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Claudio Grimaldi

Publications and source records attributed to Claudio Grimaldi.

26 records · Page 2Linked to original sources

Continuum percolation of polydisperse hyperspheres in infinite dimensions

We analyze the critical connectivity of systems of penetrable $d$-dimensional spheres having size distributions in terms of weighed random geometrical graphs, in which vertex coordinates correspond to random positions of the sphere centers and edges are formed between any two overlapping spheres. Edge weights naturally arise from the different radii of two overlapping spheres. For the case in which the spheres have bounded size distributions, we show that clusters of connected spheres are tree-like for $d\rightarrow \infty$ and they contain no closed loops. In this case, we find that the mean cluster size diverges at the percolation threshold density $η_c\rightarrow 2^{-d}$, independently of the particular size distribution. We also show that the mean number of overlaps for a particle at criticality $z_c$ is smaller than unity, while $z_c\rightarrow 1$ only for spheres with fixed radii. We explain these features by showing that in the large dimensionality limit the critical connectivity is dominated by the spheres with the largest size. Assuming that closed loops can be neglected also for unbounded radii distributions, we find that the asymptotic critical threshold for systems of spheres with radii following a lognormal distribution is no longer universal, and that it can be smaller than $2^{-d}$ for $d\rightarrow\infty$.

cond-mat.stat-mech↗

Tunneling conductivity in anisotropic nanofibre composites: a percolation-based model

The Critical Path Approximation ("CPA") is integrated with a lattice-based approach to percolation to provide a model for conductivity in nanofibre-based composites. Our treatment incorporates a recent estimate for the anisotropy in tunnelingbased conductance as a function of the relative angle between the axes of elongated nanoparticles. The conductivity is examined as a function of the volume fraction, degree of clustering, and of the mean value and standard deviation of the orientational order parameter. Results from our calculations suggest that the conductivity can depend strongly upon the standard deviation in the orientational order parameter even when all the other variables (including the mean value of the order parameter ) are held invariant.

cond-mat.dis-nn↗

Impact of tunneling anisotropy on the conductivity of nanorod dispersions

While the tunneling conductance between two spherical-like conducting particles depends on the relative inter-particle distance, the wave function overlap between states of two rod-like particles, and so the tunneling conductance, depends also on the relative orientation of the rod axes. Modeling slender rod-like particles as cylindrical quantum wells of diameter $D$ and length $L\gg D$, we calculate the matrix element of the tunneling between two rods for arbitrary relative orientations of the rod axes. We show that tunneling between two parallel rods is about $L/\sqrt{Dξ}$ times larger than the tunneling matrix element for perpendicular rods, where $ξ$ is the tunneling decay length. By considering the full dependence of the tunneling conductance on the angle between rod axes, we calculate within an effective medium theory the conductivity of dispersions of rods with different degrees of alignment. We find that for isotropically oriented rods, the effect of orientation in the tunneling processes is marginal for all rod concentrations. On the contrary, for systems of strongly aligned rods, the enhanced tunneling between nearly parallel rods increases significantly the system conductivity in a relatively large concentration range. Next, we consider systems in which short-range attraction between rods is added, as in dispersions of rods with depletion interaction. We find that the strongly anisotropic attraction promotes enhanced tunneling between neighboring parallel rods, increasing the effective medium conductivity by several orders of magnitude compared to the case in which the angular dependence of tunneling is ignored, even for relatively weak attractions.

cond-mat.dis-nn↗

Enhanced tunneling conductivity induced by gelation of attractive colloids

We show that the formation of a gel by conducting colloidal particles leads to a dramatic enhancement in bulk conductivity, due to inter-particle electron tunneling, combining predictions from molecular dynamics simulations with structural measurements in an experimental colloid system. Our results show how colloidal gelation can be used as a general route to huge enhancements of conductivity, and suggest a feasible way for developing cheap materials with novel properties and low metal content.

cond-mat.soft↗

Electrical conductivity of multi-walled carbon nanotubes-SU8 epoxy composites

We have characterized the electrical conductivity of the composite which consists of multi-walled carbon nanotubes dispersed in SU8 epoxy resin. Depending on the processing conditions of the epoxy (ranging from non-polymerized to cross-linked) we obtained tunneling and percolating-like regimes of the electrical conductivity of the composites. We interpret the observed qualitative change of the conductivity behavior in terms of reduced separation between the nanotubes induced by polymerization of the epoxy matrix.

cond-mat.mtrl-sci↗

Quasiuniversal connectedness percolation of polydisperse rod systems

The connectedness percolation threshold (eta_c) and critical coordination number (Z_c) of systems of penetrable spherocylinders characterized by a length polydispersity are studied by way of Monte Carlo simulations for several aspect ratio distributions. We find that (i) η_c is a nearly universal function of the weight-averaged aspect ratio, with an approximate inverse dependence that extends to aspect ratios that are well below the slender rod limit and (ii) that percolation of impenetrable spherocylinders displays a similar quasiuniversal behavior. For systems with a sufficiently high degree of polydispersity, we find that Z_c can become smaller than unity, in analogy with observations reported for generalized and complex networks.

cond-mat.soft↗

Percolative properties of hard oblate ellipsoids of revolution with a soft shell

We present an in-depth analysis of the geometrical percolation behavior in the continuum of random assemblies of hard oblate ellipsoids of revolution. Simulations where carried out by considering a broad range of aspect-ratios, from spheres up to aspect-ratio 100 plate-like objects, and with various limiting two particle interaction distances, from 0.05 times the major axis up to 4.0 times the major axis. We confirm the widely reported trend of a consistent lowering of the hard particle critical volume fraction with the increase of the aspect-ratio. Moreover, assimilating the limiting interaction distance to a shell of constant thickness surrounding the ellipsoids, we propose a simple relation based on the total excluded volume of these objects which allows to estimate the critical concentration from a quantity which is quasi-invariant over a large spectrum of limiting interaction distances. Excluded volume and volume quantities are derived explicitly.

cond-mat.stat-mech↗

Strain modulation of transport criticality in heterogeneous solids

A vast class of disordered conducting-insulating compounds close to the percolation threshold is characterized by nonuniversal values of transport critical exponents. The lack of universality implies that critical indexes may depend on material properties such as the particular microstructure or the nature of the constituents, and that in principle they can be influenced by suitable applied perturbations leading to important informations about the origin of nonuniversality. Here we show that in RuO$_2$-glass composites the nonuniversal exponent can be modulated by an applied mechanical strain, signaled by a logarithmic divergence of the piezoresistive response at the percolation threshold. We interpret this phenomenon as being due to a tunneling-distance dependence of the transport exponent, supporting therefore a theory of transport nonuniversality proposed some years ago.

cond-mat.dis-nn↗