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Dan Kyotani

Publications and source records attributed to Dan Kyotani.

2 recordsLinked to original sources

Continuum model for the terahertz dielectric response of glasses

Boson peak dynamics in glasses produce a robust crossover in the terahertz (THz) dielectric response that standard Debye or Lorentz models do not capture. We develop a continuum description of this THz response, coupling an infrared-effective charge fluctuation spectrum to a frequency-dependent shear modulus, and apply it to glycerol glass. The model reproduces the measured complex dielectric function and the nearly linear infrared light-vibration coupling around the boson peak, and it highlights the dominant role of transverse shear dynamics.

cond-mat.dis-nn

Relationship between the boson peak and first sharp diffraction peak in glasses

Boson peak (BP) dynamics refers to the universal excitation in the terahertz region of glass. In this study, the universal dynamics of BP were quantitatively evaluated in various glassy materials based on the heterogeneous elasticity theory (HET), and the determinants of BP were successfully extracted. A strong correlation was observed between the maximum possible coarse-graining wavenumber, which is a determinant of the BP in the HET, and the first sharp diffraction peak (FSDP) wavenumber, which is a characteristic index of the medium-range order in glasses. The results indicate that the behaviour of BP in glass can be quantitatively understood in the following two steps. First, the FSDP representing the largest structural correlation in glass is dominantly used to determine the unit size of the elastic modulus heterogeneity, and second, the magnitude of the elastic modulus fluctuation is used to determine the frequency and intensity of the BP.

cond-mat.dis-nn