in comet 67P/Churyumov-Gerasimenko, we show that they would make up a large fraction of the protosolar C inventory in the KBO-forming region based on the current widely adopted solar abundances. However, this would free up too much O to form water ice, producing solid material that is not sufficiently rock-rich to explain the uncompressed density of the Pluto-Charon system and other large KBOs; the former has been argued as the most representative value we have for the bulk composition of large KBOs (Barr & Schawmb 2016, Bierson & Nimmo 2019). This inconsistency further highlights the solar abundances problem - an ongoing challenge in reconciling spectroscopically determined heavy element abundances with helioseismology constraints. By employing a new dataset from solar CNO neutrinos and solar wind measurements of C, N, and O, we show that the uncompressed density of the Pluto-Charon system can be reproduced over a wide range of scenarios. We show that a lack of sulfates in Ryugu and Bennu samples implies a lower amount of water ice initially accreted into CI chondrite parent bodies than previously thought. These data are found to be consistent with the solar C/O ratio implied by the new dataset. Our predictions can be tested by future neutrino, helioseismology, and cosmochemical measurements.

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arXiv2024

The Geochemical Potential for Metabolic Processes on the Sub-Neptune Exoplanet K2-18b

Quantifying disequilibria is important to understand whether an environment could be habitable. It has been proposed that the exoplanet K2-18b has a hydrogen-rich atmosphere and a water ocean, making it a "hycean world". The James Webb Space Telescope recently made measurements of methane, CO$_2$, and possibly dimethyl sulfide (DMS) in the atmosphere of this planet. The initial interpretation of these data is that they may support the occurrence of hycean conditions. Here, I attempt to take a next step in exploring the prospects for habitability. I use constraints on the abundances of atmospheric gases to calculate how much chemical disequilibrium there could be, assuming K2-18b is a hycean world. I find that the presence of oxidized carbon species coexisting with abundant H$_2$ (1-1000 bar) at cool to warm (25-120°C) conditions creates a strong thermodynamic drive for methanogenesis. More than ~75 kJ (mol C)$^{-1}$ of free energy can be released from CO$_2$ hydrogenation. Partially oxidized carbon compounds such as DMS (if present) also have potential to provide metabolic energy, albeit in smaller quantities. Because of the thermodynamic instability of CO$_2$ under hycean conditions, other reductive reactions of CO$_2$ are likely to be favored, including the synthesis of amino acids. Glycine and alanine synthesis can be energy-releasing or at least much less costly on K2-18b than in Earth's ocean, even when NH$_3$ is scarce but not totally absent. These first bioenergetic calculations for a proposed ocean-bearing exoplanet lay new groundwork for assessing exoplanetary habitability.

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arXiv2024

Moderate D/H Ratios in Methane Ice on Eris and Makemake as Evidence of Hydrothermal or Metamorphic Processes in Their Interiors: Geochemical Analysis

Dwarf planets Eris and Makemake have surfaces bearing methane ice of unknown origin. D/H ratios were recently determined from James Webb Space Telescope (JWST) observations of Eris and Makemake, giving us new clues to decipher the origin of methane. Here, we develop geochemical models to test if the origin of methane could be primordial, derived from CO$_2$ or CO ("abiotic"), or sourced by organics ("thermogenic"). We find that primordial methane is inconsistent with the observational data, whereas both abiotic and thermogenic methane can have D/H ratios that overlap the observed ranges. This suggests that Eris and Makemake either never acquired a significant amount of methane during their formation, or their original inventories were removed and then replaced by a source of internally produced methane. Because producing abiotic or thermogenic methane likely requires temperatures above ~150°C, we infer that Eris and Makemake have rocky cores that underwent substantial radiogenic heating. Their cores may still be warm/hot enough to make methane. This heating could have driven hydrothermal circulation at the bottom of an ice-covered ocean to generate abiotic methane, and/or metamorphic reactions involving accreted organic matter could have occurred in response to heating in the deeper interior, generating thermogenic methane. Additional analyses of relevant thermal evolution model results and theoretical predictions of the D/H ratio of methane in the solar nebula support our findings of elevated subsurface temperatures and an apparent lack of primordial methane on Eris and Makemake. It remains an open question whether their D/H ratios may have evolved subsequent to methane outgassing. Recommendations are given for future activities to further test proposed scenarios of abiotic and thermogenic methane production on Eris and Makemake, and to explore these worlds up close.

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arXiv2024

Revealing Callisto's carbon-rich surface and CO2 atmosphere with JWST

We analyzed spectral cubes of Callisto's leading and trailing hemispheres, collected with the NIRSpec Integrated Field Unit (G395H) on the James Webb Space Telescope. These spatially resolved data show strong 4.25-micron absorption bands resulting from solid-state 12CO2, with the strongest spectral features at low latitudes near the center of its trailing hemisphere, consistent with radiolytic production spurred by magnetospheric plasma interacting with native H2O mixed with carbonaceous compounds. We detected CO2 rovibrational emission lines between 4.2 and 4.3 microns over both hemispheres, confirming the global presence of CO2 gas in Callisto's tenuous atmosphere. These results represent the first detection of CO2 gas over Callisto's trailing side. The distribution of CO2 gas is offset from the subsolar region on either hemisphere, suggesting that sputtering, radiolysis, and geologic processes help sustain Callisto's atmosphere. We detected a 4.38-micron absorption band that likely results from solid-state 13CO2. A prominent 4.57-micron absorption band that might result from CN-bearing organics is present and significantly stronger on Callisto's leading hemisphere, unlike 12CO2, suggesting these two spectral features are spatially anti-associated. The distribution of the 4.57-micron band is more consistent with a native origin and/or accumulation of dust from Jupiter's irregular satellites. Other, more subtle absorption features could result from CH-bearing organics, CO, carbonyl sulfide (OCS), and Na-bearing minerals. These results highlight the need for preparatory laboratory work and improved surface-atmosphere interaction models to better understand carbon chemistry on the icy Galilean moons before the arrival of NASA's Europa Clipper and ESA's JUICE spacecraft.

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arXiv2023

N$_2$ accretion, metamorphism of organic nitrogen, or both processes likely contributed to the origin of Pluto's N$_2$

N$_2$ plays a profound role in supporting processes on the surface and in the atmosphere of Pluto, yet the origin of Pluto's N$_2$ remains a mystery. However, this may begin to change as the $^{14}$N/$^{15}$N ratio of N$_2$ was recently estimated based on a non-detection of HC15N in Pluto's atmosphere, while accounting for $^{14}$N/$^{15}$N fractionation between HCN and N$_2$. Here, I show that, if this latter step of translating isotope ratios is adequately understood, then the derived $^{14}$N/$^{15}$N ratio represents the first distinguishing constraint on the origin of N$_2$. One finding of the present study is that isotopic fractionation between atmospheric N$_2$ and N$_2$-rich ices on Pluto does not appear to be significant. I infer a lower limit of ~197 for the $^{14}$N/$^{15}$N ratio of the dominant reservoir of N$_2$ on Pluto; i.e., mostly contained in Sputnik Planitia. From this lower limit, an endmember ammonia source of Pluto's N$_2$ can be ruled out. I perform N isotope mixing calculations that enable quantitative understanding of the relationships between contributions by primordial N$_2$, NH$_3$, and nitrogen originally sourced in organic materials (Norg) to Pluto's observed N$_2$ inventory. These calculations address how uncertainties in the isotopic composition of Norg and the history of atmospheric escape affect the allowed ranges of primordial N$_2$, NH$_3$, and Norg contributions. While present uncertainties are substantial, I find that a contribution by primordial N$_2$, Norg, or both is implied, and the sum of their contributions should be at least ~45%. Hence, Pluto likely formed from building blocks that were cold enough to trap N$_2$, or Pluto has a thermally processed and dynamic interior that supports generation of N$_2$ from Norg and N$_2$ transport to the surface. The lower limit on $^{14}$N/$^{15}$N suggests that NH$_3$ has been a less significant contributor to the origin of N$_2$ on Pluto than on Titan.

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arXiv2023

Early stages of Galilean moon formation in a water-depleted environment

A key feature of the Galilean satellite system is its monotonic decrease in bulk density with distance from Jupiter, indicating an ice mass fraction that is zero in the innermost moon Io, and about half in the outer moons Ganymede and Callisto. Jupiter formation models, and perhaps the Juno spacecraft water measurements, are consistent with the possibility that the Jovian system may have formed, at least partly, from ice-poor material. And yet, models of the formation of the Galilean satellites usually assume abundant water ice in the system. Here, we investigate the possibility that the Jovian circumplanetary disk was populated with ice-depleted chondritic minerals, including phyllosilicates. We show that the dehydration of such particles and the outward diffusion of the released water vapor allow condensation of significant amounts of ice in the formation region of Ganymede and Callisto in the Jovian circumplanetary disk. Our model predicts that Europa, Ganymede and Callisto should have accreted little if any volatiles other than water ice, in contrast to the comet-like composition of Saturn's moon Enceladus. This mechanism allows for the presence of ice-rich moons in water-depleted formation environments around exoplanets as well.

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arXiv2020

Oxidation Processes Diversify the Metabolic Menu on Enceladus

The Cassini mission to the Saturn system discovered a plume of ice grains and water vapor erupting from cracks on the icy surface of the satellite Enceladus. This moon has a global ocean in contact with a rocky core beneath its icy exterior, making it a promising location to search for evidence of extraterrestrial life in the solar system. The previous detection of H$_2$ in the plume indicates that there is free energy available for methanogenesis, the metabolic reaction of H$_2$ with CO$_2$ to form methane and water. Additional metabolic pathways could provide sources of energy in Enceladus' ocean, but require the use of other oxidants that have not been detected in the plume. Here, we perform chemical modeling to determine how the production of radiolytic O$_2$ and H$_2$O$_2$, and abiotic redox chemistry in the ocean and rocky core, contribute to chemical disequilibria that could support metabolic processes in Enceladus' ocean. We consider three possible cases for ocean redox chemistry: Case I in which reductants are not present in appreciable amounts and oxidants accumulate over time, and Cases II and III in which aqueous reductants or seafloor minerals, respectively, convert O$_2$ and H$_2$O$_2$ to SO$_4^{2-}$ and ferric oxyhydroxides. We calculate the upper limits on the concentrations of oxidants and chemical energy available for metabolic reactions in all three cases, neglecting additional abiotic reactions. For all three cases, we find that many aerobic and anaerobic metabolic reactions used by microbes on Earth could meet the minimum free energy threshold required for terrestrial life to convert ADP to ATP, as well as sustain positive cell density values within the Enceladus seafloor and/or ocean. These findings indicate that oxidant production and oxidation chemistry could contribute to supporting possible life and a metabolically diverse microbial community on Enceladus.

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arXiv2020

Formation, Composition, and History of the Pluto System: A Post-New-Horizons Synthesis

The Pluto-Charon system provides a broad variety of constraints on planetary formation, composition, chemistry, and evolution. Pluto was the first body to be discovered in what is now known as the Kuiper belt, its orbit ultimately becoming a major clue that the giant planets underwent substantial orbital migration early in Solar System history. This migration has been linked to an early instability in the orbits of the giant planets and the formation of the Kuiper belt itself, from an ancestral trans-Neptunian planetesimal disk that included Pluto. Pluto-Charon is emblematic of what are now recognized as small or dwarf planets. Far from being a cold, dead, battered icy relic, Pluto displays evidence of a complex geological history, with ongoing processes including tectonism, cryovolcanism, solid-state convection, glacial flow, atmospheric circulation, surface-atmosphere volatile exchange, aeolian processes, and atmospheric photochemistry, microphysics, and haze formation. Despite Pluto's relatively modest scale, the combination of original accretional heat, long-term internal radiogenic heat release, and external solar forcing, when combined with sufficiently volatile (and thus mobile) materials, yields an active world. Pluto may have inherited a large organic mass fraction during accretion, which may responsible, in part, for its surface and atmospheric volatiles. Charon, Pluto's major moon, displays evidence of extensive early tectonism and cryovolcanism. Dwarf planets are thus truly planetary in terms of satellite systems and geological and atmospheric complexity (if not ongoing activity). What they may lack in mass is made up in number, and the majority of the Solar System's dwarf planets remain undiscovered.

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arXiv2019

Decomposition of Amino Acids in Water with Application to In-Situ Measurements of Enceladus, Europa and Other Hydrothermally Active Icy Ocean Worlds

To test the potential of using amino acid abundances as a biosignature at icy ocean worlds, we investigate whether primordial amino acids (accreted or formed by early aqueous processes) could persist until the present time. By examining the decomposition kinetics of amino acids in aqueous solution based on existing laboratory rate data, we find that all fourteen proteinogenic amino acids considered in this study decompose to a very large extent (>99.9%) over relatively short lengths of time in hydrothermally active oceans. Therefore, as a rule of thumb, we suggest that if amino acids are detected at Enceladus, Europa, or other hydrothermally active ocean worlds above a concentration of 1 nM, they should have been formed recently and not be relicts of early processes. In particular, the detection of aspartic acid (Asp) and threonine (Thr) would strongly suggest active production within the ocean, as these amino acids cannot persist beyond 1 billion years even at the freezing point temperature of 273K. Identifying amino acids from the oceans of icy worlds can provide key insight into their history of organic chemistry.

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