arXiv subjects

Daniel Bafia

Publications and source records attributed to Daniel Bafia.

6 recordsLinked to original sources

arXiv2025

Impact of Nitrogen and Oxygen Interstitials on Niobium SRF Cavity Performance

Superconducting radiofrequency (SRF) cavities are the leading technology for highly efficient particle acceleration, and their performance can be significantly enhanced through the controlled introduction of interstitial impurities into bulk niobium. Nitrogen doping has demonstrated a substantial reduction in surface resistance, which improves the quality factor of the cavities. More recently, oxygen doping has emerged as a promising alternative, demonstrating comparable reductions in surface resistance. In this study, we combine cavity measurements on 1.3 GHz niobium SRF cavities subjected to a range of nitrogen- and oxygen-based treatments with material characterizations performed on cavity cutouts processed under identical conditions. This approach allows us to quantitatively assess the contribution of each impurity to the reduction of surface resistance. We find that nitrogen is ten times more effective than oxygen in reducing surface resistance at 16 MV/m. We also observe an additive effect of O and N impurities in reducing R$_\mathrm{T}$. We discuss these results in the context of field dependent nonequilibrium superconductivity, gap enhancement, and hydrogen trapping mechanisms.

physics.acc-ph↗

arXiv2025

Discovery of Niobium Hydride Precipitates in Superconducting Qubits

We report the evidence of the formation of niobium hydride phase within niobium films on silicon substrates in superconducting qubits fabricated at Rigetti Computing. For this study, we combined complementary techniques, including room-temperature and cryogenic atomic force microscopy (AFM), synchrotron Xray diffraction, and time of flight secondary ion mass spectroscopy (ToF-SIMS), to directly reveal the existence of niobium hydride precipitates in the Rigetti chip area. Upon cryogenic cooling, we observed variation in the size and morphology of the hydrides, ranging from small (5 nm) irregular shapes to large (~10-100 nm) domain within the Nb grains, fully converted to niobium hydrides. Since niobium hydrides are non-superconducting and can easily change in size and location upon different cooldowns to cryogenic temperature, our finding highlights a new and previously unknown source of decoherence in superconducting qubits. This contributes to both quasiparticle and two level system (TLS) losses, offering a potential explanation for changes in qubit performance upon cooldowns. Finally, by leveraging the RF performance of a 3D bulk Nb resonator, we can quantify RF dissipation on a superconducting qubit, caused by hydrogen concentration variation, and are able to propose a practical engineering pathway to mitigate the formation of the Nb hydrides for superconducting qubit applications.

cond-mat.supr-con↗

arXiv2025

Ultracoherent superconducting cavity-based multiqudit platform with error-resilient control

Realizing the promise of quantum computing requires simultaneously increasing Hilbert-space size and coherence times. While qubit-based architectures have long been the dominant paradigm, large local Hilbert spaces enable qudits, which offer more compact circuits and natural representations for quantum simulation in chemistry, condensed matter, and high-energy physics. Superconducting radio-frequency (SRF) cavities are attractive building blocks for qudit-based quantum technologies because of their exceptionally low dissipation and large bosonic Hilbert spaces, but turning them into programmable modules requires extra effort because the nonlinear circuitry required for control and measurement often introduces loss and noise that erode the memory advantage. Here we demonstrate a two-mode SRF cavity module weakly coupled to an ancillary transmon circuit and engineered to suppress controller-induced dissipation and dephasing, achieving single-photon lifetimes of 20.6 ms and 15.6 ms and a dephasing time exceeding 40 ms. Using sideband interactions together with error-resilient protocols incorporating measurement-based correction and post-selection, we prepare Fock states up to $N=20$ with fidelities exceeding 95% and generate two-mode entanglement near the coherence limit, approaching 99.9%. By combining ultracoherent storage with high-fidelity control, this work moves cavity-based hardware beyond memory-only operation and establishes a practical route toward high-dimensional encodings and scalable modular quantum information processing.

quant-ph↗

arXiv2025

Demonstrating magnetic field robustness and reducing temporal T1 noise in transmon qubits through magnetic field engineering

The coherence of superconducting transmon qubits is often disrupted by fluctuations in the energy relaxation time (T1), limiting their performance for quantum computing. While background magnetic fields can be harmful to superconducting devices, we demonstrate that both trapped magnetic flux and externally applied static magnetic fields can suppress temporal fluctuations in T1 without significantly degrading its average value or qubit frequency. Using a three-axis Helmholtz coil system, we applied calibrated magnetic fields perpendicular to the qubit plane during cooldown and operation. Remarkably, transmon qubits based on tantalum-capped niobium (Nb/Ta) capacitive pads and aluminum-based Josephson junctions (JJs) maintained T1 lifetimes near 300 {\mu}s even when cooled in fields as high as 600 mG. Both trapped flux up to 600 mG and applied fields up to 400 mG reduced T1 fluctuations by more than a factor of two, while higher field strengths caused rapid coherence degradation. We attribute this stabilization to the polarization of paramagnetic impurities, the role of trapped flux as a sink for non-equilibrium quasiparticles (QPs), and partial saturation of fluctuating two-level systems (TLSs). These findings challenge the conventional view that magnetic fields are inherently detrimental and introduce a strategy for mitigating noise in superconducting qubits, offering a practical path toward more stable and scalable quantum systems.

quant-ph↗

arXiv2023

Systematic Improvements in Transmon Qubit Coherence Enabled by Niobium Surface Encapsulation

We present a novel transmon qubit fabrication technique that yields systematic improvements in T$_1$ relaxation times. We fabricate devices using an encapsulation strategy that involves passivating the surface of niobium and thereby preventing the formation of its lossy surface oxide. By maintaining the same superconducting metal and only varying the surface structure, this comparative investigation examining different capping materials, such as tantalum, aluminum, titanium nitride, and gold, and film substrates across different qubit foundries definitively demonstrates the detrimental impact that niobium oxides have on the coherence times of superconducting qubits, compared to native oxides of tantalum, aluminum or titanium nitride. Our surface-encapsulated niobium qubit devices exhibit T$_1$ relaxation times 2 to 5 times longer than baseline niobium qubit devices with native niobium oxides. When capping niobium with tantalum, we obtain median qubit lifetimes above 300 microseconds, with maximum values up to 600 microseconds, that represent the highest lifetimes to date for superconducting qubits prepared on both sapphire and silicon. Our comparative structural and chemical analysis suggests why amorphous niobium oxides may induce higher losses compared to other amorphous oxides. These results are in line with high-accuracy measurements of the niobium oxide loss tangent obtained with ultra-high Q superconducting radiofrequency (SRF) cavities. This new surface encapsulation strategy enables even further reduction of dielectric losses via passivation with ambient-stable materials, while preserving fabrication and scalable manufacturability thanks to the compatibility with silicon processes.

quant-ph↗

arXiv2021

Oxygen Vacancies in Niobium Pentoxide as a Source of Two-Level System Losses in Superconducting Niobium

We identify a major source of quantum decoherence in three-dimensional superconducting radio-frequency (SRF) resonators and two-dimensional transmon qubits composed of oxidized niobium: oxygen vacancies in the niobium pentoxide which drive two-level system (TLS) losses. By probing the effect of sequential \textit{in situ} vacuum baking treatments on the RF performance of bulk Nb SRF resonators and on the oxide structure of a representative Nb sample using time-of-flight secondary ion mass spectrometry (ToF-SIMS), we find a non-monotonic evolution of cavity quality factor $Q_0$ which correlates with the interplay of Nb\textsubscript{2}O\textsubscript{5} vacancy generation and oxide thickness reduction. We localize this effect to the oxide itself and present the insignificant role of diffused interstitial oxygen in the underlying Nb by regrowing a new oxide \textit{via} wet oxidation which reveals a mitigation of aggravated TLS losses. We hypothesize that such vacancies in the pentoxide serve as magnetic impurities and are a source of TLS-driven RF loss.

physics.app-ph↗