arXiv subjects

D. J. McCarron

Publications and source records attributed to D. J. McCarron.

16 recordsLinked to original sources

arXiv2023

Hyperfine structure of the $\mathbf{A^{1}Π}$ state of AlCl and its relevance to laser cooling and trapping

The majority of molecules proposed for laser cooling and trapping experiments have $Σ$-type ground states. Specifically, $^2Σ$ states have cycling transitions analogous to D1-lines in alkali-metal atoms while $^1Σ$ states offer both strong and weak cycling transitions analogous to those in alkaline-earth atoms. Despite this proposed variety, to date, only molecules with $^2Σ$-type ground states have successfully been confined and cooled in magneto-optical traps. While none of the proposed $^1Σ$-type molecules have been successfully laser cooled and trapped, they are expected to have various advantages in terms of exhibiting a lower chemical reactivity and an internal structure that benefits the cooling schemes. Here, we present the prospects and strategies for optical cycling in AlCl -- a $^1Σ$ molecule -- and report on the characterization of the $A^{1}Π$ state hyperfine structure. Based on these results, we carry out detailed simulations on the expected capture velocity of a magneto-optical trap for AlCl. Finally, using {\it ab initio} calculations, we identify the photodissociation via a $3^1Π$ state and photoionization process via the $3^1Σ^+$ state as possible loss mechanisms for a magneto-optical trap of AlCl.

physics.atom-ph↗

arXiv2021

Cold CH radicals for laser cooling and trapping

Ultracold CH radicals promise a fruitful testbed for probing quantum-state controllable organic chemistry. In this work, we calculate CH vibrational branching ratios (VBRs) and rotational branching ratios (RBRs) with ground state mixing. We subsequently use these values to inform optical cycling proposals and consider two possible radiative cooling schemes using the $X^{2}Π\leftarrow A^{2}Δ$ and $X^{2}Π\leftarrow B^{2}Σ^{-}$ transitions. As a first step towards laser cooled CH, we characterize the effective buffer gas cooling of this species and produce $\sim5\times10^{10}$ CH molecules per pulse with a rotational temperature of 2(1) K and a translational temperature of 7(2) K. We also determine the CH-helium collisional cross section to be $2.4(8)\times10^{-14}$ cm$^{2}$. This value is crucial to correctly account for collisional broadening and accurately extract the in-cell CH density. These cold CH molecules mark an ideal starting point for future laser cooling and trapping experiments and tests of cold organic chemistry.

physics.atom-ph↗

arXiv2021

A stable 2 W continuous-wave 261.5 nm laser for cooling and trapping aluminum monochloride

We present a high-power tunable deep-ultraviolet (DUV) laser that uses two consecutive cavity enhanced doubling stages with LBO and CLBO crystals to produce the fourth harmonic of an amplified homebuilt external cavity diode laser. The system generates up to 2.75 W of 261.5 nm laser light with a ~2 W stable steady-state output power and performs second harmonic generation in a largely unexplored high intensity regime in CLBO for continuous wave DUV light. We use this laser to perform fluorescence spectroscopy on the $X^1Σ\leftarrow A^1Π$ transition in a cold, slow beam of AlCl molecules and probe the $A^{1} Π|v'=0,~J'=1>$ state hyperfine structure for future laser cooling and trapping experiments. This work demonstrates that the production of tunable, watt-level DUV lasers is becoming routine for a variety of wavelength-specific applications in atomic, molecular and optical physics.

physics.optics↗

arXiv2021

Resonance Raman optical cycling for high-fidelity fluorescence detection of molecules

We propose and demonstrate a novel technique that combines Raman scattering and optical cycling in molecules with diagonal Franck-Condon factors. This resonance Raman optical cycling manipulates molecules to behave like efficient fluorophores with discrete absorption and emission profiles that are readily separated for sensitive fluorescence detection in high background light environments. Using a molecular beam of our test species, SrF, we realize up to an average of $\approx20$ spontaneously emitted photons per molecule, limited by the interaction time, while using a bandpass filter to suppress detected scattered laser light by $\sim10^{6}$. This general technique represents a powerful tool for high-fidelity fluorescence detection of molecules in any setting and is particularly well-suited to molecular laser cooling and trapping experiments.

physics.atom-ph↗

arXiv2020

Bright, continuous beams of cold free radicals

We demonstrate a cryogenic buffer gas-cooled molecular beam source capable of producing bright, continuous beams of cold and slow free radicals via laser ablation over durations of up to 60~seconds. The source design uses a closed liquid helium reservoir as a large thermal mass to minimize heating and ensure reproducible beam properties during operation. Under typical conditions, the source produces beams of our test species SrF, containing $5\times10^{12}~$molecules per steradian per second in the $X^{2}Σ(v=0, N=1)$ state with a rotational temperature of $1.0(2)~$K and a forward velocity of $140~$m/s. The beam properties are robust and unchanged for multiple cell geometries but depend critically on the helium buffer gas flow rate, which must be $\geq10~$ standard cubic centimeters per minute to produce bright, continuous beams of molecules for an ablation repetition rate of $55~$Hz.

physics.atom-ph↗

arXiv2018

Deflection of a Molecular Beam Using the Bichromatic Stimulated Force

We demonstrate that a bichromatic standing-wave laser field can exert a significantly larger force on a molecule than ordinary radiation pressure. Our experiment measures the deflection of a pulsed supersonic beam of CaF molecules by a two-frequency laser field detuned symmetrically about resonance with the nearly closed $X (v=0) \rightarrow B (v'=0)$ transition. The inferred force as a function of relative phase between the two counterpropagating beams is in reasonable agreement with numerical simulations of the bichromatic force in this multilevel system. The large magnitude of the force, coupled with the reduced rate of spontaneous emission, indicates its potential utility in the production and manipulation of ultracold molecules.

physics.atom-ph↗

arXiv2017

Magnetically-Trapped Molecules Efficiently Loaded from a Molecular MOT

We describe experiments demonstrating efficient transfer of molecules from a magneto-optical trap (MOT) into a conservative magnetic quadrupole trap. Our scheme begins with a blue-detuned optical molasses to cool SrF molecules to $\sim\!50$ $μ$K. Next, we optically pump the molecules into a strongly-trapped sublevel. This two-step process reliably transfers $64\%$ of the molecules initially trapped in the MOT into the magnetic trap, comparable to similar atomic experiments. Once loaded, the magnetic trap is compressed by increasing the magnetic field gradient. Finally, we demonstrate a magnetic trap lifetime of over $1$ s. This opens a promising new path to the study of ultracold molecular collisions, and potentially the production of quantum-degenerate molecular gases.

physics.atom-ph↗

arXiv2015

Sub-millikelvin dipolar molecules in a radio-frequency magneto-optical trap

We demonstrate a scheme for magneto-optically trapping strontium monofluoride (SrF) molecules at temperatures one order of magnitude lower and phase space densities three orders of magnitude higher than obtained previously with laser-cooled molecules. In our trap, optical dark states are destabilized by rapidly and synchronously reversing the trapping laser polarizations and the applied magnetic field gradient. The number of molecules and trap lifetime are also significantly improved from previous work by loading the trap with high laser power and then reducing the power for long-term trapping. With this procedure, temperatures as low as 400 $μ$K are achieved.

physics.atom-ph↗

arXiv2014

Improved magneto-optical trapping of a diatomic molecule

We present experimental results from a new scheme for magneto-optically trapping strontium monofluoride (SrF) molecules, which provides increased confinement compared to our original work. The improved trap employs a new approach to magneto-optical trapping presented by M. Tarbutt, \emph{arXiv preprint} 1409.0244, which provided insight for the first time into the source of the restoring force in magneto-optical traps (MOTs) where the cycling transition includes dark Zeeman sublevels (known as type-II MOTs). We measure a radial spring constant $20\times$ greater than in our original work with SrF, comparable to the spring constants reported in atomic type-II MOTs. We achieve a trap lifetime $τ_{\rm{MOT}}=136(2)$~ms, over $2\times$ longer than originally reported for SrF. Finally, we demonstrate further cooling of the trapped molecules by briefly increasing the trapping lasers' detunings. Our trapping scheme remains a straightforward extension of atomic techniques and marks a step towards the direct production of large, dense, ultracold molecular gases via laser cooling.

physics.atom-ph↗

arXiv2014

Repeated output coupling of ultracold Feshbach molecules from a Cs BEC

We investigate magnetoassociation of ultracold Feshbach molecules from a Bose- Einstein condensate of Cs atoms and explore the spectrum of weakly bound molecular states close to the atomic threshold. By exploiting the variation of magnetic field experienced by a molecular cloud falling in the presence of a magnetic field gradient, we demonstrate the repeated output coupling of molecules from a single atomic cloud using a Feshbach resonance at 19.89 G. Using this method we are able to produce up to 24 separate pulses of molecules from a single atomic condensate, with a molecular pulse created every 7.2 ms. Furthermore, by careful control of the magnetic bias field and gradient we are able to utilise an avoided crossing in the bound state spectrum at 13.3G to demonstrate exquisite control over the dynamics of the molecular clouds.

physics.atom-ph↗

arXiv2014

Magneto-optical trapping of a diatomic molecule

Laser cooling and trapping are central to modern atomic physics. The workhorse technique in cold-atom physics is the magneto-optical trap (MOT), which combines laser cooling with a restoring force from radiation pressure. For a variety of atomic species, MOTs can capture and cool large numbers of particles to ultracold temperatures (<1 mK); this has enabled the study of a wide range of phenomena from optical clocks to ultracold collisions whilst also serving as the ubiquitous starting point for further cooling into the regime of quantum degeneracy. Magneto-optical trapping of molecules could provide a similarly powerful starting point for the study and manipulation of ultracold molecular gases. Here, we demonstrate three-dimensional magneto-optical trapping of a diatomic molecule, strontium monofluoride (SrF), at a temperature of approximately 2.5 mK. This method is expected to be viable for a significant number of diatomic species. Such chemical diversity is desired for the wide array of existing and proposed experiments which employ molecules for applications ranging from precision measurement, to quantum simulation and quantum information, to ultracold chemistry.

physics.atom-ph↗

arXiv2012

Equilibrium solutions of immiscible two-species Bose-Einstein condensates in perturbed harmonic traps

We investigate the mean--field equilibrium solutions for a two--species immiscible Bose--Einstein condensate confined by a harmonic confinement with additional linear perturbations. We observe a range of equilibrium density structures, including `ball and shell' formations and axially/radially separated states, with a marked sensitivity to the potential perturbations and the relative atom number in each species. Incorporation of linear trap perturbations, albeit weak, are found to be essential to match the range of equilibrium density profiles observed in a recent Rb-87 - Cs-133 Bose-Einstein condensate experiment [D. J. McCarron et al., Phys. Rev. A, 84, 011603(R) (2011)]. Our analysis of this experiment demonstrates that sensitivity to linear trap perturbations is likely to be important factor in interpreting the results of similar experiments in the future.

cond-mat.quant-gas↗

arXiv2011

Dual-Species Bose-Einstein Condensate of $^{87}$Rb and $^{133}$Cs

We report the formation of a dual-species Bose-Einstein condensate of $^{87}$Rb and $^{133}$Cs in the same trapping potential. Our method exploits the efficient sympathetic cooling of $^{133}$Cs via elastic collisions with $^{87}$Rb, initially in a magnetic quadrupole trap and subsequently in a levitated optical trap. The two condensates each contain up to $2\times10^{4}$ atoms and exhibit a striking phase separation, revealing the mixture to be immiscible due to strong repulsive interspecies interactions. Sacrificing all the $^{87}$Rb during the cooling, we create single species $^{133}$Cs condensates of up to $6\times10^{4}$ atoms.

physics.atom-ph↗

arXiv2011

A high phase-space density mixture of $^{87}$Rb and $^{133}$Cs: towards ultracold heteronuclear molecules

We report the production of a high phase-space density mixture of $^{87}$Rb and $^{133}$Cs atoms in a levitated crossed optical dipole trap as the first step towards the creation of ultracold RbCs molecules via magneto-association. We present a simple and robust experimental setup designed for the sympathetic cooling of $^{133}$Cs via interspecies elastic collisions with $^{87}$Rb. Working with the $|F=1, m_F=+1 >$ and the $|3, +3 >$ states of $^{87}$Rb and $^{133}$Cs respectively, we measure a high interspecies three-body inelastic collision rate $\sim 10^{-25}-10^{-26} \rm{cm}^{6}\rm{s}^{-1}$ which hinders the sympathetic cooling. Nevertheless by careful tailoring of the evaporation we can produce phase-space densities near quantum degeneracy for both species simultaneously. In addition we report the observation of an interspecies Feshbach resonance at 181.7(5) G and demonstrate the creation of Cs$_{2}$ molecules via magneto-association on the 4g(4) resonance at 19.8 G. These results represent important steps towards the creation of ultracold RbCs molecules in our apparatus.

physics.atom-ph↗

arXiv2011

Bose-Einstein condensation of 87Rb in a levitated crossed dipole trap

We report an apparatus and method capable of producing Bose-Einstein condensates (BECs) of ~1x10^6 87Rb atoms, and ultimately designed for sympathetic cooling of 133Cs and the creation of ultracold RbCs molecules. The method combines several elements: i) the large recapture of a magnetic quadrupole trap from a magneto-optical trap, ii) efficient forced RF evaporation in such a magnetic trap, iii) the gain in phase-space density obtained when loading the magnetically trapped atoms into a far red-detuned optical dipole trap and iv) efficient evaporation to BEC within the dipole trap. We demonstrate that the system is capable of sympathetically cooling the |F=1,m_F=-1> and |1,0> sublevels with |1,+1> atoms. Finally we discuss the applicability of the method to sympathetic cooling of 133Cs with 87Rb.

physics.atom-ph↗

arXiv2008

Modulation transfer spectroscopy in atomic rubidium

We report modulation transfer spectroscopy on the D2 transitions in 85Rb and 87Rb using a simple home-built electro-optic modulator (EOM). We show that both the gradient and amplitude of modulation transfer spectroscopy signals, for the 87Rb F=2 to F'=3 and the 85Rb F=3 to F'=4 transitions, can be significantly enhanced by expanding the beams, improving the signals for laser frequency stabilization. The signal gradient for these transitions is increased by a factor of 3 and the peak to peak amplitude was increased by a factor of 2. The modulation transfer signal for the 85Rb F=2 to F' transitions is also presented to highlight how this technique can generate a single, clear line for laser frequency stabilization even in cases where there are a number of closely spaced hyperfine transitions.

physics.atom-ph↗