arXiv subjects

D. Wlodarczyk

Publications and source records attributed to D. Wlodarczyk.

4 recordsLinked to original sources

arXiv2024

Luminescence of the Cs2ZrCl6 under high pressure

The luminescence and Raman spectra of the Cs2ZrCl6 crystal in a wide range of pressures were studied in this work for the first time. Luminescence measurements were performed up to 10 GPa, while the Raman spectra were measured up to 20 GPa. The luminescence data revealed a linear blue shift of the emission maximum from about 2.5 eV at ambient pressure to 3.1 eV at 5 GPa and a strong intensity quenching. The indirect-to-direct bandgap transition at about 5 GPa, a phenomenon previously predicted only theoretically, was used to explain the strong quenching of the luminescence. This model was confirmed by fitting luminescence intensity data and analysis of the luminescence decay kinetics, which exhibited a shortening of the pulse decay time with the pressure increase. Raman spectra confirmed the stability of Cs2ZrCl6 up to 20 GPa and showed no evidence of the pressure-induced structural phase transitions. An energetic scheme of excitonic levels, which takes into account the indirect-to-direct band gasp transition, was proposed to explain the rapid luminescence quenching with increasing pressure.

cond-mat.mtrl-sci↗

arXiv2024

Temperature and Pressure Dependent Luminescence Mechanism of Zinc-Blende Structured ZnS:Mn Nanophosphor under UV and X-ray Excitations

A comprehensive photoluminescence and mechanoluminescence analysis of ZnS:Mn2+ nano-phosphor with zinc blende structure is presented. The sample containing quantum dot-sized nanocrystallites were synthesized by the chemical precipitation method and shows excellent orange luminescence at ambient conditions related to the 4T1->6A1 transition. The sample shows stable and identical luminescence behavior under both UV and X-ray excitation at ambient conditions and also shows excellent self-powered mechanoluminescence properties. The pressure and temperature-induced luminescence mechanism of the phosphor is also established. The shift of the 4T1->6A1 luminescence band of Mn2+ with both pressure and temperature and the luminescence mechanism is explained via the d5 Tanabe Sugano diagram. The broad luminescence band of 4T1->6A1 transition shifts from visible to near-infrared range at a rate of -35.8 meV/GPa with the increase of pressure and it is subsequently quenched completely at a pressure of 16.41 GPa due to a reversible phase transition from zinc blende to rocksalt phase. The high-pressure and temperature-dependent decay kinetics measurements of the sample luminescence are also reported.

cond-mat.mtrl-sci↗

arXiv2018

Non equilibrium anisotropic excitons in atomically thin ReS$_2$

We present a systematic investigation of the electronic properties of bulk and few layer ReS$_2$ van der Waals crystals using low temperature optical spectroscopy. Weak photoluminescence emission is observed from two non-degenerate band edge excitonic transitions separated by $\sim$ 20 meV. The comparable emission intensity of both excitonic transitions is incompatible with a fully thermalized (Boltzmann) distribution of excitons, indicating the hot nature of the emission. While DFT calculations predict bilayer ReS$_2$ to have a direct fundamental band gap, our optical data suggests that the fundamental gap is indirect in all cases.

cond-mat.mes-hall↗

arXiv2017

Observation of A$_g^1$ Raman mode splitting in few layers black phosphorus encapsulated with hexagonal boron nitride

We investigate the impact of the encapsulation with hexagonal boron nitride (h-BN) on the Raman spectrum of few layer black phosphorus. The encapsulation results in a significant reduction of the line width of the Raman modes of black phosphorus, due to a reduced phonon scattering rate. We observe a so far elusive peak in the Raman spectra $\sim$4cm$^{-1}$ above the A$_{\text{g}}^1$ mode in trilayer and thicker flakes, which had not been observed experimentally. The newly observed mode originates from the strong black phosphorus inter-layer interaction, which induces a hardening of the surface atoms vibration with respect to the corresponding modes of the inner layers. The observation of this mode suggests a significant impact of h-BN encapsulation on the properties of black phosphorus and can serve as an indicator of the quality of its surface.

cond-mat.mes-hall↗