arXiv subjects

D. Navarro-Almaida

Publications and source records attributed to D. Navarro-Almaida.

At least 19 recordsLinked to original sources

arXiv2026

Series of core collapse numerical simulations (SOLANUM) I: Modelling the early and late infall in a sun-like protostar

Magnetohydrodynamical simulations and interferometric observations toward young stellar objects reveal the accretion of gas that may alter the physical properties and chemical composition of protostellar disks. Our goal is to constrain the physical history and properties of late infalling gas, and assess its potential to change the physical and chemical properties of the disk. We carried out a core collapse simulation of 5 M$_{\odot}$ of gas endowed with tracer and sink particles during $\sim 3.6\times 10^{5}$ yr. We analyzed the properties of the rotationally supported disk, and the origin and physical history of the gas from which it is initially formed. We also selected the tracer particles that describe the late infall to analyze their origin and physical history, and compare them to the information obtained from the disk. The final mass of the sink reaches 1.02 M$_\odot$, while the mass of the disk stays fairly constant around 0.02 M$_\odot$. Throughout its evolution, the disk radius increases up to $\sim 40$ au and its density is reduced by a factor of $\sim 8$. Filaments that channel gas from the envelope to the disk and sink appear as a result of the magnetic interchange instability. Tracer particles can identify late infalling gas, whose physical properties resemble that of observed streamers and are only accreted in the final snapshots of the simulation. The origin and physical history of the late infalling gas are different from those of the gas that initially forms the disk. Core collapse simulations predict the appearance of filaments that connect the envelope to the disk. The late accretion of gas through these channels has properties similar to those of streamers and brings gas to the disk with a different physical history that could translate into a different chemical composition.

astro-ph.GA↗

arXiv2026

Discovery of sulfur oxides in the ejecta of a B[e] supergiant

B[e] supergiants represent a rare class of luminous, evolved massive stars surrounded by dusty circumstellar disks. Since their intense UV fields were long thought to sterilize their surroundings, molecular detections beyond carbon monoxide have remained elusive, leaving their chemical reservoirs largely unexplored. Whether these environments can sustain a complex molecular chemistry is a fundamental question with significant astrochemical implications. Here we report the detection of chemically rich molecular gas surrounding the B[e] supergiant HD~87643, using ALMA observations. Our data reveal the presence of the sulfur oxides SO and SO$_2$ and other sulfur-bearing species, marking the first detection of these molecules in an early-type evolved massive star. We find a high fractional abundance of SO$_2$ relative to H$_2$, which our chemical modelling can reproduce in timescales as short as $\sim$10$^4$ yr in an oxygen-rich environment. These results indicate that the detected molecules trace a short-lived, rapidly evolving phase of out-of-equilibrium chemistry. Furthermore, we measure an anomalously low $^{32}$SO/$^{33}$SO, that we attribute to mass-independent fractionation driven by intense photochemistry. This mechanism mirrors processes proposed to explain the $^{33}$S excesses in the atmosphere of the Archaean Earth. Our findings suggest that B[e] supergiants could serve as unique laboratories for studying sulfur chemistry under extreme radiation conditions, opening potential avenues to investigate the fractionation processes that shaped the isotopic signatures found in the early geological record.

astro-ph.SR↗

arXiv2026

Evolution of Chemistry in the envelope of HOt corinoS (ECHOS). III. Sulphur chemistry in the Class 0 objects HH 212 and NGC 1333 IRAS 4A

Our goal is to find chemical diagnostics to determine the physical conditions in protostellar envelopes and help establish the development of matter during the formation of a low-mass star, as well as investigating a possible variation of sulphur depletion during the star formation process at the scale of the cold envelope. With observations with the Yebes-40m and IRAM-30m telescopes, we estimate column densities of sulphur-bearing species in the Class 0 objects HH212 and NGC1333 IRAS4A. A neural emulator of the chemical code Nautilus is used to constrain the chemical time, density, gas temperature, cosmic ray ionization rate, and sulphur elemental abundance in the cold envelope of these objects. We compare the resulting abundances of these species with those towards the Class 0 object B335. While sulphur-bearing species containing carbon chains are between 3 and 7 times more abundant in B335 than in the other two objects, sulphur oxides and nitrogen-bearing species are 3 times more abundant in NGC1333 IRAS4A. Our chemical modelling shows that, while the chemistry of HH212 and NGC1333 IRAS4A is well reproduced considering a gas temperature of 25 K and a sulphur depletion of a factor of 100 in their envelopes, significant differences are found in their average density and cosmic ray ionization rate. Comparing with similar studies in pre-stellar and protostellar cores, we derive an increase in the SO/CS and SO$_2$/C$_2$S ratios of about two orders of magnitude and a potential decrease in the HCS$^+$/CS ratio of a factor of 10 in the transition from the pre-stellar to the Class 0 phase. Sulphur compounds are good evolutionary tracers of the pre- to protostellar phase transition, with oxygen-bearing species being more abundant than those containing carbon in the evolved sources. Nonetheless, sulphur depletion in the cold envelope of Class 0 objects remains similar to that in starless cores.

astro-ph.GA↗

arXiv2026

Modeling the UV-photon irradiation of CS$_2$-bearing ices in the laboratory with the pyRate gas-grain astrochemical code. New insights into the missing sulfur problem

Observations indicate that the total abundance of S-bearing species in dense clouds is orders of magnitude lower than the cosmic sulfur abundance. Addressing this "missing sulfur problem" requires a combination of astronomical observations, laboratory experiments, and theoretical models. In this work, we use the pyRate astrochemical model to simulate the VUV photon irradiation of a CO$_2$:CS$_2$ ice mixture at 10 K in the laboratory, with the goal of supporting the interpretation of the experimental results and testing our current understanding of the sulfur evolution in interstellar ices. For this purpose, the astrochemical model was adapted to the experimental conditions, and the chemical network was compiled from several sources to ensure that all known reactions involving sulfur species were included. The results indicate that nondiffusive chemistry is necessary to reproduce the formation of S-bearing species observed in the experiment. However, some discrepancies were found in the major S-bearing ice chemistry products predicted by the model and the experiment. The compounds OCS, CS, and SO are overpredicted by the model, while it falls short in accounting for $\rm SO_2$ and sulfur allotropes. These discrepancies are likely due to a combination of an incomplete knowledge of the chemical reactions at play (either because of missing reactions and/or because of unconstrained reaction barriers), and uncertainties in the experimental analysis. This work represents the first effort to model the chemistry of a multicomponent ice analog with a rate-equation based code, and highlights the complementary nature of theoretical and experimental astrochemistry to disentangle the chemical evolution of sulfur in the interstellar medium.

astro-ph.GA↗

arXiv2026

Chemical study of two starless cores in the B213/L1495 filament

The chemical evolution of pre-stellar cores during their transition to a protostellar stage is not yet fully understood. Detailed chemical characterizations of these sources are needed to better define their chemistry during star formation. Our goal is to characterize the chemistry of the starless cores C2 and C16 in the B213/L1495 filament of the Taurus Molecular Cloud, and to understand how it relates to the environmental conditions and the evolutionary state of the cores. We made use of two complete spectral surveys at 7 mm of these sources, carried out using the Yebes 40-m telescope. Derived molecular abundances were compared with those of other sources in different evolutionary stages and with values computed by chemical models. Including isotopologs, 22 molecules were detected in B213-C2, and 25 in B213-C16. The derived rotational temperatures have values of between $\sim$ 5 K and $\sim$ 9 K. A comparison of the two sources shows lower abundances in C2, except for l-C$_{3}$H and HOCO$^{+}$, which have similar values in both cores. Model results indicate that both cores are best fit assuming early-time chemistry, and point to C2 being in a more advanced evolutionary stage, as it presents a higher molecular hydrogen density and sulfur depletion, and a lower cosmic-ray ionization rate. Our chemical modeling successfully accounts for the abundances of most molecules, including complex organic molecules and long cyanopolynes (HC$_{5}$N, HC$_{7}$N), but fails to reproduce those of the carbon chains CCS and C$_{3}$O. Chemical differences between C2 and C16 could stem from the evolutionary stage of the cores, with C2 being closer to the pre-stellar phase. Both cores are better fit assuming early-time chemistry of t $\sim$ 0.1 Myr. The more intense UV radiation in the northern region of B213 could account for the high abundances of l-C$_{3}$H and HOCO$^{+}$ in C2.

astro-ph.GA↗

arXiv2025

Observations of sulfuretted species in HL Tau

Protoplanetary disks inherit their chemical composition from their natal molecular cloud, but the extent to which this material is preserved versus reset through chemical reprocessing remains an open question. Understanding this balance is a major topic in astrochemistry. Comparing the chemical composition of the envelope and the protoplanetary disk is key to solving the topic. The goal of this paper is to investigate the chemical differences between the disk and the surrounding envelope by comparing the column density ratios of a few selected species in each region. The source we focus on is HL Tau. We present new NOEMA observations of HL Tau targeting the following species: CS, H2CO, H2S, and SO2. We produced zeroth-, first-, and second-moment maps for the species where emission was detected and used them to analyze the spatial distribution and kinematic properties of the different molecules in the disk and the envelope. We derived the column densities and compared the values derived for the envelope and disk. We also computed the rotational diagram for the SO2 detected transitions. Assuming two different temperature regimes, 17 and 58 K, we derived column densities for the species surveyed in the disk and compared them with values derived for the envelope. We find large differences in the derived column density ratios of the surveyed molecules, especially for N(CS)/N(H2S), which is 40 to 50 times larger in the envelope. We attribute these variations to the different excitation and UV-irradiation regimes in the disk and envelope. We also note strong gradients in the ratios between different positions of the disk and tentatively attribute them to different levels of turbulence at different azimuths. The observed differences in molecular ratios in the envelope and the disk are suggestive of chemical reprocessing of the gas during the formation and evolution of the protoplanetary disk.

astro-ph.SR↗

arXiv2025

A quest for sulfur-bearing refractory species. Identification of CaS in the interstellar medium

The recent detection of refractory molecules in massive star-forming regions provides a means of probing the innermost regions of disks around massive stars. These detections also make it possible to explore the chemical composition of refractories through gas-phase observations. In this regard, identifying refractory compounds containing sulfur could reveal potential connections between sulfur and refractories, as well as help determine the sulfur budget in these extreme environments. We find convincing evidence of a reliable detection of CaS, and tentative detections of KS and KSH in the disk G351.77-mm1. These are the first ever identifications of these species in the interstellar medium. The CaS, KS, and KSH column densities are about 3 orders of magnitude lower than those of the abundant sulfur compounds SO$_2$, CH$_3$SH and SiS, proving that these species are not the major reservoir of sulfur at the spatial scales probed by our observations. Higher angular resolution observations at different wavelengths are required to confirm these detections, which are of paramount importance to gain insights into the formation of gas-phase refractory molecules.

astro-ph.GA↗

arXiv2025

Fine-tuning the complex organic molecule formation: sulfur and CO ice as regulators of surface chemistry

Grain-surface chemistry plays a crucial role in the formation of molecules of astrobiological interest, including H$_{2}$S and complex organic molecules (COMs). They are commonly observed in the gas phase toward star-forming regions, but their detection in ices remains limited. Combining gas-phase observations with chemical modeling is therefore essential for advancing our understanding of their chemistry. In this paper we investigate the factors that promote or hinder molecular complexity combining gas-phase observations of CH$_{3}$OH, H$_{2}$S, OCS, N$_{2}$H$^{+}$, and C$^{18}$O with chemical modeling in two dense cores: Barnard-1b and IC348. We observed millimeter emission lines of CH$_{3}$OH, H$_{2}$S, OCS, N$_{2}$H$^{+}$, and C$^{18}$O along strips using the IRAM 30m and Yebes 40m telescopes. We used the gas-grain chemical model \texttt{Nautilus} to reproduce the observed abundance profiles adjusting parameters such as initial sulfur abundances and binding energies. H$_{2}$S, N$_{2}$H$^{+}$ and C$^{18}$O gas-phase abundances vary up to one order of magnitude towards the extinction peak. CH$_{3}$OH abundance remains quite uniform. These abundances can only be reproduced assuming a decreasing sulfur budget, which lowers H$_{2}$S and enhances CH$_{3}$OH abundances. Decreasing binding energies, which are expected in CO-rich apolar ices, are also required. The sulfur depletion required by H$_2$S is generally higher than that required by CH$_3$OH, suggesting unknown sulfur sinks. These findings highlight the intricate relationship between sulfur chemistry and COM formation, driven by the competition between sulfur and CO for hydrogen atoms. Our study emphasizes that the growth of CO ice and the progressive sequestration of hydrogen atoms by sulfur are critical in determining whether chemical complexity can develop, providing key insights into the early stages of star and planet formation.

astro-ph.GA↗

arXiv2025

Gas-phase Elemental abundances in Molecular cloudS (GEMS) XI. The evolution of HCN, HNC, and N2H+ isotopic ratios in starless cores

Isotopic ratios have been used as chemical diagnostics to investigate the origin of the material in the Solar System. We have determined the HCN, HNC, and N2H+ isotopic ratios and the chemical age in a large sample of 23 starless cores located in different environments. This work uses IRAM 30m data to constrain the D/H ratio of HCN, HNC, and N2H+ as well as the 14N/15N ratio of HCN and HNC. The observed abundances have been modeled using the chemical code DNAUTILUS 2.0. Deuterated compounds are detected in all of our sample cores, with average DNC/HNC, DCN/HCN, and N2D+/N2H+ values of 0.054$\pm$0.019, 0.036$\pm$0.033, and 0.15$\pm$0.11, respectively. The deuterium fractions (Dfrac) show a weak correlation with temperature and a large scatter that reflects that other factors such as core evolution could also play a significant role. Our chemical model is able to reproduce all the observed values with 0.2-0.3 Myr in Taurus and 0.3-0.5 Myr in Perseus and Orion. The 14N/15N isotopic ratio is found to be different between HCN/HC15N (430$\pm$120) and HNC/H15NC (296$\pm$64). We find no correlation between these ratios and the deuterium fractions, but we report a weak correlation with temperature. The Dfrac of HCN, HNC, and N2H+ can be used as evolutionary tracers of starless cores as long as the physical parameters are well constrained. The HCN/HC15N and HNC/H15NC ratios are not correlated with Dfrac, suggesting that the detected variations are not correlated with the core evolutionary stage. The average value of the HCN/HC15N ratio in our sample is significantly higher than the values measured in protostars and protoplanetary disks, possibly indicating that nitrogen fractionation processes are taking place during the protostellar phase.

astro-ph.GA↗

arXiv2025

PRODIGE VI -- Envelope to Disk with NOEMA: VI. The Missing Sulfur Problem

Determining the amount of sulfur in volatiles and refractories in the ISM remains one of the main problems in astrochemistry. The detection of H$_2$S ices, which are thought to be one of the main sulfur reservoirs, has not been achieved yet, and the only S-bearing species detected in the ices to date is OCS. PRODIGE large survey observations with NOEMA of several Class 0/I protostars in the Perseus Molecular Cloud provide a perfect opportunity to study the H$_2$S and OCS composition of the ices through the volatiles sublimated in the warm inner core (T$>$100K, n $\sim10^6$cm$^{-3}$) of these protostars. Our aim is to determine the H$_2$S/OCS ratio in the warm inner core of 24 protostars in order to study how it is affected by different factors during its evolution. We used the NOEMA millimeter observations from the PRODIGE program of H$_2$S, H$_2^{33}$S, OCS, OC$^{33}$S and OC$^{34}$S to estimate the H$_2$S and OCS column densities in the warm inner cores. We used SO and SO$_2$ data from the ALMA archive to give a rough estimate of the total sulfur abundance. We explore the chemistry of H$_2$S and OCS in the warm cores using chemical and dynamical simulations of the collapse of a dense core to form a protostar. The estimated H$_2$S/OCS ratio reveals a segregation of the sources into ``OCS-poor'' and ``OCS-rich'' protostars, where the OCS-poor protostars present higher H$_2$S/OCS ratios than the OCS-rich ones. Total sulfur abundance is always dominated by either H$_2$S or OCS, grows with evolution during the Class 0 phase up to $D_S<8$, and decreases again in the Class I. Simulations show that temperature changes in the pre-stellar phase and during the collapse can produce substantial differences in the H$_2$S and OCS abundances and in the H$_2$S/OCS ratio. Our analysis shows that the H$_2$S/OCS ratio is strongly influenced by the environment and the initial conditions of the cloud.

astro-ph.GA↗

arXiv2025

Predicting the detectability of sulphur-bearing molecules in the solid phase with simulated spectra of JWST instruments

To date, gas phase observations of sulphur in dense interstellar environments have only constrained the molecular carriers of 1% of its predicted cosmic abundance. An additional 5% is known to be locked up in molecular solids in dense clouds, leaving the main reservoir of depleted sulphur in the solid phase unknown. The spectral resolution and sensitivity of the JWST could make a substantial difference in detecting part of this missing sulphur, with its wavelength coverage that includes vibrational absorption features of the S-carriers H2S, OCS, SO2, CS2, SO, CS, and S8. The aim of this study is to determine whether these molecules may be viable candidates for detection. We carried out new laboratory measurements of the IR absorption spectra of CS2 and S8 to update the IR band strength of the most intense CS2 absorption feature at 6.8 μm, as well as to determine that of S8 at 20.3 μm for the first time. These data, along with values previously reported in the literature, allow us to evaluate which S-bearing species could be potentially detected with JWST in interstellar ices. Taking the literature abundances of the major ice species determined by previous IR observations towards starless cores, LYSOs and MYSOs, we generated simulated IR spectra using the characteristics of the instruments on the JWST. Thus, we have been able to establish a case study for three stages of the star formation process. We conclude that the detection of S-bearing molecules remains challenging. Despite these obstacles, the detection of H2S and potentially SO2 should be possible in regions with favourable physical and chemical conditions. In contrast, S8 would remain undetected. Although the sensitivity of JWST is insufficient to determine the sulphur budget in the solid state, the detection of an additional icy sulphur compound (H2S, SO2) would enable us to elevate our knowledge of sulphur chemistry.

astro-ph.GA↗

arXiv2024

Evolution of Chemistry in the envelope of HOt CorinoS (ECHOS) II. The puzzling chemistry of isomers as revealed by the HNCS/HSCN ratio

The observational detection of some metastable isomers in the interstellar medium with abundances comparable to those of the most stable isomer, or even when the stable isomer is not detected, highlights the importance of non-equilibrium chemistry. This challenges our understanding of the interstellar chemistry. We present a chemical study of isomers through the sulphur isomer pair HNCS and HSCN, since HSCN has been observed in regions where its stable isomer has not been detected, and the observed HNCS/HSCN ratio seems to significantly vary from cold to warm regions. We have used the Nautilus chemical code to model the formation and destruction paths of HNCS and HSCN in different astrochemical scenarios, and the time evolution of the HNCS/HSCN ratio. We have also analysed the influence of the environmental conditions on their chemical abundances. We present an observational detection of the metastable isomer HSCN in the Class I object B1-a, but not of the stable isomer HNCS, despite HNCS lying 3200 K lower in energy than HSCN. Our results show an HNCS/HSCN ratio sensitive to the gas temperature and the evolutionary time, with the highest values obtained at early stages (t<10^4 yr) and low (Tg<20 K) temperatures. The results suggest a different efficiency of the isomerisation processes depending on the source temperature. The progressive decrease of HNCS/HSCN with gas temperature at early evolutionary times indicates that this ratio may be used as a tracer of cold young objects. This work also demonstrates the key role of grain surface chemistry in the formation of the isomer pair HNCS and HSCN in cold regions, and the importance of the ions H2NCS+ and HNCSH+ in warm/hot regions. Since most of the interstellar regions where HSCN is detected are cold regions, a larger sample including sources characterised by high temperatures are needed to corroborate the theoretical results.

astro-ph.GA↗

arXiv2024

Gas phase Elemental abundances in Molecular cloudS (GEMS). X. Observational effects of turbulence on the chemistry of molecular clouds

(Abridged) We explore the chemistry of the most abundant C, O, S, and N bearing species in molecular clouds, in the context of the IRAM 30 m Large Programme Gas phase Elemental abundances in Molecular Clouds (GEMS). In this work, we aim to assess the limitations introduced in the observational works when a uniform density is assumed along the line of sight for fitting the observations, developing a very simple numerical model of a turbulent box. We perform a MHD simulation in order to reproduce the turbulent steady-state of a turbulent box with properties typical of a molecular filament before collapse. We post-process the results of the MHD simulation with a chemical code to predict molecular abundances, and then post-process this cube with a radiative transfer code to create synthetic emission maps for a series of rotational transitions observed during the GEMS project. From the chemical point of view, we find that turbulence produces variations on the predicted abundances, but they are more or less critical depending on the chosen transition and the chemical age. When compared to real observations, the results from the turbulent simulation provides a better fit than when assuming a uniform gas distribution along the line of sight. In the view of our results, we conclude that taking into account turbulence when fitting observations might significantly improve the agreement with model predictions. This is especially important for sulfur bearing species that are very sensitive to the variations of density produced by turbulence at early times (0.1 Myr). The abundance of CO is also quite sensitive to turbulence when considering the evolution beyond a few 0.1 Myr.

astro-ph.GA↗

arXiv2024

A fast neural emulator for interstellar chemistry

Astrochemical models are important tools to interpret observations of molecular and atomic species in different environments. However, these models are time-consuming, precluding a thorough exploration of the parameter space, leading to uncertainties and biased results. Using neural networks to simulate the behavior of astrochemical models is a way to circumvent this problem, providing fast calculations that are based on real astrochemical models. In this paper, we present a fast neural emulator of the astrochemical code Nautilus based on conditional neural fields. The resulting model produces the abundance of 192 species for arbitrary times between 1 and 10$^7$ years. Uncertainties well below 0.2 dex are found for all species, while the computing time is of the order of 10$^4$ smaller than Nautilus. This will open up the possibility of performing much more complex forward models to better understand the physical properties of the interstellar medium. As an example of the power of these models, we ran a feature importance analysis on the electron abundance predicted by Nautilus. We found that the electron density is coupled to the initial sulphur abundance in a low density gas. Increasing the initial sulphur abundance from a depleted scenario to the cosmic abundance leads to an enhancement of an order of magnitude of the electron density. This enhancement can potentially influence the dynamics of the gas in star formation sites.

astro-ph.IM↗

arXiv2024

Grain growth and its chemical impact in the first hydrostatic core phase

The first hydrostatic core (FHSC) phase is a brief stage in the protostellar evolution that is difficult to detect. Our goal is to characterize the chemical evolution of gas and dust during the formation of the FHSC. Moreover, we are interested in analyzing, for the first time with 3D magnetohydrodynamic (MHD) simulations, the role of grain growth in its chemistry. We postprocessed $2\times10^{5}$ tracer particles from a $\texttt{RAMSES}$ non-ideal MHD simulation using the codes $\texttt{NAUTILUS}$ and $\texttt{SHARK}$ to follow the chemistry and grain growth throughout the simulation. A great chemical inheritance is seen, as gas-phase abundances of most of the C, O, N, and S reservoirs in the hot corino at the end of the simulation match the ice-phase abundances from the prestellar phase. Additionally, interstellar complex organic molecules (iCOMs) such as methyl formate, acetaldehyde, and formamide are formed during the warm-up process. The typical grain size in the hot corino $(n_{\rm H}>10^{11}\ {\rm cm^{-3}})$ increases forty-fold during the last 30 kyr, with negligible effects on its chemical composition. At moderate densities $(10^{10}<n_{\rm H}<10^{11}\ {\rm cm^{-3}})$ and cool temperatures $15<T<50$ K, increasing grain sizes delay molecular depletion. Finally, at low densities $(n_{\rm H}\sim10^{7}\ {\rm cm^{-3}})$, grains do not grow significantly. We also compared our results with a two-step model that reproduces well the abundances of C and O reservoirs, but not the N and S reservoirs. We conclude that the chemical composition of the FHSC is heavily determined by that of the parent prestellar core, chemo-MHD computations are needed for an accurate prediction of the abundances of the main N and S elemental reservoirs, and that the impact of grain growth in moderately dense areas delaying depletion permits the use of abundance ratios as grain growth proxies.

astro-ph.GA↗

arXiv2023

NIKA2 observations of starless cores in Taurus and Perseus

Dusty starless cores play an important role in regulating the initial phases of the formation of stars and planets. In their interiors, dust grains coagulate and ice mantles form, thereby changing the millimeter emissivities and hence the ability to cool. We mapped four regions with more than a dozen cores in the nearby Galactic filaments of Taurus and Perseus using the NIKA2 camera at the IRAM 30-meter telescope. Combining the 1mm to 2mm flux ratio maps with dust temperature maps from Herschel allowed to create maps of the dust emissivity index $β_{1,2}$ at resolutions of 2430 and 5600 a.u. in Taurus and Perseus, respectively. Here, we study the variation with total column densities and environment. $β_{1,2}$ values at the core centers ($A_V=12-19$mag) vary significantly between $\sim1.1$ and $2.3$. Several cores show a strong rise of $β_{1,2}$ from the outskirts at $\sim4$mag to the peaks of optical extinctions, consistent with the predictions of grain models and the gradual build-up of ice mantles on coagulated grains in the dense interiors of starless cores.

astro-ph.GA↗

arXiv2023

Evolution of Chemistry in the envelope of Hot Corinos (ECHOS). I. Extremely young sulphur chemistry in the isolated Class 0 object B335

Within the project Evolution of Chemistry in the envelope of HOt corinoS (ECHOS), we present a study of sulphur chemistry in the envelope of the Class 0 source B335 through observations in the spectral range 7, 3, and 2 mm. We have modelled observations assuming LTE and LVG approximation. We have also used the code Nautilus to study the time evolution of sulphur species. We have detected 20 sulphur species with a total gas-phase S abundance similar to that found in the envelopes of other Class 0 objects, but with significant differences in the abundances between sulphur carbon chains and sulphur molecules containing oxygen and nitrogen. Our results highlight the nature of B335 as a source especially rich in sulphur carbon chains unlike other Class 0 sources. The low presence or absence of some molecules, such as SO and SO+, suggests a chemistry not particularly influenced by shocks. We, however, detect a large presence of HCS+ that, together with the low rotational temperatures obtained for all the S species (<15 K), reveals the moderate or low density of the envelope of B335. We also find that observations are better reproduced by models with a sulphur depletion factor of 10 with respect to the sulphur cosmic elemental abundance. The comparison between our model and observational results for B335 reveals an age of 10$^4$$<$t$<$10$^5$ yr, which highlights the particularly early evolutionary stage of this source. B335 presents a different chemistry compared to other young protostars that have formed in dense molecular clouds, which could be the result of accretion of surrounding material from the diffuse cloud onto the protostellar envelope of B335. In addition, the analysis of the SO2/C2S, SO/CS, and HCS+/CS ratios within a sample of prestellar cores and Class 0 objects show that they could be used as good chemical evolutionary indicators of the prestellar to protostellar transition.

astro-ph.GA↗

arXiv2022

Linking the dust and chemical evolution: Taurus and Perseus -- New collisional rates for HCN, HNC, and their C, N, and H isotopologues

HCN, HNC, and their isotopologues are ubiquitous molecules that can serve as chemical thermometers and evolutionary tracers to characterize star-forming regions. Despite their importance in carrying information that is vital to studies of the chemistry and evolution of star-forming regions, the collision rates of some of these molecules have not been available for rigorous studies in the past. We perform an up-to-date gas and dust chemical characterization of two different star-forming regions, TMC 1-C and NGC 1333-C7, using new collisional rates of HCN, HNC, and their isotopologues. We investigated the possible effects of the environment and stellar feedback in their chemistry and their evolution. With millimeter observations, we derived their column densities, the C and N isotopic fractions, the isomeric ratios, and the deuterium fractionation. The continuum data at 3 mm and 850 $μ$m allowed us to compute the emissivity spectral index and look for grain growth as an evolutionary tracer. The H$^{13}$CN/HN$^{13}$C ratio is anticorrelated with the deuterium fraction of HCN, thus it can readily serve as a proxy for the temperature. The spectral index $(β\sim 1.34-2.09)$ shows a tentative anticorrelation with the H$^{13}$CN/HN$^{13}$C ratio, suggesting grain growth in the evolved, hotter, and less deuterated sources. Unlike TMC 1-C, the south-to-north gradient in dust temperature and spectral index observed in NGC 1333-C7 suggests feedback from the main NGC 1333 cloud. With this up-to-date characterization of two star-forming regions, we found that the chemistry and the physical properties are tightly related. The dust temperature, deuterium fraction, and the spectral index are complementary evolutionary tracers. The large-scale environmental factors may dominate the chemistry and evolution in clustered star-forming regions.

astro-ph.GA↗