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Czesław Kapusta

Publications and source records attributed to Czesław Kapusta.

4 recordsLinked to original sources

Complex magnetic properties of EuAgAs single crystals

EuAgAs is an antiferromagnetic topological material exhibiting intriguing magnetic behavior. We investigate its structural, magnetic, and local electronic properties using X ray diffraction, Mössbauer spectroscopy, dc magnetization, ac susceptibility, and heat capacity measurements. The results confirm antiferromagnetic ordering below $T_\text{N}$ and reveal pronounced magnetic anisotropy and several field induced metamagnetic transitions. We construct the magnetic phase diagram of EuAgAs, identifying several distinct magnetic regions. The field and temperature dependent behavior observed suggests a noncollinear magnetic structure in the low field regime. The sequence of field induced transitions resembles that observed in centrosymmetric rare earth compounds hosting skyrmion phases, suggesting that competing magnetic interactions may play an important role in stabilizing the observed magnetic states.

cond-mat.mtrl-sci↗

Ambient and high pressure studies of structural, electronic and magnetic properties of EuZn$_2$P$_2$ single crystal

A thorough study of EuZn$_2$P$_2$ single crystals, which were grown from Sn flux, was performed using both bulk (heat capacity, ac susceptibility, dc magnetization, electrical resistivitivity, magnetoresistance) and microscopic (Mössbauer spectroscopy) techniques. Electrical resistance and magnetic susceptibility were measured also under high pressure conditions (up to 19 GPa and 9.5 GPa, respectively). Further insight into electronic properties and phonons is provided by ab initio calculations. The results indicate that EuZn$_2$P$_2$ is an antiferromagnet with strong Eu-Eu exchange coupling of ferromagnetic type within the basal plane and weaker antiferromagnetic interaction along the c axis. The Eu magnetic moments are tilted from the basal plane. Hydrostatic pressure strongly affects both magnetic (increase of the Néel temperature) and electronic (suppression of the band gap and semi metallic behavior) properties, indicating a strong interplay of structure with magnetic and electronic degrees of freedom.

cond-mat.mtrl-sci↗

Determination of oxygen vacancy limit in Mn substituted YSZ ceramics

The series of Mnx(Y0.148Zr0.852)1-xO2-δ ceramics was systematically studied by means of X-ray absorption and emission spectroscopy and DC magnetic susceptibility. XAS and XES results show changes in manganese oxidation state and a gradual evolution of the local atomic environment around Mn ions upon increasing dopants content, which is due to structural relaxation caused by growing amount of oxygen vacancies. Magnetic susceptibility measurements reveal that Mn3O4 precipitates are formed for x greater than or equal to 0.1 and enable independent determination of actual quantity of Mn ions dissolved in YSZ solid solution. We show that amount of oxygen vacancies generated by manganese doping into YSZ is limited to 0.19 per formula unit.

cond-mat.mtrl-sci↗

New Perspective on the Phase Diagram of Cuprate High-Temperature Superconductors

Universal scaling laws can guide the understanding of new phenomena, and for cuprate high-temperature superconductivity such an early influential relation showed that the critical temperature of superconductivity ($T_c$) correlates with the density of the superfluid measured at low temperatures. This famous Uemura relation has been inspiring the community ever since. Here we show that the charge content of the bonding orbitals of copper and oxygen in the ubiquitous CuO$_2$ plane, accessible with nuclear magnetic resonance (NMR), is tied to the Uemura scaling. This charge distribution between copper and oxygen varies between cuprate families and with doping, and it allows us to draw a new phase diagram that has different families sorted with respect to their maximum $T_c$. Moreover, it also shows that $T_c$ could be raised substantially if we were able to synthesize materials in which more oxygen charge is transferred to the approximately half filled copper orbital.

cond-mat.supr-con↗