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Clement Wong

Publications and source records attributed to Clement Wong.

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Health feature extraction from battery energy storage system field fault data

Health monitoring methods are critical for lithium-ion battery modules connected to the grid to prevent faults that can lead to catastrophic events. However, assessing the health of cells in modules from their operational data presents challenges including variable operating conditions, which directly confound health features, and sparse sensing in the modules, particularly within cells in parallel, which prevents observing critical states of individual cells. Here, we present a framework for extracting and calibrating health features for battery modules from their operational data to identify discriminative features for separating faulty parallel-connected cell groups within the modules. We applied this framework to operational data from 25 commercial grid-connected lithium-ion Battery Energy Storage System (BESS) modules. Each module consisted of 14 series-connected parallel groups, one of which was confirmed as faulty via post-mortem investigation; in total, the dataset included 25 faulty and 325 non-faulty cell groups. A statistical evaluation of these calibrated features demonstrated that group-level capacity, capacity degradation rate, and dV/dQ peak heights separate faulty parallel-connected cell groups within the modules with statistical significance (p<0.05). Conversely, group internal resistance did not (p>0.05), indicating that increased resistance was not a primary characteristic of the faults in this dataset. These findings challenge the exclusive reliance on resistance features for fault detection. The observed feature signatures suggest potential failure mechanisms, furthering the understanding of fault behavior in lithium-ion battery modules during field operation. More importantly, this work demonstrates a framework for robustly monitoring the health of cells in lithium-ion battery modules under real-world operations.

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The potential and viability of V2G for California BEV drivers

Vehicle-to-Grid (V2G) adoption is hindered by uncertainties regarding its effects on battery lifetime and vehicle usability. These uncertainties are compounded by limited insight into real-world vehicle usage. Here, we leverage real-world Californian BEV usage data to design and evaluate a user-centric V2G strategy. We identified four clustered driver profiles for V2G assessment, ranging from "Daily Chargers" to "Public Chargers". We show that V2G participation is most feasible for "Daily Chargers," and that the effects on battery lifetime depend on calendar aging sensitivity. For batteries with low sensitivity, V2G participation increases capacity loss for all drivers. However, for batteries with high sensitivity, V2G participation can lead to negligible changes in capacity or even improved capacity retention, particularly for drivers who tend to keep their batteries at high states of charge. Our findings enable stakeholders to better assess the potential and viability of V2G adoption.

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Differential Voltage Analysis and Patterns in Parallel-Connected Pairs of Imbalanced Cells

Diagnosing imbalances in capacity and resistance within parallel-connected cells in battery packs is critical for battery management and fault detection, but it is challenging given that individual currents flowing into each cell are often unmeasured. This work introduces a novel method useful for identifying imbalances in capacity and resistance within a pair of parallel-connected cells using only voltage and current measurements from the pair. Our method utilizes differential voltage analysis (DVA) when the pair is under constant current discharge and demonstrates that features of the pair's differential voltage curve (dV/dQ), namely its mid-to-high SOC dV/dQ peak's height and skewness, are sensitive to imbalances in capacity and resistance. We analyze and explain how and why these dV/dQ peak shape features change in response to these imbalances, highlighting that the underlying current imbalance dynamics resulting from these imbalances contribute to these changes. Ultimately, we demonstrate that dV/dQ peak shape features can identify the product of capacity imbalance and resistance imbalance, but cannot uniquely identify the imbalances. This work lays the groundwork for identifying imbalances in capacity and resistance in parallel-connected cell groups in battery packs, where commonly only a single current sensor is placed for each parallel cell group.

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Current imbalance in dissimilar parallel-connected batteries and the fate of degradation convergence

This paper proposes an analytical framework describing how initial capacity and resistance variability in parallel-connected battery cells may inflict additional variability or reduce variability while the cells age. We derive closed-form equations for current and SOC imbalance dynamics within a charge or discharge cycle. These dynamics are represented by a first-order equivalent circuit model and validated against experimental data. To demonstrate how current and SOC imbalance leads to cell degradation, we developed a successive update scheme in which the inter-cycle imbalance dynamics update the intra-cycle degradation dynamics, and vice versa. Using this framework, we demonstrate that current imbalance can cause convergent degradation trajectories, consistent with previous reports. However, we also demonstrate that different degradation assumptions, such as those associated with SOC imbalance, may cause divergent degradation. We finally highlight the role of different cell chemistries, including different OCV function nonlinearities, on system behavior, and derive analytical bounds on the SOC imbalance using Lyapunov analysis.

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A Fast Diagnostic to Inform Screening of Discarded or Retired Batteries

With the increased pervasiveness of Lithium-ion batteries, there is growing concern for the amount of retired batteries that will be entering the waste stream. Although these batteries no longer meet the demands of their first application, many still have a significant portion of their initial capacity remaining for use in secondary applications. Yet, direct repurposing is generally not possible and each cell in a battery must be evaluated, increasing the cost of the repurposed packs due to the time intensive screening process. In this paper, a rapid assessment of the internal resistance of a cell is proposed. First, this method of measuring the resistance is completed on cells from twelve retired battery packs and one fresh pack using a hybrid pulse power characterization (HPPC) test as a benchmark for the analysis. Results from these tests show relatively constant resistance measurements across mid to high terminal voltages, allowing this metric to be independent of state of charge (SOC). Then, the relation between internal resistance and capacity across the various packs is discussed. Initial experimental results from this study show a correlation between internal resistance and capacity which can be approximated with a linear fit, suggesting internal resistance measurements taken above a threshold cell terminal voltage may be a suitable initial screening metric for the capacity of retired cells without knowledge of the SOC.

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