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D. Teyssier

Publications and source records attributed to D. Teyssier.

At least 55 records · Page 3Linked to original sources

Velocity-resolved [CII] emission and [CII]/FIR Mapping along Orion with Herschel

We present the first 7.5'x11.5' velocity-resolved map of the [CII]158um line toward the Orion molecular cloud-1 (OMC-1) taken with the Herschel/HIFI instrument. In combination with far-infrared (FIR) photometric images and velocity-resolved maps of the H41alpha hydrogen recombination and CO J=2-1 lines, this data set provides an unprecedented view of the intricate small-scale kinematics of the ionized/PDR/molecular gas interfaces and of the radiative feedback from massive stars. The main contribution to the [CII] luminosity (~85%) is from the extended, FUV-illuminated face of the cloud G_0>500, n_H>5x10^3 cm^-3) and from dense PDRs (G_0~10^4, n_H~10^5 cm^-3) at the interface between OMC-1 and the HII region surrounding the Trapezium cluster. Around 15% of the [CII] emission arises from a different gas component without CO counterpart. The [CII] excitation, PDR gas turbulence, line opacity (from [13CII]) and role of the geometry of the illuminating stars with respect to the cloud are investigated. We construct maps of the [CII]/FIR and FIR/M_Gas ratios and show that [CII]/FIR decreases from the extended cloud component (10^-2-10^-3) to the more opaque star-forming cores (10^-3-10^-4). The lowest values are reminiscent of the "[CII] deficit" seen in local ultra-luminous IR galaxies hosting vigorous star formation. Spatial correlation analysis shows that the decreasing [CII]/FIR ratio correlates better with the column density of dust through the molecular cloud than with FIR/M_Gas. We conclude that the [CII] emitting column relative to the total dust column along each line of sight is responsible for the observed [CII]/FIR variations through the cloud.

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New observations and models of circumstellar CO line emission of AGB stars in the Herschel SUCCESS programme

CONTEXT: Asymptotic giant branch (AGB) stars are in one of the latest evolutionary stages of low to intermediate-mass stars. Their vigorous mass loss has a significant effect on the stellar evolution, and is a significant source of heavy elements and dust grains for the interstellar medium. The mass-loss rate can be well traced by carbon monoxide (CO) line emission. AIMS: We present new Herschel HIFI and IRAM 30m telescope CO line data for a sample of 53 galactic AGB stars. The lines cover a fairly large range of excitation energy from the $J=1\to0$ line to the $J=9\to8$ line, and even the $J=14\to13$ line in a few cases. We perform radiative transfer modelling for 38 of these sources to estimate their mass-loss rates. METHODS: We used a radiative transfer code based on the Monte Carlo method to model the CO line emission. We assume spherically symmetric circumstellar envelopes that are formed by a constant mass-loss rate through a smoothly accelerating wind. RESULTS: We find models that are consistent across a broad range of CO lines for most of the stars in our sample, i.e., a large number of the circumstellar envelopes can be described with a constant mass-loss rate. We also find that an accelerating wind is required to fit, in particular, the higher-J lines and that a velocity law will have a significant effect on the model line intensities. The results cover a wide range of mass-loss rates ($\sim 10^{-8}$ to $2\times 10^{-5}~\mathrm{M}_\odot~\mathrm{ yr}^{-1}$) and gas expansion velocities (2 to $21.5$ km s$^{-1}$), and include M-, S-, and C-type AGB stars. Our results generally agree with those of earlier studies, although we tend to find slightly lower mass-loss rates by about 40%, on average. We also present "bonus" lines detected during our CO observations.

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Herschel observations of extreme OH/IR stars - the isotopic ratios of oxygen as a sign-post for the stellar mass

Aim: The late stages of stellar evolution are mainly governed by the mass of the stars. Low- and intermediate-mass stars lose copious amounts of mass during the asymptotic giant branch (AGB) which obscure the central star making it difficult to study the stellar spectra and determine the stellar mass. In this study, we present observational data that can be used to determine lower limits to the stellar mass. Method: Spectra of nine heavily reddened AGB stars taken by the Herschel Space Observatory display numerous molecular emission lines. The strongest emission lines are due to H2O. We search for the presence of isotopologues of H2O in these objects. Result: We detected the 16O and 17O isotopologues of water in these stars, but lines due to H2^{18}O are absent. The lack of 18O is predicted by a scenario where the star has undergone hot-bottom burning which preferentially destroys 18O relative to 16O and 17O. From stellar evolution calculations, this process is thought to occur when the stellar mass is above 5 Msun for solar metallicity. Hence, observations of different isotopologues of H2O can be used to help determine the lower limit to the initial stellar mass. Conclusion: From our observations, we deduce that these extreme OH/IR stars are intermediate-mass stars with masses of >= 5 Msun. Their high mass-loss rates of ~ 1.0e-4 Msun/yr may affect the enrichment of the interstellar medium and the overall chemical evolution of our Galaxy.

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Discovery of Time Variation of the Intensity of Molecular Lines in IRC+10216 in The Submillimeter and Far Infrared Domains

We report on the discovery of strong intensity variations in the high rotational lines of abundant molecular species towards the archetypical circumstellar envelope of IRC+10216. The observations have been carried out with the HIFI instrument on board \textit{Herschel}\thanks{\textit{Herschel} is an ESA space observatory with science instruments provided by European-led Principal Investigator consortia and with important participation from NASA} and with the IRAM\thanks{This work was based on observations carried out with the IRAM 30-meter telescope. IRAM is supported by INSU/CNRS (France), MPG (Germany) and IGN (Spain)} 30-m telescope. They cover several observing periods spreading over 3 years. The line intensity variations for molecules produced in the external layers of the envelope most probably result from time variations in the infrared pumping rates. We analyze the main implications this discovery has on the interpretation of molecular line emission in the envelopes of Mira-type stars. Radiative transfer calculations have to take into account both the time variability of infrared pumping and the possible variation of the dust and gas temperatures with stellar phase in order to reproduce the observation of molecular lines at different epochs. The effect of gas temperature variations with stellar phase could be particularly important for lines produced in the innermost regions of the envelope. Each layer of the circumstellar envelope sees the stellar light radiation with a different lag time (phase). Our results show that this effect must be included in the models. The sub-mm and FIR lines of AGB stars cannot anymore be considered as safe intensity calibrators.

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Physical structure of the photodissociation regions in NGC 7023. Observations of gas and dust emission with Herschel

The determination of the physical conditions in molecular clouds is a key step towards our understanding of their formation and evolution of associated star formation. We investigate the density, temperature, and column density of both dust and gas in the photodissociation regions (PDRs) located at the interface between the atomic and cold molecular gas of the NGC 7023 reflection nebula. We study how young stars affect the gas and dust in their environment. Our approach combining both dust and gas delivers strong constraints on the physical conditions of the PDRs. We find dense and warm molecular gas of high column density in the PDRs.

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The wind of W Hya as seen by Herschel. II. The molecular envelope of W Hya

The evolution of low- and intermediate-mass stars on the asymptotic giant branch (AGB) is mainly controlled by the rate at which these stars lose mass in a stellar wind. Understanding the driving mechanism and strength of the stellar winds of AGB stars and the processes enriching their surfaces with products of nucleosynthesis are paramount to constraining AGB evolution and predicting the chemical evolution of galaxies. In a previous paper we have constrained the structure of the outflowing envelope of W Hya using spectral lines of the $^{12}$CO molecule. Here we broaden this study by modelling an extensive set of H$_{2}$O and $^{28}$SiO lines observed by the three instruments on board Herschel using a state-of-the-art molecular excitation and radiative transfer code. The oxygen isotopic ratios and the $^{28}$SiO abundance profile can be connected to the initial stellar mass and to crucial aspects of dust formation at the base of the stellar wind, respectively. The modelling of H$_{2}$O and $^{28}$SiO confirms the properties of the envelope model of W Hya derived from $^{12}$CO lines. We find an H$_2$O ortho-to-para ratio of 2.5\,$^{+2.5}_{-1.0}$, consistent with what is expected for an AGB wind. The O$^{16}$/O$^{17}$ ratio indicates that W Hya has an initial mass of about 1.5 M$_\odot$. Although the ortho- and para-H$_{2}$O lines observed by HIFI appear to trace gas of slightly different physical properties, a turbulence velocity of $0.7\pm0.1$ km s$^{-1}$ fits the HIFI lines of both spin isomers and those of $^{28}$SiO well. The ortho- and para-H$_2^{16}$O and $^{28}$SiO abundances relative to H$_{2}$ are $(6^{+3}_{-2}) \times 10^{-4}$, $(3^{+2}_{-1}) \times 10^{-4}$, and $(3.3\pm 0.8)\times 10^{-5}$, respectively. Assuming a solar silicon-to-carbon ratio, the $^{28}$SiO line emission model is consistent with about one-third of the silicon atoms being locked up in dust particles.

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Confirmation of circumstellar phosphine

Phosphine (PH3) was tentatively identified a few years ago in the carbon star envelopes IRC+10216 and CRL2688 from observations of an emission line at 266.9 GHz attributable to the J=1-0 rotational transition. We report the detection of the J=2-1 rotational transition of PH3 in IRC+10216 using the HIFI instrument on board Herschel, which definitively confirms the identification of PH3. Radiative transfer calculations indicate that infrared pumping to excited vibrational states plays an important role in the excitation of PH3 in the envelope of IRC+10216, and that the observed lines are consistent with phosphine being formed anywhere between the star and 100 R* from the star, with an abundance of 1e-8 relative to H2. The detection of PH3 challenges chemical models, none of which offers a satisfactory formation scenario. Although PH3 locks just 2 % of the total available phosphorus in IRC+10216, it is together with HCP, one of the major gas phase carriers of phosphorus in the inner circumstellar layers, suggesting that it could be also an important phosphorus species in other astronomical environments. This is the first unambiguous detection of PH3 outside the solar system, and a further step towards a better understanding of the chemistry of phosphorus in space.

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Polarisation Observations of H$_{2}$O $J_{K_{-1}K_{1}} = 5_{32} - 4_{41}$ 620.701 GHz Maser Emission with Herschel/HIFI in Orion KL

Context. The high intensities and narrow bandwidths exhibited by some astronomical masers make them ideal tools for studying star-forming giant molecular clouds. The water maser transition $J_{K_{-1}K_{1}}=5_{32}-4_{41}$ at 620.701 GHz can only be observed from above Earth's strongly absorbing atmosphere; its emission has recently been detected from space. Aims. We sought to further characterize the star-forming environment of Orion KL by investigating the linear polarisation of a source emitting a narrow 620.701 GHz maser feature with the heterodyne spectrometer HIFI on board the Herschel Space Observatory. Methods. High-resolution spectral datasets were collected over a thirteen month period beginning in 2011 March, to establish not only the linear polarisation but also the temporal variability of the source. Results. Within a $3σ$ uncertainty, no polarisation was detected to an upper limit of approximately 2%. These results are compared with coeval linear polarisation measurements of the 22.235 GHz $J_{K_{-1}K_{1}}=6_{16}-5_{23}$ maser line from the Effelsberg 100-m radio telescope, typically a much stronger maser transition. Although strongly polarised emission is observed for one component of the 22.235 GHz maser at 7.2 km s$^{-1}$, a weaker component at the same velocity as the 620.701 GHz maser at 11.7 km s$^{-1}$ is much less polarised.

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Herschel observations of gas and dust in comet C/2006 W3 (Christensen) at 5 AU from the Sun

We aimed to measure the H2O and dust production rates in C/2006 W3 (Christensen) with the Herschel Space Observatory at a heliocentric distance of ~ 5 AU. We have searched for emission in the H2O and NH3 ground-state rotational transitions at 557 GHz and 572 GHz, simultaneously, with HIFI onboard Herschel on UT 1.5 September 2010. Photometric observations of the dust coma in the 70 and 160 μm channels were acquired with the PACS instrument on UT 26.5 August 2010. A tentative 4-σ H2O line emission feature was found in the spectra obtained with the HIFI wide-band and high-resolution spectrometers, from which we derive a water production rate of $2.0(5) \times 10^{27}$ molec. s$^{-1}$. A 3-σ upper limit for the ammonia production rate of <$1.5 \times 10^{27}$ molec. s$^{-1}$ is obtained taking into account the contribution from all hyperfine components. The blueshift of the water line detected by HIFI suggests preferential emission from the subsolar point. However, it is also possible that water sublimation occurs in small ice-bearing grains that are emitted from an active region on the nucleus surface at a speed of ~ 0.2 km s$^{-1}$. The dust thermal emission was detected in the 70 and 160 μm filters, with a more extended emission in the blue channel. The dust production rates, obtained for a dust size distribution index that explains the fluxes at the photocenters of the PACS images, lie in the range 70-110 kg s$^{-1}$. Scaling the CO production rate measured post-perihelion at 3.20 and 3.32 AU, these values correspond to a dust-to-gas production rate ratio in the range 0.3-0.4. The dust production rates derived in August 2010 are roughly one order of magnitude lower than in September 2009, suggesting that the dust-to-gas production rate ratio remained approximately constant during the period when the activity became increasingly dominated by CO outgassing.

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Herschel and IRAM-30m Observations of Comet C/2012 S1 (ISON) at 4.5 AU from the Sun

Our goal was to characterize the distant gaseous and dust activity of comet C\2012 S1 (ISON), inbound, from observations of H2O, CO and the dust coma in the far-infrared and submillimeter domains. In this paper, we report observations undertaken with the Herschel Space Observatory on 8 & 13 March 2013 (rh = 4.54 - 4.47AU) and with the 30m telescope of Institut de Radioastronomie Millimétrique (IRAM) in March and April 2013 (rh = 4.45 - 4.18 AU). The HIFI instrument aboard Herschel was used to observe the H$_{2}$O $1_{10}-1_{01}$ line at 557 GHz, whereas images of the dust coma at 70 and 160 μm were acquired with the PACS instrument. Spectra acquired at the IRAM 30m telescope cover the CO J(2-1) line at 230.5 GHz. The spectral observations were analysed with excitation and radiative transfer models. A model of dust thermal emission taking into account a range of dust sizes is used to analyse the PACS maps. While H$_{2}$O was not detected in our 8 March 2013 observation, we derive a sensitive 3 $σ$ upper limit of QH$_{2}$O < 3.5 x 10$^{26}$ molecules/s for this date. A marginal 3.2 $σ$ detection of CO is found, corresponding to a CO production rate of QCO = 3.5 x 10$^{27}$ molecules/s. The Herschel PACS measurements show a clear detection of the coma and tail in both the 70 μm and 160 μm maps. Under the assumption of a 2 km radius nucleus, we infer dust production rates in the range 10 - 13 kg/s or 40 - 70 kg/s depending on whether a low or high gaseous activity from the nucleus surface is assumed. We constrain the size distribution of the emitted dust by comparing PACS 70 and 160 μm data, and considering optical data. Size indices between -4 and -3.6 are suggested. The morphology of the tail observed on 70 μm images can be explained by the presence of grains with ages older than 60 days.

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Herschel celestial calibration sources: Four large main-belt asteroids as prime flux calibrators for the far-IR/sub-mm range

Celestial standards play a major role in observational astrophysics. They are needed to characterise the performance of instruments and are paramount for photometric calibration. During the Herschel Calibration Asteroid Preparatory Programme approximately 50 asteroids have been established as far-IR/sub-mm/mm calibrators for Herschel. The selected asteroids fill the flux gap between the sub-mm/mm calibrators Mars, Uranus and Neptune, and the mid-IR bright calibration stars. All three Herschel instruments observed asteroids for various calibration purposes, including pointing tests, absolute flux calibration, relative spectral response function, observing mode validation, and cross-calibration aspects. Here we present newly established models for the four large and well characterized main-belt asteroids (1) Ceres, (2) Pallas, (4) Vesta, and (21) Lutetia which can be considered as new prime flux calibrators. The relevant object-specific properties (size, shape, spin-properties, albedo, thermal properties) are well established. The seasonal (distance to Sun, distance to observer, phase angle, aspect angle) and daily variations (rotation) are included in a new thermophysical model setup for these targets. The thermophysical model predictions agree within 5% with the available (and independently calibrated) Herschel measurements. The four objects cover the flux regime from just below 1,000 Jy (Ceres at mid-IR N-/Q-band) down to fluxes below 0.1 Jy (Lutetia at the longest wavelengths). Based on the comparison with PACS, SPIRE and HIFI measurements and pre-Herschel experience, the validity of these new prime calibrators ranges from mid-infrared to about 700 micron, connecting nicely the absolute stellar reference system in the mid-IR with the planet-based calibration at sub-mm/mm wavelengths.

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HIFISTARS Herschel/HIFI observations of VY Canis Majoris. Molecular-line inventory of the envelope around the largest known star

To gain insight into the physical conditions and kinematics of the warm (100-1000 K) gas around the red hyper-giant VY CMa, we performed sensitive high spectral resolution observations of molecular lines in the sub-mm/FIR using the HIFI instrument of the Herschel Space Observatory. We observed CO, H2O, and other molecular species, sampling excitation energies from a few tens to a few thousand K. These observations are part of the Herschel Guaranteed Time Key Program HIFISTARS. We detected the J=6-5, J=10-9, and J=16-15 lines of 12CO and 13CO at about 100, 300, and 750K above the ground state (and the 13CO J=9-8 line). These lines are crucial for improving the modelling of the internal layers of the envelope around VY CMa. We also detected 27 lines of H2O and its isotopomers, and 96 lines of species such as NH3, SiO, SO, SO2 HCN, OH and others, some of them originating from vibrationally excited levels. Three lines were not unambiguously assigned. Our observations confirm that VY CMa's envelope must consist of two or more detached components. The molecular excitation in the outer layers is significantly lower than in the inner ones, resulting in strong self-absorbed profiles in molecular lines that are optically thick in this outer envelope, for instance, low-lying lines of H2O. Except for the most abundant species, CO and H2O, most of the molecular emission detected at these sub-mm/FIR wavelengths arise from the central parts of the envelope. The spectrum of VY CMa is very prominent in vibrationally excited lines, which are caused by the strong IR pumping present in the central regions. Compared with envelopes of other massive evolved stars, VY CMa's emission is particularly strong in these vibrationally excited lines, as well as in the emission from less abundant species such as H13CN, SO, and NH3.

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Nitrogen isotopic ratios in Barnard 1: a consistent study of the N2H+, NH3, CN, HCN and HNC isotopologues

The 15N isotopologue abundance ratio measured today in different bodies of the solar system is thought to be connected to 15N-fractionation effects that would have occured in the protosolar nebula. The present study aims at putting constraints on the degree of 15N-fractionation that occurs during the prestellar phase, through observations of D, 13C and 15N-substituted isotopologues towards B1b. Both molecules from the nitrogen hydride family, i.e. N2H+ and NH3, and from the nitrile family, i.e. HCN, HNC and CN, are considered in the analysis. As a first step, we model the continuum emission in order to derive the physical structure of the cloud, i.e. gas temperature and H2 density. These parameters are subsequently used as an input in a non-local radiative transfer model to infer the radial abundances profiles of the various molecules. Our modeling shows that all the molecules are affected by depletion onto dust grains, in the region that encompasses the B1-bS and B1-bN cores. While high levels of deuterium fractionation are derived, we conclude that no fractionation occurs in the case of the nitrogen chemistry. Independently of the chemical family, the molecular abundances are consistent with 14N/15N~300, a value representative of the elemental atomic abundances of the parental gas. The inefficiency of the 15N-fractionation effects in the B1b region can be linked to the relatively high gas temperature ~17K which is representative of the innermost part of the cloud. Since this region shows signs of depletion onto dust grains, we can not exclude the possibility that the molecules were previously enriched in 15N, earlier in the B1b history, and that such an enrichment could have been incorporated into the ice mantles. It is thus necessary to repeat this kind of study in colder sources to test such a possibility.

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OH/IR stars and their superwinds as observed by the Herschel Space Observatory

Aim : In order to study the history of mass loss in extreme OH/IR stars, we observed a number of these objects using CO as a tracer of the density and temperature structure of their circumstellar envelopes. Method : Combining CO observations from the Herschel Space Observatory with those from the ground, we trace mass loss rates as a function of radius in five extreme OH/IR stars. Using radiative transfer modelling, we modelled the dusty envelope as well as the CO emission. The high-rotational transitions of CO indicate that they originate in a dense superwind region close to the star while the lower transitions tend to come from a more tenuous outer wind which is a result of the mass loss since the early AGB phase. Result : The models of the circumstellar envelopes around these stars suggest that they have entered a superwind phase in the past 200 - 500 years. The low 18O/17O (~ 0.1 compared to the solar abundance ratio of ~ 5) and 12C/13C (3-30 cf. the solar value of 89) ratios derived from our study support the idea that these objects have undergone hot-bottom burning and hence that they are massive M >= 5 solar-mass AGB stars.

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The hyperfine structure in the rotational spectrum of CF+

Context. CF+ has recently been detected in the Horsehead and Orion Bar photo-dissociation regions. The J=1-0 line in the Horsehead is double-peaked in contrast to other millimeter lines. The origin of this double-peak profile may be kinematic or spectroscopic. Aims. We investigate the effect of hyperfine interactions due to the fluorine nucleus in CF+ on the rotational transitions. Methods. We compute the fluorine spin rotation constant of CF+ using high-level quantum chemical methods and determine the relative positions and intensities of each hyperfine component. This information is used to fit the theoretical hyperfine components to the observed CF+ line profiles, thereby employing the hyperfine fitting method in GILDAS. Results. The fluorine spin rotation constant of CF+ is 229.2 kHz. This way, the double-peaked CF+ line profiles are well fitted by the hyperfine components predicted by the calculations. The unusually large hyperfine splitting of the CF+ line therefore explains the shape of the lines detected in the Horsehead nebula, without invoking intricate kinematics in the UV-illuminated gas.

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Herschel/HIFI observations of red supergiants and yellow hypergiants: I. Molecular inventory

Red supergiant stars (RSGs) and yellow hypergiant stars (YHGs) are believed to be the high-mass counterparts of stars in the AGB and early post-AGB phases. We study the mass-loss in the post main-sequence evolution of massive stars, through the properties of their envelopes in the intermediate and warm gas layers. These are the regions where the acceleration of the gas takes place and the most recent mass-loss episodes can be seen. We used the HIFI instrument on-board the Herschel Space Observatory to observe sub-mm and FIR transitions of CO, water, and their isotopologues in a sample of two RSGs (NML Cyg and Betelgeuse) and two YHGs (IRC+10420 and AFGL 2343) stars. We present an inventory of the detected lines and analyse the information revealed by their spectral profiles. On the basis of the results presented in an earlier study, we model the CO and 13CO emission in IRC+10420 and compare it to a set of lines ranging from the mm, to the FIR. Red supergiants have stronger high-excitation lines than the YHGs, indicating that they harbour dense and hot inner shells contributing to these transitions. Consequently, these high-J lines in RSGs originate from acceleration layers that have not yet reached the circumstellar terminal velocity and have narrower profiles than their flat-topped lower-J counterparts. The YHGs tend to lack this inner component, in line with the picture of detached, hollow envelopes derived from studies at longer wavelengths. NH3 is only detected in two sources (NML Cyg, IRC+10420), which are also observed to be the strongest water-line emitters of the studied sample. In contrast, OH is detected in all sources and does not seem to correlate with the water line intensities. We show that the IRC+10420 model derived solely from mm low-J CO transitions is capable of reproducing the high-J transitions when the temperature in the inner shell is simply lowered by about 30%.

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The IRAM-30m line survey of the Horsehead PDR: I. CF+ as a tracer of C+ and a measure of the Fluorine abundance

C+ is a key species in the interstellar medium but its 158 μm fine structure line cannot be observed from ground-based telescopes. Current models of fluorine chemistry predict that CF+ is the second most important fluorine reservoir, in regions where C+ is abundant. We detected the J = 1-0 and J = 2-1 rotational lines of CF+ with high signal-to-noise ratio towards the PDR and dense core positions in the Horsehead. Using a rotational diagram analysis, we derive a column density of N(CF+) = (1.5 - 2.0) \times 10^12 cm^-2. Because of the simple fluorine chemistry, the CF+ column density is proportional to the fluorine abundance. We thus infer the fluorine gas-phase abundance to be F/H = (0.6 - 1.5) \times 10^-8. Photochemical models indicate that CF+ is found in the layers where C+ is abundant. The emission arises in the UV illuminated skin of the nebula, tracing the outermost cloud layers. Indeed, CF+ and C+ are the only species observed to date in the Horsehead with a double peaked line profile caused by kinematics. We therefore propose that CF+, which is detectable from the ground, can be used as a proxy of the C+ layers.

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Herschel/HIFI observations of O-rich AGB stars : molecular inventory

Spectra, taken with the heterodyne instrument, HIFI, aboard the Herschel Space Observatory, of O-rich asymptotic giant branch (AGB) stars which form part of the guaranteed time key program HIFISTARS are presented. The aim of this program is to study the dynamical structure, mass-loss driving mechanism, and chemistry of the outflows from AGB stars as a function of chemical composition and initial mass. We used the HIFI instrument to observe nine AGB stars, mainly in the H2O and high rotational CO lines We investigate the correlation between line luminosity, line ratio and mass-loss rate, line width and excitation energy. A total of nine different molecules, along with some of their isotopologues have been identified, covering a wide range of excitation temperature. Maser emission is detected in both the ortho- and para-H2O molecules. The line luminosities of ground state lines of ortho- and para-H2O, the high-J CO and NH3 lines show a clear correlation with mass-loss rate. The line ratios of H2O and NH3 relative to CO J=6-5 correlate with the mass-loss rate while ratios of higher CO lines to the 6-5 is independent of it. In most cases, the expansion velocity derived from the observed line width of highly excited transitions formed relatively close to the stellar photosphere is lower than that of lower excitation transitions, formed farther out, pointing to an accelerated outflow. In some objects, the vibrationally excited H2O and SiO which probe the acceleration zone suggests the wind reaches its terminal velocity already in the innermost part of the envelope, i.e., the acceleration is rapid. Interestingly, for R Dor we find indications of a deceleration of the outflow in the region where the material has already escaped from the star.

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