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D. C. Lis

Publications and source records attributed to D. C. Lis.

At least 19 recordsLinked to original sources

Interstellar Complex Organic Molecules and Molecular Outflows in NGC 1333 IRAS 4B and 4B' Observed Using NOEMA

We present interferometric observations with the Northern Extended Millimeter Array (NOEMA) of NGC 1333 IRAS 4B and 4B', two young stellar objects (YSOs) within the Perseus molecular cloud. YSOs, especially Class 0 protostars, are rich in gas-phase interstellar complex organic molecules (iCOMs), but relatively little is known about the spatial distribution of these important prebiotic molecules. Various molecules were imaged within IRAS 4B and the surrounding area in the 145 GHz spectral range, revealing hundreds of molecular transitions within the warm inner envelope of IRAS 4B. This work provides derived physical parameters (rotational temperature, column density, velocity shift with respect to local standard of rest, and full-width at half-maximum spectral line width) for 11 molecules toward IRAS 4B including methanol (CH$_3$OH and isotopologues), methyl formate (HCOOCH$_3$), dimethyl ether (CH$_3$OCH$_3$), acetaldehyde (CH$_3$CHO), ethanol (C$_2$H$_5$OH), glycolaldehyde (CH$_2$OHCHO), acetone (CH$_3$COCH$_3$), and isocyanic acid (HNCO). Out of these molecules, 10 are iCOMs (excluding HNCO) that trace the inner envelope of IRAS 4B and mark it as a rich source of organic material. There is a strong spatial correlation between the continuum emission of IRAS 4B and iCOM molecular emission and among various iCOMs with each other. Physical parameter and integrated intensity maps show that IRAS 4B is a binary protostar system that drives a jet in a north-south orientation and an outflow in a northwest-southeast orientation. IRAS 4B' also drives a west-east outflow but shows no evidence of molecular emission cospatial with its continuum emission.

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ALMAGAL IX. The chemical complexity of AG318.9477-00.1960: A line-identification template for ALMAGAL

We present a detailed molecular line analysis of one of the most chemically rich cores in the ALMAGAL sample, the high-mass core~9 in the AG318.9477-00.1960 clump (AG318-c9), located at a heliocentric distance of \sim 10.4\,\rm kpc. We further assessed whether the emission of selected COMs, that is, ethylene glycol ((CH_2OH)_2; EG), glycolaldehyde (CH_2(OH)CHO; GA), and methyl formate (CH_3OCHO; MF), can be used to trace the innermost regions of hot molecular cores (HMCs). We analysed ALMA Band~6 observations (\sim 217-221GHz). Spectral line identification and local thermodynamic equilibrium modelling were performed using the software MADCUBA. We derived the physical parameters, including the column density (N), excitation temperature (Tex), velocity, line width, and molecular abundances relative to H_2, for all detected species. The chemical inventory of AG318-c9 was compared with that of the HMC G31.41+0.31 (G31). In addition, we performed a pixel-by-pixel analysis of EG, GA, and MF to generate spatially resolved N and Tex maps and corresponding radial profiles.

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HyGAL: Characterizing the Galactic ISM with observations of hydrides and other small molecules. III. The absorption lines of [O I], CH, and OH

The HyGAL Stratospheric Observatory for Infrared Astronomy (SOFIA) legacy program aims at characterizing the interstellar medium in the Milky Way using hydrides, [C II], and [O I] absorption lines with the 2.7 m SOFIA telescope toward twenty-five submillimeter-bright Galactic star-forming regions. As part of HyGAL, we investigated correlations among the known H$_2$ tracers -- CH and OH from SOFIA observations, and HCO$^+$ and CCH from ancillary absorption line data from ground-based telescopes. We also examined the abundance variation of neutral atomic oxygen, [O I], observed in absorption. CH, OH, HCO$^+$, and CCH all exhibit strong mutual correlations. OH in particular shows tight correlations with HCO$^+$ and CCH, reflecting their linked chemical and physical pathways. Column density ratios among these H$_2$ tracers are consistent with previous measurements in local diffuse clouds and remain uniform across Galactic environments and velocity intervals. The gas phase oxygen abundance relative to total hydrogen, $\langle X$(O)$\rangle=N$(O)/$N$(H$_{\rm total}$), is $(3.09\pm0.64)\times10^{-4}$, slightly below the elemental solar value but consistent with the previous observations measuring gas-phase abundances. We also find that $N$(HI) decreases toward the regions where the molecular fraction exceeds $f_{H_2}^N \sim 0.5$, marking the onset of the molecular phase. While the atomic oxygen abundance remains roughly constant, the abundances of OH, HCO$^+$, and CCH increase with the molecular fraction. Gas traced by the HCO$^+$ absorption corresponds to higher molecular fractions than that traced by HI and hydride ions, highlighting density variations in the diffuse-to-translucent ISM along different lines of sight.

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ALMAGAL VIII. Early phases of triggered star formation in source AG286.0716$-$1.8229

Several theoretical and observational studies have shown that new waves of triggered star-formation can be induced by the feedback from newly formed massive protostars, due to the expansion of H II regions. We used the millimeter dust continuum data of the ALMAGAL survey and the Anderson et al. 2014 catalog of H II regions and selected one ALMAGAL source for ALMA follow-up observations. In fact, in source AG286.0716$-$1.8229 six cores were detected at a resolution of $\sim7600$ au, but only two at a higher resolution. The 4 cores not detected at higher resolution are prestellar core candidates. We used archival data from the SMGPS and RACS to confirm whether an H II region is present in the field. We observed the source with with ALMA in Band 4, covering the emission of DCO$^+$ (2$-$1), N$_2$D$^+$ (2$-$1), DCN (2$-$1), and CH$_3$CCH (9$-$8), to estimates whether these cores are in an early phase of the star-formation process. The new Band 4 continuum image revealed three cores outside of the ALMAGAL field of view, for a total of 9 cores in the region, 8 of which are located along an arch of radius $\sim0.75$ pc. We have derived a spectral index between -0.14 and -0.4, in the frequency range of 0.8-1.6 GHz for the candidate H II region, which is consistent with optically thin free-free emission. Using plausible temperature ranges, based on the information from chemical tracers and the dust continuum, we derived mass ranges for the cores ($\sim2-16\,$M$_{\odot}$) and ranges for the virial parameter ($\sim0.3-5$). All the cores along the arch have virial parameters $\lesssim$2, with only one exception. Comparing the typical separation and mass of the cores with those expected in the case of the collect and collapse scenario and with the thermal Jean length and mass, the best agreement is found with the characteristic scales in the case of triggered star formation.

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A Multi-Wavelength Study of Comet C/2022 E3 (ZTF): Complementary ALMA and JWST Investigations of Water and Methanol in Cometary Comae

Long-period comets, which are often considered to be representative of material in the protoplanetary disk that formed the Solar System, are ideal to investigate the question of chemical inheritance in astronomy. Determining the chemistry of comets, both individually and as a population, has become of great importance in comparative studies against sources representative of evolutionary precursors to planetary systems. Contemporaneous observations of long-period comet C/2022 E3 (ZTF) were obtained with the JWST and the Atacama Large Millimeter/submillimeter Array (ALMA) in early 2023 March. This work focuses on \ce{CH3OH} measurements from both ALMA and JWST as well as \ce{H2O} measurements from JWST. Radiative transfer modeling of \ce{CH3OH} and \ce{H2O} was performed to investigate spatial variations in rotational temperature, column density, and production rates, as well as a comparison of derived values between the two telescopes. Most of the spatial distributions of the modeled values are centrally peaked, and the modeled values from JWST are all within the error bars of the average values from ALMA. C/2022 E3 (ZTF) also displays an enhancement in modeled rotational temperature in the anti-Sunward direction that is shown to be statistically significant. Based on non-LTE radiative transfer modeling, the declining \ce{H2O} rotational temperatures as a function of nucleocentric distance observed by JWST can be explained primarily as a result of rotational line cooling. The values derived in this work are in general agreement with single-dish millimeter-wave observations.

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ALMAGAL VI. The spatial distribution of dense cores during the evolution of cluster-forming massive clump

High-mass stars and star clusters form from the fragmentation of massive dense clumps driven by gravity, turbulence, and magnetic fields. The ALMAGAL project observed $\sim1000$ clumps at $\sim$1000\,au resolution, enabling a statistically significant characterization of this process across a large range of clump physical parameters and evolutionary stages. In this work, we investigated the spatial distribution of dense cores in the 514 massive, potentially cluster-forming, clumps hosting at least 4 cores, to trace fragmentation's initial conditions and early evolution. We used quantitative descriptors, evaluated against the clump bolometric luminosity-to-mass ratio as an indicator of evolution. Core separations were measured with the minimum spanning tree method (MST) and compared with the Jeans gravitational fragmentation theory. We used the $Q$ parameter and the mass segregation ratio, $\Lambda_{MSR}$, to evaluate whether cores have specific arrangements or differences depending on their masses. ALMAGAL cores are usually arranged in elliptical groups with an axis ratio $e\sim2.2$, but $e\geq$5 is also observed. A single characteristic core separation per clump is found in $\sim76$% of cases, but signatures of multiple fragmentation lengths not rare. Typical core separations are compatible with the clump-averaged thermal Jeans length, $\lambda^{th}_{J}$, though a population, typical of low-fragmented/young clumps, has wider separations with $l\approx3\times\lambda^{th}_{J}$. The core separation decreases on average from $l\sim22000$ au in younger systems to $l\sim7000$ au in more evolved ones. Cores are typically distributed in fractal-type subclusters, with centrally concentrated patterns appearing only at later stages, but without a progressive evolutionary transition. Finally, mass segregation is found in 110 systems, with its occurrence increasing with evolution.

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ALMAGAL V. Relations between the core populations and the parent clump physical properties

Context. The fragmentation of massive molecular clumps into smaller, potentially star-forming cores plays a key role in the processes of high-mass star formation. The ALMAGAL project offers high-resolution data to investigate these processes across various evolutionary stages in the Galactic plane. Aims. This study aims at correlating the fragmentation properties of massive clumps, obtained from ALMA observations, with their global physical parameters (e.g., mass, surface density, and temperature) and evolutionary indicators (such as luminosity-to-mass ratio and bolometric temperature) obtained from Herschel observations. It seeks to assess whether the cores evolve in number and mass in tandem with their host clumps, and to determine the possible factors influencing the formation of massive cores (M > 24M_\odot). Methods. We analyzed the masses of 6348 fragments, estimated from 1.4 mm continuum data for 1007 ALMAGAL clumps. Leveraging this unprecedentedly large data set, we evaluated statistical relationships between clump parameters, estimated over about 0.1 pc scales, and fragment properties, corresponding to scales of a few 1000 au, while accounting for potential biases related to distance and observational resolution. Our results were further compared with predictions from numerical simulations. Results. The fragmentation level correlates preferentially with clump surface density, supporting a scenario of density-driven fragmentation, whereas it does not show any clear dependence on total clump mass. Both the mass of the most massive core and the core formation efficiency show a broad range and increase on average by an order of magnitude in the intervals spanned by evolutionary indicators such as clump dust temperature and the luminosity-to-mass ratio. This suggests that core growth continues throughout the clump evolution, favoring clump-fed over core-fed theoretical scenarios.

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Expanding the Ice Inventory of NGC 1333 IRAS 2A with INDRA using JWST Observations: Tracing Organic Refractories and Beyond

In the era of JWST, with its unprecedented sensitivity and spectral resolution, infrared spectral surveys have revealed a rich inventory of ices, including complex organic molecules (COMs), in young stellar objects (YSOs). However, robust methods to decompose and quantify these absorption features particularly across broad spectral ranges, are still under investigation. We present INDRA (Ice-fitting with NNLS-based Decomposition and Retrieval Algorithm), a fully Python-based tool that performs continuum and silicate removal, global ice fitting using Weighted Non-Negative Least Squares (NNLS), and estimates column densities and statistical significance. We apply INDRA to NGC 1333 IRAS 2A, a target from the JWST Observations of Young protoStars (JOYS+) program previously studied using local fitting. We derive optical depths via polynomial continuum subtraction and remove silicate absorption using a synthetic model, isolating ice features for global MIRI fitting. Our results are consistent with previous local fits, confirming simple species and COMs, and expand the inventory by identifying additional absorption features from CO2 and NH4+. We also propose the presence of organic refractories contributing up to 9.6% in the spectral region of 5-8 microns among the various ice components, whose inclusion significantly improves the global spectral fitting. These broad absorption features, extending across 5.5-11 microns, are likely produced by large, complex molecules containing carbonyl (C=O), hydroxyl (O-H), amine (N-H), and C-H bending modes. Our expanded inventory, now incorporating these organic residues, offers new insights into the chemical evolution of ices in star-forming regions and highlights the importance of global spectral fitting in constraining ice compositions.

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A D/H Ratio Consistent with Earth's Water in Halley-type Comet 12P from ALMA HDO Mapping

Isotopic measurements of Solar System bodies provide a primary paradigm within which to understand the origins and histories of planetary materials. The D/H ratio in particular, helps reveal the relationship between (and heritage of) different H$_2$O reservoirs within the Solar System. Here we present interferometric maps of water (H$_2$O) and semiheavy water (HDO) in the gas-phase coma of a comet (Halley-type comet 12P/Pons-Brooks), obtained using the Atacama Large Millimeter/submillimeter Array (ALMA). The maps are consistent with outgassing of both H$_2$O and HDO directly from the nucleus, and imply a coma D/H ratio (for water) of $(1.71 \pm 0.44)\times10^{-4}$. This is at the lower end of the range of previously-observed values in comets, and is consistent with D/H in Earth's ocean water. Our results suggest a possible common heritage between a component of the Oort cloud's water ice reservoir, and the water that was delivered to the young Earth during the early history of the Solar System.

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ALMAGAL IV. Morphological comparison of molecular and thermal dust emission using the histogram of oriented gradients (HOG) method

The study of molecular line emission is crucial to unveil the kinematics and the physical conditions of gas in star-forming regions. Our aim is to quantify the reliability of using individual molecular transitions to derive physical properties of the bulk of the H2 gas, looking at morphological correlations in their overall integrated molecular line emission with the cold dust. For this study we selected transitions of H2CO, CH$_3$OH, DCN, HC$_3$N, CH$_3$CN, CH$_3$OCHO, SO, and SiO and compared them with the 1.38 mm dust continuum emission at different spatial scales in the ALMAGAL sample, that observed a total of 1013 targets covering all evolutionary stages of the high-mass star-formation process and different conditions of clump fragmentation. We used the method of the histogram of oriented gradients (HOG) implemented in the tool astroHOG to compare the morphology of integrated line emission with maps of the 1.38 mm dust continuum emission. Moreover, we calculated the Spearman's correlation coefficient, and compared it with our astroHOG results. Only H$_2$CO, CH$_3$OH, and SO show emission on spatial scales comparable with the diffuse continuum emission. However, from the HOG method, the median correlation of the emission of each of these species with the continuum is only $\sim$24-29%. In comparison with the dense fragments these molecular species still have low values of correlation. On the other hand DCN, HC$_3$N, CH$_3$CN, and CH$_3$OCHO show a good correlation with the dense dust fragments, above 60%. The worst correlation is seen with SiO, both with the extended continuum emission and with compact sources. From the comparison of the results of the HOG method and the Spearman's correlation coefficient, the HOG method gives much more reliable results than the intensity-based coefficient in estimating the level of similarity of the emission morphology.

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ALMAGAL II. The ALMA evolutionary study of high-mass protocluster formation in the Galaxy. ALMA data processing and pipeline

The ALMAGAL Large Program has observed 1017 high-mass star-forming regions distributed throughout the Galaxy, sampling different evolutionary stages and environmental conditions. In this work, we present the acquisition and processing of the ALMAGAL data. The main goal is to set up a robust pipeline that generates science-ready products, with a good and uniform quality across the whole sample. ALMAGAL observations were performed with the Atacama Large Millimeter/submillimeter Array (ALMA). Each field was observed in three different telescope arrays, being sensitive to spatial scales ranging from 1000 au up to 0.1 pc. The spectral setup allows sensitive imaging of the continuum emission at 219 GHz, and it covers multiple molecular spectral lines observed in four different spectral windows that span about 4 GHz in frequency coverage. We have designed a Python-based processing workflow to calibrate and image these observational data. This ALMAGAL pipeline includes an improved continuum determination, suited for line-rich sources; an automatic self-calibration process that improves the dynamical range of the final images; and the combination of data from different telescope arrays to produce science-ready, fully combined images. The fully combined products have spatial resolutions in the range 800-2000 au, and mass sensitivities in the range 0.02-0.07 Mo. We also present a first analysis of the spectral line information included in the ALMAGAL setup, and its potential for future scientific studies. As an example, specific spectral lines at 1000 au scales resolve the presence of multiple outflows in clusters and will help us to search for disk candidates around massive protostars. Moreover, the broad frequency bands provide information on the chemical richness of the different cluster members, which can be used to study the chemical evolution during the formation process of star clusters.

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ALMAGAL III. Compact source catalog: Fragmentation statistics and physical evolution of the core population

The mechanisms behind the fragmentation of high-mass dense clumps into compact star-forming cores are fundamental topics in current astrophysical research. The ALMAGAL survey provides the opportunity to study this process at an unprecedented level of detail and statistical significance, featuring high-angular resolution $1.38$ mm ALMA observations of $1013$ massive dense clumps at various Galactic locations. These clumps cover a wide range of distances, masses, surface densities, and evolutionary stages. Here, we present the catalog of compact sources obtained with the CuTEx algorithm from continuum images of the full ALMAGAL clump sample combining ACA-$7$m and $12$m ALMA arrays, reaching a uniform high median spatial resolution of $\sim1400$ au. We discuss the fragmentation properties and the estimated physical parameters of the core population. The ALMAGAL compact source catalog includes $6348$ cores detected in $844$ clumps ($83\%$ of the total), with a number of cores per clump between $1$ and $49$ (median of $5$). The estimated core diameters are mostly within $\sim800-3000$ au (median of $1700$ au). We obtained core masses from $0.002$ to $345\,\mathrm{M_{\odot}}$. We evaluated the variation in the core mass function (CMF) with evolution as traced by the clump $L/M$, finding a clear, robust shift and change in slope among CMFs within subsamples at different stages. This finding suggests that the CMF shape is not constant throughout the star formation process, but rather it builds (and flattens) with evolution, with higher core masses reached at later stages. We found that all cores within a clump grow in mass on average with evolution, and the number of cores increases with the core masses. Our results favor a clump-fed scenario for high-mass star formation, in which cores form as low-mass seeds, and then gain mass while further fragmentation occurs in the clump.

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Ice inventory towards the protostar Ced 110 IRS4 observed with the James Webb Space Telescope. Results from the ERS Ice Age program

This work focuses on the ice features toward the binary protostellar system Ced 110 IRS 4A and 4B, and observed with JWST as part of the Early Release Science Ice Age collaboration. We aim to explore the JWST observations of the binary protostellar system Ced~110~IRS4A and IRS4B to unveil and quantify the ice inventories toward these sources. We compare the ice abundances with those found for the same molecular cloud. The analysis is performed by fitting or comparing laboratory infrared spectra of ices to the observations. Spectral fits are carried out with the ENIIGMA fitting tool that searches for the best fit. For Ced~110~IRS4B, we detected the major ice species H$_2$O, CO, CO$_2$ and NH$_3$. All species are found in a mixture except for CO and CO$_2$, which have both mixed and pure ice components. In the case of Ced~110~IRS4A, we detected the same major species as in Ced~110~IRS4B, as well as the following minor species CH$_4$, SO$_2$, CH$_3$OH, OCN$^-$, NH$_4^+$ and HCOOH. Tentative detection of N$_2$O ice (7.75~$μ$m), forsterite dust (11.2~$μ$m) and CH$_3^+$ gas emission (7.18~$μ$m) in the primary source are also presented. Compared with the two lines of sight toward background stars in the Chameleon I molecular cloud, the protostar has similar ice abundances, except in the case of the ions that are higher in IRS4A. The clearest differences are the absence of the 7.2 and 7.4~$μ$m absorption features due to HCOO$^-$ and icy complex organic molecules in IRS4A and evidence of thermal processing in both IRS4A and IRS4B as probed by the CO$_2$ ice features. We conclude that the binary protostellar system Ced~110~IRS4A and IRS4B has a large inventory of icy species. The similar ice abundances in comparison to the starless regions in the same molecular cloud suggest that the chemical conditions of the protostar were set at earlier stages in the molecular cloud.

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Chemical composition of comets C/2021 A1 (Leonard) and C/2022 E3 (ZTF) from radio spectroscopy and the abundance of HCOOH and HNCO in comets

We present the results of a molecular survey of long period comets C/2021 A1 (Leonard) and C/2022 E3 (ZTF). Comet C/2021 A1 was observed with the IRAM 30-m radio telescope in November-December 2021 before perihelion when it was closest to the Earth. We observed C/2022 E3 in January-February 2023 with the Odin 1-m space telescope and IRAM 30-m, shortly after its perihelion, and when it was closest to the Earth. Snapshots were obtained during 12-16 November 2021 period for comet C/2021 A1. Spectral surveys were undertaken over the 8-13 December 2021 period for comet C/2021 A1 (8, 16, and 61 GHz bandwidth in the 3 mm, 2 mm, and 1 mm window) and over the 3-7 February 2023 period for comet C/2022 E3 (25 and 61 GHz at 2 and 1mm). We report detections of 14 molecular species (HCN, HNC, CH3CN, HNCO, NH2CHO, CH3OH, H2CO, HCOOH, CH3CHO, H2S, CS, OCS, C2H5OH and aGg-(CH2OH)2 ) in both comets plus HC3N and CH2OHCHO marginally detected in C/2021 A1 and CO and H2O (with Odin detected in C/2022 E3. The spatial distribution of several species is investigated. Significant upper limits on the abundances of other molecules and isotopic ratios are also presented. The activity of comet C/2021 A1 did not vary significantly between 13 November and 13 December 2021. Short-term variability in the outgassing of comet C/2022 E3 on the order of +-20% is present and possibly linked to its 8h rotation period. Both comets exhibit rather low abundances relative to water for volatiles species such as CO (< 2%) and H2S (0.15%). Methanol is also rather depleted in comet C/2021 A1 (0.9%). Following their revised photo-destruction rates, HNCO and HCOOH abundances in comets have been reevaluated. Both molecules are relatively enriched in these two comets (0.2% relative to water). We cannot exclude that these species could be produced by the dissociation of ammonium salts.

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Dynamical Accretion Flows -- ALMAGAL: Flows along filamentary structures in high-mass star-forming clusters

We use data from the ALMA Evolutionary Study of High Mass Protocluster Formation in the Galaxy (ALMAGAL) survey to study 100 ALMAGAL regions at $\sim$ 1 arsecond resolution located between $\sim$ 2 and 6 kpc distance. Using ALMAGAL $\sim$ 1.3mm line and continuum data we estimate flow rates onto individual cores. We focus specifically on flow rates along filamentary structures associated with these cores. Our primary analysis is centered around position velocity cuts in H$_2$CO (3$_{0,3}$ - 2$_{0,2}$) which allow us to measure the velocity fields, surrounding these cores. Combining this work with column density estimates we derive the flow rates along the extended filamentary structures associated with cores in these regions. We select a sample of 100 ALMAGAL regions covering four evolutionary stages from quiescent to protostellar, Young Stellar Objects (YSOs), and HII regions (25 each). Using dendrogram and line analysis, we identify a final sample of 182 cores in 87 regions. In this paper, we present 728 flow rates for our sample (4 per core), analysed in the context of evolutionary stage, distance from the core, and core mass. On average, for the whole sample, we derive flow rates on the order of $\sim$10$^{-4}$ M$_{sun}$yr$^{-1}$ with estimated uncertainties of $\pm$50%. We see increasing differences in the values among evolutionary stages, most notably between the less evolved (quiescent/protostellar) and more evolved (YSO/HII region) sources. We also see an increasing trend as we move further away from the centre of these cores. We also find a clear relationship between the flow rates and core masses $\sim$M$^{2/3}$ which is in line with the result expected from the tidal-lobe accretion mechanism. Overall, we see increasing trends in the relationships between the flow rate and the three investigated parameters; evolutionary stage, distance from the core, and core mass.

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A JWST/MIRI analysis of the ice distribution and PAH emission in the protoplanetary disk HH 48 NE

Ice-coated dust grains provide the main reservoir of volatiles that play an important role in planet formation processes and may become incorporated into planetary atmospheres. However, due to observational challenges, the ice abundance distribution in protoplanetary disks is not well constrained. We present JWST/MIRI observations of the edge-on disk HH 48 NE carried out as part of the IRS program Ice Age. We detect CO$_2$, NH$_3$, H$_2$O and tentatively CH$_4$ and NH$_4^+$. Radiative transfer models suggest that ice absorption features are produced predominantly in the 50-100 au region of the disk. The CO$_2$ feature at 15 micron probes a region closer to the midplane (z/r = 0.1-0.15) than the corresponding feature at 4.3 micron (z/r = 0.2-0.6), but all observations trace regions significantly above the midplane reservoirs where we expect the bulk of the ice mass to be located. Ices must reach a high scale height (z/r ~ 0.6; corresponding to modeled dust extinction Av ~ 0.1), in order to be consistent with the observed vertical distribution of the peak ice optical depths. The weakness of the CO$_2$ feature at 15 micron relative to the 4.3 micron feature and the red emission wing of the 4.3 micron CO$_2$ feature are both consistent with ices being located at high elevation in the disk. The retrieved NH$_3$ abundance and the upper limit on the CH$_3$OH abundance relative to H$_2$O are significantly lower than those in the interstellar medium (ISM), but consistent with cometary observations. Full wavelength coverage is required to properly study the abundance distribution of ices in disks. To explain the presence of ices at high disk altitudes, we propose two possible scenarios: a disk wind that entrains sufficient amounts of dust, thus blocking part of the stellar UV radiation, or vertical mixing that cycles enough ices into the upper disk layers to balance ice photodesorption.

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HCN emission from translucent gas and UV-illuminated cloud edges revealed by wide-field IRAM 30m maps of Orion B GMC: Revisiting its role as tracer of the dense gas reservoir for star formation

We present 5 deg^2 (~250 pc^2) HCN, HNC, HCO+, and CO J=1-0 maps of the Orion B GMC, complemented with existing wide-field [CI] 492 GHz maps, as well as new pointed observations of rotationally excited HCN, HNC, H13CN, and HN13C lines. We detect anomalous HCN J=1-0 hyperfine structure line emission almost everywhere in the cloud. About 70% of the total HCN J=1-0 luminosity arises from gas at A_V < 8 mag. The HCN/CO J=1-0 line intensity ratio shows a bimodal behavior with an inflection point at A_V < 3 mag typical of translucent gas and UV-illuminated cloud edges. We find that most of the HCN J=1-0 emission arises from extended gas with n(H2) ~< 10^4 cm^-3, even lower density gas if the ionization fraction is > 10^-5 and electron excitation dominates. This result explains the low-A_V branch of the HCN/CO J=1-0 intensity ratio distribution. Indeed, the highest HCN/CO ratios (~0.1) at A_V < 3 mag correspond to regions of high [CI] 492 GHz/CO J=1-0 intensity ratios (>1) characteristic of low-density PDRs. Enhanced FUV radiation favors the formation and excitation of HCN on large scales, not only in dense star-forming clumps. The low surface brightness HCN and HCO+ J=1-0 emission scale with I_FIR (a proxy of the stellar FUV radiation field) in a similar way. Together with CO J=1-0, these lines respond to increasing I_FIR up to G0~20. On the other hand, the bright HCN J=1-0 emission from dense gas in star-forming clumps weakly responds to I_FIR once the FUV radiation field becomes too intense (G0>1500). The different power law scalings (produced by different chemistries, densities, and line excitation regimes) in a single but spatially resolved GMC resemble the variety of Kennicutt-Schmidt law indexes found in galaxy averages. As a corollary for extragalactic studies, we conclude that high HCN/CO J=1-0 line intensity ratios do not always imply the presence of dense gas.

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A JWST inventory of protoplanetary disk ices: The edge-on protoplanetary disk HH 48 NE, seen with the Ice Age ERS program

Ices are the main carriers of volatiles in protoplanetary disks and are crucial to our understanding of the chemistry that ultimately sets the organic composition of planets. The ERS program Ice Age on the JWST follows the ice evolution through all stages of star and planet formation. JWST/NIRSpec observations of the edge-on Class II protoplanetary disk HH~48~NE reveal spatially resolved absorption features of the major ice components H$_2$O, CO$_2$, CO, and multiple weaker signatures from less abundant ices NH$_3$, OCN$^-$, and OCS. Isotopologue $^{13}$CO$_2$ ice has been detected for the first time in a protoplanetary disk. Since multiple complex light paths contribute to the observed flux, the ice absorption features are filled in by ice-free scattered light. The $^{12}$CO$_2$/$^{13}$CO$_2$ ratio of 14 implies that the $^{12}$CO$_2$ feature is saturated, without the flux approaching 0, indicative of a very high CO$_2$ column density on the line of sight, and a corresponding abundance with respect to hydrogen that is higher than ISM values by a factor of at least a few. Observations of rare isotopologues are crucial, as we show that the $^{13}$CO$_2$ observation allows us to determine the column density of CO$_2$ to be at an order of magnitude higher than the lower limit directly inferred from the observed optical depth. Radial variations in ice abundance, e.g., snowlines, are significantly modified since all observed photons have passed through the full radial extent of the disk. CO ice is observed at perplexing heights in the disk, extending to the top of the CO-emitting gas layer. We argue that the most likely interpretation is that we observe some CO ice at high temperatures, trapped in less volatile ices like H$_2$O and CO$_2$. Future radiative transfer models will be required to constrain the implications on our current understanding of disk physics and chemistry.

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