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Claudio A. Cerdeiriña

Publications and source records attributed to Claudio A. Cerdeiriña.

2 recordsLinked to original sources

Theory of supercooled water

We introduce a model of water contemplating true supercooled-liquid states that, as such, are metastable with respect to the crystalline-solid ones. Its numerical solutions reproduce from Speedy-Angell's stability-limit picture to Poole et al.'s metastable liquid--liquid criticality. The real existence of a liquid--liquid critical point is found to gain significant theoretical plausibility from a hitherto unnoticed analogy with the ``inversion thermodynamics'' of Joule-Thomson gas throttling process and, by extension, with the equivalent phenomenology exhibited by black holes.

cond-mat.stat-mech↗

Ising Model for the Freezing Transition

A spin-1 Ising model incorporating positional order to a standard lattice gas with no attractive interactions is introduced and found to be consistent with all known attributes of the freezing transition of the hard-sphere system. Implementation of attractive interactions in a fairly natural way then allows every aspect of the phase diagram of a simple substance to be reproduced. The \emph{whole} phase behavior of such sort of substances is thus found to sharply manifest the van der Waals picture highlighting the relevance of harsh repulsive forces.

cond-mat.stat-mech↗