arXiv subjects

Dalini D. Maharaj

Publications and source records attributed to Dalini D. Maharaj.

6 recordsLinked to original sources

arXiv2022

A Prototype Compact Accelerator Driven Neutron Source for Canada Supporting Medical and Scientific Applications

Canada recently lost its major supply of neutron beams with the closure of the National Research Universal reactor at Chalk River Laboratories in March 2018. This issue is further exacerbated by the closure of other reactors abroad, which also served as centers for neutron research. Consequently, there is a demand for new sources, both for Canada and internationally, as the global supply shrinks. Compact accelerator driven neutron sources provide an avenue to realize an intense source of pulsed neutron beams, with a capital cost significantly lower than spallation sources. In an effort to close the neutron gap in Canada, a Prototype Canadian compact accelerator driven neutron source (PC-CANS) is proposed for installation at the University of Windsor. The PC-CANS is envisaged to serve two neutron science instruments, a boron neutron capture therapy (BNCT) station and a beamline for fluorine-18 radioisotope production for positive emission tomography. To serve these diverse applications of neutron beams, a linear accelerator solution is selected to provide 10 MeV protons with a peak current of 10 mA within a 5\% duty cycle. The accelerator is based on an RFQ and a DTL with a post-DTL pulsed kicker system to simultaneously deliver macro-pulses to each end-station. The neutron production targets for both neutron science and BNCT will be made of beryllium and engineered to handle the high beam power density. Conceptual studies of the accelerator and benchmarking studies of neutron production and moderation with FLUKA and MCNP, in support of the target-moderator-reflector design are reported

physics.acc-ph↗

arXiv2020

Multipolar magnetism in d-orbital systems: Crystal field levels, octupolar order, and orbital loop currents

Quantum magnets with spin $J=2$, which arise in spin-orbit coupled Mott insulators, can potentially display multipolar orders. We carry out an exact diagonalization study of a simple octahedral crystal field Hamiltonian for two electrons, incorporating spin-orbit coupling (SOC) and interactions, finding that either explicitly including the $e_g$ orbitals, or going beyond the rotationally invariant Coulomb interaction within the $t_{2g}$ sector, causes a degeneracy breaking of the $J\!=\!2$ level degeneracy. This can lead to a low-lying non-Kramers doublet carrying quadrupolar and octupolar moments and an excited triplet which supports magnetic dipole moments, bolstering our previous phenomenological proposal for the stabilization of ferro-octupolar order in heavy transition metal oxides. We show that the spontaneous time-reversal symmetry breaking due to ferro-octupolar ordering within the non-Kramers doublet leads to electronic orbital loop currents. The resulting internal magnetic fields can potentially explain the small fields inferred from muon-spin relaxation ($μ$SR) experiments on cubic $5d^2$ osmate double perovskites Ba$_2$ZnOsO$_6$, Ba$_2$CaOsO$_6$, and Ba$_2$MgOsO$_6$, which were previously attributed to weak dipolar magnetism. We make further predictions for oxygen NMR experiments on these materials. We also study the reversed level scheme, where the $J\!=\!2$ multiplet splits into a low-lying magnetic triplet and excited non-Kramers doublet, presenting single-ion results for the magnetic susceptibility in this case, and pointing out its possible relevance for the rhenate Ba$_2$YReO$_6$. Our work highlights the intimate connection between the physics of heavy transition metal oxides and that of $f$-electron based heavy fermion compounds.

cond-mat.str-el↗

arXiv2020

Octupolar order in d-orbital Mott insulators

Motivated by experimental and theoretical interest in realizing multipolar orders in $d$-orbital materials, we discuss the quantum magnetism of $J\!=\!2$ ions which can be realized in spin-orbit coupled oxides with $5d^2$ transition metal ions. Based on the crystal field environment, we argue for a splitting of the $J\!=\!2$ multiplet, leading to a low lying non-Kramers doublet which hosts quadrupolar and octupolar moments. We discuss a microscopic mechanism whereby the combined perturbative effects of orbital repulsion and antiferromagnetic Heisenberg spin interactions leads to ferro-octupolar coupling between neighboring sites, and stabilizes ferro-octupolar order for a face-centered cubic lattice. This same mechanism is also shown to disfavor quadrupolar ordering. We show that studying crystal field levels via Raman scattering in a magnetic field provides a probe of octupolar order. We study spin dynamics in the ferro-octupolar state using a slave-boson approach, uncovering a gapped and dispersive magnetic exciton. For sufficiently strong magnetic exchange, the dispersive exciton can condense, leading to conventional type-I antiferromagnetic (AFM) order which can preempt octupolar order. Our proposal for ferrooctupolar order, with specific results in the context of a model Hamiltonian, provides a comprehensive understanding of thermodynamics, $μ$SR, X-ray diffraction, and inelastic neutron scattering measurements on a range of cubic $5d^2$ double perovskite materials including Ba$_2$ZnOsO$_6$, Ba$_2$CaOsO$_6$, and Ba$_2$MgOsO$_6$. Our proposal for exciton condensation leading to type-I AFM order may be relevant to materials such as Sr$_2$MgOsO$_6$.

cond-mat.str-el↗

arXiv2019

Octupolar vs Néel Order in Cubic 5$d^2$ double perovskites

We report time-of-flight neutron spectroscopic and diffraction studies of the 5$d^2$ cubic double pervoskite magnets, Ba$_2$MOsO$_6$ ($M$ = Zn, Mg, Ca). These cubic materials are all described by antiferromagnetically-coupled 5$d^2$ Os$^{6+}$ ions decorating a face-centred cubic (FCC) lattice. They all exhibit thermodynamic anomalies consistent with phase transitions at a temperature $T^*$, and exhibit a gapped magnetic excitation spectrum with spectral weight concentrated at wavevectors typical of type I antiferromagnetic orders. While muon spin resonance experiments show clear evidence for time reversal symmetry breaking, no corresponding magnetic Bragg scattering is observed at low temperatures. These results, consistent with low temperature octupolar or quadrupolar order, are discussed in the context of other 5$d^2$ DP magnets, and theories for $d^2$ ions on a FCC lattice which predict exotic orders driven by multipolar interactions.

cond-mat.str-el↗

arXiv2018

Two-dimensional spin liquid behaviour in the triangular-honeycomb antiferromagnet TbInO$_3$

Spin liquid ground states are predicted to arise within several distinct scenarios in condensed matter physics. The observation of these disordered magnetic states is particularly pervasive amongst a class of materials known as frustrated magnets, in which the competition between various magnetic exchange interactions prevents the system from adopting long-range magnetic order at low temperatures. Spin liquids continue to be of great interest due to their exotic nature and the possibility that they may support fractionalised excitations, such as Majorana fermions. Systems that allow for such phenomena are not only fascinating from a fundamental perspective but may also be practically significant in future technologies based on quantum computation. Here we show that the underlying antiferromagnetic sublattice in TbInO$_3$ undergoes a crystal field induced triangular-to-honeycomb dilution at low temperatures. The absence of a conventional magnetic ordering transition at the lowest measurable temperatures indicates that another critical mechanism must govern in the ground state selection of TbInO$_3$. We propose that anisotropic exchange interactions, mediated through strong spin-orbit coupling on the emergent honeycomb lattice of TbInO$_3$, give rise to a highly frustrated spin liquid.

cond-mat.str-el↗

arXiv2017

Crystal field excitations from $\mathrm{Yb^{3+}}$ ions at defective sites in highly stuffed $\rm Yb_2Ti_2O_7$

The pyrochlore magnet $\rm Yb_2Ti_2O_7$ has been proposed as a quantum spin ice candidate, a spin liquid state expected to display emergent quantum electrodynamics with gauge photons among its elementary excitations. However, $\rm Yb_2Ti_2O_7$'s ground state is known to be very sensitive to its precise stoichiometry. Powder samples, produced by solid state synthesis at relatively low temperatures, tend to be stoichiometric, while single crystals grown from the melt tend to display weak "stuffing" wherein $\mathrm{\sim 2\%}$ of the $\mathrm{Yb^{3+}}$, normally at the $A$ site of the $A_2B_2O_7$ pyrochlore structure, reside as well at the $B$ site. In such samples $\mathrm{Yb^{3+}}$ ions should exist in defective environments at low levels, and be subjected to crystalline electric fields (CEFs) very different from those at the stoichiometric $A$ sites. New neutron scattering measurements of $\mathrm{Yb^{3+}}$ in four compositions of $\rm Yb_{2+x}Ti_{2-x}O_{7-y}$, show the spectroscopic signatures for these defective $\mathrm{Yb^{3+}}$ ions and explicitly demonstrate that the spin anisotropy of the $\mathrm{Yb^{3+}}$ moment changes from XY-like for stoichiometric $\mathrm{Yb^{3+}}$, to Ising-like for "stuffed" $B$ site $\mathrm{Yb^{3+}}$, or for $A$ site $\mathrm{Yb^{3+}}$ in the presence of an oxygen vacancy.

cond-mat.str-el↗