arXiv subjects

Chung-Chieh Chang

Publications and source records attributed to Chung-Chieh Chang.

5 recordsLinked to original sources

arXiv2019

Possible Topological Phase Transition in Fe-Vacancy-Ordered $β$-Fe$_{4+δ}$Se$_{5}$ Nanowires

We studied the electrical transport on $β$-Fe$_{4+δ}$Se$_{5}$ single-crystal nanowires, exhibiting $\sqrt{5}\times\sqrt{5}$ Fe-vacancy order and mixed valence of Fe. We observed a first-order metal-insulator transition of the transition temperature at $\sim$28~K at zero magnetic field. The dielectric relaxation reveals that the transition is related to an energy gap expansion of $\sim$12~meV, involving the charge-orbital ordering. At nearly 28~K, colossal positive magnetoresistance emerges, resulting from the magnetic-field dependent shift of the transition temperature. Through the transition, the magnetotransport behavior transits from two-dimension-like to one-dimension-like conduction. The transition temperature demonstrates anisotropy with the $c$-axis as the preferred orientation in magnetic fields, suggesting the spin-orbital coupling. Our findings demonstrate the novel magnetoresistive transition intimating a topological transition in the Fe-vacancy-ordered $β$-Fe$_{4+δ}$Se$_{5}$ nanowires. The results provide valuable information to better understand the orbital nature and the emergence of superconductivity in FeSe-based materials.

cond-mat.supr-con↗

arXiv2015

Disordered Fe vacancies and superconductivity in potassium-intercalated iron selenide (K2-xFe4+ySe5)

The parent compound of an unconventional superconductor must contain unusual correlated electronic and magnetic properties of its own. In the high-Tc potassium intercalated FeSe, there has been significant debate regarding what the exact parent compound is. Our studies unambiguously show that the Fe-vacancy ordered K2Fe4Se5 is the magnetic, Mott insulating parent compound of the superconducting state. Non-superconducting K2Fe4Se5 becomes a superconductor after high temperature annealing, and the overall picture indicates that superconductivity in K2-xFe4+ySe5 originates from the Fe-vacancy order to disorder transition. Thus, the long pending question whether magnetic and superconducting state are competing or cooperating for cuprate superconductors may also apply to the Fe-chalcogenide superconductors. It is believed that the iron selenides and related compounds will provide essential information to understand the origin of superconductivity in the iron-based superconductors, and possibly to the superconducting cuprates.

cond-mat.supr-con↗

arXiv2014

Observation of pseudogap-like feature above Tc in LiFeAs and (Ba0.6K0.4)Fe2As2 by ultrafast optical measurement

We utilize ultrafast optical measurement to study the quasiparticle relaxation in stoichiometric LiFeAs and nearly optimally doped (BaK)Fe2As2 crystals. According to our temperature-dependent studies of LiFeAs, we have observed pseudogap-like feature at onset temperature of ~ 55 K, which is above Tc = 15 K. In addition, the onset temperature of pseudogap ~90K was also observed in Ba0.6K0.4Fe2As2 (Tc = 36 K). Our findings seem implying that the pseudogap feature, which is due to antiferromagnetic fluctuations, is universal for the largely studied 11, 111, 122, and 1111 iron-based superconductors.

cond-mat.supr-con↗

arXiv2013

Fe-vacancy order and superconductivity in PbO-type tetragonal β-Fe1-xSe

Several superconducting transition temperatures in the range of 30-40 K were reported in the recently discovered intercalated FeSe sytem (A1-xFe2-ySe2, A = K, Rb, Cs, Tl). Although the superconducting phases were not yet conclusively decided, more than one magnetic phase with particular orders of iron vacancy and/or potassium vacancy were identified, and some were argued to be the parent phase. Here we show the discovery of the presence and ordering of iron vacancy in nonintercalated FeSe (PbO-type tetragonal β-Fe1-xSe). Three types of iron-vacancy order were found through analytical electron microscopy, and one was identified to be nonsuperconducting and magnetic at low temperature. This discovery suggests that the rich-phases found in A1-xFe2-ySe2 are not exclusive in Fe-Se related superconductors. In addition, the magnetic β-Fe1-xSe phases with particular iron-vacancy orders are more likely to be the parent phase of FeSe superconducting system, instead of the previously assigned β-Fe1+δTe.

cond-mat.supr-con↗

arXiv2012

Multiferroicity in Geometrically Frustrated α-MCr_2O_4 systems (M=Ca, Sr, Ba)

We have successfully synthesized three quasi-2D geometrically frustrated magnetic compounds (α-MCr_2O_4, M=Ca, Sr, Ba) using the spark-plasma-sintering technique. All these members of the α-MCr_2O_4 family consist of the stacking planar triangular lattices of Cr$^{3+}$ spins (${\rm S}=3/2$), separated by non-magnetic alkaline earth ions. Their corresponding magnetic susceptibility, specific heat, dielectric permittivity and ferroelectric polarization are systematically investigated. A long-range magnetic ordering arises below the Néel temperature (around 40K) in each member of the α-MCr_2O_4 family, which changes to the quasi-120\degree proper-screw-type helical spin structure at low temperature. A very small but confirmed spontaneous electric polarization emerges concomitantly with this magnetic ordering. The direction of electric polarization is found within the basal triangular plane. The multiferroicity in α-MCr_2O_4 can not be explained within the frameworks of the magnetic exchange striction or the inverse Dzyaloshinskii-Moriya interaction. The observed results are more compatible with the newly proposed Arima mechanism that is associated the d-p hybridization between the ligand and transition metal ions, modified by the spin-orbit coupling. The evolution of multiferroic properties with the increasing inter-planar spacing (as M changes from Ca to Ba) reveals the importance of interlayer interaction in this new family of frustrated magnetic systems.

cond-mat.mtrl-sci↗