arXiv subjects

D. Riquelme

Publications and source records attributed to D. Riquelme.

At least 19 recordsLinked to original sources

arXiv2026

Class I CH3OH Maser Emission from Bar-Driven Inflow Colliding with the Central Molecular Zone

The Central Molecular Zone of the Milky Way is shaped by the interplay of bar-driven inflows, shocks, and star formation. At Galactic longitude l=1.3, gas inflowing along the near-side dust lane has been proposed to interact with the CMZ boundary and overshoot above the Galactic plane, making this a key site to investigate how large-scale gas dynamics regulates star formation. We aim to investigate the presence of Class I methanol maser emission in this transitional region, testing whether large-scale gas interactions in the CMZ can trigger widespread maser activity via star formation or shocks. We conducted a dedicated search for the 36.2 and 44.1 GHz Class I CH3OH maser lines, along with the 48.4 GHz thermal transition, using the Yebes 40m telescope. We complemented these data with archival data from the Herschel-HiGAL survey and the CHIMPS2 survey to explore links between masers, shocks, and star formation. We detect widespread 36.2 GHz maser emission and two candidate 44.1 GHz masers in a region extending several parsecs. The brightest maser has an isotropic luminosity 0.9x10^-3 L_Sun, placing it among the most luminous Galactic Class I masers. Thermal CH3OH and SiO emission extend over mapped area of 24 pc, with both species showing enhanced fractional abundances. CO position-velocity analysis further shows that the masers are associated with an extended velocity feature at VLSR~100 km/s. We conclude that the observed masers are primarily associated with shock-processed gas in a kinematically complex bar-CMZ interface region. Large-scale gas interactions are likely to play an important role in producing the maser emission, although a subset of the masers may also be linked to shocks driven by local star-formation activity. This region therefore provides a promising Galactic analogue of shock-dominated Class I CH3OH maser environments observed in nuclear regions of barred galaxies.

astro-ph.GA↗

arXiv2025

Faint absorption of the ground state hyperfine-splitting transitions of hydroxyl at 18 cm in the Galactic Disk

The interstellar hydride hydroxyl (OH) is a potential tracer of CO-dark molecular gas. We present new absorption line observations of OH at 18-cm wavelength towards four continuum sources. We compare these to the [CII] line at 1.9 THz obtained with SOFIA, observations of the neutral atomic hydrogen 21 cm line with the VLA, and CO lines obtained with APEX. We trace OH over a large range of molecular hydrogen column densities, and derive OH abundances with respect to molecular and total hydrogen column densities. Increased sensitivity and spectral resolution allowed us to detect weak and narrow features. We identify only one OH absorption component out of 23 without CO counterpart, yet several with intermediate molecular gas fractions. A potential association of [CII] 158 mu m emission with an OH absorption component is seen toward one sightline. Our results confirm that OH absorption traces molecular gas across diffuse and dense environments of the interstellar medium. At the sensitivity limits of the present observations our detection of only one CO-dark molecular gas feature appears in agreement with previous studies. We conclude that if OH absorption was to be used as a CO-dark molecular gas tracer, deeper observations or stronger background targets are necessary to unveil its full potential as a CO-dark molecular gas tracer, and yet it will never be an exclusive tracer of CO-dark molecular gas. For OH hyperfine-splitting transitions in the vicinity of photodissociation regions in W43-South, we detect a spectral and spatial offset between the peak of the inversion of the OH 1612 MHz line and the absorption of the OH 1720 MHz line on the one hand, and the absorption of the OH main lines on the other hand, which provides additional constraints on the interpretation of the OH 18 cm line signatures typical of HII regions.

astro-ph.GA↗

arXiv2025

SOFIA/upGREAT imaging spectroscopy of the [C II] 158 um fine structure line toward the Sgr A region in the Galactic center

We present SOFIA/upGREAT velocity-resolved spectral imaging and analysis of the 158 um [C II] spectral line toward the central 80 by 43\,pc region of the Central Molecular Zone of the Galaxy. The field we imaged with 14" (0.6 pc) spatial and 1 km/s spectral resolution contains the Circum-Nuclear Disk (CND) around the central black hole Sgr A*, the neighboring thermal Arched Filaments, the nonthermal filaments of the Radio Arc, and the three luminous central star clusters. [C II] traces emission from the CND's inner edge to material orbiting at a distance of approximately 6 pc. Its velocity field reveals no sign of inflowing material nor interaction with winds from the Sgr A East supernova remnant. Wide-field imaging of the Sgr A region shows multiple circular segments, including the thermal Arched Filaments, that are centered on a region that includes the Quintuplet cluster. We examine the possibility that the Arched Filaments and other large-scale arcs trace transient excitation events from supernova blast waves. Along the Arched Filaments, comparisons among far-IR fine structure lines show changes in ionization state over small scales and that high-excitation lines are systematically shifted in position from the other lines. These also point to transient fast winds that shocked on the surface of the Arches cloud to produce additional local UV radiation to excite the Arched Filaments on a cloud surface illuminated by UV from hot stars.

astro-ph.GA↗

arXiv2024

Star Formation in Extreme Environments: A 200 pc High Velocity Gas Stream in the Galactic Centre

The expanding molecular ring (EMR) manifests itself as a parallelogram in the position-velocity diagram of spectral line emission from the Central Molecular Zone (CMZ) surrounding the Galacic centre (GC). Using multiwavelength data, we investigate the gas kinematics, star formation activity, and the presence of shocked gas in a 200 pc long high velocity gas stream (V~ +150 km/s) with a double helix morphology named the helix stream, that is located 15-55 pc above the CMZ and is kinematically associated with the EMR/parallelogram. We carried out molecular line observations using the IRAM 30m, Yebes 40m, and APEX 12m telescopes. The detection of four rotational transitions of the SiO molecule indicate the presence of shocks. We derived the SiO column densities and abundances in different regions of the helix stream. The presence of protostellar clumps and a candidate HII region signify the ongoing star formation activity within the helix stream. The cloud is massive (2.5x10^6 M_sun) and highly turbulent. We find evidence of cloud-cloud collisions towards the eastern edge (l~1.3°), suggesting a dynamic interaction with the CMZ. An expanding shell is detected within the cloud with radius of 6.7 pc and an expansion velocity of 35 km/s. The shell might be powered by several supernovae or a single hypernova. The SiO abundance within the helix stream implies extensive shock processes occurring on large scales. The helical or cork-screw velocity structure of the helix stream indicates twisting and turning motions within the cloud. We propose that the helix stream is the continuation of the near side bar lane, that is overshooting after brushing the CMZ. Our findings carry profound implications for understanding star formation in extreme conditions and elucidate the intricate properties of gas and dust associated with nuclear inflows in barred spiral galaxies.

astro-ph.GA↗

arXiv2023

A CO Funnel in the Galactic Centre: Molecular Counterpart of the Northern Galactic Chimney?

We report the discovery of a velocity coherent, funnel shaped ^13CO emission feature in the Galactic centre (GC) using data from the SEDIGISM survey. The molecular cloud appears as a low velocity structure (V_LSR=[-3.5, +3.5] km/s) with an angular extent of 0.95° x 1°, extending toward positive Galactic latitudes. The structure is offset from Sgr A* toward negative Galactic longitudes and spatially and morphologically correlates well with the northern lobe of the 430 pc radio bubble, believed to be the radio counterpart of the multiwavelength GC chimney. Spectral line observations in the frequency range of 85-116 GHz have been carried out using the IRAM 30 metre telescope toward 12 positions along the funnel-shaped emission. We examine the ^12C/^13C isotopic ratios using various molecules and their isotopologues. The mean ^12C/^13C isotope ratio (30.6+-2.9) is consistent with the structure located within inner 3 kpc of the Galaxy and possibly in the GC. The velocity of the molecular funnel is consistent with previous radio recombination line measurements of the northern lobe of radio bubble. Our multiwavelength analysis suggests that the funnel shaped structure extending over 100 pc above the Galactic plane is the molecular counterpart of the northern GC chimney.

astro-ph.GA↗

arXiv2021

SOFIA-upGREAT imaging spectroscopy of the [C II] 158um fine structure line of the Sgr B region in the Galactic center

We report SOFIA-upGREAT spectroscopic imaging of the [C II] 158um spectral line, as well as a number of [O I] 63um spectra, across a 67x45 pc field toward the Sgr B region in our Galactic center. The fully-sampled and velocity-resolved [C II] images have 0.55 pc spatial and 1 km/s velocity resolutions. We find that Sgr B extends as a coherent structure spanning some 34 pc along the Galactic plane. Bright [C II] emission encompasses Sgr B1 (G0.5-0.0), the G0.6-0.0 HII region, and passes behind and beyond the luminous star forming cores toward Sgr B2 (G0.7-0.0). Sgr B is a major contributor to the entire Galactic center's [C II] luminosity, with surface brightness comparable to [C II] from the Arches region. [C II], 70um, and 20cm emission share nearly identical spatial distributions. Combined with the lack of [C II] self-absorption, this indicates that these probes trace UV on the near surfaces of more extended clouds visible in CO isotopologues and 160um continuum. Stars from regions of local star formation likely dominate the UV field. Photodissociation regions and HII regions contribute similar amounts of [C II] flux. The extreme star formation cores of Sgr B2 contribute negligible amounts to the total [C II] intensity from the Sgr B region. Velocity fields and association with a narrow dust lane indicate that they may have been produced in a local cloud-cloud collision. The cores are likely local analogs of the intense star formation regions where ideas to explain the "C+ deficit" in ultra-luminous galaxies can be tested.

astro-ph.GA↗

arXiv2021

The Dense Warm Ionized Medium in the Inner Galaxy

Ionized interstellar gas is an important component of the interstellar medium and its lifecycle. The recent evidence for a widely distributed highly ionized warm interstellar gas with a density intermediate between the warm ionized medium (WIM) and compact HII regions suggests that there is a major gap in our understanding of the interstellar gas. Here we investigate the properties of the dense warm ionized medium (D-WIM) in the Milky Way using spectrally resolved SOFIA GREAT [NII] 205 micron line emission and Green Bank Telescope hydrogen radio recombination lines (RRL) data, supplemented by Herschel PACS [NII] 122 micron data, and spectrally resolved 12CO. We observed eight lines of sight in the 20deg 50% of the observed [CII] intensity along these LOS. The kinetic temperatures we derive are too low to explain the presence of N+ resulting from electron collisional ionization and/or proton charge transfer of atomic nitrogen. Rather, these regions most likely are ionized by extreme ultraviolet radiation.

astro-ph.GA↗

arXiv2021

The distribution of ionized, atomic and PDR gas around S1 in Rho Ophiuchus

The early B star S1 in the Rho Ophiuchus cloud excites an HII region and illuminates a large egg-shaped photodissociation (PDR) cavity. The PDR is restricted to the west and south-west by the dense molecular Rho Oph A ridge, expanding more freely into the diffuse low density cloud to the north-east. We analyze new SOFIA GREAT, GMRT and APEX data together with archival data from Herschel/PACS, JCMT/HARPS to study the properties of the photo-irradiated ionized and neutral gas in this region. The tracers include [C II] at 158 micron, [O I] at 63 and 145 micron, J=6-5 transitions of CO and 13CO, HCO+ (4-3), radio continuum at 610 and 1420 MHz and HI at 21 cm. The PDR emission is strongly red-shifted to the south-east of the nebula, and primarily blue-shifted on the north western side. The [C II] and and [O I]63 spectra are strongly self-absorbed over most of the PDR. By using the optically thin counterparts, [13C II] and [O I]145 respectively, we conclude that the self-absorption is dominated by the warm (>80 K) foreground PDR gas and not by the surrounding cold molecular cloud. We estimate the column densities of C+ and O of the PDR to be 3e18 and 2e19 cm^-2, respectively. Comparison of stellar far-ultraviolet flux and reprocessed infrared radiation suggest enhanced clumpiness of the gas to the north-west. Analysis of the emission from the PDR gas suggests the presence of at least three density components consisting of high density (10^6 cm^-3) clumps, medium density (10^4 cm^-3) and diffuse (10^3 cm^-3) interclump medium. The medium density component primarily contributes to the thermal pressure of the PDR gas which is in pressure equilibrium with the molecular cloud to the west. We find that the PDR is tilted and warped with the south-eastern side of the cavity being denser on the front and the north-western side being denser on the rear.

astro-ph.GA↗

arXiv2021

Bottlenecks to interstellar sulfur chemistry: Sulfur-bearing hydrides in UV-illuminated gas and grains

Hydride molecules lie at the base of interstellar chemistry, but the synthesis of sulfuretted hydrides is poorly understood. Motivated by new observations of the Orion Bar PDR - 1'' resolution ALMA images of SH+; IRAM 30m detections of H2S, H2S34, and H2S33; H3S+ (upper limits); and SOFIA observations of SH - we perform a systematic study of the chemistry of S-bearing hydrides. We determine their column densities using coupled excitation, radiative transfer as well as chemical formation and destruction models. We revise some of the key gas-phase reactions that lead to their chemical synthesis. This includes ab initio quantum calculations of the vibrational-state-dependent reactions SH+ + H2 <-> H2S+ + H and S + H2 <-> SH + H. We find that reactions of UV-pumped H2 (v>1) with S+ explain the presence of SH+ in a high thermal-pressure gas component, P_th~10^8 cm^-3 K, close to the H2 dissociation front. However, subsequent hydrogen abstraction reactions of SH+, H2S+, and S with vibrationally excited H2, fail to ultimately explain the observed H2S column density (~2.5x10^14 cm^-2, with an ortho-to-para ratio of 2.9+/-0.3). To overcome these bottlenecks, we build PDR models that include a simple network of grain surface reactions leading to the formation of solid H2S (s-H2S). The higher adsorption binding energies of S and SH suggested by recent studies imply that S atoms adsorb on grains (and form s-H2S) at warmer dust temperatures and closer to the UV-illuminated edges of molecular clouds. Photodesorption and, to a lesser extent, chemical desorption, produce roughly the same H2S column density (a few 10^14 cm-^2) and abundance peak (a few 10^-8) nearly independently of n_H and G_0. This agrees with the observed H2S column density in the Orion Bar as well as at the edges of dark clouds without invoking substantial depletion of elemental sulfur abundances.

astro-ph.GA↗

arXiv2020

Interstellar anatomy of the TeV gamma-ray peak in the IC443 supernova remnant

Supernovae remnants (SNRs) represent a major feedback source from stars on the interstellar medium of galaxies. During the latest stage of supernovae explosions, shock waves produced by the initial blast modify the chemistry of gas and dust, inject kinetic energy in the surroundings, and may alter star formation characteristics. Simultaneously, gamma-ray emission is generated by the interaction between the ambiant medium and the cosmic rays. We study the stellar and interstellar contents of IC443, an evolved shell type SNR at a distance of 1.9 kpc, with an estimated age of 30 kyr. We aim to measure the mass of the gas within the extended G region, which corresponds to the peak of gamma-ray emission detected by VERITAS and Fermi. We performed 10'x10' mapped observations of 12CO and 13CO J=1-0, J=2-1 and J=3-2 pure rotational lines, as well as C18O J=1-0 and J=2-1 obtained with the IRAM-30m and APEX telescopes. We first compared our data with local thermodynamic equilbrium (LTE) models. We estimated the optical depth of each line from the emission of the isotopologues 13CO and C18O. We used the population diagram and large velocity gradient (LVG) assumption to measure the column density, mass, and kinetic temperature of the gas using 12CO and 13CO lines. We used complementary data (stars, gas, and dust at multiple wavelengths) and infrared point source catalogues to search for protostar candidates. Our results emphasize how the mass associated with the ring-like structure and the cloudlet cannot be overlooked when quantifying the interaction of cosmic rays with the dense local medium. Additionally, the presence of numerous possible protostars in the region might represent a fresh source of CR, which must also be taken into account in the interpretation of gamma-ray observations in this region.

astro-ph.HE↗

arXiv2020

Sulphur and carbon isotopes towards Galactic centre clouds

Measuring isotopic ratios is a sensitive technique used to obtain information on stellar nucleosynthesis and chemical evolution. We present measurements of the carbon and sulphur abundances in the interstellar medium of the central region of our Galaxy. The selected targets are the +50km/s Cloud and several l.o.s. clouds towards Sgr B2(N). Towards the +50km/s Cloud, we observed the J=2-1 rotational transitions of CS, C34S, 13CS, C33S, and 13C34S, and the J=3-2 transitions of CS and C34S with the IRAM-30m telescope, as well as the J=6-5 transitions of C34S and 13CS with the APEX 12m telescope, all in emission. The J=2-1 rotational transitions of CS, C34S, 13CS, and 13C34S were observed with ALMA in the envelope of Sgr B2(N), with those of CS and C34S also observed in the l.o.s. clouds towards Sgr B2(N), all in absorption. In the +50km/s Cloud we derive a 12C13C isotopic ratio of ~22.1, that leads, with the measured 13CS/C34S line intensity ratio, to a 32S/34S ratio of 16.3+3.0-2.4. We also derive the 32S/34S isotopic ratio more directly from the two isotopologues 13CS and 13C34S, which leads to an independent 32S/34S estimation of 16.3+2.1-1.7 and 17.9+-5.0 for the +50km/s Cloud and Sgr B2(N), respectively. We also obtain a 34S/33S ratio of ~4.3 in the +50 km/s Cloud. Previous studies observed a decreasing trend in the 32S/34S isotopic ratios when approaching the Galactic centre. Our result indicates a termination of this tendency at least at a galactocentric distance of 130-30+60 pc. This is at variance with findings based on 12C/13C, 14N/15N and 18O/17O isotope ratios, where the above-mentioned trend is observed to continue right to the central molecular zone. This can indicate a drop in the production of massive stars at the Galactic centre, in the same line as recent metallicity gradient studies, and opens the work towards a comparison with Galactic and stellar evolution models.

astro-ph.GA↗

arXiv2020

On the effects of UV photons/X-rays on the chemistry of the Sgr B2 cloud

The lines of HOC$^+$, HCO and CO$^+$ are considered good tracers of photon-dominated regions (PDRs) and X-ray dominated regions. We study these tracers towards regions of the Sgr B2 cloud selected to be affected by different heating mechanisms. We find the lowest values of the column density ratios of HCO$^+$ versus HOC$^+$, HCO and CO$^+$ in dense HII gas, where UV photons dominate the heating and chemistry of gas. HOC$^+$, HCO and CO$^+$ abundances and the above ratios are compared with those of chemical modeling, finding that high temperature chemistry, a cosmic-ray ionization rate of 10$^{-16}$ s$^{-1}$ and timescales $>$10$^{5.0}$ years explain well the HOC$^+$ abundances in quiescent Sgr B2 regions, while shocks are also needed to explain the highest HCO abundances derived for these regions. CO$^+$ is mainly formed in PDRs since the highest CO$^+$ abundances of $\sim$(6-10)$\times$10$^{-10}$ are found in HII regions with electron densities $>$540 cm$^{-3}$ and that CO$^+$ emission is undetected in quiescent gas. Between the ratios, the HCO$^+$/HCO ratio is sensitive to the electron density as it shows different values in dense and diffuse HII regions. We compare SiO J=2-1 emission maps of Sgr B2 with X-ray maps from 2004 and 2012. One known spot shown on the 2012 X-ray map is likely associated with molecular gas at velocities of 15-25 km s$^{-1}$. We also derive the X-ray ionization rate of $\sim$10$^{-19}$ s$^{-1}$ for Sgr B2 regions pervaded by X-rays in 2004, which is quite low to affect the chemistry of the molecular gas.

astro-ph.GA↗

arXiv2019

Opening the Treasure Chest in Carina

We have mapped the G287.84-0.82 cometary globule (with the Treasure Chest cluster embedded in it) in the South Pillars region of Carina (i) in [CII], 63micron [OI], and CO(11-10) using upGREAT on SOFIA and (ii) in J=2-1 transitions of CO, 13CO, C18O and J=3-2 transitions of H2CO using the APEX telescope in Chile. We probe the morphology, kinematics, and physical conditions of the molecular gas and the photon dominated regions (PDRs) in G287.84-0.82. The [CII] and [OI] emission suggest that the overall structure of the pillar (with red-shifted photo evaporating tails) is consistent with the effect of FUV radiation and winds from eta-Car and O stars in Trumpler 16. The gas in the head of the pillar is strongly influenced by the embedded cluster, whose brightest member is an O9.5V star, CPD-59 2661. The emission of the [CII] and [OI] lines peak at a position close to the embedded star, while all other tracers peak at another position lying to the north-east consistent with gas being compressed by the expanding PDR created by the embedded cluster. The molecular gas inside the globule is probed with the J=2-1 transitions of CO and isotopologues as well as H2CO, and analyzed using a non-LTE model (escape-probability approach), while we use PDR models to derive the physical conditions of the PDR. We identify at least two PDR gas components; the diffuse part (~10^4 cm^-3) is traced by [CII], while the dense (n~ 2-8x10^5 cm^-3) part is traced by [CII], [OI], CO(11-10). Using the F=2-1 transition of [13CII] detected at 50 positions in the region, we derive optical depths (0.9-5), excitation temperatures of [CII] (80-255 K), and N(C+) of 0.3-1x10^19 cm^-2. The total mass of the globule is ~1000 Msun, about half of which is traced by [CII]. The dense PDR gas has a thermal pressure of 10^7-10^8 K cm^-3, which is similar to the values observed in other regions.

astro-ph.GA↗

arXiv2018

The upGREAT dual frequency heterodyne arrays for SOFIA

We present the performance of the upGREAT heterodyne array receivers on the SOFIA telescope after several years of operations. This instrument is a multi-pixel high resolution (R > 10^7) spectrometer for the Stratospheric Observatory for Far-Infrared Astronomy (SOFIA). The receivers use 7-pixel subarrays configured in a hexagonal layout around a central pixel. The low frequency array receiver (LFA) has 2x7 pixels (dual polarization), and presently covers the 1.83-2.06 THz frequency range, which allows to observe the [CII] and [OI] lines at 158 um and 145 um wavelengths. The high frequency array (HFA) covers the [OI] line at 63 um and is equipped with one polarization at the moment (7 pixels, which can be upgraded in the near future with a second polarization array). The 4.7 THz array has successfully flown using two separate quantum-cascade laser local oscillators from two different groups. NASA completed the development, integration and testing of a dual-channel closed-cycle cryocooler system, with two independently operable He compressors, aboard SOFIA in early 2017 and since then, both arrays can be operated in parallel using a frequency separating dichroic mirror. This configuration is now the prime GREAT configuration and has been added to SOFIA's instrument suite since observing cycle 6.

astro-ph.IM↗

arXiv2018

Abundant Z-cyanomethanimine in the interstellar medium: paving the way to the synthesis of adenine

We report the first detection in the interstellar medium of the Z-isomer of cyanomethanimine (HNCHCN), an HCN dimer proposed as precursor of adenine. We identified six transitions of Z-cyanomethanimine, along with five transitions of E-cyanomethanimine, using IRAM 30m observations towards the Galactic Center quiescent molecular cloud G+0.693. The Z-isomer has a column density of (2.0$\pm$0.6)$\times$10$^{14}$ cm$^{-2}$ and an abundance of 1.5$\times$10$^{-9}$. The relative abundance ratio between the isomers is [Z/E]$\sim$6. This value cannot be explained by the two chemical formation routes previously proposed (gas-phase and grain surface), which predicts abundances ratios between 0.9 and 1.5. The observed [Z/E] ratio is in good agreement with thermodynamic equilibrium at the gas kinetic temperature (130$-$210 K). Since isomerization is not possible in the ISM, the two species may be formed at high temperature. New chemical models, including surface chemistry on dust grains and gas-phase reactions, should be explored to explain our findings. Whatever the formation mechanism, the high abundance of Z-HNCHCN shows that precursors of adenine are efficiently formed in the ISM.

astro-ph.GA↗

arXiv2018

Complex organic molecules in the Galactic Centre: the N-bearing family

We present an unbiased spectral line survey toward the Galactic Centre (GC) quiescent giant molecular cloud (QGMC), G+0.693 using the GBT and IRAM 30$\,$ telescopes. Our study highlights an extremely rich organic inventory of abundant amounts of nitrogen (N)-bearing species in a source without signatures of star formation. We report the detection of 17 N-bearing species in this source, of which 8 are complex organic molecules (COMs). A comparison of the derived abundances relative to H$_2$ is made across various galactic and extragalactic environments. We conclude that the unique chemistry in this source is likely to be dominated by low-velocity shocks with X-rays/cosmic rays also playing an important role in the chemistry. Like previous findings obtained for O-bearing molecules, our results for N-bearing species suggest a more efficient hydrogenation of these species on dust grains in G+0.693 than in hot cores in the Galactic disk, as a consequence of the low dust temperatures coupled with energetic processing by X-ray/cosmic ray radiation in the GC.

astro-ph.GA↗

arXiv2017

Phosphorus-bearing molecules in the Galactic Center

Phosphorus (P) is one of the essential elements for life due to its central role in biochemical processes. Recent searches have shown that P-bearing molecules (in particular PN and PO) are present in star-forming regions, although their formation routes remain poorly understood. In this Letter, we report observations of PN and PO towards seven molecular clouds located in the Galactic Center, which are characterized by different types of chemistry. PN is detected in five out of seven sources, whose chemistry is thought to be shock-dominated. The two sources with PN non-detections correspond to clouds exposed to intense UV/X-rays/cosmic-ray radiation. PO is detected only towards the cloud G+0.693$-$0.03, with a PO/PN abundance ratio of $\sim$1.5. We conclude that P-bearing molecules likely form in shocked gas as a result of dust grain sputtering, while are destroyed by intense UV/X-ray/cosmic ray radiation.

astro-ph.GA↗

arXiv2017

The foot points of the Giant Molecular Loops in the Galactic center region

Aims: To reveal the morphology, chemical composition, kinematics and to establish the main processes prevalent in the gas at the foot points of the giant molecular loops (GMLs) in the Galactic center region Methods: Using the 22-m Mopra telescope, we mapped the M$-3.8+0.9$ molecular cloud, placed at the foot points of a giant molecular loop, in 3-mm range molecular lines. To derive the molecular hydrogen column density, we also observed the $^{13}$CO $(2-1)$ line at 1 mm using the 12-m APEX telescope. From the 3 mm observations 12 molecular species were detected, namely HCO$^+$, HCN, H$^{13}$CN, HNC, SiO, CS, CH$_3$OH, N$_2$H$^+$, SO, HNCO, OCS, and HC$_3$N. Results: Maps revealing the morphology and kinematics of the M$-3.8+0.9$ molecular cloud in different molecules are presented. We identified six main molecular complexes. We derive fractional abundances in 11 selected positions of the different molecules assuming local thermodynamical equilibrium. Conclusions: Most of the fractional abundances derived for the M$-3.8+0.9$ molecular cloud are very similar over the whole cloud. However, the fractional abundances of some molecules show significant difference with respect to those measured in the central molecular zone (CMZ). The abundances of the shock tracer SiO are very similar between the GMLs and the CMZ. The methanol emission is the most abundant specie in the GMLs. This indicates that the gas is likely affected by moderate $\sim $ 30 km s$^{-1}$ or even high velocity (50 km s$^{-1}$) shocks, consistent with the line profile observed toward one of the studied position. The origin of the shocks is likely related to the flow of the gas throughout the GMLs towards the foot points.

astro-ph.GA↗