arXiv subjects

D. A. Glazov

Publications and source records attributed to D. A. Glazov.

At least 19 recordsLinked to original sources

arXiv2026

Axion-Exchange Contribution to the Energy of Lithium-Like Ions

Axions and axion-like particles are among the most promising candidates for dark matter and for manifestations of new physics beyond the Standard Model. In the present work, the contribution of axion exchange to the energy of lithium-like ions is investigated within the framework of relativistic bound-state quantum electrodynamics. A formalism for the interelectronic interaction mediated by axion exchange is developed in the Furry picture with finite nuclear size taken into account. Energy shifts are calculated for a wide range of nuclear charge numbers $Z$ and axion masses. The magnitude of the axion-induced contribution is shown to increase with increasing $Z$ for all states considered. Based on the analysis of lithium-like bismuth, constraints on the axion-electron interaction parameters are obtained in the high-mass region. The results indicate that precision spectroscopy of highly charged ions is a promising tool for searches for new physics associated with the exchange of pseudoscalar bosons.

physics.atom-ph↗

arXiv2026

Quadratic Zeeman effect in light boron-like ions

The quadratic Zeeman effect is calculated for the ground $^2P_{1/2}$ state of light boron-like ions in the range of nuclear-charge numbers $Z = 10-24$. The calculations are performed in the Furry picture using three models for the zeroth-order approximation potential: pure nuclear Coulomb potential and two effective screening potentials $-$ core-Hartree and Kohn-Sham. First-order perturbation-theory contributions are considered: the one-photon-exchange correction and the radiative corrections associated with the self-energy and vacuum-polarization diagrams. The dominant contributions from the self-energy diagrams are calculated within a rigorous QED approach. The vacuum polarization corrections are obtained within the electric-loop approximation in the leading order, which is given by the Uehling potential. As a result, theoretical predictions for the contribution of the quadratic Zeeman effect to the binding energy of the valence electron in the $^2P_{1/2}$ state are obtained. The results can be used for the analysis of high-precision $g$-factor and fine-structure splitting measurements in boron-like highly charged ions.

physics.atom-ph↗

arXiv2026

Bound-electron self-energy calculations in Feynman and Coulomb gauges: detailed analysis

The energy correction associated with the self-energy diagram is the leading (in magnitude) and fundamental (in significance) contribution to the Lamb shift in highly charged ions. Conventional approaches to this correction rely on partial-wave expansions, which is a stumbling block limiting accuracy. To elucidate the issue, we perform a comprehensive comparative analysis of partial-wave-expansion convergence between two gauges: Feynman and Coulomb. Some tricks for improving the convergence are discussed as well.

physics.atom-ph↗

arXiv2026

Thermal one-loop self-energy correction for hydrogen-like systems: Relativistic approach

Within a fully relativistic framework, the one-loop self-energy correction for a bound electron is derived and extended to incorporate the effects of external thermal radiation. In a series of previous works, it was shown that in quantum electrodynamics at finite temperature (QED), the description of effects caused by blackbody radiation can be reduced to using the thermal part of the photon propagator. As a consequence of the non-relativistic approximation in the calculation of the thermal one-loop self-energy correction, well-known quantum-mechanical (QM) phenomena emerge at successive orders: the Stark effect arises at leading order in $αZ$, the Zeeman effect appears in the next-to-leading non-relativistic correction, accompanied by diamagnetic contributions and their relativistic refinements, among other perturbative corrections. The fully relativistic approach used in this work for calculating the SE contribution allows for accurate calculations of the thermal shift of atomic levels, in which all these effects are automatically taken into account. The hydrogen atom serves as the basis for testing a fully relativistic approach to such calculations. Additionally, an analysis is presented of the behavior of the thermal shift caused by the thermal one-loop correction to the self-energy of a bound electron for hydrogen-like ions with an arbitrary nuclear charge $Z$. The significance of these calculations lies in their relevance to contemporary high-precision experiments, where thermal radiation constitutes one of the major contributions to the overall uncertainty budget.

physics.atom-ph↗

arXiv2025

QED effects in quadratic Zeeman splitting in highly charged hydrogen-like ions

We present ab initio calculations of one-electron quantum electrodynamical corrections to the second-order Zeeman splitting for the $1s_{1/2}$, $2s_{1/2}$, and $2p_{1/2}$ states in highly charged hydrogen-like ions. The self-energy correction is evaluated using the rigorous QED approach. The vacuum polarization correction is evaluated within the electric-loop approximation. Calculations are performed for the wide range of nuclear charge number: $Z = 14 - 92$.

physics.atom-ph↗

arXiv2025

Sturmian basis set for the Dirac equation with finite nuclear size: Application to polarizability, Zeeman and hyperfine splitting, and vacuum polarization

We investigate the application of the Sturmian basis set in relativistic atomic structure calculations. We propose a simple implementation of this approach and demonstrate its ability to provide various quantities for hydrogen-like ions, including binding energies, static dipole polarizability, $g$ factor, hyperfine splitting, and nuclear magnetic shielding. Finally, we calculate the all-order (Wichmann-Kroll) vacuum polarization charge density, which was a challenge for the finite-basis-set approach until recently. Comparison of the obtained results with the previously published numerical and analytical calculations is presented. All calculations are performed with the finite size of the nucleus and can in principle be extended to arbitrary binding potentials.

physics.atom-ph↗

arXiv2025

$g$ factor of the $2p_j$ excited states in lithium-like ions

Relativistic calculations for the $g$ factor of the lowest excited states $2p_{1/2}$ and $2p_{3/2}$ of lithium-like ions over a wide range of the nuclear charge numbers $Z=10-92$ are presented. Interelectronic interaction is considered within the perturbation theory up to the second order. One-loop QED contributions are calculated to all orders in $αZ$. Leading contributions of the nuclear recoil effects are taken into account. The quadratic and cubic terms in magnetic field are considered as well. A set of screening potentials is used in all calculations to estimate the unknown higher-order correlation effects.

physics.atom-ph↗

arXiv2024

Vacuum polarization and Wichmann-Kroll correction in the finite basis set approximation

The finite basis set method is commonly used to calculate atomic spectra, including QED contributions such as bound-electron self-energy. Still, it remains problematic and underexplored for vacuum-polarization calculations. We fill this gap by trying this approach in its application to the calculation of the vacuum-polarization charge density and the Wichmann-Kroll correction to the electron binding energy in a hydrogen-like ion. We study the convergence of the method with different types and sizes of basis sets. We cross-check our results for the Wichmann-Kroll correction by direct integration of the Green's function. As a relevant example, we consider several heavy hydrogen-like ions and evaluate the vacuum polarization correction for $S$ and $P$ electron orbitals.

physics.atom-ph↗

arXiv2024

Excitation of the $^{229}$Th nucleus by the hole in the inner electronic shells

The $^{229}$Th nucleus has a long-lived isomeric state $A^*$ at 8.338(24) eV [Kraemer et al, Nature, \textbf{617}, 706 (2023)]. This state is connected to the ground state by an M1 transition. For a hydrogenlike Th ion in the $1s$ state the hyperfine structure splitting is about 0.7 eV. This means that the hyperfine interaction can mix the nuclear ground state with the isomeric state with a mixing coefficient $β$ about 0.03. If the electron is suddenly removed from this system, the nucleus will be left in the mixed state. The probability to find the nucleus in the isomeric state $A^*$ is equal to $β^2\sim 10^{-3}$. For the $2s$ state the effect is roughly two orders of magnitude smaller. An atom with a hole in the $1s$ or $2s$ shell is similar to the hydrogenlike atom, only the hole has a short lifetime $τ$. After the hole is filled, there is a non-zero probability to find the nucleus in the $A^*$ state. Estimates of this probability are presented along with a discussion of possible experiments on Th-doped xenotime-type orthophosphate crystals and other broad band gap materials.

physics.atom-ph↗

arXiv2023

Electron correlation effects on the $g$ factor of lithiumlike ions

We present the systematic QED treatment of the electron correlation effects on the $g$ factor of lithiumlike ions for the wide range of nuclear charge number $Z= 14$ -- $82$. The one- and two-photon exchange corrections are evaluated rigorously within the QED formalism. The electron-correlation contributions of the third and higher orders are accounted for within the Breit approximation employing the recursive perturbation theory. The calculations are performed in the framework of the extended Furry picture, i.e., with inclusion of the effective local screening potential in the zeroth-order approximation. In comparison to the previous theoretical calculations, the accuracy of the interelectronic-interaction contributions to the bound electron $g$ factor in lithiumlike ions is substantially improved.

physics.atom-ph↗

arXiv2023

Model-QED-operator approach to relativistic calculations of the nuclear recoil effect in many-electron atoms and ions

A model-operator approach to fully relativistic calculations of the nuclear recoil effect on energy levels in many-electron atomic systems is worked out. The one-electron part of the model operator for treating the normal mass shift beyond the Breit approximation is represented by a sum of semilocal and nonlocal potentials. The latter ones are constructed by employing the diagonal and off-diagonal matrix elements rigorously evaluated for hydrogenlike ions to first order in the electron-to-nucleus mass ratio. The specific mass shift beyond the lowest-order relativistic approximation has a form which can be directly employed in calculations. The capabilities of the method are probed by comparison of its predictions with the results of ab initio QED calculations. The proposed operator can be easily incorporated into any relativistic calculation based on the Dirac-Coulomb-Breit Hamiltonian.

physics.atom-ph↗

arXiv2022

Model-QED operator for superheavy elements

The model-QED-operator approach [Phys. Rev. A 88, 012513 (2013)] to calculations of the radiative corrections to binding and transition energies in atomic systems is extended to the range of nuclear charges $110 \leqslant Z \leqslant 170$. The self-energy part of the model operator is represented by a nonlocal potential based on diagonal and off-diagonal matrix elements of the ab initio self-energy operator with the Dirac-Coulomb wave functions. The vacuum-polarization part consists of the Uehling contribution which is readily computed for an arbitrary nuclear-charge distribution and the Wichmann-Kroll contribution represented in terms of matrix elements similarly to the self-energy part. Performance of the method is studied by comparing the model-QED-operator predictions with the results of ab initio calculations. The model-QED operator can be conveniently incorporated in any numerical approach based on the Dirac-Coulomb-Breit Hamiltonian to account for the QED effects in a wide variety of superheavy elements.

physics.atom-ph↗

arXiv2022

Ground-state $g$ factor of highly charged $^{229}$Th ions: an access to the M1 transition probability between the isomeric and ground nuclear states

A method is proposed to determine the $M1$ nuclear transition amplitude and hence the lifetime of the "nuclear clock transition" between the low-lying ($\sim 8$ eV) first isomeric state and the ground state of $^{229}$Th from a measurement of the ground-state $g$ factor of few-electron $^{229}$Th ions. As a tool, the effect of nuclear hyperfine mixing (NHM) in highly charged $^{229}$Th-ions such as $^{229}$Th$^{89+}$ or $^{229}$Th$^{87+}$ is utilized. The ground-state-only $g$-factor measurement would also provide first experimental evidence of NHM in atomic ions. Combining the measurements for H-, Li-, and B-like $^{229}$Th ions has a potential to improve the initial result for a single charge state and to determine the nuclear magnetic moment to a higher accuracy than that of the currently accepted value. The calculations include relativistic, interelectronic-interaction, QED, and nuclear effects.

physics.atom-ph↗

arXiv2022

Redefined vacuum approach and gauge-invariant subsets in two-photon-exchange diagrams for a closed-shell system with a valence electron

The two-photon-exchange diagrams for atoms with single valence electrons are investigated. Calculation formulas are derived for an arbitrary state within the rigorous bound-state QED framework utilizing the redefined vacuum formalism. In contrast to other methods, the redefined vacuum approach enables the identification of eight gauge-invariant subsets and, thus, efficiently checks the consistency of the obtained results. The gauge invariance of found subsets is demonstrated both analytically (for an arbitrary state) as well as numerically for 2s, 2p1/2, and 2p3/2 valence electrons in Li-like ions. Identifying gauge-invariant subsets in the framework of the proposed approach opens a way to tackle more complex diagrams, e.g., three-photon exchange, where the fragmentation on simpler subsets is crucial for its successful calculation.

physics.atom-ph↗

arXiv2022

g Factor of Lithiumlike Silicon and Calcium: Resolving the Disagreement between Theory and Experiment

The bound-electron g factor is a stringent tool for tests of the Standard Model and the search for new physics. The comparison between an experiment on the g factor of lithiumlike silicon and the two recent theoretical values revealed the discrepancies of $1.7σ$ [D. A. Glazov $\textit{et al}$., Phys. Rev. Lett. $\textbf{123}$, 173001 (2019)] and $5.2σ$ [V. A. Yerokhin $\textit{et al}$., Phys. Rev. A $\textbf{102}$, 022815 (2020)]. To identify the reason for this disagreement, we accomplish large-scale high-precision computation of the interelectronic-interaction and many-electron QED corrections. The calculations are performed within the extended Furry picture of QED, and the dependence of the final values on the choice of the binding potential is carefully analyzed. As a result, we significantly improve the agreement between the theory and experiment for the g factor of lithiumlike silicon. We also report the most accurate theoretical prediction to date for lithiumlike calcium, which perfectly agrees with the experimental value.

physics.atom-ph↗

arXiv2021

Nuclear magnetic shielding in highly charged ions

The nuclear magnetic shielding is considered within the fully relativistic approach for the ground state of H-, Li-, and B-like ions in the range Z=32-92. The interelectronic interaction is evaluated to the first order of the perturbation theory in Li- and B-like ions. The calculations are based on the finite-field method. The numerical solution of the Dirac equation with the magnetic-field and hyperfine interactions included within the dual-kinetic-balance method is employed. The nuclear magnetic shielding constant is an important ingredient for accurate determination of the nuclear magnetic moments from the high-precision g-factor measurements.

physics.atom-ph↗

arXiv2021

Relativistic calculations of the chemical properties of the superheavy element with $Z=119$ and its homologues

Relativistic calculations of the electronic structure of the superheavy element of the eighth period $-$ eka-francium ($Z=119$) and its homologues, which form the group of alkali metals, are performed in the framework of the configuration-interaction method and many-body perturbation theory using the basis of the Dirac-Fock-Sturm orbitals (DFS). The obtained values of the ionization potentials, electron affinities, and root-mean-square radii are compared with the corresponding values calculated within the non-relativistic approximation. A comparison with the available experimental data and the results of previous theoretical calculations is given as well. The analysis of the obtained results indicates a significant influence of the relativistic effects for the francium and eka-francium atoms, which leads to a violation of the monotonic behaviour of the listed above chemical properties as a function of the alkaline-element atomic number. In addition, the quantum electrodynamics corrections to the ionization potentials are evaluated by employing the model Lamb-shift operator (QEDMOD).

physics.atom-ph↗

arXiv2021

Ab initio calculations of energy levels in Be-like xenon: strong interference between electron-correlation and QED effects

The strong mixing of close levels with two valence electrons in Be-like xenon greatly complicates ab initio QED calculations beyond the first-order approximation. Due to a strong interplay between the electron-electron correlation and QED effects, the standard single-level perturbative QED approach may fail, even if it takes into account the second-order screened QED diagrams. In the present Letter, the corresponding obstacles are overcome by working out the QED perturbation theory for quasidegenerate states. The contributions of all the Feynman diagrams up to the second order are taken into account. The many-electron QED effects are rigorously evaluated in the framework of the extended Furry picture to all orders in the nuclear-strength parameter $αZ$. The higher-order electron-correlation effects are considered within the Breit approximation. The nuclear recoil effect is accounted for as well. The developed approach is applied to high-precision QED calculations of the ground and singly excited energy levels in Be-like xenon. The most accurate theoretical predictions for the binding and excitation energies are obtained. These results deviate from the most precise experimental value by $3σ$ but perfectly agree with a more recent measurement.

physics.atom-ph↗