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Claudia Felser

Publications and source records attributed to Claudia Felser.

At least 271 records · Page 15Linked to original sources

Characterization of topological band structures away from the Fermi level by anomalous Nernst measurements

Resolving the structure of energy bands in transport experiments is a major challenge in condensed matter physics and material science. Sometimes, however, traditional electrical conductance or resistance measurements only provide very small signals, and thus limit the ability to obtain direct band structure information. In this case, it has been proven beneficial to employ thermoelectric measurements which are sensitive to the first derivative of the density of states with respect to energy, rather than to its value itself. Due to the large interest in topological effects these days, it is important to identify a similar concept for detecting the Berry curvature in a band structure. Nowadays, the common way to access the Berry curvature directly via measurements is the anomalous Hall effect, but the corresponding signal can be too small to be detected when the topological features of the band structure lie too far off the Fermi level. In this work we propose to investigate topological band structure features utilizing the anomalous Nernst effect which is tied to the derivative of the anomalous Hall effect with respect to energy. Thereby, also signatures become resolvable, which are elusive in anomalous Hall measurements. We demonstrate the underlying mechanisms for a minimal effective four-band model and exemplary for the real Heusler compounds Co$_2$Fe$X$ ($X$=Ge,Sn), which host topological nodal lines about 100 meV above the Fermi level. This work demonstrates that anomalous Nernst measurements can be an effective tool for the characterization of topological band structures, both at room temperature and in the quantum transport regime at cryogenic temperatures.

cond-mat.mtrl-sci↗

Large anomalous Nernst effect in thin films of the Weyl semimetal Co2MnGa

The magneto-thermoelectric properties of Heusler compound thin films are very diverse. Here, we discuss the anomalous Nernst response of Co$_2$MnGa thin films. We systematically study the anomalous Nernst coefficient as a function of temperature, and we show that unlike the anomalous Hall effect, the anomalous Nernst effect in Co$_2$MnGa strongly varies with temperature. We exploit the on-chip thermometry technique to quantify the thermal gradient, which enables us to directly evaluate the anomalous Nernst coefficient. We compare these results to a reference CoFeB thin film. We show that the 50-nm-thick Co$_2$MnGa films exhibit a large anomalous Nernst effect of -2$μ$V/K at 300 K, whereas the 10-nm-thick Co$_2$MnGa film exhibits a significantly smaller anomalous Nernst coefficient despite having similar volume magnetizations. These findings suggest that the microscopic origin of the anomalous Nernst effect in Co$_2$MnGa is complex and may contain contributions from skew-scattering, side-jump or intrinsic Berry phase. In any case, the large anomalous Nernst coefficent of Co$_2$MnGa thin films at room temperature makes this material system a very promising candidate for efficient spin-caloritronic devices.

cond-mat.mes-hall↗

Anomalous Nernst effect beyond the magnetization scaling relation in the ferromagnetic Heusler compound Co$_2$MnGa

Applying a temperature gradient in a magnetic material generates a voltage that is perpendicular to both the heat flow and the magnetization. This is the anomalous Nernst effect (ANE) which was thought to be proportional to the value of the magnetization for a long time. However, more generally, the ANE has been predicted to originate from a net Berry curvature of all bands near the Fermi level. Subsequently, a large anomalous Nernst thermopower has recently been observed in topological materials with no net magnetization but large net Berry curvature around E$_F$. These experiments clearly fall outside the scope of the conventional magnetization-model of the ANE, but a significant question remains: Can the value of the ANE in topological ferromagnets exceed the highest values observed in conventional ferromagnets? Here, we report a remarkably high anomalous Nernst thermopower value of ~6.0 μV/K at 1 T in the ferromagnetic topological Heusler compound Co$_2$MnGa at room temperature, which is around 7-times larger than any anomalous Nernst thermopower value ever reported for a conventional ferromagnet. Combined electrical, thermoelectric and first-principles calculations reveal that this high value of the ANE arises from a large net Berry curvature near the Fermi level associated with nodal lines and Weyl points.

cond-mat.mtrl-sci↗

Minimizing hysteresis in martensite phase transforming magnetocaloric Heusler alloys

The large magnetocaloric effect in Heusler alloys showing martensite phase transformation puts them forward as efficient materials for magnetic refrigeration. However, irreversibility of the magnetocaloric cooling cycle is a major challenge for real applications. This irreversibility is directly linked to the thermal hysteresis at the first-order martensite phase transition. Therefore, minimizing the hysteresis is essential in order to achieve reversibility. Here we show a large reduction in the thermal hysteresis at the martensite transition in the Ni$_{2}$Mn$_{1.4}$In$_{0.6}$ and Ni$_{1.8}$Co$_{0.2}$Mn$_{1.4}$In$_{0.6}$ Heusler alloys upon the application of hydrostatic pressure. Our pressure dependent X-ray diffraction study on Ni$_{2}$Mn$_{1.4}$In$_{0.6}$ reveals that with increasing pressure the lattice parameters of the two crystallographic phases (austenite and martensite) change in such a way that they increasingly satisfy the geometric compatibility (co-factor) condition. These results provide an opportunity to overcome the hysteresis problem and hence the irreversible behavior in Heusler materials using pressure as an external parameter.

cond-mat.mtrl-sci↗

Coexisting surface states in the weak and crystalline topological insulator Bi_2TeI

The established diversity of electronic topology classes lends the opportunity to pair them into dual topological complexes. Bulk-surface correspondence then ensures the coexistence of a combination of boundary states that cannot be realized but only at the various surfaces of such a dual topological material. We show that the layered compound Bi_2TeI realizes a dual topological insulator. It exhibits band inversions at two time reversal symmetry points of the bulk band which classify it as a weak topological insulator with metallic states on its (010) 'side' surfaces. Additional mirror symmetry of the crystal structure concurrently classifies it as a topological crystalline insulator. Bi2TeI is therefore predicted to host a pair of Dirac cones protected by time reversal symmetry on its 'side' surfaces and three pairs of Dirac cones protected by mirror symmetry on its 'top' and 'bottom' (001) surfaces. We spectroscopically map the top cleaved surface of Bi_2TeI, and crystallographic step edges therein. We show the existence of both two dimensional surface states which are susceptible to mirror symmetry breaking, as well as one dimensional channels that reside along the step edges. Their mutual coexistence on the step edge where both facets join is facilitated by momentum and energy segregation. Our observations of a dual topological insulator make way to additional pairing of other dual topology classes with distinct surface manifestations coexisting at their boundaries.

cond-mat.mes-hall↗

Helical magnetic structure and the anomalous and topological Hall effects in epitaxial B20 Fe$_{1-y}$Co$_y$Ge films

Epitaxial films of the B20-structure alloy Fe$_{1-y}$Co$_y$Ge were grown by molecular beam epitaxy on Si (111) substrates. The magnetization varied smoothly from the bulk-like values of one Bohr magneton per Fe atom for FeGe to zero for non-magnetic CoGe. The chiral lattice structure leads to a Dzyaloshinskii-Moriya interaction (DMI), and the films' helical magnetic ground state was confirmed using polarized neutron reflectometry measurements. The pitch of the spin helix, measured by this method, varies with Co content $y$ and diverges at $y \sim 0.45$. This indicates a zero-crossing of the DMI, which we reproduced in calculations using first principle methods. We also measured the longitudinal and Hall resistivity of our films as a function of magnetic field, temperature, and Co content $y$. The Hall resistivity is expected to contain contributions from the ordinary, anomalous, and topological Hall effects. Both the anomalous and topological Hall resistivities show peaks around $y \sim 0.5$. Our first principles calculations show a peak in the topological Hall constant at this value of $y$, related to the strong spin-polarisation predicted for intermediate values of $y$. Half-metallicity is predicted for $y = 0.6$, consistent with the experimentally observed linear magnetoresistance at this composition. Whilst it is possible to reconcile theory with experiment for the various Hall effects for FeGe, the large topological Hall resistivities for $y \sim 0.5$ are much larger then expected when the very small emergent fields associated with the divergence in the DMI are taken into account.

cond-mat.mtrl-sci↗

Strong spin-Hall and Nernst effects in a p-band semimetal

Since spin currents can be generated, detected, and manipulated via the spin Hall effect (SHE), the design of strong SHE materials has become a focus in the field of spintronics. Because of the recent experimental progress also the spin Nernst effect (SNE), the thermoelectrical counterpart of the SHE, has attracted much interest. Empirically strong SHEs and SNEs are associated with $d$-band compounds, such as transition metals and their alloys -- the largest spin Hall conductivity (SHC) in a $p$-band material is $\sim 450$ $\left(\hbar/e\right)\left(Ω\cdot cm\right)^{-1}$ for a Bi-Sb alloy, which is only about a fifth of platinum. This raises the question whether either the SHE and SNE are naturally suppressed in $p$-bands compounds, or favourable $p$-band systems were just not identified yet. Here we consider the $p$-band semimetal InBi, and predict it has a record SHC $σ_{xy}^{z}\approx 1100 \ \left(\hbar/e\right)\left(Ω\cdot cm\right)^{-1}$ which is due to the presence of nodal-lines in its band structure. Also the spin-Nernst conductivity $α_{zx}^y\approx 1.2 \ (\hbar/e)(A/m\cdot K)$ is very large, but our analysis shows its origin is different as the maximum appears in a different tensor element. This insight gained on InBi provides guiding principles to obtain a strong SHE and SNE in $p$-band materials and establishes a more comprehensive understanding of the relationship between the SHE and SNE.

cond-mat.mtrl-sci↗

Photogalvanic Effect in Weyl Semimetals from First Principles

Using first-principles calculations, we investigate the photogalvanic effect in the Weyl semimetal material TaAs. We find colossal photocurrents caused by the Weyl points in the band structuure in a wide range of laser frequency. Our calculations reveal that the photocurrent is predominantly contributed by the three-band transition from the occupied Weyl band to the empty Weyl band via an intermediate band away from the Weyl cone, for excitations both by linearly and circularly polarized lights. Therefore, it is significant to sum over all three-band transitions by considering a full set of Bloch bands (both Weyl bands and trivial bands) in the first-principles band structure while it does not suffice to only consider the two-band direct transition within a Weyl cone. Calculated photoconductivities are well consistent with recent experiment measurements. Our work provides the first first-principles calculation on nonlinear optical phenomena of Weyl semimetals and serves as a deep understanding of the photogalvanic effects in complexed materials.

cond-mat.str-el↗

Topological Contributions to the Anomalous Nernst and Hall Effect in the Chiral Double-Helimagnetic System

MnP and FeP are show complex magnetic spiral states with geometric phase contributions to the anomalous Hall effect and the topological Hall effect, where both have thermoelectric Nernst counterparts. We use state of the art first principle calculations to show that both Hall and Nernst effects are enhanced in MnP and FeP due to the temperature dependent magnetic texture. At ambient pressure the inversion breaking crystals shows a transition from a double-spiral helimagnetic phase to a topologically trivial magnetic phase. This helimagnetic structure is determined by exchange frustration and the Dzyaloshinskii-Moriya interaction. In the presence of an external magnetic field the magnetic structure transforms into a fan-like phase with a finite spin chirality that gives rise to an effective magnetic field on the order $\sim$1 T. The topological Hall and Nernst effect from this field are comparable or larger to tightly-wound skyrmion systems. Lastly, we show that the topological effects are strongly dependent on the Fermi surface topology, which has strong variations and even sign changes for similar magnetic textures.

cond-mat.mtrl-sci↗

Electrically tuneable nonlinear anomalous Hall effect in two-dimensional transition-metal dichalcogenides WTe2 and MoTe2

We studied the nonlinear electric response in WTe2 and MoTe2 monolayers. When the inversion symmetry is breaking but the the time-reversal symmetry is preserved, a second-order Hall effect called the nonlinear anomalous Hall effect (NLAHE) emerges owing to the nonzero Berry curvature on the nonequilibrium Fermi surface. We reveal a strong NLAHE with a Hall-voltage that is quadratic with respect to the longitudinal current. The optimal current direction is normal to the mirror plane in these two-dimensional (2D) materials. The NLAHE can be sensitively tuned by an out-of-plane electric field, which induces a transition from a topological insulator to a normal insulator. Crossing the critical transition point, the magnitude of the NLAHE increases, and its sign is reversed. Our work paves the way to discover exotic nonlinear phenomena in inversion-symmetry-breaking 2D materials.

cond-mat.mtrl-sci↗

Magnetic Weyl Semimetal in Quasi Two-dimensional Half Metallic Co$_3$Sn$_2$Se$_2$

We have found a ferromagnetic Weyl semimetal (WSM) in half metallic Co$_3$Sn$_2$Se$_2$. The three pairs of Weyl points near Fermi level (E$_F$) are derived from nodal lines gapped by spin-orbit coupling (SOC). Though the Weyl points are 0.11 eV above the charge neutral point, Fermi arc related states in the cleaved surface can range from E$_F$ -0.15 to E$_F$ +0.11 eV in energy space, due to the surface bands dispersion. Hence, Weyl points related physics should be detected by surface measurements, such as ARPES and STM. Because of the large Berry curvature deriving from the gapped nodal lines and Weyl points, the anomalous Hall conductivity of Co$_3$Sn$_2$Se$_2$ can keep above 620 S/cm in a large energy window. Beside magnetic WSM, Co$_3$Sn$_2$Se$_2$ also possesses a Z$_2$ topological semimetal phase as the temperature is above Curie temperature. Owing to the quasi two-dimensional lattice structure, it is also possible to realize quantum anomalous Hall effect in its 2D limit via the size effect. Therefore, Co$_3$Sn$_2$Se$_2$ provides a good platform for the interplay of different topological states and magnetic states.

cond-mat.mtrl-sci↗

Thermoelectric signatures of the electron-phonon fluid in PtSn4

In most materials, transport can be described by the motion of distinct species of quasiparticles, such as electrons and phonons. Strong interactions between quasiparticles, however, can lead to collective behaviour, including the possibility of viscous hydrodynamic flow. In the case of electrons and phonons, an electron-phonon fluid is expected to exhibit strong phonon-drag transport signatures and an anomalously low thermal conductivity. The Dirac semi-metal PtSn4 has a very low resistivity at low temperatures and shows a pronounced phonon drag peak in the low temperature thermopower; it is therefore an excellent candidate for hosting a hydrodynamic electron-phonon fluid. Here we report measurements of the temperature and magnetic field dependence of the longitudinal and Hall electrical resistivities, the thermopower and the thermal conductivity of PtSn4. We confirm a phonon drag peak in the thermopower near 14 K and observe a concurrent breakdown of the Lorenz ratio below the Sommerfeld value. Both of these facts are expected for an electron-phonon fluid with a quasi-conserved total momentum. A hierarchy between momentum-conserving and momentum-relaxing scattering timescales is corroborated through measurements of the magnetic field dependence of the electrical and Hall resistivity and of the thermal conductivity. These results show that PtSn4 exhibits key features of hydrodynamic transport.

cond-mat.mtrl-sci↗

Canted ferrimagnetism and giant coercivity in the non-stoichiometric double perovskite La2Ni1.19Os0.81O6

The non-stoichiometric double perovskite oxide La2Ni1.19Os0.81O6 was synthesized by solid state reaction and its crystal and magnetic structures were investigated by powder x-ray and neutron diffraction. La2Ni1.19Os0.81O6 crystallizes in the monoclinic double perovskite structure (general formula A2BB'O6) with space group P21/n, where the B site is fully occupied by Ni and the B' site by 19 % Ni and 81 % Os atoms. Using x-ray absorption spectroscopy an Os4.5+ oxidation state was established, suggesting presence of about 50 % paramagnetic Os5+ (5d3, S = 3/2) and 50 % non-magnetic Os4+ (5d4, Jeff = 0) ions at the B' sites. Magnetization and neutron diffraction measurements on La2Ni1.19Os0.81O6 provide evidence for a ferrimagnetic transition at 125 K. The analysis of the neutron data suggests a canted ferrimagnetic spin structure with collinear Ni2+ spin chains extending along the c axis but a non-collinear spin alignment within the ab plane. The magnetization curve of La2Ni1.19Os0.81O6 features a hysteresis with a very high coercive field, HC = 41 kOe, at T = 5 K, which is explained in terms of large magnetocrystalline anisotropy due to the presence of Os ions together with atomic disorder. Our results are encouraging to search for rare earth free hard magnets in the class of double perovskite oxides.

cond-mat.str-el↗

Heusler, Weyl, and Berry

Heusler materials, initially discovered by Fritz Heusler more than a century ago, have grown into a family of more than 1000 compounds, synthesized from combinations of more than 40 elements. These materials show a wide range of properties, but new properties are constantly being found. Most recently, by incorporating heavy elements that can give rise to strong spin-orbit coupling (SOC), non-trivial topological phases of matter, such as topological insulators (TIs), have been discovered in Heusler materials. Moreover, the interplay of symmetry, SOC and magnetic structure allows for the realization of a wide variety of topological phases through Berry curvature design. Weyl points and nodal lines can be manipulated by various external perturbations, which results in exotic properties such as the chiral anomaly, and large anomalous spin and topological Hall effects. The combination of a non-collinear magnetic structure and Berry curvature gives rise a non-zero anomalous Hall effect, which was first observed in the antiferromagnets Mn3Sn and Mn3Ge. Besides this k-space Berry curvature, Heusler compounds with non-collinear magnetic structures also possess real-space topological states in the form of magnetic antiskyrmions, which have not yet been observed in other materials. The possibility of directly manipulating the Berry curvature shows the importance of understanding both the electronic and magnetic structures of Heusler compounds. Together, with the new topological viewpoint and the high tunability, novel physical properties and phenomena await discovery in Heusler compounds.

cond-mat.mtrl-sci↗

Temperature-induced inversion of the spin-photogalvanic effect in WTe$_2$ and MoTe$_2$

We investigate the generation and temperature-induced evolution of optically-driven spin photocurrents in WTe$_2$ and MoTe$_2$. By correlating the scattering-plane dependence of the spin photocurrents with the symmetry analysis, we find that a sizeable spin photocurrent can be controllably driven along the chain direction by optically exciting the system in the high-symmetry $y$-$z$ plane. Temperature dependence measurements show that pronounced variations in the spin photocurrent emerge at temperatures that coincide with the onset of anomalies in their transport and optical properties. The decreasing trend in the temperature dependence starting below 150 K is attributed to the temperature-induced Lifshitz transition. The sign inversion of the spin photocurrent, observed around 50 K in WTe$_2$ and around 120 K in MoTe$_2$, may have its origin in an interaction that involves multiple kinds of carriers.

cond-mat.mtrl-sci↗

Topological Weyl semimetals in $\rm Bi$$_{1-x}$$\rm Sb$$_{x}$ alloys

We have investigated the Weyl semimetal (WSM) phases in bismuth antimony ($\rm Bi$$_{1-x}$$\rm Sb$$_{x}$) alloys by the combination of atomic composition and arrangement. Via first principles calculations, we have found two WSM states with the Sb concentration of $x=0.5$ and $x=0.83$ with specific inversion symmetry broken elemental arrangement. The Weyl points are close to the Fermi level in both of these two WSM states. Therefore, it has a good opportunity to obtain Weyl points in Bi-Sb alloy. The WSM phase provides a reasonable explanation for the current transport study of BiSb alloy with the violation of Ohm's law [Dongwoo Shin, et al., Nature Materials 16, 1096 (2017)]. This work shows that the topological phases in Bi-Sb alloys depend on both elemental composition and their specific arrangement.

cond-mat.mtrl-sci↗

Weyl Fermions in antiferromagnetic Mn(3)Sn and Mn(3)Ge

The anomalous Hall effect in the noncollinear antiferromagnetic metals Mn(3)Ge and Mn(3)Sn has been observed after a theoretical prediction made by us (EPL, 108, 67001 (2014)). The experimental values of the anomalous Hall conductivities (AHC) are large as are the theoretical values. Recently measured thermoelectric properties mirror the large AHC and clearly show that the transport is by quasiparticles at the Fermi energy. We here make an attempt to unravel the origin of the large AHC and propose that both Mn(3)Sn and Mn(3)Ge host Weyl points, which were recently discovered in semimetals. For this purpose we determine the electronic structure ab initio in the local spin-density functional approximation. The Weyl points are found to occur below the Fermi energy and we argue that spots of large Berry flux ('hot spot') that are seen at the Fermi surface are produced by the Weyl nodes.

cond-mat.mtrl-sci↗