arXiv subjects

Chunhua Qi

Publications and source records attributed to Chunhua Qi.

At least 91 records · Page 5Linked to original sources

arXiv2015

Analytical Formulas of Molecular Ion Abundances and N2H+ Ring in Protoplanetary Disks

We investigate the chemistry of ion molecules in protoplanetary disks, motivated by the detection of N$_2$H$^+$ ring around TW Hya. While the ring inner radius coincides with the CO snow line, it is not apparent why N$_2$H$^+$ is abundant outside the CO snow line in spite of the similar sublimation temperatures of CO and N$_2$. Using the full gas-grain network model, we reproduced the N$_2$H$^+$ ring in a disk model with millimeter grains. The chemical conversion of CO and N$_2$ to less volatile species (sink effect hereinafter) is found to affect the N$_2$H$^+$ distribution. Since the efficiency of the sink depends on various parameters such as activation barriers of grain surface reactions, which are not well constrained, we also constructed the no-sink model; the total (gas and ice) CO and N$_2$ abundances are set constant, and their gaseous abundances are given by the balance between adsorption and desorption. Abundances of molecular ions in the no-sink model are calculated by analytical formulas, which are derived by analyzing the full-network model. The N$_2$H$^+$ ring is reproduced by the no-sink model, as well. The 2D (R-Z) distribution of N$_2$H$^+$, however, is different among the full-network model and no-sink model. The column density of N$_2$H$^+$ in the no-sink model depends sensitively on the desorption rate of CO and N$_2$, and the flux of cosmic ray. We also found that N$_2$H$^+$ abundance can peak at the temperature slightly below the CO sublimation, even if the desorption energies of CO and N$_2$ are the same.

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arXiv2015

The cometary composition of a protoplanetary disk as revealed by complex cyanides

Observations of comets and asteroids show that the Solar Nebula that spawned our planetary system was rich in water and organic molecules. Bombardment brought these organics to the young Earth's surface, seeding its early chemistry. Unlike asteroids, comets preserve a nearly pristine record of the Solar Nebula composition. The presence of cyanides in comets, including 0.01% of methyl cyanide (CH3CN) with respect to water, is of special interest because of the importance of C-N bonds for abiotic amino acid synthesis. Comet-like compositions of simple and complex volatiles are found in protostars, and can be readily explained by a combination of gas-phase chemistry to form e.g. HCN and an active ice-phase chemistry on grain surfaces that advances complexity[3]. Simple volatiles, including water and HCN, have been detected previously in Solar Nebula analogues - protoplanetary disks around young stars - indicating that they survive disk formation or are reformed in situ. It has been hitherto unclear whether the same holds for more complex organic molecules outside of the Solar Nebula, since recent observations show a dramatic change in the chemistry at the boundary between nascent envelopes and young disks due to accretion shocks[8]. Here we report the detection of CH3CN (and HCN and HC3N) in the protoplanetary disk around the young star MWC 480. We find abundance ratios of these N-bearing organics in the gas-phase similar to comets, which suggests an even higher relative abundance of complex cyanides in the disk ice. This implies that complex organics accompany simpler volatiles in protoplanetary disks, and that the rich organic chemistry of the Solar Nebula was not unique.

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arXiv2015

A Ring of C2H in the Molecular Disk Orbiting TW Hya

We have used the Submillimeter Array to image, at ~1.5" resolution, C2H (3-2) emission from the circumstellar disk orbiting the nearby (D = 54 pc), ~8 Myr-old, ~0.8 Msun classical T Tauri star TW Hya. The SMA imaging reveals that the C2H emission exhibits a ring-like morphology. Based on a model in which the C2H column density follows a truncated radial power-law distribution, we find that the inner edge of the ring lies at ~45 AU, and that the ring extends to at least ~120 AU. Comparison with previous (single-dish) observations of C2H (4-3) emission indicates that the C2H molecules are subthermally excited and, hence, that the emission arises from the relatively warm, tenuous upper atmosphere of the disk. We propose that the C2H emission most likely traces particularly efficient photo-destruction of small grains and/or photodesorption and photodissociation of hydrocarbons derived from grain ice mantles in the surface layers of the outer disk. The presence of a C2H ring in the TW Hya disk hence likely serves as a marker of dust grain processing and radial and vertical grain size segregation within the disk.

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arXiv2015

Evidence for DCO+ as a probe of ionization in the warm disk surface

In this Letter we model the chemistry of DCO$^{+}$ in protoplanetary disks. We find that the overall distribution of the DCO$^{+}$ abundance is qualitatively similar to that of CO but is dominated by thin layer located at the inner disk surface. To understand its distribution, we investigate the different key gas-phase deuteration pathways that can lead to the formation of DCO$^{+}$. Our analysis shows that the recent update in the exothermicity of the reaction involving CH$_2$D$^{+}$ as a parent molecule of DCO$^{+}$ favors deuterium fractionation in warmer conditions. As a result the formation of DCO$^{+}$ is enhanced in the inner warm surface layers of the disk where X-ray ionization occurs. Our analysis points out that DCO$^{+}$ is not a reliable tracer of the CO snow line as previously suggested. We thus predict that DCO$^{+}$ is a tracer of active deuterium and in particular X-ray ionization of the inner disk.

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arXiv2014

Constraining the X-ray and Cosmic Ray Ionization Chemistry of the TW Hya Protoplanetary Disk: Evidence for a Sub-interstellar Cosmic Ray Rate

We present an observational and theoretical study of the primary ionizing agents (cosmic rays and X-rays) in the TW Hya protoplanetary disk. We use a set of resolved and unresolved observations of molecular ions and other molecular species, encompassing eleven lines total, in concert with a grid of disk chemistry models. The molecular ion constraints comprise new data from the Submillimeter Array on HCO$^+$, acquired at unprecedented spatial resolution, and data from the literature, including ALMA observations of N$_2$H$^+$. We vary the model incident CR flux and stellar X-ray spectra and find that TW Hya's HCO$^+$ and N$_2$H$^+$ emission are best fit by a moderately hard X-ray spectra, as would be expected during the "flaring" state of the star, and a low CR ionization rate, $ζ_{\rm CR}\lesssim10^{-19}$ s$^{-1}$. This low CR rate is the first indication of the presence of CR exclusion by winds and/or magnetic fields in an actively accreting T Tauri disk system. With this new constraint, our best fit ionization structure predicts a low turbulence "dead-zone" extending from the inner edge of the disk out to $50-65$ AU. This region coincides with an observed concentration of millimeter grains, and we propose that the inner region of TW Hya is a dust (and possibly planet) growth factory as predicted by previous theoretical work.

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arXiv2014

Peculiar Near-Nucleus Outgassing of Comet 17P/Holmes During Its 2007 Outburst

We present high angular resolution Submillimeter Array observations ofthe outbursting Jupiter family comet 17P/Holmes on 2007 October 26-29, achieving a spatial resolution of 2.5", or ~3000 km at the comet distance. The observations resulted in detections of the rotational lines CO 3-2, HCN 4-3, H$^{13}$CN 4-3, CS 7-6, H$_2$CO 3$_{1,2}$-2$_{1,1}$, H$_2$S 2$_{2,0}$-2$_{1,1}$, and multiple CH$_3$OH lines, along with the associated dust continuum at 221 and 349 GHz. The continuum has a spectral index of 2.7$\pm$0.3, slightly steeper than blackbody emission from large dust particles. From the imaging data, we identify two components in the molecular emission. One component is characterized by a relatively broad line width (~1 km s$^{-1}$ FWHM) exhibiting a symmetric outgassing pattern with respect to the nucleus position. The second component has a narrower line width (<0.5 km s$^{-1}$ FWHM) with the line center red-shifted by 0.1-0.2 km s$^{-1}$ (cometocentric frame), and shows a velocity shift across the nucleus position with the position angle gradually changing from 66 to 30 degrees within the four days of observations. We determine distinctly different CO/HCN ratios for each of the components. For the broad-line component we find CO/HCN <7, while in the narrow-line component, CO/HCN = 40$\pm$5. We hypothesize that the narrow-line component originates from the ice grain halo found in near-nucleus photometry, believed to be created by sublimating recently released ice grains around the nucleus during the outburst. In this interpretation, the high CO/HCN ratio of this component reflects the more pristine volatile composition of nucleus material released in the outburst.

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arXiv2014

Physical and chemical structure of planet-forming disks probed by millimeter observations and modeling

Protoplanetary disks composed of dust and gas are ubiquitous around young stars and are commonly recognized as nurseries of planetary systems. Their lifetime, appearance, and structure are determined by an interplay between stellar radiation, gravity, thermal pressure, magnetic field, gas viscosity, turbulence, and rotation. Molecules and dust serve as major heating and cooling agents in disks. Dust grains dominate the disk opacities, reprocess most of the stellar radiation, and shield molecules from ionizing UV/X-ray photons. Disks also dynamically evolve by building up planetary systems which drastically change their gas and dust density structures. Over the past decade significant progress has been achieved in our understanding of disk chemical composition thanks to the upgrade or advent of new millimeter/Infrared facilities (SMA, PdBI, CARMA, Herschel, e-VLA, ALMA). Some major breakthroughs in our comprehension of the disk physics and chemistry have been done since PPV. This review will present and discuss the impact of such improvements on our understanding of the disk physical structure and chemical composition.

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arXiv2013

A Significantly Low CO Abundance Toward the TW Hya Protoplanetary Disk: A Path to Active Carbon Chemistry?

In this Letter we report the CO abundance relative to H2 derived toward the circumstellar disk of the T-Tauri star TW Hya from the HD (1-0) and C18O (2-1) emission lines. The HD (1-0) line was observed by the Herschel Space Observatory Photodetector Array Camera and Spectrometer whereas C18O (2-1) observations were carried out with the Submillimeter Array at a spatial resolution of 2.8" x 1.9" (corresponding to 142 x 97 AU). In the disk's warm molecular layer (T>20 K) we measure a disk-averaged gas-phase CO abundance relative to H2 of $χ{\rm(CO)}=(0.1-3)x10^{-5}$, substantially lower than the canonical value of $χ{\rm(CO)}=10^{-4}$. We infer that the best explanation of this low $χ$(CO) is the chemical destruction of CO followed by rapid formation of carbon chains, or perhaps CO2, that can subsequently freeze-out, resulting in the bulk mass of carbon locked up in ice grain mantles and oxygen in water. As a consequence of this likely time-dependent carbon sink mechanism, CO may be an unreliable tracer of H2 gas mass.

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arXiv2013

Imaging of the CO Snow Line in a Solar Nebula Analog

Planets form in the disks around young stars. Their formation efficiency and composition are intimately linked to the protoplanetary disk locations of "snow lines" of abundant volatiles. We present chemical imaging of the CO snow line in the disk around TW Hya, an analog of the solar nebula, using high spatial and spectral resolution Atacama Large Millimeter/Submillimeter Array (ALMA) observations of N2H+, a reactive ion present in large abundance only where CO is frozen out. The N2H+ emission is distributed in a large ring, with an inner radius that matches CO snow line model predictions. The extracted CO snow line radius of ~ 30 AU helps to assess models of the formation dynamics of the Solar System, when combined with measurements of the bulk composition of planets and comets.

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arXiv2013

A Spatially Resolved Vertical Temperature Gradient in the HD 163296 Disk

We analyze sensitive, sub-arcsecond resolution ALMA Science Verification observations of CO emission lines in the protoplanetary disk hosted by the young, isolated Ae star HD 163296. The observed spatial morphology of the 12CO J=3-2 emission line is asymmetric across the major axis of the disk; the 12CO J=2-1 line features a much less pronounced, but similar, asymmetry. The J=2-1 emission from 12CO and its main isotopologues have no resolved spatial asymmetry. We associate this behavior as the direct signature of a vertical temperature gradient and layered molecular structure in the disk. This is demonstrated using both toy models and more sophisticated calculations assuming non-local thermodynamic equilibrium (non LTE) conditions. A model disk structure is developed to reproduce both the distinctive spatial morphology of the 12CO J=3-2 line as well as the J=2-1 emission from the CO isotopologues assuming relative abundances consistent with the interstellar medium. This model disk structure has tau=1 emitting surfaces for the 12CO emission lines that make an angle of about 15 degrees with respect to the disk midplane. Furthermore, we show that the spatial and spectral sensitivity of these data can distinguish between models that have sub-Keplerian gas velocities due to the vertical extent of the disk and its associated radial pressure gradient (a fractional difference in the bulk gas velocity field of approximately greater than 5%).

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arXiv2013

An Old Disk That Can Still Form a Planetary System

From the masses of planets orbiting our Sun, and relative elemental abundances, it is estimated that at birth our Solar System required a minimum disk mass of ~0.01 solar masses within ~100 AU of the star. The main constituent, gaseous molecular hydrogen, does not emit from the disk mass reservoir, so the most common measure of the disk mass is dust thermal emission and lines of gaseous carbon monoxide. Carbon monoxide emission generally probes the disk surface, while the conversion from dust emission to gas mass requires knowledge of the grain properties and gas-to-dust mass ratio, which likely differ from their interstellar values. Thus, mass estimates vary by orders of magnitude, as exemplified by the relatively old (3--10 Myr) star TW Hya, with estimates ranging from 0.0005 to 0.06 solar masses. Here we report the detection the fundamental rotational transition of hydrogen deuteride, HD, toward TW Hya. HD is a good tracer of disk gas because it follows the distribution of molecular hydrogen and its emission is sensitive to the total mass. The HD detection, combined with existing observations and detailed models, implies a disk mass >0.05 solar masses, enough to form a planetary system like our own.

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arXiv2013

First detection of c-C3H2 in a circumstellar disk

We report the first detection of c-C3H2 in a circumstellar disk. The c-C3H2 J=6-5 line (217.882 GHz) is detected and imaged through Atacama Large Millimeter Array (ALMA) Science Verification observations toward the disk around the Herbig Ae star HD 163296 at 0.8" resolution. The emission is consistent with that arising from a Keplerian rotating disk. Two additional c-C3H2 transitions are also tentatively detected, bolstering the identification of this species, but with insufficient signal-to-noise ratio to constrain the spatial distribution. Using a previously developed model for the physical structure of this disk, we fit a radial power-law distribution model to the c-C3H2 6-5 emission and find that c-C3H2 is present in a ring structure from an inner radius of about 30 AU to an outer radius of about 165 AU. The column density is estimated to be 1e12-1e13 cm-2. The clear detection and intriguing ring structure suggest that c-C3H2 has the potential to become a useful probe of radiation penetration in disks.

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arXiv2013

H2CO and N2H+ in Protoplanetary Disks: Evidence for a CO-ice Regulated Chemistry

We present Submillimeter Array observations of H2CO and N2H+ emission in the disks around the T Tauri star TW Hya and the Herbig Ae star HD 163296 at 2"-6" resolution and discuss the distribution of these species with respect to CO freeze-out. The H2CO and N2H+ emission toward HD 163296 does not peak at the continuum emission center that marks the stellar position but is instead significantly offset. Using a previously developed model for the physical structure of this disk, we show that the H2CO observations are reproduced if H2CO is present predominantly in the cold outer disk regions. A model where H2CO is present only beyond the CO snow line (estimated at a radius of 160 AU) matches the observations well. We also show that the average H2CO excitation temperature, calculated from two transitions of H2CO observed in these two disks and a larger sample of disks around T Tauri stars in the DISCS (the Disk Imaging Survey of Chemistry with SMA) program, is consistent with the CO freeze-out temperature of 20 K. In addition, we show that N2H+ and H2CO line fluxes in disks are strongly correlated, indicative of co-formation of these species across the sample. Taken together, these results imply that H2CO and N2H+ are generally present in disks only at low temperatures where CO depletes onto grains, consistent with fast destruction of N2H+ by gas-phase CO, and in situ formation of H2CO through hydrogenation of CO ice. In this scenario H2CO, CH3OH and N2H+ emission in disks should appear as rings with the inner edge at the CO midplane snow line. This prediction can be tested directly using observations from ALMA with higher resolution and better sensitivity.

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arXiv2012

Kinematics of the CO Gas in the Inner Regions of the TW Hya Disk

We present a detailed analysis of the spatially and spectrally resolved 12CO J=2-1 and J=3-2 emission lines from the TW Hya circumstellar disk, based on science verification data from the Atacama Large Millimeter/Submillimeter Array (ALMA). These lines exhibit substantial emission in their high-velocity wings (with projected velocities out to 2.1 km/s, corresponding to intrinsic orbital velocities >20 km/s) that trace molecular gas as close as 2 AU from the central star. However, we are not able to reproduce the intensity of these wings and the general spatio-kinematic pattern of the lines with simple models for the disk structure and kinematics. Using three-dimensional non-local thermodynamic equilibrium molecular excitation and radiative transfer calculations, we construct some alternative models that successfully account for these features by modifying either (1) the temperature structure of the inner disk (inside the dust-depleted disk cavity; r < 4 AU); (2) the intrinsic (Keplerian) disk velocity field; or (3) the distribution of disk inclination angles (a warp). The latter approach is particularly compelling because a representative warped disk model qualitatively reproduces the observed azimuthal modulation of optical light scattered off the disk surface. In any model scenario, the ALMA data clearly require a substantial molecular gas reservoir located inside the region where dust optical depths are known to be substantially diminished in the TW Hya disk, in agreement with previous studies based on infrared spectroscopy. The results from these updated model prescriptions are discussed in terms of their potential physical origins, which might include dynamical perturbations from a low-mass companion with an orbital separation of a few AU.

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arXiv2012

Evidence for Multiple Pathways to Deuterium Enhancements in Protoplanetary Disks

The distributions of deuterated molecules in protoplanetary disks are expected to depend on the molecular formation pathways. We use observations of spatially resolved DCN emission from the disk around TW Hya, acquired during ALMA Science verification with a ~3" synthesized beam, together with comparable DCO+ observations from the Submillimeter Array, to investigate differences in the radial distributions of these species and hence differences in their formation chemistry. In contrast to DCO+, which shows an increasing column density with radius, DCN is better fit by a model that is centrally peaked. We infer that DCN forms at a smaller radii and thus at higher temperatures than DCO+. This is consistent with chemical network model predictions of DCO+ formation from H2D+ at T<30 K and DCN formation from additional pathways involving CH2D+ at higher temperatures. We estimate a DCN/HCN abundance ratio of ~0.017, similar to the DCO+/HCO+ abundance ratio. Deuterium fractionation appears to be efficient at a range of temperatures in this protoplanetary disk. These results suggest caution in interpreting the range of deuterium fractions observed in Solar System bodies, as multiple formation pathways should be taken into account.

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arXiv2011

The TW Hya Disk at 870 microns: Comparison of CO and Dust Radial Structures

We present high resolution (0.3" = 16 AU), high signal-to-noise ratio Submillimeter Array observations of the 870 microns (345 GHz) continuum and CO J=3--2 line emission from the protoplanetary disk around TW Hya. Using continuum and line radiative transfer calculations, those data and the multiwavelength spectral energy distribution are analyzed together in the context of simple two-dimensional parametric disk structure models. Under the assumptions of a radially invariant dust population and (vertically integrated) gas-to-dust mass ratio, we are unable to simultaneously reproduce the CO and dust observations with model structures that employ either a single, distinct outer boundary or a smooth (exponential) taper at large radii. Instead, we find that the distribution of millimeter-sized dust grains in the TW Hya disk has a relatively sharp edge near 60 AU, contrary to the CO emission (and optical/infrared scattered light) that extends to a much larger radius of at least 215 AU. We discuss some possible explanations for the observed radial distribution of millimeter-sized dust grains and the apparent CO-dust size discrepancy, and suggest that they may be hallmarks of substructure in the dust disk or natural signatures of the growth and radial drift of solids that might be expected for disks around older pre-main sequence stars like TW Hya.

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arXiv2011

The Ionization Fraction in the DM Tau Protoplanetary Disk

We present millimeter-wave observations of several molecular ions in the disk around the pre-main-sequence star DM Tau and use these to investigate the ionization fraction in different regions of the disk. New Submillimeter Array (SMA) observations of H2D+ J=1_10 - 1_11, N2H+ J=4-3 and CO J=3-2 are presented. H2D+ and N2H+ are not detected and using the CO 3-2 disk size the observations result in an upper limit of <0.47 K km s-1 for both lines, a factor of 2.5 below previous single-dish H2D+ observations. Assuming LTE, a disk midplane temperature of 10-20 K and estimates of the H2D+ o/p ratio, the observed limit corresponds to NH2D+ < 4 - 21 \times 1012 cm-2. We adopt a parametric model for the disk structure from the literature and use new IRAM 30 meter telescope observations of the H13CO+ J=3-2 line and previously published SMA observations of the N2H+ J=3-2, HCO+ J=3-2 and DCO+ J=3-2 lines to constrain the ionization fraction, xi, in three temperature regions in the disk where theoretical considerations suggest different ions should dominate: (1) a warm, upper layer with T>20 K where CO is in the gas-phase and HCO+ is most abundant, where we estimate xi \simeq 4 \times 10-10, (2) a cooler molecular layer with T = 16-20 K where N2H+ and DCO+ abundances are predicted to peak, with xi \simeq 3\times10-11, and (3) the cold, dense midplane with T<16 K where H3+ and its deuterated isotopologues are the main carriers of positive charge, with xi < 3\times10-10. While there are considerable uncertainties, these estimates are consistent with a decreasing ionization fraction into the deeper, colder, and denser disk layers. Stronger constraints on the ionization fraction in the disk midplane will require not only substantially more sensitive observations of the H2D+ 1_10 - 1_11 line, but also robust determinations of the o/p ratio, observations of D2H+ and stronger constraints on where N2 is present in the gas phase.

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arXiv2011

Millimeter Observations of the Transition Disk around HD135344B (SAO 206462)

We present \sim1" resolution 1.3 millimeter dust continuum and spectral line (12CO and 13CO J=2-1) observations of the transitional disk system HD 135344B obtained with the Submillimeter Array. The disk shows a Keplerian rotation pattern with an inclination of \sim11°, based on the spatially and spectrally resolved 12CO and 13CO emission. The data show clear evidence for both dust and gas surface density reductions in the inner region of the disk (radius \lesssim 50 AU) from the continuum and 13CO J=2-1 data, respectively. The presence of this inner cavity in both the dust and gas is more consistent with clearing by giant planet formation than by photoevaporation or by grain growth. There is also an indication of global CO gas depletion in the disk, as the mass estimated from 13CO emission (\sim3.8 \times 10^(-4) M\odot) is about two orders of magnitude lower than that derived from the 1.3 mm continuum (\sim2.8 \times 10^(-2) M\odot).

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