arXiv subjects

D. C. B. Whittet

Publications and source records attributed to D. C. B. Whittet.

At least 19 recordsLinked to original sources

arXiv2022

SpeX near-infrared spectroscopic extinction curves in the Milky Way

Interstellar dust extinction curves provide valuable information about dust properties, including the composition and size of the dust grains, and are essential to correct observations for the effects of interstellar dust. In this work, we measure a representative sample of near-infrared (NIR; 0.8-5.5 $μ$m) spectroscopic extinction curves for the first time, enabling us to investigate the extinction at wavelengths where it is usually only measured in broad photometric bands. We use IRTF/SpeX spectra of a sample of reddened and comparison stars to measure 15 extinction curves with the pair method. Our sample spans A(V) values from 0.78 to 5.65 and R(V) values from 2.43 to 5.33. We confirm that the NIR extinction curves are well fit by a power law, with indices and amplitudes differing from sight line to sight line. Our average diffuse NIR extinction curve can be represented by a single power law with index $α= 1.7$, but because of the sight line-to-sight line variations, the shape of any average curve will depend on the parental sample. We find that most of the variation in our sample can be linked to the ratio of total-to-selective extinction R(V), a rough measurement of the average dust grain size. Two sight lines in our sample clearly show the ice extinction feature at 3 $μ$m, which can be fitted by a modified Drude profile. We find tentative ice detections with slightly over 3$σ$ significance in two other sight lines. In our average diffuse extinction curve, we measure a 3$σ$ upper limit of A(ice)/A(V) = 0.0021 for this ice feature.

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arXiv2021

Milky Way Mid-Infrared Spitzer Spectroscopic Extinction Curves: Continuum and Silicate Features

We measured the mid-infrared (MIR) extinction using Spitzer photometry and spectroscopy (3.6--37 micron) for a sample of Milky Way sightlines (mostly) having measured ultraviolet extinction curves. We used the pair method to determine the MIR extinction that we then fit with a power law for the continuum and modified Drude profiles for the silicate features. We derived 16 extinction curves having a range of A(V) (1.8-5.5) and R(V) values (2.4-4.3). Our sample includes two dense sightlines that have 3 micron ice feature detections and weak 2175 A bumps. The average A(lambda)/A(V) diffuse sightline extinction curve we calculate is lower than most previous literature measurements. This agrees better with literature diffuse dust grain models, though it is somewhat higher. The 10 micron silicate feature does not correlate with the 2175 A bump, for the first time providing direct observational confirmation that these two features arise from different grain populations. The strength of the 10 micron silicate feature varies by $\sim$2.5 and is not correlated with A(V) or R(V). It is well fit by a modified Drude profile with strong correlations seen between the central wavelength, width, and asymmetry. We do not detect other features with limits in A(lambda)/A(V) units of 0.0026 (5--10 micron), 0.004 (10--20 micron), and 0.008 (20-40 micron). We find that the standard prescription of estimating R(V) from C times E(K_s-V)/E(B-V) has C = -1.14 and a scatter of $\sim$7%. Using the IRAC 5.6 micron band instead of K_s gives C = -1.03 and the least scatter of $\sim$3\%.

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arXiv2013

Chemical and Physical Conditions in Molecular Cloud Core DC 000.4-19.5 (SL42) in Corona Australis

Chemical reactions in starless molecular clouds are heavily dependent on interactions between gas phase material and solid phase dust and ices. We have observed the abundance and distribution of molecular gases in the cold, starless core DC 000.4-19.5 (SL42) in Corona Australis using data from the Swedish ESO Submillimeter Telescope. We present column density maps determined from measurements of C18O(J=2-1,1-0) and N2H+(J=1-0) emission features. Herschel data of the same region allow a direct comparison to the dust component of the cloud core and provide evidence for gas phase depletion of CO at the highest extinctions. The dust color emperature in the core calculated from Herschel maps ranges from roughly 10.7 to 14.0 K. This range agrees with the previous determinations from Infrared Space Observatory and Planck observations. The column density profile of the core can be fitted with a Plummer-like density distribution approaching n(r) ~ r^{-2} at large distances. The core structure deviates clearly from a critical Bonnor-Ebert sphere. Instead, the core appears to be gravitationally bound and to lack thermal and turbulent support against the pressure of the surrounding low-density material: it may therefore be in the process of slow contraction. We test two chemical models and find that a steady-state depletion model agrees with the observed C18O column density profile and the observed N(C18O) versus AV relationship.

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arXiv2011

Ices in the Quiescent IC 5146 Dense Cloud

This paper presents spectra in the 2 to 20 micron range of quiescent cloud material located in the IC 5146 cloud complex. The spectra were obtained with NASA's Infrared Telescope Facility (IRTF) SpeX instrument and the Spitzer Space Telescope's Infrared Spectrometer. We use these spectra to investigate dust and ice absorption features in pristine regions of the cloud that are unaltered by embedded stars. We find that the H2O-ice threshold extinction is 4.03+/-0.05 mag. Once foreground extinction is taken into account, however, the threshold drops to 3.2 mag, equivalent to that found for the Taurus dark cloud, generally assumed to be the touchstone quiescent cloud against which all other dense cloud and embedded young stellar object observations are compared. Substructure in the trough of the silicate band for two sources is attributed to CH3OH and NH3 in the ices, present at the ~2% and ~5% levels, respectively, relative to H2O-ice. The correlation of the silicate feature with the E(J-K) color excess is found to follow a much shallower slope relative to lines of sight that probe diffuse clouds, supporting the previous results by Chiar et al. (2007).

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arXiv2010

The Uptake of Interstellar Gaseous CO into Icy Grain Mantles in a Quiescent Dark Cloud

Data from the Five College Radio Astronomy Observatory CO Mapping Survey of the Taurus molecular cloud are combined with extinction data for a sample of 292 background field stars to investigate the uptake of CO from the gas to icy grain mantles on dust within the cloud. On the assumption that the reservoir of CO in the ices is well represented by the combined abundances of solid CO and solid CO2 (which forms by oxidation of CO on the dust), we find that the total column density (gas + solid) correlates tightly with visual extinction (Av) over the range 5 < Av < 30 mag, i.e., up to the highest extinctions covered by our sample. The mean depletion of gas-phase CO increases monotonically from negligible levels for Av < 5 to approximately 30 percent at Av = 10 and 60 percent at Av = 30. As these results refer to line-of-sight averages, they must be considered lower limits to the actual depletion at loci deep within the cloud, which may approach 100 percent. We show that it is plausible for such high levels of depletion to be reached in dense cores on timescales of order 0.6 Myr, comparable with their expected lifetimes. Dispersal of cores during star formation may be effective in maintaining observable levels of gaseous CO on the longer timescales estimated for the age of the cloud.

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arXiv2009

Oxygen Depletion in the Interstellar Medium: Implications for Grain Models and the Distribution of Elemental Oxygen

This paper assesses the implications of a recent discovery (Jenkins 2009) that atomic oxygen is being depleted from diffuse interstellar gas at a rate that cannot be accounted for by its presence in silicate and metallic oxide particles. To place this discovery in context, the uptake of elemental O into dust is considered over a wide range of environments, from the tenuous intercloud gas and diffuse clouds sampled by the depletion observations to dense clouds where ice mantles and gaseous CO become important reservoirs of O. The distribution of O in these contrasting regions is quantified in terms of a common parameter, the mean number density of hydrogen. At the interface between diffuse and dense phases (just before the onset of ice mantle growth) as much as 160 ppm of the O abundance is unaccounted for. If this reservoir of depleted oxygen persists to higher densities it has implications for the oxygen budget in molecular clouds, where a shortfall of the same order is observed. Of various potential carriers, the most plausible appears to be a form of O-bearing carbonaceous matter similar to the organics found in cometary particles returned by the Stardust mission. The "organic refractory" model for interstellar dust is re-examined in the light of these findings, and it is concluded that further observations and laboratory work are needed to determine whether this class of material is present in quantities sufficient to account for a significant fraction of the unidentified depleted oxygen.

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arXiv2009

Near-Infrared Circular Polarimetry and Correlation Diagrams in the Orion BN/KL Region: Contribution of Dichroic Extinction

We present a deep circular polarization image of the Orion BN/KL nebula in the Ks band and correlations of circular polarization, linear polarization, and H-Ks color representing extinction. The image of circular polarization clearly reveals the quadrupolar structure around the massive star IRc2, rather than BN. H-Ks color is well correlated with circular polarization. A simple relation between dichroic extinction, color excess, circular and linear polarization is derived. The observed correlation between the Stokes parameters and the color excess agrees with the derived relation, and suggests a major contribution of dichroic extinction to the production of circular polarization in this region, indicating the wide existence of aligned grains.

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arXiv2009

The Nature of Carbon Dioxide Bearing Ices in Quiescent Molecular Clouds

The properties of the ices that form in dense molecular clouds represent an important set of initial conditions in the evolution of interstellar and preplanetary matter in regions of active star formation. Of the various spectral features available for study, the bending mode of solid CO2 near 15 microns has proven to be a particularly sensitive probe of physical conditions, especially temperature. We present new observations of this absorption feature in the spectrum of Q21-1, a background field star located behind a dark filament in the Cocoon Nebula (IC5146). We show the profile of the feature be consistent with a two-component (polar + nonpolar) model for the ices, based on spectra of laboratory analogs with temperatures in the range 10-20K. The polar component accounts for 85% of the CO2 in the line of sight. We compare for the first time 15 micron profiles in three widely separated dark clouds (Taurus, Serpens and IC5146), and show that they are indistinguishable to within observational scatter. Systematic differences in the observed CO2/H2O ratio in the three clouds have little or no effect on the 15 micron profile. The abundance of elemental oxygen in the ices appears to be a unifying factor, displaying consistent behavior in the three clouds. We conclude that the ice formation process is robust and uniformly efficient, notwithstanding compositional variations arising from differences in how the O is distributed between the primary species (H2O, CO2 and CO) in the ices.

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arXiv2008

A Catalog of Background Stars Reddened by Dust in the Taurus Dark Clouds

Normal field stars located behind dense clouds are a valuable resource in interstellar astrophysics, as they provide continua in which to study phenomena such as gas-phase and solid-state absorption features, interstellar extinction and polarization. This paper reports the results of a search for highly reddened stars behind the Taurus Dark Cloud complex. We use the Two Micron All Sky Survey (2MASS) Point Source Catalog to survey a 50 sq deg area of the cloud to a limiting magnitude of K = 10.0. Photometry in the 1.2-2.2 micron passbands from 2MASS is combined with photometry at longer infrared wavelengths (3.6-12 micron) from the Spitzer Space Telescope and the Infrared Astronomical Satellite to provide effective discrimination between reddened field stars and young stellar objects (YSOs) embedded in the cloud. Our final catalog contains 248 confirmed or probable background field stars, together with estimates of their total visual extinctions, which span the range 2-29 mag. We also identify the 2MASS source J04292083+2742074 (IRAS 04262+2735) as a previously unrecognized candidate YSO, based on the presence of infrared emission greatly in excess of that predicted for a normal reddened photosphere at wavelengths >5 microns.

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arXiv2007

The Efficiency of Grain Alignment in Dense Interstellar Clouds: A Reassessment of Constraints from Near Infrared Polarization

A detailed study of interstellar polarization efficiency toward molecular clouds is used to attempt discrimination between grain alignment mechanisms in dense regions of the ISM. Background field stars are used to probe polarization efficiency in quiescent regions of dark clouds, yielding a dependence on visual extinction well-represented by a power law. No significant change in this behavior is observed in the transition region between the diffuse outer layers and dense inner regions of clouds, where icy mantles are formed, and we conclude that mantle formation has little or no effect on the efficiency of grain alignment. Young stellar objects generally exhibit greater polarization efficiency compared with field stars at comparable extinctions, displaying enhancements by factors of up to 6. Of the proposed alignment mechanisms, that based on radiative torques appears best able to explain the data. The attenuated external radiation field accounts for the observed polarization in quiescent regions, and radiation from the embedded stars themselves may enhance alignment in the lines of sight to YSOs. Enhancements in polarization efficiency observed in the ice features toward several YSOs are of greatest significance, as they demonstrate efficient alignment in cold molecular clouds associated with star formation.

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arXiv2007

Fully Sampled Maps of Ices and Silicates in Front of Cepheus A East with Spitzer

We report the first fully sampled maps of the distribution of interstellar CO2 ices, H2O ices and total hydrogen nuclei, as inferred from the 9.7 micron silicate feature, toward the star-forming region Cepheus A East with the IRS instrument onboard the Spitzer Space Telescope. We find that the column density distributions for these solid state features all peak at, and are distributed around, the location of HW2, the protostar believed to power one of the outflows observed in this star-forming region. A correlation between the column density distributions of CO2 and water ice with that of total hydrogen indicates that the solid state features we mapped mostly arise from the same molecular clumps along the probed sight lines. We therefore derive average CO2 ice and water ice abundances with respect to the total hydrogen column density of X(CO2)_ice~1.9x10^-5 and X(H2O)_ice~7.5x10^-5. Within errors, the abundances for both ices are relatively constant over the mapped region exhibiting both ice absorptions. The fraction of CO2 ice with respect to H2O ice is also relatively constant at a value of 22% over that mapped region. A clear triple-peaked structure is seen in the CO2 ice profiles. Fits to those profiles using current laboratory ice analogs suggest the presence of both a low-temperature polar ice mixture and a high-temperature methanol-rich ice mixture along the probed sightlines. Our results further indicate that thermal processing of these ices occurred throughout the sampled region.

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arXiv2007

The Relationship between the Optical Depth of the 9.7 micron Silicate Absorption Feature and Infrared Differential Extinction in Dense Clouds

We have examined the relationship between the optical depth of the 9.7 micron silicate absorption feature (tau_9.7) and the near-infrared color excess, E(J-Ks) in the Serpens, Taurus, IC 5146, Chameleon I, Barnard 59, and Barnard 68 dense clouds/cores. Our data set, based largely on Spitzer IRS spectra, spans E(J-Ks)=0.3 to 10 mag (corresponding to visual extinction between about 2 and 60 mag.). All lines of sight show the 9.7 micron silicate feature. Unlike in the diffuse ISM where a tight linear correlation between the 9.7 micron silicate feature optical depth and the extinction (Av) is observed, we find that the silicate feature in dense clouds does not show a monotonic increase with extinction. Thus, in dense clouds, tau_9.7 is not a good measure of total dust column density. With few exceptions, the measured tau_9.7 values fall well below the diffuse ISM correlation line for E(J-Ks) > 2 mag (Av >12 mag). Grain growth via coagulation is a likely cause of this effect.

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arXiv2006

Spectropolarimetry of the 3.4 micron Feature in the Diffuse ISM toward the Galactic Center Quintuplet Cluster

Aliphatic hydrocarbons exhibit an absorption feature at 3.4 micron observed toward sources that sample diffuse regions of the interstellar medium. The absorbers responsible for this feature are assumed to reside in some component of interstellar dust, but the physical nature of the particles (size, shape, structure, etc.) is uncertain. Observations of interstellar polarization provide discrimination. Since the grains that carry the silicate absorption feature are known to be aligned, polarization across the 3.4 micron hydrocarbon feature can be used to test the silicate core-organic refractory mantle grain theory. Although the 3.4 micron feature has been observed to be devoid of polarization for one line of sight toward the Galactic center, a corresponding silicate polarization measurement for the same line of sight was not available. Here, we present spectropolarimetric observations toward GCS 3-II and GCS 3-IV toward the Galactic center, where the 9.7 micron silicate polarization has been previously observed. We show that polarization is not detected across the 3.4 micron feature to a limit of 0.06 +/- 0.13% (GCS 3-II) and 0.15 +/- 0.31% (GCS 3-IV), well below the lowest available prediction of polarization on the basis of the core-mantle model. We conclude that the hydrocarbons in the diffuse ISM do not reside on the same grains as the silicates and likely form a separate population of small grains.

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arXiv2005

FUSE Measurements of Far Ultraviolet Extinction. II. Magellanic Cloud Sight Lines

We present an extinction analysis of 9 paths through the LMC and SMC based on FUSE observations. To date, just two LMC sight lines have probed dust grain composition and size distributions in the Clouds using spectra including wavelengths as short as 950 A. We supplement these with results from 4 regions distinguished by their IR through UV extinction curves and grouped as LMCAvg, LMC2, SMC bar and SMC wing. Despite the distinct characters of Milky Way and Magellanic Cloud extinction, our results are generally analogous to those found for Galactic curves in that the FUSE portions of each extinction curve are described reasonably well by FM curves fitted only to longer wavelength data and lack any dramatic new extinction features, and any deviations from the CCM formalism continue into FUV wavelengths. An MEM analysis of these curves suggests that LMCAvg and SMC wing sight lines require more silicon and/or carbon in dust than current abundance measurements would allow, while the requirements for LMC2 and SMC bar sight lines do not fully tax the available reservoirs. An intermediate product of this analysis is the measurement of new H_2 abundances in the Magellanic Clouds. Collectively considering Cloud sight lines that possess significant H_2 column densities, E(B-V)/N(HI) ratios are reduced by significant factors relative to the Galactic mean, whereas the corresponding E(B-V)/N(H_2) values more closely resemble their Galactic counterpart. These trends reflect the fact that among these sight lines f(H_2)-values are lower than those common in the Milky Way for paths with similar degrees of reddening.

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arXiv2005

FUSE Measurements of Far Ultraviolet Extinction. I. Galactic Sight Lines

We present extinction curves that include data down to far ultraviolet wavelengths (FUV; 1050 - 1200 A) for nine Galactic sight lines. The FUV extinction was measured using data from the Far Ultraviolet Spectroscopic Explorer. The sight lines were chosen for their unusual extinction properties in the infrared through the ultraviolet; that they probe a wide range of dust environments is evidenced by the large spread in their measured ratios of total-to-selective extinction, R_V = 2.43 - 3.81. We find that extrapolation of the Fitzpatrick & Massa relationship from the ultraviolet appears to be a good predictor of the FUV extinction behavior. We find that predictions of the FUV extinction based upon the Cardelli, Clayton & Mathis (CCM) dependence on R_V give mixed results. For the seven extinction curves well represented by CCM in the infrared through ultraviolet, the FUV extinction is well predicted in three sight lines, over-predicted in two sight lines, and under-predicted in 2 sight lines. A Maximum Entropy Method analysis using a simple three component grain model shows that seven of the nine sight lines in the study require a larger fraction of grain materials to be in dust when FUV extinction is included in the models. Most of the added grain material is in the form of small (radii < 200 A) grains.

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arXiv2003

The Role of Polycyclic Aromatic Hydrocarbons in Ultraviolet Extinction. I. Probing small molecular PAHs

We have obtained new STIS/HST spectra to search for structure in the ultraviolet interstellar extinction curve, with particular emphasis on a search for absorption features produced by polycyclic aromatic hydrocarbons (PAHs). The presence of these molecules in the interstellar medium has been postulated to explain the infrared emission features seen in the 3-13 $μ$m spectra of numerous sources. UV spectra are uniquely capable of identifying specific PAH molecules. We obtained high S/N UV spectra of stars which are significantly more reddened than those observed in previous studies. These data put limits on the role of small (30-50 carbon atoms) PAHs in UV extinction and call for further observations to probe the role of larger PAHs. PAHs are of importance because of their ubiquity and high abundance inferred from the infrared data and also because they may link the molecular and dust phases of the interstellar medium. A presence or absence of ultraviolet absorption bands due to PAHs could be a definitive test of this hypothesis. We should be able to detect a 20 Åwide feature down to a 3$σ$ limit of $\sim$0.02 A$_V$. No such absorption features are seen other than the well-known 2175 Åbump.

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arXiv2003

Infrared and Visual Interstellar Absorption Features toward Heavily- Reddened Field Stars

We present measurements of the 3.4-micron hydrocarbon dust absorption feature, and four visual diffuse interstellar bands, for twelve highly reddened (9.0<A(V)<15.8), early-type stars identified from the Stephenson (1992) catalogue, covering a range of Galactic longitude. The hydrocarbon feature is detected in eleven sightlines with optical depths of up to 0.05, and corresponding column densities are derived. The feature is weaker per unit A(V) than previously reported, further underlining earlier observations of its enhancement in the Galactic Centre. A comparison of the 3.4-micron feature substructure indicates organic material similar to that seen in earlier diffuse medium studies, suggesting a uniform formation history across the Galactic disc. The profile is well matched by both meteoritic material and several laboratory-prepared analogues. The diffuse interstellar bands (DIBs) measured were at 6177, 6203, 6284 and 6614 Angstroms; no strong correlations were detected, either between these bands themselves or between the DIBs and the 3.4-micron feature, although 6284 and 6614 appear to vary together. If the carriers of the DIBs are organic and molecular in nature and have cosmic carbon abundance requirements similar to those of the C-H stretch, these results imply that there is little direct carbon exchange between them and the aliphatic dust component. Measurements of the extinction to these objects suggest luminosity anomalies similar to that already seen in Cyg OB2 No. 12.

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arXiv2002

A New Feature in the Interstellar Extinction Curve at 2700 A: Diamonds in the Rough?

Space Telescope Imaging Spectrograph (STIS) and archival International Ultraviolet Explorer (IUE) data were used to search for structure in the ultraviolet interstellar extinction curve. Between 1250 and 3200 A, in addition to the well-known 2175 A bump, there is only one fairly small (10%) absorption feature at 2700 A. The feature is very broad (>400 A). It coincides extremely well in position and shape with laboratory measurements of presolar diamond grains found in meteorites. As this feature appears in both the new STIS and archival IUE data, it is unlikely to be an instrumental effect. This feature appears to be ubiquitous in the ISM as it is seen along sightlines toward various clouds with reddenings in the range of E(B-V) = 0.35 to 1.73 mag. The identification with diamonds remains tentative since it is based on a single, weak feature. If the feature is due to interstellar diamonds then they require an order of magnitude more absorption strength per gram/cm^2 than the presolar meteoritic diamonds measured in the lab.

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