arXiv subjects

D. Barrado

Publications and source records attributed to D. Barrado.

At least 19 recordsLinked to original sources

arXiv2026

JWST-SUPER I: New insights into irradiated warm Neptunes atmospheres from MIRI observations of HD 106315 c

Sulphur-bearing molecules have recently emerged as powerful tracers of atmospheric photochemistry in exoplanets observed with JWST. In several warm giant planets, SO$_2$ has been detected as a product of UV-driven chemical processing, suggesting a close connection between stellar irradiation, atmospheric metallicity, and sulphur chemistry. Whether these trends extend to Neptune-mass planets orbiting hotter stars remains largely unexplored. We investigate the atmospheric composition of the warm Neptune HD 106315 c, a Neptune-mass planet orbiting an F-type host star and subjected to a strong ultraviolet (UV) irradiation environment. Here, we report the low-resolution transmission spectrum between 5 and 12 $\mu$m of HD 106315 c obtained with the MIRI Low-Resolution Spectrometer on-board JWST. Our work also includes re-analysis of archival data from HST WFC3 G141 mode of HD 106315 c, as well as contemporaneous XMM and Swift monitoring of the star in the UV and X-ray wavelength ranges. Together with the archival HST WFC3 data, we detect H$_2$O and find tentative evidence for NH$_3$, retrieving abundances of $\log_{10}$(H$_2$O)$=-1.40^{+0.40}_{-0.74}$ and $\log_{10}$(NH$_3$)$=-2.47^{+0.57}_{-0.89}$, together with an isothermal terminator temperature of $747^{+150}_{-155}$ K. We place stringent upper limits on CH$_4$, SO$_2$, and CS$_2$, finding no robust evidence for any sulphur-bearing species despite the intense irradiation received by the planet. The inferred water abundance implies a strongly metal-enriched atmosphere. Elevated intrinsic temperatures can reconcile the non-detections of CH$_4$ and CS$_2$ through carbon--sulphur coupling, while the absence of SO$_2$ points toward a reduced atmospheric sulphur inventory or a near-solar to mildly enhanced C/O ratio, and places HD 106315 c near the transition between sulphur-rich and sulphur-poor chemical regimes.

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arXiv2026

Euclid Early Release Observations of the Barnard 30 dark cloud I. Brown dwarfs and planetary mass candidate members at the core of the association

This study aims to identify very low-mass members within the Barnard 30 dark cloud, with a particular focus on detecting objects in the substellar domain, including those within the planetary-mass regime. We employed deep photometric observations using data from the Euclid mission, incorporating advanced data processing techniques, in particular the DeNeb tool for optimized source detection. We also analyze multi-wavelength ancillary observations and perform a Spectral Energy Distribution analysis for each candidate member. In addition, low-resolution near-infrared spectroscopy was obtained for one candidate to further assess its nature and properties. Our initial photometric analysis yielded a initial sample of nearly one hundred candidate members in the substellar mass range. A subsample of 23 probable members, located close to the 3 Myr isochrone, has been identified. Thus, we have substantially expanded the known population of faint, cool sources associated with the region. Low resolution near-IR spectroscopic analysis of one candidate reveals an L2 spectral type with low gravity, consistent with a young ultra-cool dwarf. If its membership is confirmed, its estimated mass lies in the range 15-20 Mjup. These findings validate the reliability of our multi-wavelength photometric selection methodology. These results offer valuable insights into the low-mass end of the initial mass function (IMF) and demonstrate the effectiveness of Euclid in identifying brown dwarf and planetary-mass candidates in nearby, densely packed star-forming regions.

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arXiv2026

CHEOPS photometry from 2024 reveals a reversal in the transit-timing variations of AU Mic c

We present new CHEOPS transit observations of AU Mic b and AU Mic c obtained between June and September 2024, extending the baseline of transit-timing measurements of this young planetary system. For AU Mic b, the timing signal is well established, with a semi-amplitude (10 $\pm$ 3 min) and a characteristic modulation timescale (1168 $\pm$ 20 d) consistent with previous determinations. By contrast, the new CHEOPS data show that the large transit-timing deviation of AU Mic c reported previously was not sustained. After the steadily increasing timing trend observed in 2022 and 2023, the 2024 timings returned closer to the zero point of the observed-minus-calculated diagram, indicating a reversal of the previously reported behavior. For AU Mic c, both the transit-timing semi-amplitude (46 $\pm$ 26 min) and the characteristic modulation timescale (2150 $\pm$ 110 d) remain tentative. These results highlight the importance of continued long-term monitoring of the AU Mic system.

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arXiv2026

CAFE follow-up of TESS hot Jupiter candidates left behind: I. Five newly confirmed planets and a false positive

Hot Jupiters are key targets for understanding planet formation, migration, and atmospheres. Yet, most ground-based follow-up resources for the TESS mission are focused on confirming low-mass planet candidates, leaving many giant planets without mass determinations or definitive confirmation. We use the \cafe{} spectrograph at Calar Alto Observatory to monitor the radial velocity of stars hosting hot-Jupiter candidates that have received little follow-up, aiming to confirm their planetary nature. We present results for seven candidates. We monitored the radial velocity of TOI-603, TOI-1137, TOI-1837, TOI-2114, TOI-4492, TOI-5806, and TOI-5811, jointly modeling the CAFE radial velocities and TESS photometry to determine the nature and properties of the transiting objects. We confirm five new planets: TOI-603 b ($33.0^{+6.5}_{-6.2}$ M$_{\oplus}$, $16.2$ d), TOI-2114 b ($1.01^{+0.14}_{-0.12}$ M$_{\rm Jup}$, $6.2$ d), TOI-4492 b ($5.92^{+0.67}_{-0.64}$ M$_{\rm Jup}$, $4.4$ d), TOI-5806 b ($2.77^{+0.34}_{-0.32}$ M$_{\rm Jup}$, $3.2$ d), and TOI-5811 B b ($0.81^{+0.11}_{-0.10}$ M$_{\rm Jup}$, $6.3$ d). TOI-603 b lies in the "Neptune savanna", whereas the other four are hot Jupiters orbiting slightly evolved stars. We find TOI-5811.01 to be a planet transiting the nearby bound companion TOI-5811 B (hence TOI-5811 B b), and identify a stellar companion to TOI-5806 at a projected separation of 248 au, making both S-type planetary systems. TOI-1837.01 is an eclipsing binary, while TOI-1137.01 remains inconclusive. The five confirmed planets orbit bright stars (${\rm G}=8.6-10.2$~mag), and four are excellent targets for atmospheric studies, with transmission spectroscopy metrics above 90. These results highlight the importance of intensive follow-up observations to establish the nature of transiting planet candidates.

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arXiv2026

Chronos: Towards a self-consistent and absolute stellar age scale. I. A Bayesian hierarchical lithium-age model: Validation on the Pleiades cluster

Context. Establishing a self-consistent age scale for stellar populations requires physically well-calibrated chronometers. Among these, lithium-based diagnostics, particularly the lithium depletion boundary (LDB), provide one of the most robust age constraints for stellar populations in the low-mass regime. However, their application is limited by heterogeneous temperature scales and astrophysical dispersion, especially among FGK stars, where rotation can significantly affect lithium abundances. Aims. As a first step towards a self-consistent age scale, our aim has been to formulate Chronos, the first version of a Bayesian hierarchical lithium-based age-dating model combined with a neural network trained on stellar evolutionary models. Methods. We implemented a Bayesian hierarchical model that jointly infers stellar effective temperatures, lithium abundances, and the global age of a stellar association. The theoretical LDB is provided by a pre-trained multilayer perceptron based on BT--Settl evolutionary models. The model incorporates a temperature-dependent transition between fully convective ultra-cool dwarfs (UCDs) and FGKM dwarf stars, together with a two-component FGK mixture to account for rotation-induced lithium enhancement. We applied the method to the Pleiades cluster and performed a validation using synthetic datasets. Results. For the Pleiades cluster, Chronos yields a posterior age distribution centred at $\mathrm{Age}=124.53_{-2.70}^{+3.34}$ Myr, consistent with classical LDB estimates, while simultaneously constraining both global and stellar-level rotation parameters. Conclusions. This work demonstrates that lithium-based stellar chronology can be recast as a coherent hierarchical inference problem, providing a flexible and statistically robust framework for making age determinations for young (1--600 Myr) stellar populations.

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arXiv2026

Oxygen and nitrogen isotopologues on cold COCONUTS-2b observed with MIRI/MRS

Linking the composition of gas giant planets to their formation paths has long been a goal in exoplanet science. Especially, cold gas giants with temperatures below $\sim$500K have been out of reach for detailed atmospheric characterization. With JWST, however, we can reach high signal-to-noise (S/N) spectra for such cool worlds and can can measure not only their main trace gas abundances, but even their isotopic content unlocking new possibilities in linking them to their formation paths. In this study, we present the spectrum of one of the coldest planetary-mass companions COCONUTS-2b ($\mathrm{T_{eff}}\approx$480K, separation of $\sim$6400 au from its M dwarf host star) obtained with the Mid-InfraRed Instrument Medium Resolution Spectrometer (MIRI/MRS). Combining the MIRI and archival Gemini/FLAMINGOS-2 data sets, we aim to characterize the chemical composition and physical structure of its frigid atmosphere, setting the stage to uncover insights on the formation of COCONUTS-2b. For the first time on a MIRI/MRS data set, we use the full spectral resolution of MIRI/MRS and perform atmospheric retrievals to unlock the search for faint absorption features by rare molecules and isotopologues. The latter are identified using a leave-one-out analysis and Bayes factor comparison. We robustly detect three isotopologues, namely $^{15}$NH$_3$, H$_2^{18}$O and H$_2^{17}$O in the atmosphere of COCONUTS-2b. We find the first clear evidence of oxygen isotopes in water in a cold companion. This data set demonstrates the capability of MIRI/MRS to characterize such cold planetary-mass companion's atmospheres with respect to their compositional and isotopic content. In the future, the constrained elemental and isotope ratios provide a unique avenue in comparing with the host star's abundances and eventually in tracing formation scenarios.

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arXiv2026

The multi-planet system TOI-5624: Four transiting sub-Neptunes with an outer companion revealed by transit-timing variations

Following the 2022 alert of a TESS object of interest transiting TOI-5624 (a G7 V star $\sim$100 pc away), a CHEOPS campaign in 2023 detected four planetary signals at $P_b\approx3.4$, $P_c\approx7.9$, $P_d\approx13.7$, and $P_e\approx21.5$ days, later confirmed by additional TESS and CHEOPS photometry in 2024-2025. After analysing the TESS & CHEOPS photometric data, we extracted and modelled the HARPS-N & SOPHIE RV time series using two independent methodologies both within an MCMC framework. We further integrated the N-body equations of motion, while simultaneously fitting the transit times and the detrended RVs, to dynamically characterise the system. We present the discovery of four transiting sub-Neptunes with radii of $R_b=2.314\pm0.035 R_{\oplus}$, $R_c=2.474\pm0.042 R_{\oplus}$, $R_d=3.584_{-0.050}^{+0.051} R_{\oplus}$, and $R_e=3.247_{-0.043}^{+0.042} R_{\oplus}$ and masses of $M_b=9.4\pm1.4 M_{\oplus}$, $M_c=4.8\pm1.9 M_{\oplus}$, $M_d=4.9\pm2.2 M_{\oplus}$, and $M_e=8.9_{-3.0}^{+2.9} M_{\oplus}$. Our photometric analysis reveals that the outermost transiting planet TOI-5624 e shows significant TTVs. We find a robust Keplerian signal in the RV time series close to the 2:1 period commensurability with TOI-5624 e, which explains the TTV pattern exhibited by TOI-5624 e according to our dynamical analysis. We label this non-transiting planet as TOI-5624 f and find its minimum mass to be $M_f\sin{i_f}=13.0\pm3.7 M_{\oplus}$. Among the known systems hosting more than four planets, the remarkable precision with which the radii have been measured (<1.7%) and the firm assessment (>3$\sigma$) of the mass for at least three planets has been previously reached only for TRAPPIST-1. Additional photometric observations will enable a better sample of the TTV modulation and a more robust dynamical determination of the masses.

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arXiv2026

Information content of JWST transmission spectroscopy of the exoplanet HAT-P-12b from the optical to the mid-infrared

The James Webb Space Telescope (JWST) provides low- to medium-resolution spectra with unprecedented precision and broad near- to mid-infrared wavelength coverage, enabling detailed characterization of exoplanet atmospheres. We present a new JWST NIRISS SOSS transit observation of the warm sub-Saturn HAT-P-12b. Combined with NIRSpec G395M and MIRI LRS data, this enables an assessment of the information content across JWST instruments over the full accessible wavelength range. The NIRISS data were reduced and the impact of reduction choices on the transmission spectrum evaluated. Atmospheric retrievals were performed for all JWST combinations, with selected cases including archival HST data. Four molecules are significantly detected: H2O, CO2, CO, and H2S. Except for H2O, detections require NIRSpec coverage, while H2S is only detected in multi-instrument retrievals. NIRISS SOSS is essential to establish robust evidence for non-gray cloud behavior. A moderate scattering slope (p < 4) is consistently retrieved. Single-instrument retrievals tend to overestimate abundances, whereas combined JWST datasets yield more consistent constraints. The C/O ratio remains sensitive to differences between NIRSpec reductions. Results broadly agree with studies of WASP-39b, but highlight variations in information content across exoplanet types.

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arXiv2026

IRAM 04191+1522: a compact proto-brown dwarf binary candidate

Very low-luminosity objects in nearby star-forming regions have been identified as promising proto-brown dwarf candidates. The study of their multiplicity can shed light on the dominant formation mechanism of these substellar objects. We aim at studying the multiplicity of the very low luminosity object IRAM 04191+1522. To do so, we have obtained 0.89mm ALMA observations with a very extended configuration, achieving an angular resolution of ~0.04 arcsec (6 au at 140 pc). We have complemented our data with new VLA observations, and ALMA archival data at 1.3mm. As a result, we resolve IRAM04191+1522 into a close binary candidate for the first time. The binary is detected in the ALMA continuum data with a projected separation of ~80 mas, or 11 au at a distance of 140 pc. The two sources are oriented in the East-West direction, with the eastern component being brighter and more extended than the western one, which is marginally resolved. The analysis of C18O(2-1) archival data reveals gaseous material in rotation around the binary, presumably from a circumbinary disk with ~27 au of radius centered on the faintest ALMA component. A fit of the position-velocity diagram allows us to estimate a total dynamical mass for the system of 50+-40 MJup. Therefore, we classify IRAM04191 as a tight proto-brown dwarf binary candidate. The VLA data reveals the detection of a single object closer to the western ALMA source, and with a spectral index consistent with a radio jet.

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arXiv2025

Why the Northern Hemisphere Needs a 30-40 m Telescope and the Science at Stake. How do Planetary Systems Form?

The detection and characterization of protoplanets in protoplanetary disks around young stars is emerging as a transformative field that will redefine our understanding of how planetary systems form. While current facilities have revealed the diversity of mature exoplanets and the complex structures of disks, we still lack the crucial observational link between them: a statistically meaningful census of planets caught in the act of formation. This white paper argues that such a breakthrough requires access to the nearest and most informative star-forming regions, roughly half of which are poorly accessible or entirely unreachable from Cerro Armazones. Although the ELT alone will strongly impact our knowledge of planet formation, its location prevents Europe from fully exploiting the necessary parameter space. A 30-40 m telescope in the northern hemisphere is therefore essential for obtaining diffraction-limited imaging of protoplanets and disks across the entire sky, enabling robust demographics, exploiting synergies with ngVLA, Gaia, and other facilities covering the north, and ensuring that Europe remains at the forefront of the planet-formation revolution in the coming decades.

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arXiv2025

Giant Outer Transiting Exoplanet Mass (GOTEM) Survey.VII. TOI-6041: a multi-planet system including a warm Neptune exhibiting strong TTVs

We present the characterization of the TOI-6041 system, a bright ($V = 9.84 \pm 0.03$) G7-type star hosting at least two planets. The inner planet, TOI-6041b, is a warm Neptune with a radius of $4.55^{+0.18}_{-0.17}\,R_\oplus$, initially identified as a single-transit event in \textit{TESS} photometry. Subsequent observations with \textit{TESS} and \textit{CHEOPS} revealed additional transits, enabling the determination of its $26.04945^{+0.00033}_{-0.00034}$~d orbital period and the detection of significant transit timing variations (TTVs), exhibiting a peak-to-peak amplitude of about 1~hour. Radial velocity (RV) measurements obtained with the APF spectrographs allow us to place a $3\sigma$ upper mass limit of $28.9\,M_\oplus$ on TOI-6041b. In addition, the RV data reveal a second companion, TOI-6041c, on an 88~d orbit, with a minimum mass of $0.25\,M_{\mathrm{Jup}}$. A preliminary TTV analysis suggests that the observed variations could be caused by gravitational perturbations from planet c; however, reproducing the observed amplitudes requires a relatively high eccentricity of about 0.3 for planet c. Our dynamical stability analysis indicates that such a configuration is dynamically viable and places a $1\sigma$ upper limit on the mass of TOI-6041c at $0.8\,M_{\mathrm{Jup}}$. An alternative is the presence of a third, low-mass planet located between planets b and c, or on an inner orbit relative to planet b -- particularly near a mean-motion resonance with planet b -- which could account for the observed variations. These findings remain tentative, and further RV and photometric observations are essential to better constrain the mass of planet b and to refine the TTV modeling, thereby improving our understanding of the system's dynamical architecture.

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arXiv2025

HARPS-N, TESS, and CHEOPS discover a transiting sub-Neptune and two outer companions around the bright solar analogue HD 85426

We provide a detailed characterisation of the planetary system orbiting HD 85426 (TOI-1774). This bright G-type star ($M_{\ast}$: 0.99 $\text{M}_{\odot}$; $R_{\ast}$: 1.13 $\text{R}_{\odot}$; age: 7.4 Gyr; V mag: 8.25) hosts a transiting sub-Neptune, HD 85426 b, with an orbital period of 16.71 days and a blackbody equilibrium temperature of $824^{+11}_{-11}$ K. By jointly analysing HARPS-N RVs, TESS, and CHEOPS photometric data and using two different stellar activity mitigation techniques, we constrain planet b's mass to $6.0^{+1.5}_{-1.6}$ $\text{M}_{\oplus}$ and $8.5^{+1.3}_{-1.4} $ $\text{M}_{\oplus}$, depending on the mitigation technique. We investigate the dependence of these results on the priors, data selection, and inclusion of other Keplerians in the modelling. Using this approach, we identify the presence of two non-transiting planetary companions with minimum masses near 10 $\text{M}_{\oplus}$ and orbital periods of 35.7 and 89 days. Additionally, we reject the initial hypothesis that the 35.7-day periodic signal was due to stellar activity. We also determine HD 85426 b's radius to be $2.78^{+0.05}_{-0.04}$ $\text{R}_{\oplus}$ and compute a transmission spectroscopy metric in the range of 82 to 115, making this planet a highly valuable target for atmospheric characterisation.

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arXiv2025

Transit Timing Variations in HIP 41378: CHEOPS and TESS confirm a non-transiting sixth planet in the system

In multiple-planet systems, gravitational interactions of exoplanets could lead to transit timing variations (TTVs), whose amplitude becomes significantly enhanced when planets are in or near mean-motion resonances (MMRs). In cases where both TTVs and radial velocity (RV) measurements are available, combined analysis can break degeneracies and provide robust planetary and system characterization, even detecting non-transiting planets. In this context, HIP 41378 hosts five confirmed transiting planets with periods ranging from 15 to over 542 days, providing a unique dynamical laboratory for investigating wide multi-planet systems analogous to the Solar System. In this study, we present an intensive space-based photometric follow-up of HIP 41378, combining 15 new CHEOPS observations with eight TESS sectors, alongside data from K2, Spitzer, HST, and HARPS. We dynamically modeled the TTVs and RV signals of the two inner sub-Neptunes via N-body integration. These planets, HIP 41378 b ($P_{b}$ = 15.57 days) and HIP 41378 c ($P_{c}$ = 31.71 days), are close to ($\Delta\sim1.8$ %) a 2:1 period commensurability. We report a clear detection of TTVs with amplitudes of 20 mins for planet b and greater than 3 hrs for planet c. We dynamically confirm the planetary nature of HIP 41378 g, a non-transiting planet with a period of about 64 days and a mass of about 7 $M_{\oplus}$, close to a 2:1 commensurability with planet c, suggesting a possible MMR chain in the inner system. Our precise determination of the masses, eccentricities, and radii of HIP 41378 b and c enabled us to investigate their possible volatile-rich compositions. Finally, by leveraging on the last TESS sectors we constrained the period of HIP 41378 d to three possible aliases ($P_{d} =$ 278, 371, and 1113 days) suggesting that the system could be placed in a double quasi resonant chain, highlighting its complex dynamical architecture.

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arXiv2025

A four-planet system orbiting the old thick disk star TOI-1203

TOI-1203 is a bright (V=8.6) G3 V star known to host a transiting warm sub-Neptune on a 25.5 d orbit. Here we report on an intensive high-precision radial velocity and photometric follow-up campaign carried out with the HARPS spectrograph and the CHEOPS space telescope. We found that TOI-1203 has an enhancement of $\alpha$ elements relative to iron of [$\alpha$/Fe]=$0.21\pm0.04$. With an age of $\sim$12.5 Gyr, TOI-1203 belongs to the old, $\alpha$-element enhanced stellar population of the galactic thick disk. We spectroscopically confirmed the planetary nature of the 25.5 d sub-Neptune TOI-1203 d, measured its mass ($M_{d}=7.39\pm0.62~M_{\oplus}$) and refined its radius ($R_{d}=2.918_{-0.045}^{+0.046}~R_{\oplus}$). We discovered the presence of an additional transiting super-Earth on a 4.2 d orbit (TOI-1203 b) with a mass of $M_{b}=3.51_{-0.32}^{+0.33}~M_{\oplus}$ and a radius of $R_{b}=1.520_{-0.046}^{+0.045}~R_{\oplus}$. We also revealed the presence of two additional low-mass planets at 13.1 d and 204.6 d (TOI-1203 c and e), with minimum masses of $5.46_{-0.50}^{+0.51}~M_{\oplus}$ and $42.10_{-1.78}^{+1.83}~M_{\oplus}$. We found that the outer planet TOI-1203 e lies on an eccentric orbit with $e_{e}=0.152\pm0.029$. We performed a stability analysis of the system confirming that there are configurations consistent with the observed parameters that are dynamically stable over billion-year timescales. While analyzing the HARPS time series, we discovered that the FWHM of the HARPS cross-correlation function shows a significant long-period signal ($\sim$615 d) that has no counterpart in the radial velocity data or in the remaining HARPS ancillary time series. We significantly detected the same signal in the FWHM of the Th-Ar calibration lines used to compute the nightly wavelength solution, and attributed this systematic effect to a long-term variation of the HARPS instrumental profile.

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arXiv2025

Improved characterization of the TOI-2141 system: a dense sub-Neptune with non-transiting inner and outer companions

We aim to refine the fundamental parameters of the TOI-2141 planetary system, which includes a transiting sub-Neptune orbiting a Sun-like star in a relatively long orbit of 18.26 days, by combining new photometric and spectroscopic observations. We analyze new space-based photometry from TESS and CHEOPS as well as 61 radial velocity measurements from HARPS-N. We perform individual and joint photometric and RV analyses using several modeling tools within a Bayesian model comparison framework. We refine the radius and mass of the transiting planet TOI-2141 b to 3.15 $\pm$ 0.04 $R_\oplus$ and 20.1 $\pm$ 1.6 $M_\oplus$, respectively, five and two times more precise than the previously reported values. Our radial velocity analysis reveals two additional non-transiting companions with orbital periods of 5.46 and 60.45 days. Despite the innermost planet's high geometric transit probability, we find no evidence for transits in the photometric data. The bulk properties of TOI-2141 b suggest a significant volatile envelope atop an Earth-like core, with modeling indicating a hydrogen-rich atmosphere that may have experienced mild photoevaporation over the system's history. Planets b and c must exhibit a modest mutual inclination of at least 2.4 degrees.

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arXiv2025

Detection of CO$_2$, CO, and H$_2$O in the atmosphere of the warm sub-Saturn HAT-P-12b

The chemical composition of warm gas giant exoplanet atmospheres (with Teq < 1000 K) is not well known due to the lack of observational constraints. HAT-P-12 b is a warm, sub-Saturn-mass transiting exoplanet that is ideal for transmission spectroscopy. One transit of HAT-P-12 b was observed with JWST NIRSpec in the 2.87--5.10 $\mu$m range with a resolving power of $\sim$1000. The JWST data are combined with archival observations from HST WFC3 covering the 1.1--1.7 $\mu$m range. The data were analysed using two data reduction pipelines and two atmospheric retrieval tools. Atmospheric simulations using chemical forward models were performed. CO2, CO, and H2O are detected at 12.2, 4.1, and 6.0 $\sigma$ confidence, respectively. Their volume mixing ratios are consistent with an atmosphere of $\sim10\times$ solar metallicity and production of CO2 by photochemistry. CH4 is not detected and seems to be lacking, which could be due to a high intrinsic temperature with strong vertical mixing or other phenomena. SO2 is also not detected and its production seems limited by low upper atmosphere temperatures ($\sim$500 K at $P<10^{-3}$ bar derived from one-dimensional retrievals), insufficient to produce it in detectable quantities ($\gtrsim$ 800 K required according to photochemical models). Retrievals indicate the presence of clouds between 2 and 269 mbar. This study points towards an atmosphere for HAT-P-12 b that could be enriched in carbon and oxygen with respect to its host star. When including the production of CO2 via photochemistry, an atmospheric metallicity that is close to Saturn's can explain the observations. Metallicities inferred for other gas giant exoplanets based on their CO2 mixing ratios may need to account for its photochemical production pathways. This may impact studies on mass-metallicity trends and links between exoplanet atmospheres, interiors, and formation history.

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arXiv2025

Evidence for SiO cloud nucleation in the rogue planet PSO J318

Silicate clouds are known to significantly impact the spectra of late L-type brown dwarfs, with observable absorption features at ~ 10 micron. JWST has reopened our window to the mid-infrared with unprecedented sensitivity, bringing the characterization of silicates into focus again. Using JWST, we characterize the planetary-mass brown dwarf PSO J318.5338-22.8603, concentrating on any silicate cloud absorption the object may exhibit. PSO J318's spectrum is extremely red, and its flux is variable, both of which are likely hallmarks of cloud absorption. We present JWST NIRSpec PRISM, G395H, and MIRI MRS observations from 1-18 micron. We introduce a method based on PSO J318's brightness temperature to generate a list of cloud species that are likely present in its atmosphere. We then test for their presence with petitRADTRANS retrievals. Using retrievals and grids from various climate models, we derive bulk parameters from PSO J318's spectra, which are mutually compatible. Our retrieval results point to a solar to slightly super-solar atmospheric C/O, a slightly super-solar metallicity, and a 12C/13C below ISM values. The atmospheric gravity proves difficult to constrain for both retrievals and grid models. Retrievals describing the flux of PSO J318 by mixing two 1-D models (``two-column models'') appear favored over single-column models; this is consistent with PSO J318's variability. The JWST spectra also reveal a pronounced absorption feature at 10 micron. This absorption is best reproduced by introducing a high-altitude cloud layer of small (<0.1 micron), amorphous SiO grains. The retrieved particle size and location of the cloud is consistent with SiO condensing as cloud seeding nuclei. High-altitude clouds comprised of small SiO particles have been suggested in previous studies, therefore the SiO nucleation we potentially observe in PSO J318 could be a more wide-spread phenomenon.

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arXiv2025

JWST/MIRI observations of the young TWA 27 system: hydrocarbon disk chemistry, silicate clouds, evidence for a CPD

The Mid-Infrared Instrument (MIRI) on the James Webb Space Telescope (JWST) enables the characterisation of young self-luminous gas giants at previously inaccessible wavelengths, revealing physical processes in gas, dust, and clouds. We characterise the young planetary system TWA 27 (2M1207) in the mid-infrared (MIR), studying the atmosphere and disk spectra of the M9 brown dwarf TWA 27A and its L6 planetary-mass companion TWA 27b. We obtained data with the MIRI Medium Resolution Spectrometer (MRS) from 4.9 to 20 um, and MIRI Imaging in the F1000W and F1500W filters. We applied high-contrast imaging methods to extract the companion's spectral energy distribution up to 15 um at 0.78 arcsec separation and a contrast of 60. Combining these with published JWST/NIRSpec spectra, we analysed the 1-20 um range using self-consistent atmospheric grids and 0D slab models for molecular disk emission. The atmosphere of TWA 27A is well fitted by a BT-SETTL model with Teff 2780 K, log g 4.3, plus a 740 K blackbody for the inner disk rim. The disk shows at least 11 organic molecules, with no water or silicate dust emission detected. The atmosphere of TWA 27b is matched by a Teff 1400 K low-gravity model with extinction, best fit by the ExoREM grid. MIRI spectra and photometry for TWA 27b reveal a silicate cloud absorption feature between 8-10 um and significant (>5 sigma) infrared excess at 15 um consistent with circumplanetary disk emission. These MIRI observations provide new insights into TWA 27, revealing diverse features to study the formation and evolution of circumplanetary disks and young dusty atmospheres.

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