arXiv2023
The electronic orders appearing in condensed matter systems are originating from the precise arrangement of atoms constituting the crystal as well as their nature. This teneous relationship can lead to highly different phases in condensed matter, and drive electronic phase transitions. Here, we show that a very slight deformation of the crystal structure of TbTe$_3$ can have a dramatic influence on the electronic order that is stabilized. In particular, we show that the Charge Density Wave (CDW) developping along the $\vec{c}$ axis in the pristine state, switches to an orientation along $\vec{a}$ when the naturally orthorhombic system is turned into a tetragonal system. This is achieved by performing true biaxial mechanical deformation of a TbTe$_3$ sample from 250K to 375K, and by measuring both structural and electronic parameters with x-ray diffraction and transport measurements. We show that this switching transition is driven by the tetragonality parameter $a/c$, and that the transition occurs for $a=c$, with a coexistence region for $0.9985< a/c < 1.002$. The CDW transition temperature $T_c$ is found to have a linear dependence with $a/c$, with no saturation in the deformed states investigated here, while the gap saturates out of the coexistence region. The linear dependence of $T_c$ is accounted for within a tight-binding model. Our results question the relationship between the gap and $T_c$ in RTe$_3$ systems. More generally, our method of applying true biaxial deformation at cryogenic temperatures can be applied to many systems displaying electronic phase transitions, and opens a new route towards the study of coexisting or competing electronic orders in condensed matter.