arXiv subjects

Chunguo Duan

Publications and source records attributed to Chunguo Duan.

7 recordsLinked to original sources

arXiv2026

Molecule-dependent Abundance Behavior of Oxygen-bearing Complex Organics in High-Mass Star-Forming Regions: A Uniform 50-source Survey

We present a uniform IRAM-30\,m survey analysis of four oxygen-bearing complex organic molecules (COMs), methanol (CH$_3$OH), acetaldehyde (CH$_3$CHO), methyl formate (CH$_3$OCHO), and dimethyl ether (CH$_3$OCH$_3$), toward 50 high-mass star-forming regions (HMSFRs) associated with 6.7\,GHz methanol masers. Column densities were derived through a homogeneous rotation-diagram approach, with CH$_3$CN used as a proxy excitation-temperature reference when needed. In CH$_3$OH-normalized abundance-ratio space, CH$_3$OCHO/CH$_3$OH and CH$_3$OCH$_3$/CH$_3$OH show the strongest pairwise correlation, whereas the correlations involving CH$_3$CHO are weaker. No clear monotonic trends are found with Galactocentric distance or beam-averaged H$_2$ column density. Comparison with previous observations places the CH$_3$OCHO--CH$_3$OCH$_3$ behavior within the range of earlier abundance-ratio measurements, while CH$_3$CHO shows larger inter-study variation. A representative warm-up chemical model is used only for qualitative comparison with the observed abundance ranges, which are most closely matched during the decline from the post-desorption abundance peaks in the model. These results provide homogeneous beam-averaged abundance-ratio constraints for common O-bearing COMs in high-mass star-forming regions and show that their source-to-source behavior is molecule-dependent rather than fully described by a single common abundance pattern.

astro-ph.GA↗

arXiv2026

First Interstellar Detection of Methyl Carbamate: A New Observational Anchor for Glycine Chemistry

Glycine-the simplest amino acid-has remained undetected in the interstellar medium despite decades of sensitive searches, motivating alternative approaches to constrain its astrochemical origin. A promising strategy is to investigate the broader $\rm C_{2}H_{5}O_{2}N$ isomer family and identify detectable members that can serve as observational anchors for glycine-related chemistry. Herein, we report the first robust interstellar detection of methyl carbamate toward the hot molecular core G358.93-0.03 MM1 using ALMA 1 mm observations. Ten unblended rotational transitions are identified, yielding a column density of (4.21$\pm0.84)\times10^{15} \rm cm^{-2}$ and an excitation temperature of $204\pm10$ K. We also searched for other $\rm C_{2}H_{5}O_{2}N$ isomers with available rotational spectroscopic data, including glycine, but none were detected, allowing us to derive upper limits on their column densities. The resulting abundance pattern deviates significantly from the Minimum Energy Principle predictions, highlighting that the $\rm C_{2}H_{5}O_{2}N$ family is shaped primarily by kinetic chemical process rather than thermodynamic equilibrium. The observed methyl carbamate abundance is consistent with a grain-surface formation scenario involving radical-radical recombination ($\rm CH_{3}$O + $\rm NH_{2}$CO), further supported by its correlated abundances with its proposed precursors, methanol and formamide, across diverse astrophysical environments. This detection establishes methyl carbamate as a new observational anchor for glycine chemistry, providing critical constraints on the formation pathways of amino-acid-related molecules in star-forming regions.

astro-ph.GA↗

arXiv2026

Tentative Detection of the Glycine Isomer Glycolamide in Hot Molecular Core

Understanding whether prebiotic molecules can endure and reform through the energetic stages of star formation is essential for tracing the continuity of interstellar chemistry toward life. Glycolamide, an isomer of glycine, was recently detected in the molecular cloud G+0.693-0.027. However, establishing its presence in warm, high-density environments is crucial to evaluate the chemical continuity of amides. Here we report the tentative detection of glycolamide in a hot molecular core, G358.93-0.03 MM1, using ALMA 1 mm observations. Seven unblended or only mildly blended emission lines were identified, yielding an abundance of (1.7$\pm$0.2)$\times 10^{-10}$ relative to H$_{2}$. The comparable formamide/glycolamide and acetamide/glycolamide abundance ratios in both sources suggest a chemically connected amide network across different environments. These results demonstrate that amides can persist and chemically evolve during massive star formation, tracing the chemical continuity from interstellar to protostellar environments.

astro-ph.GA↗

arXiv2025

The ALMA-QUARKS survey: Extensive detection of acetamide in multiple high-mass star-forming regions

Acetamide (CH$_{3}$CONH$_{2}$), a key interstellar amide and a methyl derivative of formamide (NH$_{2}$CHO), has been sparsely detected, limiting insights into its prebiotic relevance. We present the first systematic survey for acetamide toward 52 hot molecular cores using ALMA Band 6 data. Acetamide has been detected in 10 cores, markedly expanding the inventory of known emitters. The derived column densities of acetamide range from $(2.5\pm0.9)\times10^{14}$ to $(1.5\pm0.6)\times10^{16}$ cm$^{-2}$, compared to formamide's $(1.1\pm0.1)\times10^{15}$ to $(6.9\pm0.4)\times10^{16}$ cm$^{-2}$. The nearly constant abundance ratios (~3-9) and strong abundance correlation between the two amides across sources suggest a chemically linked formation pathway, likely on grain surfaces. The presence of peptide-like molecules in these regions implies that complex organic species can survive star formation processes, offering a potential pathway toward prebiotic chemistry. These findings constrain the dominant grain surface formation routes of acetamide, confirm its broader prevalence in highmass star-forming regions, and underscore the importance of targeted amide surveys in tracing the chemical evolution toward prebiotic complexity.

astro-ph.GA↗

arXiv2025

An ALMA Study of Molecular Complexity in the Hot Core G336.99-00.03 MM1

High-mass star formation involves complex processes, with the hot core phase playing a crucial role in chemical enrichment and the formation of complex organic molecules. However, molecular inventories in hot cores remain limited. Using data from the ALMA Three-millimeter Observations of Massive Star-forming regions survey (ATOMS), the molecular composition and evolutionary stages of two distinct millimeter continuum sources in the high-mass star forming region G336.99-00.03 have been characterized. MM1, with 19 distinct molecular species detected, along with 8 isotopologues and several vibrationally/torsionally excited states, has been identified as a hot core. MM2 with only 5 species identified, was defined as a HII region. Isotopic ratios in MM1 were derived, with $^{12}$C/$^{13}$C ranging from 16.0 to 29.2, $^{16}$O/$^{18}$O at 47.7, and $^{32}$S/$^{34}$S at 19.2. Molecular abundances in MM1 show strong agreement with other sources and three-phase warm-up chemical models within an order of magnitude for most species. Formation pathways of key molecules were explored, revealing chemical links and reaction networks. This study provides a detailed molecular inventory of two millimeter continuum sources, shedding light on the chemical diversity and evolutionary processes in high-mass star-forming regions. The derived molecular parameters and isotopic ratios offer benchmarks for astrochemical models, paving the way for further investigation into the formation and evolution of complex organic molecules during the hot core phase.

astro-ph.GA↗

arXiv2024

3 mm Spectroscopic Observations of Massive Star-Forming Regions with IRAM 30-m

Broadband spectroscopic observations with high sensitivity provide an unbiased way to detect emissions of molecules in space. We present deep observations from ~ 105.8 GHz to 113.6 GHz toward 50 Galactic massive star-forming regions using IRAM 30-m millimeter telescope, with noise levels ranging from 6 to 29 at frequency channel spacing of 195 kHz, which corresponds to ~ 0.54 km/s at 110 GHz. Totally, 27 molecular species have been identified, of which 16 are complex organic molecules. The related parameters, such as peak temperature, integrated intensity, and line width of the identified molecular lines were obtained. The line widths of the chemically related molecules show strong positive correlations, suggesting they likely originate from similar gases within star-forming regions. This work highlights the fundamental properties of the detected molecular lines and offers a valuable dataset for further studies on the astrochemical evolution of molecules in massive star-forming cores.

astro-ph.SR↗

arXiv2024

The Milky Way atlas for linear filaments II. clump rotation versus filament orientation

Dense clumps distributed along filaments are the immediate medium for star formation. Kinematic properties of the clumps, such as velocity gradient and angular momentum, combined with filament orientation, provide important clues to the formation mechanism of filament-clump configurations and the role of filaments in star formation. By cross-matching the Milky Way atlas for linear filaments and the Structure, Excitation and Dynamics of the Inner Galactic Interstellar Medium (SEDIGISM) 13CO (2-1) data, we aim to derive the velocity gradient and its direction, the specific angular momentum (J/M), and the ratio (\beta) between the rotational energy and gravitational energy of clumps, as well as to investigate the alignment between clump rotation and filament orientation. We found a monotonic increase in J/M as a function of clump size (R), following a power-law relation J/M~\propto~R^{1.5\pm0.2}. The ratio \beta ranges from 1.1~\times~10^{-5} to 0.1, with a median value 1.0~\times~10^{-3}, suggesting that clump rotation provides insignificant support against gravitational collapse. The distribution of the angle between clump rotation and natal filament orientation is random, indicating that the clumps' rotational axes have no discernible correlation with the orientation of their hosting filaments. Counting only the most massive clump in each filament also finds no alignment between clump rotation and filament orientation.

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