arXiv subjects

D. C. Larbalestier

Publications and source records attributed to D. C. Larbalestier.

At least 19 recordsLinked to original sources

arXiv2018

Effect of $α$-particle irradiation on a NdFeAs(O,F) thin film

The effect of $α$-particle irradiation on a NdFeAs(O,F) thin film has been investigated to determine how the introduction of defects affects basic superconducting properties, including the critical temperature $T_c$ and the upper critical field $H_{c2}$, and properties more of interest for applications, like the critical current density $J_c$ and the related pinning landscape. The irradiation-induced suppression of the film $T_c$ is significantly smaller than on a similarly damaged single crystal. Moreover $H_{c2}$ behaves differently, depending on the field orientation: for H//c the $H_{c2}$ slope monotonically increases with increasing disorder, whereas for H//ab it remains constant at low dose and it increases only when the sample is highly disordered. This suggests that a much higher damage level is necessary to drive the NdFeAs(O,F) thin film into the dirty limit. Despite the increase in the low temperature $H_{c2}$, the effects on the $J_c$(H//c) performances are moderate in the measured temperature and field ranges, with a shifting of the pinning force maximum from 4.5 T to 6 T after an irradiation of $2\times10^{15} cm^{-2}$. On the contrary, $J_c$(H//ab) is always suppressed. The analysis demonstrates that irradiation does introduce point defects acting as pinning centres proportionally to the irradiation fluence but also suppresses the effectiveness of c-axis correlated pinning present in the pristine sample. We estimate that significant performance improvements may be possible at high field or at temperatures below 10 K. The suppression of the $J_c$(H//ab) performance is not related to a decrease of the $J_c$ anisotropy as found in other superconductors. Instead it is due to the presence of point defects that decrease the efficiency of the ab-plane intrinsic pinning typical of materials with a layered structure.

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arXiv2016

Intrinsic and extrinsic pinning in NdFeAs(O,F): vortex trapping and lock-in by the layered structure

The Fe-based superconductors (FBS) present a large variety of compounds whose properties are affected to different extents by their crystal structures. Amongst them, the $\it{RE}$FeAs(O,F) ($\it{RE}$1111, where $\it{RE}$ is a rare earth element) is the family with the highest critical temperature $T_c$ but also with a large anisotropy and Josephson vortices as demonstrated in the flux-flow regime in Sm1111 ($T_c$ $\sim$ 55 K). Here we focus our attention on the pinning properties of the lower-$T_c$ Nd1111 in the flux-creep regime. We demonstrate that for H//c critical current density $J_c$ at high temperatures is dominated by point-defect pinning centres, whereas at low temperatures surface pinning by planar defects parallel to the $\it{c}$-axis and vortex shearing prevail. When the field approaches the $\it{ab}$-planes, two different regimes are observed at low temperatures as a consequence of the transition between 3D-Abrikosov and 2D-Josephson vortices: one is determined by the formation of a vortex staircase structure and one by lock-in of the vortices parallel to the layers. This is the first study on FBS showing this behaviour in a full temperature, field, and angular range and it demonstrates that, despite the lower $T_c$ and anisotropy of Nd1111 with respect to Sm1111, this compound is substantially affected by intrinsic pinning generating a strong $\it{ab}$-peak in $J_c$.

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arXiv2016

Significant enhancement of compositional and superconducting homogeneity in Ti rather than Ta-doped Nb3Sn

Nb3Sn wires are now very close to their final optimization but despite its classical nature, detailed understanding of the role of Ta and Ti doping in the A15 is not fully understood. Long thought to be essentially equivalent in their influence on Hc2, they were interchangeably applied. Here we show that Ti produces significantly more homogeneous chemical and superconducting properties. Despite Ta-doped samples having a slightly higher Tc onset in zero-field, they always have a wider Tc-distribution. In particular, whereas the Ta-doped A15 has a Tc-distribution extending from 18 down to 5-6 K (the lowest expected Tc for the binary A15 phase), the Ti-doped samples have no A15 phase with Tc below 12 K. The much narrower Tc distribution in the Ti-doped samples has a positive effect on their in-field Tc-distribution too, leading to an extrapolated Hc2(0) 2 Tesla larger than the Ta-doped one. Ti-doping also appears to be very homogeneous even when the Sn content is reduced in order to inhibit breakdown of the diffusion barriers in very high Jc conductors. The enhanced homogeneity of the Ti-doped samples appears to result from its assistance of rapid diffusion of Sn into the filaments and by its incorporation into the A15 phase interchangeably with Sn on the Sn sites of the A15 phase.

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arXiv2015

Demonstration of an iron-pnictide bulk superconducting magnet capable of trapping over 1 T

A trapped field of over 1 T at 5 K and 0.5 T at 20 K has been measured between a stack of magnetized cylinders of bulk polycrystalline Ba0.6K0.4Fe2As2 superconductors 10 mm in diameter and 18 mm in combined thickness. The trapped field showed a low magnetic creep rate (~3% after 24 hours at 5 K), while magneto-optical imaging revealed a trapped field distribution corresponding to uniform macroscopic current loops circulating through the sample. The superconductors were manufactured by hot isostatic pressing of pre-reacted powders using the scalable powder-in-tube technique. A high Vickers hardness of ~3.5 GPa and a reasonable fracture toughness of ~2.35 MPa m0.5 were measured. Given the untextured polycrystalline nature of the cylinders and their large irreversibility field (> 90 T), it is expected that larger bulks could trap fields in excess of 10 T.

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arXiv2014

Development of very high Jc in Ba(Fe1-xCox)2As2 thin films grown on CaF2

Ba(Fe1-xCox)2As2 is the most tunable of the Fe-based superconductors (FBS) in terms of acceptance of high densities of self-assembled and artificially introduced pinning centres which are effective in significantly increasing the critical current density, Jc. Moreover, FBS are very sensitive to strain, which induces an important enhancement in critical temperature, Tc, of the material. In this paper we demonstrate that strain induced by the substrate can further improve Jc of both single and multilayer films by more than that expected simply due to the increase in Tc. The multilayer deposition of Ba(Fe1-xCox)2As2 on CaF2 increases the pinning force density Fp by more than 60% compared to a single layer film, reaching a maximum of 84 GN/m^3 at 22.5T and 4.2 K, the highest value ever reported in any 122 phase.

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arXiv2014

Comparison of grain texture in round Bi2212 and flat Bi2223 superconducting wires and its relation to high critical current densities

Why Bi2Sr2CaCu2Ox (Bi2212) allows high critical current density Jc in round wires rather than only in the anisotropic tape form demanded by all other high temperature superconductors is important for future magnet applications. Here we compare the local texture of state-of-the-art Bi2212 and Bi2223 ((Bi,Pb)2Sr2Ca2Cu3O10), finding that round wire Bi2212 generates a dominant a-axis growth texture that also enforces a local biaxial texture (FWHM <15°) while simultaneously allowing the c-axes of its polycrystals to rotate azimuthally along and about the filament axis so as to generate macroscopically isotropic behavior. By contrast Bi2223 shows only a uniaxial (FWHM <15°) c-axis texture perpendicular to the tape plane without any in-plane texture. Consistent with these observations, a marked, field-increasing, field-decreasing Jc(H) hysteresis characteristic of weak-linked systems appears in Bi2223 but is absent in Bi2212 round wire. Growth-induced texture on cooling from the melt step of the Bi2212 Jc optimization process appears to be the key step in generating this highly desirable microstructure.

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arXiv2014

Examination of the tradeoff between intrinsic and extrinsic properties in the optimization of a modern internal tin Nb3Sn conductor

In modern Nb3Sn wires there is a fundamental compromise to be made between optimizing the intrinsic properties associated with the superfluid density in the A15 phase (e.g. Tc, Hc, Hc2, all of which are composition dependent), maximizing the quantity of A15 that can be formed from a given mixture of Nb, Sn and Cu, minimizing the A15 composition gradients within each sub-element, while at the same time generating a high vortex pinning critical current density, Jc, by maximizing the grain boundary density with the additional constraint of maintaining the RRR of the Cu stabilizer above 100. Here we study these factors in a Ta-alloyed Restacked-Rod-Process (RRP) wire with ~70 microns diameter sub-elements. Consistent with many earlier studies, maximum non-Cu Jc(12T,4.2K) requires preventing A15 grain growth, rather than by optimizing the superfluid density. In wires optimized for 12T, 4.2K performance, about 60% of the non-Cu cross-section is A15, 35% residual Cu and Sn core, and only 5% a residual Nb7.5wt.%Ta diffusion barrier. The specific heat and chemical analyses show that in this 60% A15 fraction there is a wide range of Tc and chemical composition that does diminish for higher heat treatment temperatures, which, however, are impractical because of the strong RRR degradation that occurs when only about 2% of the A15 reaction front breaches the diffusion barrier. As this kind of Nb3Sn conductor design is being developed for sub-elements 1/2 the present size, it is clear that better barriers are essential to allowing higher temperature reactions with better intrinsic A15 properties. We present here multiple and detailed intrinsic and extrinsic evaluations because we believe that only such broad and quantitative descriptions are capable of accurately tracking the limitations of individual conductor designs where optimization will always be a compromise between inherently conflicting goals

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arXiv2013

Artificially engineered superlattices of pnictide superconductor

Significant progress has been achieved in fabricating high quality bulk and thinfilm iron-based superconductors. In particular, artificial layered pnictide superlattices offer the possibility of tailoring the superconducting properties and understanding the mechanism of the superconductivity itself. For high field applications, large critical current densities (Jc) and irreversibility fields (Hirr) are indispensable along all crystal directions. On the other hand, the development of superconducting devices such as tunnel junctions requires multilayered heterostructures. Here we show that artificially engineered undoped Ba-122 / Co doped Ba-122 compositionally modulated superlattices produce ab-aligned nanoparticle arrays. These layer and self-assemble along c-axis aligned defects, and combine to produce very large Jc and Hirr enhancements over a wide angular range. We also demonstrate a structurally modulated SrTiO3 (STO) / Co doped Ba-122 superlattice with sharp interfaces. Success in superlattice fabrication involving pnictides will aid the progress of heterostructured systems exhibiting novel interfacial phenomena and device applications.

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arXiv2013

A transformative superconducting magnet technology for fields well above 30 T using isotropic round wire multifilament Bi2Sr2CaCu2O8-x conductor

We report here that magnetic fields of almost 34 T, far above the upper 24 T limit of Nb3Sn, can be generated using a multifilament round wire conductor made of the high temperature cuprate superconductor Bi2Sr2CaCu2O8-x (Bi-2212). A remarkable attribute of this Bi-2212 conductor is that it does not exhibit macroscopic texture and contains many high angle grain boundaries but nevertheless attains very high superconducting critical current densities Jc of 2500 A/mm2 at 20 T and 4.2 K. This Bi-2212 conductor does not possess the extreme texture that high Jc coated conductors of REBa2Cu3O7-x (REBCO) require, avoiding also its high aspect ratio, large superconducting anisotropy and the inherent sensitivity to defects of a single filament conductor. Bi-2212 wires can be wound or cabled into almost any type of superconducting magnet and will be especially valuable for very high field NMR magnets beyond the present 1 GHz proton resonance limit of Nb3Sn technology. This demonstration that grain boundary limits to high Jc can be practically overcome suggests the huge value of a renewed focus on grain boundary properties in non-ideal geometries, especially with the goal of translating the lessons of this Bi-2212 conductor into fabrication of multifilament round wire REBCO or Fe-based superconductors.

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arXiv2012

Artificial and self-assembled pinning centers in Ba(Fe1-xCox)2As2 thin films as a route to very high current density

We report on the superior vortex pinning of single and multilayer Ba(Fe1-xCox)2As2 thin films with self-assembled c-axis and artificially introduced ab-plane pins. Ba(Fe1-xCox)2As2 can accept a very high density of pins (15-20 vol%) without Tc suppression. The matching field is greater than 12 T, producing a significant enhancement of the critical current density Jc, an almost isotropic Jc (Theta,20T) > 10^5 A/cm2, and global pinning force density Fp of about 50 GN/m^3. This scenario strongly differs from the high temperature cuprates where the addition of pins without Tc suppression is limited to 2-4 vol%, leading to small HIrr enhancements and improved Jc only below 3-5 Tesla.

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arXiv2012

High intergrain critical current density in fine-grain (Ba0.6K0.4)Fe2As2 wires and bulks

The K- and Co-doped BaFe2As2 (Ba-122) superconducting compounds are potentially useful for applications because they have upper critical fields (Hc2) of well over 50 T, Hc2 anisotropy Gamma < 2, and thin film critical current densities exceeding 1 MAcm-2 at 4.2 K. However, thin-film bicrystals of Co-doped Ba-122 clearly exhibit weak link behavior for [001] tilt misorientations of more than about 5 degrees, suggesting that textured substrates would be needed for applications, as in the cuprates. Here we present a contrary and very much more positive result in which untextured polycrystalline (Ba0.6K0.4)Fe2As2 bulks and round wires with high grain boundary density have transport critical current densities well over 0.1 MAcm-2 (SF, 4.2 K), more than 10 times higher than that of any other ferropnictide wire. The enhanced grain connectivity is ascribed to their much improved phase purity and to the enhanced vortex stiffness of this low-anisotropy compound (Gamma ~ 1-2) compared to YBa2Cu3O7-x (Gamma ~ 5).

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arXiv2012

Anisotropy of the irreversibility field for Zr-doped $(Y,Gd)Ba_2Cu_3O_{7-x}$ thin films up to 45T

The anisotropic irreversibility field B$_{Irr}$ of two $YBa_2Cu_3O_{7-x}$ thin films doped with additional rare earth (RE)=(Gd,Y) and Zr and containing strong correlated pins (splayed BaZrO$_{3}$ nanorods, and $RE_2O_3$ nanoprecipitates), has been measured over a very broad range up to 45T at temperatures 56 K<T<$T_c$. We found that the experimental angular dependence of $B_{Irr}(θ)$ does not follow the mass anisotropy scaling $B_{Irr}(θ)=B_{Irr}(0)(cos^2θ+γ^{-2}sin^2θ)^{-1/2}$, where $γ=(m_c/m_{ab})^{1/2}=5-6$ for the RE-doped $YBa_2Cu_3O_{7-x}$ (REBCO) crystals, m$_{ab}$ and m$_{c}$ are the effective masses along the ab plane and the c-axis, respectively, and $θ$ is the angle between B and the c-axis. For B parallel to the ab-planes and to the c-axis correlated pinning strongly enhances B$_{Irr}$, while at intermediate angles, $B_{Irr}(θ)$ follows the scaling behavior $B_{Irr}(θ)\propto(cos^2θ+γ_{RP}^2sin^2θ)^{1/2}$ with the effective anisotropy factor $γ_{RP}\approx3$ significantly smaller than the mass anisotropy would suggest. In spite of the strong effects of c-axis BaZrO$_{3}$ nanorods, we found even greater enhancements of B$_{Irr}$ for fields along the ab-planes than for fields parallel to the c-axis, as well as different temperature dependences of the correlated pinning contributions to B$_{Irr}$ for B//ab and B//c. Our results show that the dense and strong pins, which can now be incorporated into REBCO thin films in a controlled way, exert major and diverse effects on the measured vortex pinning anisotropy and the irreversibility field over wide ranges of B and T. In particular, we show that the relative contribution of correlated pinning to B$_{Irr}$ for B//c increases as the temperature increases due to the suppression of thermal fluctuations of vortices by splayed distribution of BaZrO$_{3}$ nanorods.

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arXiv2011

On the large role of weak uncorrelated pinning introduced by BZO nanorods at low temperatures in REBCO thin films

REBa$_{2}$Cu$_{3}$O$_{x}$ films can achieve remarkably high critical current density values by the incorporation of insulating nanoparticles. A particular interesting case concerns BaZrO$_{3}$ (BZO) nanorods, whose strongly correlated effect is seen at high temperatures. Here we investigate the field, temperature and angular dependence of the critical current density over a wide temperature range from 4.2 K to 77 K, and magnetic fields up to 31 T. We show that the correlated c-axis pinning of BZO nanorods becomes progressively less obvious at lower temperature. Indeed at 4.2 K and fields up to 31 T, the only correlated pinning is for fields parallel to the film plane. We interpret the change as being due to significant contributions from dense but weak pins that thermal fluctuations render ineffective at high temperatures but which become strong at lower temperatures.

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arXiv2011

Significant enhancement of upper critical fields by doping and strain in Fe-based superconductors

We report measurements of Hc2(T) up to 85 Tesla on Ba1-xKxAs2Fe2 single crystals and FeSe1-xTex films tuned by doping and strain. We observed an Hc2 enhancement by nearly 25 T at 30 K for the optimally-doped Ba1-xKxAs2Fe2 as compared to the previous results and extraordinarily high slopes dHc2/dT = 250-500 T/K near Tc in FeSe1-xTex indicating an almost complete suppression of the orbital pair-breaking. Theoretical analysis of Hc2(T) in FeSe1-xTex and the optimally doped Ba1-xKxAs2Fe2 predicts an inhomogeneous Fulde-Ferrel-Larkin-Ovchinnikov state for H//ab and T < 3-10 K, and shows that Hc2 in multiband Fe based superconductor can be enhanced by doping and strain much more effectively than by the conventional way of increasing disorder.

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arXiv2011

The behavior of grain boundaries in the Fe-based superconductors

The Fe-based superconductors (FBS) are an important new class of superconducting materials. As with any new superconductor with a high transition temperature and upper critical field, there is a need to establish what their applications potential might be. Applications require high critical current densities, so the usefulness of any new superconductor is determined both by the capability to develop strong vortex pinning and by the absence or ability to overcome any strong current-limiting mechanisms of which grain boundaries in the cuprates are a cautionary example. In this review we first consider the positive role that grain boundary properties play in the metallic, low temperature superconductors and then review the theoretical background and current experimental data relating to the properties of grain boundaries in FBS polycrystals, bi-crystal thin films, and wires. Based on this evidence, we conclude that grain boundaries in FBS are weak linked in a qualitatively similar way to grain boundaries in the cuprate superconductors, but also that the effects are a little less marked. Initial experiments with the textured substrates used for cuprate coated conductors show similar benefit for the critical current density of FBS thin films too. We also note that the particular richness of the pairing symmetry and the multiband parent state in FBS may provide opportunities for grain boundary modification as a better understanding of their pairing state and grain boundary properties are developed.

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arXiv2011

Superfluid density measurements of Ba(CoxFe1-x)2As2 films near optimal doping

We report the first direct measurements of superfluid density, ns(T) \propto λ-2(T), in films of Fe-pnictide superconductors. The magnetic penetration depth, λ(0), in our epitaxial, single-crystal Ba(CoxFe1-x)2As2 films near optimal doping (x=0.08) is 350 nm to 430 nm, comparable to bulk single crystals. The T-dependence of λ-2 indicates a small s-wave gap, 2Δ(0)/kBTc = 2.2 \pm 0.1. In detail, λ has power-law behavior at low T: λ(T)/λ(0) - 1 \approx 0.60*(T/Tc)2.5\pm0.1. The small gap, together with power-law behavior at low T, suggests strong intraband scattering on the larger-gap Fermi surface and significant interband scattering between large-gap and small-gap Fermi surfaces.

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arXiv2010

Observation of a coherence peak and pair-breaking effects in THz conductivity of BaFe$_{2-2x}$Co$_{2x}$As$_2$

We report a study of high quality pnictide superconductor BaFe$_{1.84}$Co$_{0.16}$As$_2$ thin films using time-domain THz spectroscopy. Near T$_c$ we find evidence for a coherence peak and qualitative agreement with the weak-coupling Mattis-Bardeen form of the conductivity. At low temperature, we find that the real part of the THz conductivity is not fully suppressed and $σ_2$ is significantly smaller than the Matthis-Bardeen expectation. The temperature dependence of the penetration depth $λ$ follows a power law with an unusually high exponent of 3.1. We interpret these results as consistent with impurity scattering induced pair-breaking. Taken together our results are strong evidence for an extended s$\pm$ symmetry order parameter.

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arXiv2010

Strong vortex pinning in Co-doped BaFe2As2 single crystal thin films

We report measurements of the field and angular dependences of Jc of truly epitaxial Co-doped BaFe2As2 thin films grown on SrTiO3/(La,Sr)(Al,Ta)O3 with different SrTiO3 template thicknesses. The films show Jc comparable to Jc of single crystals and a maximum pinning force Fp(0.6Tc) > 5 GN/m3 at H/Hirr ~ 0.5 indicative of strong vortex pinning effective up to high fields. Due to the strong correlated c-axis pinning, Jc for field along the c-axis exceeds Jc for H//ab plane, inverting the expectation of the Hc2 anisotropy. HRTEM reveals that the strong vortex pinning is due to a high density of nanosize columnar defects.

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